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Bryan Mound InSAR Analysis U.S. Strategic petroleum Reserve

Lord, Anna S.

The U.S. Strategic Petroleum Reserve (SPR) is a stockpile of emergency crude oil to be tapped into if a disruption in the nation's oil supply occurs. The SPR is comprised of four salt dome sites. Subsidence surveys have been conducted either annually or biennially at all four sites over the life of the program. Monitoring of surface behavior is a first line defense to detecting possible subsurface cavern integrity issues. Over the life of the Bryan Mound site, subsidence rates over abandoned Cavern 3 have continuously been the highest at the site. In an effort to try and understand the subsurface dynamics, specifically over Bryan Mound Cavern 3, historic interferometric synthetic aperture radar (InSAR) data was acquired and processed by TRE Altamira. InSAR involves the processing of multiple satellite synthetic aperture radar scenes acquired across the same location of the Earth's surface at different times to map surface deformation. The analysis of the data has the ability to detect millimeters of motion spanning days, months, year and decades, across specific sites. The intent in regards to the Bryan Mound site was (1) to confirm the higher subsidence rates recorded over abandoned Cavern 3 indicated by land survey and (2) understand the regional surface behavior. This report describes the InSAR analysis results, how those results compare to the historical collection of land survey data, and what additional information the data has provided towards understanding the response recorded at the surface.

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Consortium for Verification Technology Fellowship Report

Sadler, Lorraine E.

As one recipient of the Consortium for Verification Technology (CVT) Fellowship, I spent eight days as a visiting scientist at the University of Michigan, Department of Nuclear Engineering and Radiological Sciences (NERS). During this time, I participated in multiple department and research group meetings and presentations, met with individual faculty and students, toured multiple laboratories, and taught one-half of a one-unit class on Risk Analysis in Nuclear Arms control (six 1.5 hour lectures). The following report describes some of the interactions that I had during my time as well as a brief discussion of the impact of this fellowship on members of the consortium and on me/my laboratory’s technical knowledge and network.

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Plenoptic Imaging for Three-Dimensional Particle Field Diagnostics

Guildenbecher, Daniel R.; Hall, Elise M.

Plenoptic imaging is a promising emerging technology for single-camera, 3D diagnostics of particle fields. In this work, recent developments towards quantitative measurements of particle size, positions, and velocities are discussed. First, the technique is proven viable with measurements of the particle field generated by the impact of a water drop on a thin film of water. Next, well cont rolled experiments are used to verify diagnostic uncertainty. Finally, an example is presented of 3D plenoptic imaging of a laboratory scale, explosively generated fragment field.

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FRMAC Assessment Manual Volume 1 Overview and Methods

Hunt, Brian D.

The Federal Radiological Monitoring and Assessment Center (FRMAC) Assessment Manual is the tool used to organize and guide activities of the FRMAC Assessment Division. The mission of the FRMAC Assessment Division in a radiological emergency is to interpret radiological data and predict worker and public doses. This information is used by Decision Makers to recommend protective actions in accordance with Protection Action Guides (PAGs) issued by government agencies. This manual integrates many health physics tools and techniques used to make these assessments.

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Brain Science and International Nuclear Safeguards: Implications from Cognitive Science and Human Factors Research on the Provision and Use of Safeguards-Relevant Information in the Field

ESARDA Bulletin

Gastelum, Zoe N.; Matzen, Laura E.; Smartt, Heidi A.; Horak, Karl E.; Moyer, Eric M.; St Pierre, M.E.

Today’s international nuclear safeguards inspectors have access to an increasing volume of supplemental information about the facilities under their purview, including commercial satellite imagery, nuclear trade data, open source information, and results from previous safeguards activities. In addition to completing traditional in-field safeguards activities, inspectors are now responsible for being able to act upon this growing corpus of supplemental safeguards-relevant data and for maintaining situational awareness of unusual activities taking place in their environment. However, cognitive science research suggests that maintaining too much information can be detrimental to a user’s understanding, and externalizing information (for example, to a mobile device) to reduce cognitive burden can decrease cognitive function related to memory, navigation, and attention. Given this dichotomy, how can international nuclear safeguards inspectors better synthesize information to enhance situational awareness, decision making, and performance in the field? This paper examines literature from the fields of cognitive science and human factors in the areas of wayfinding, situational awareness, equipment and technical assistance, and knowledge transfer, and describes the implications for the provision of, and interaction with, safeguards-relevant information for international nuclear safeguards inspectors working in the field.

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Bounded-Degree Connected Approximations of Stochastic Networks

IEEE Transactions on Molecular, Biological, and Multi-Scale Communications

Pinar, Ali P.; Quinn, Christopher J.; Kiyavash, Negar

We propose a method to find optimal sparse connected approximations for large complex networks of nodes interacting over time. Optimality is measured by Kullback-Leibler divergence. The sparsity is controlled by the user through specifying the in-degrees. The approximations have spanning tree subgraphs, enabling them to depict flow through a network. They can also depict feedback. The approximations can capture both significant statistical dependencies in, and preserve salient topological features of, the full (unknown) network. The proposed method can be applied to networks without restrictions on the dynamics beyond stationarity. We analyze computational and sample complexity. We demonstrate their efficacy using a large-scale simulation of the turtle visual cortex and experimental data from the primate motor cortex.

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Field Trial of the Enhanced Data Authentication System (EDAS)

ESARDA Bulletin

Thomas, Maikael A.; Hymel, R.; Baldwin, G.; Smejkal, A.; Linnebach, R.

The Enhanced Data Authentication System (EDAS) is a means to securely branch information from an existing measurement system or data stream to a secondary observer. In an international nuclear safeguards context, the EDAS connects to operator instrumentation, and provides a cryptographically secure copy of the information for a safeguards inspectorate. This novel capability could be a complement to inspector-owned safeguards instrumentation, offering context that is valuable for anomaly resolution and contingency. Sandia National Laboratories gathered operator and inspector requirements, and designed, developed, and fabricated prototype EDAS software and hardware. In partnership with Euratom, we performed an extended EDAS field trial at the Westinghouse Springfields nuclear fuel manufacturing facility in the United Kingdom. We inserted EDAS prototypes in operator instrumentation lines for a barcode scanner and weight scale at a portal where UF6 cylinders enter and exit the facility. The goal of the field trial was to demonstrate the utility of secure branching of operator instrumentation for nuclear safeguards, identify any unforeseen implementation and application issues, and confirm whether the approach is compatible with operator concerns and constraints. During the field trial, the data streams were collected for nine months, and the EDASs branched 698 barcode and 663 weight scale events. Our analysis found that both EDAS units accurately branched 100% of the data that flowed through the instrumentation lines when we compared them to the recorded operator data. With multiple deployed EDASs we found that it is possible to correlate the branched data and create a more holistic narrative of facility activities. Euratom reported the field trial as a full success due to the continuous, correct, and secure branching of safeguards relevant data. At the same time, the operator is satisfied that EDAS did not interfere with plant operations in any way. The success of this field trial is an important step toward illustrating the potential and utility of EDAS as a safeguards tool.

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Extending the excluded volume for percolation threshold estimates in polydisperse systems: The binary disk system

Applied Mathematical Modelling

Forsberg, Kelsey M.; Pantoya, Michelle L.; Green, Micah; Berg, Jordan

For dispersions containing a single type of particle, it has been observed that the onset of percolation coincides with a critical value of volume fraction. When the volume fraction is calculated based on excluded volume, this critical percolation threshold is nearly invariant to particle shape. The critical threshold has been calculated to high precision for simple geometries using Monte Carlo simulations, but this method is slow at best, and infeasible for complex geometries. This paper explores an analytical approach to the prediction of percolation threshold in polydisperse mixtures. Specifically, this paper suggests an extension of the concept of excluded volume, and applies that extension to the 2D binary disk system. The simple analytical expression obtained is compared to Monte Carlo results from the literature. The result may be computed extremely rapidly and matches key parameters closely enough to be useful for composite material design.

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Degradation of Superconducting Nb/NbN Films by Atmospheric Oxidation

IEEE Transactions on Applied Superconductivity

Henry, David; Wolfley, Steven; Young, Travis R.; Monson, Todd; Pearce, Charles J.; Lewis, Rupert M.; Clark, Blythe C.; Brunke, Lyle B.; Missert, Nancy

Niobium and niobium nitride thin films are transitioning from fundamental research toward wafer scale manufacturing with technology drivers that include superconducting circuits and electronics, optical single photon detectors, logic, and memory. Successful microfabrication requires precise control over the properties of sputtered superconducting films, including oxidation. Previous work has demonstrated the mechanism in oxidation of Nb and how film structure could have deleterious effects upon the superconducting properties. This study provides an examination of atmospheric oxidation of NbN films. By examination of the room temperature sheet resistance of NbN bulk oxidation was identified and confirmed by secondary ion mass spectrometry. Meissner magnetic measurements confirmed the bulk oxidation not observed with simple cryogenic resistivity measurements.

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Unsteady drag following shock wave impingement on a dense particle curtain measured using pulse-burst PIV

Physical Review Fluids

Demauro, Edward P.; Wagner, Justin L.; Beresh, Steven J.; Farias, Paul

High-speed, time-resolved particle image velocimetry with a pulse-burst laser was used to measure the gas-phase velocity upstream and downstream of a shock wave-particle curtain interaction at three shock Mach numbers (1.22, 1.40, and 1.45) at a repetition rate of 37.5 kHz. The particle curtain was formed from free-falling soda-lime particles resulting in volume fractions of 9% or 23% at mid-height, depending on particle diameter (106-125 and 300-355 μm, respectively). Following impingement by a shock wave, a pressure difference was created between the upstream and downstream sides of the curtain, which accelerated flow through the curtain. Jetting of flow through the curtain was observed downstream once deformation of the curtain began, demonstrating a long-term unsteady effect. Using a control volume approach, the unsteady drag on the curtain was estimated from velocity and pressure data. The drag imposed on the curtain has a strong volume fraction dependence with a prolonged unsteadiness following initial shock impingement. In addition, the data suggest that the resulting pressure difference following the propagation of the reflected and transmitted shock waves is the primary component to curtain drag.

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Review of the 9th NLTE code comparison workshop

High Energy Density Physics

Hansen, Stephanie B.; Piron, R.; Gilleron, F.; Aglitskiy, Y.; Chung, H.K.; Fontes, C.J.; Marchuk, O.; Scott, H.A.; Stambulchik, E.; Ralchenko, Yu

We review the 9th NLTE code comparison workshop, which was held in the Jussieu campus, Paris, from November 30th to December 4th, 2015. This time, the workshop was mainly focused on a systematic investigation of iron NLTE steady-state kinetics and emissivity, over a broad range of temperature and density. Through these comparisons, topics such as modeling of the dielectronic processes, density effects or the effect of an external radiation field were addressed. The K-shell spectroscopy of iron plasmas was also addressed, notably through the interpretation of tokamak and laser experimental spectra.

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A Priority-Based View of Future Challenges in International Nuclear Safeguards

Journal of the Institute of Nuclear Materials Management

Matteucci, Kayla

The international nuclear safeguards community is faced with a host of challenges in the coming years, many of which have been outlined but have not been described in terms of their urgency. Literature regarding safeguards challenges is either broad and devoid of any reference to prioritization or tailored to a specific problem and removed from the overall goals of the safeguards community. For example, developing new methods of environmental sampling, improving containment and surveillance (C/S) technologies to increase efficiency and decrease inspection time, advancing nuclear material accountancy (NMA) techniques, and planning safeguards approaches for new types of nuclear facilities are all important. They have not, however, been distinctly prioritized at a high level within the safeguards community. Based on a review of existing literature and interviews with experts on these upcoming challenges, this paper offers a high-level summary of present and future priorities in safeguards, with attention both to what is feasible and to what is most imperative. In doing so, the paper addresses the potential repercussions for failing to prioritize, with a focus on the risk of diversion of nuclear material. Within the context of shifts in the American political landscape, and keeping in mind that nonproliferation issues may take a backseat to others in the near future, a prioritized view of safeguards objectives will be vital. In the interest of expanding upon this work, the paper offers several potential conceptual models for prioritization which can be explored in greater depth upon further research.

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Uncertainty Quantification for Machine Learning

Stracuzzi, David J.; Chen, Maximillian G.; Darling, Michael C.; Peterson, Matthew G.; Vollmer, Charlie

In this paper, we assert the importance of uncertainty quantification for machine learning and sketch an initial research agenda. We define uncertainty in the context of machine learning, identify its sources, and motivate the importance and impact of its quantification. We then illustrate these issues with an image analysis example. The paper concludes by identifying several specific research issues and by discussing the potential long-term implications of uncertainty quantification for data analytics in general.

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Well Casing Baseline Analysis for the West Hackberry Strategic Petroleum Reserve Site

Moriarty, Dylan M.

This report analyzes the data from multi-arm caliper (MAC) surveys taken at the West Hackberry SPR site to determine any casing deviations from the as-built drawings. Radial arm data from MAC surveys were used to calculate the approximate wall thickness of each well. Results from this study indicate that well casings can have larger or smaller internal diameters which can lead to thinner or thicker wall thicknesses, respectively. Wells 009B, 106A, 109, and 115 exhibit potentially dangerous deviances from the as-built drawings as some casings have thinner, and therefore weaker, well walls. In addition, the only well surveyed more than once, WH 011B, shows inconsistent data between surveys. Additional analysis is suggested to determine the accuracy and repeatability of MAC surveys.

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NESHAP annual report for CY2016. Sandia National Laboratories, Tonopah Test Range

Evelo, Stacie

This National Emission Standards for Hazardous Air Pollutants (NESHAP) Annual Report has been prepared in a format to comply with the reporting requirements of 40 CFR 61.94 and the April 5, 1995 Memorandum of Agreement (MOA) between the Department of Energy (DOE) and the Environmental Protection Agency (EPA). According to the EPA approved NESHAP Monitoring Plan for the Tonopah Test Range (TTR), 40 CFR 61, subpart H, and the MOA, no additional monitoring or measurements are required at TTR in order to demonstrate compliance with the NESHAP regulation.

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PDCI Wide-Area Damping Control: PSLF Simulations of the 2017 Test Plan - Light Summer Case

Wilches-Bernal, Felipe; Pierre, Brian J.; Elliott, Ryan T.; Schoenwald, David A.; Byrne, Raymond H.; Neely, Jason C.; Trudnowski, Daniel J.; Donnelly, Matthew K.

To demonstrate and validate the performance of the wide-area damping control system, the project plans to conduct closed-loop tests on the PDCI in spring/summer 2017. A test plan details the open and closed loop tests to be conducted on the PDCI using the wide-area damping control system. To ensure the appropriate level of preparedness, simulations were performed in order to predict and evaluate any possible unsafe operations before hardware experiments are attempted. This report contains the results from these simulations using the power system dynamics software PSLF (Power System Load Flow, trademark of GE). The simulations use the WECC (Western Electricity Coordinating Council) 2016 light summer and heavy summer base cases and the 2014 dual export base case. Because of the large volume of plots, the results were divided into three reports corresponding to the three base cases. This report contains results from the 2016 light summer base case.

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PDCI Wide-Area Damping Control: PSLF Simulations of the 2017 Test Plan - Heavy Summer Case

Wilches-Bernal, Felipe; Pierre, Brian J.; Elliott, Ryan T.; Schoenwald, David A.; Byrne, Raymond H.; Neely, Jason C.; Trudnowski, Daniel J.; Donnelly, Matthew K.

To demonstrate and validate the performance of the wide-area damping control system, the project plans to conduct closed-loop tests on the PDCI in spring/summer 2017. A test plan details the open and closed loop tests to be conducted on the PDCI using the wide-area damping control system. To ensure the appropriate level of preparedness, simulations were performed in order to predict and evaluate any possible unsafe operations before hardware experiments are attempted. This report contains the results from these simulations using the power system dynamics software PSLF (Power System Load Flow, trademark of GE). The simulations use the WECC (Western Electricity Coordinating Council) 2016 light summer and heavy summer base cases and the 2014 dual export base case. Because of the large volume of plots, the results were divided into three reports corresponding to the three base cases. This report contains results from the 2016 heavy summer base case.

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PDCI Wide-Area Damping Control: PSLF Simulations of the 2017 Test Plan - Dual Export Case

Wilches-Bernal, Felipe; Pierre, Brian J.; Elliott, Ryan T.; Schoenwald, David A.; Byrne, Raymond H.; Neely, Jason C.; Trudnowski, Daniel J.; Donnelly, Matthew K.

To demonstrate and validate the performance of the wide-area damping control system, the project plans to conduct closed-loop tests on the PDCI in spring/summer 2017. A test plan details the open and closed loop tests to be conducted on the PDCI using the wide-area damping control system. To ensure the appropriate level of preparedness, simulations were performed in order to predict and evaluate any possible unsafe operations before hardware experiments are attempted. This report contains the results from these simulations using the power system dynamics software PSLF (Power System Load Flow, trademark of GE). The simulations use the WECC (Western Electricity Coordinating Council) 2016 light summer and heavy summer base cases and the 2014 dual export base case. Because of the large volume of plots, the results were divided into three reports corresponding to the three base cases. This report contains results from the 2014 dual export base case.

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Optimizing the Performance of Sparse-Matrix Vector Products on Next-Generation Processors

Hammond, Simon; Trott, Christian R.

Matrix-vector products are ubiquitous in high-performance scientific applications and have a growing set of occurrences in advanced data analysis activities. Achieving high performance for these kernels is therefore paramount, in part, because these operations can consume vast amounts of application execution time. In this report we document the development of several sparse-matrix vector product kernel implementations using a variety of programming models and approaches. Each kernel is run on a broad set of matrices selected to demonstrate the wide variety of matrix structure and sparsity that is possible with a single, generic kernel. For benchmarking and performance analysis, we utilize leading computing architectures for the NNSA/ASC program including Intel's Knights Landing processor and IBM's POWER8.

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Mixed Waste Landfill Annual Long-Term Monitoring & Maintenance Report April 2016-March 2017

Mitchell, Michael M.; Ziock, Robert; Little, Bonnie C.

Sampling activities for this reporting period included two semiannual monitoring events each for groundwater, soil-vapor, and radon. Annual soil-moisture monitoring was conducted in April 2016, annual tritium surface soil sampling was conducted in August 2016, and annual biota sampling (metals and radionuclides) was conducted in September 2016. All monitoring activities were conducted in accordance with LTMMP requirements and no monitoring results exceeded LTMMP trigger levels. All monitoring results were consistent with historic MWL monitoring data. Inspections of the MWL final cover system, storm-water diversion structures, compliance monitoring systems, and security fence were performed in accordance with LTMMP requirements. Required maintenance and repairs were minor and were generally performed during the inspections. The Evapotranspirative (ET) Cover continues to meet successful revegetation criteria and is in excellent condition with even coverage of mature, native perennial grasses. Maintenance was performed during the reporting period as a best management practice for ET Cover vegetation, and included a lower level of effort relative to previous years. The purpose of ongoing ET Cover maintenance efforts is to promote the growth and health of the desired native grass species by reducing competition with weedy species for limited moisture and nutrients. Based on previous inspections, additional best management practice activities were conducted during this reporting period to improve the site and reduce long-term ET Cover and site maintenance. These activities included improvements to site access and drainage (i.e., improvements to the access and perimeter road) and the installation of erosion and burrow control measures at the ten perimeter monitoring well locations.

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Tailoring of cyber security technology adoption practices for operational adoption in complex organizations

Avina, Glory E.; Bogner, Kathleen; Carter, James; Friedman, Art; Gordon, Susanna P.; Haney, Julie; Hart, Linda; Kittinger, Robert; Lakkaraju, Kiran; Mccann, In K.; Rhyne, Ed; Wolf, Dan

As concerns with cyber security and network protection increase, there is a greater need for organizations to deploy state-of-the-art technology to keep their cyber information safe. However, foolproof cyber security and network protection are a difficult feat since a security breach can be caused simply by a single employee who unknowingly succumbs to a cyber threat. It is critical for an organization’s workforce to holistically adopt cyber technologies that enable enhanced protection, help ward off cyber threats, and are efficient at encouraging human behavior towards safer cyber practices. It is also crucial for the workforce, once they have adopted cyber technologies, to remain consistent and thoughtful in their use of these technologies to keep resistance strong against cyber threats and vulnerabilities. Adoption of cyber technology can be difficult. Many organizations struggle with their workforce adopting newly-introduced cyber technologies, even when the technologies themselves have proven to be worthy solutions. Research, especially in the domain of cognitive science and the human dimension, has sought to understand how technology adoption works and can be leveraged. This paper reviews what empirical literature has found regarding cyber technology adoption, the current research gaps, and how non-research based efforts can influence adoption. Focusing on current efforts accomplished by a government-sponsored activity entitled “ACT” (Adoption of Cybersecurity Technologies), the aim of this paper is to empirically study cyber technology adoption to better understand how to influence operational adoption across the government-sector as well as how what can be done to develop a model that enables cyber technology adoption.

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Design and Characterization of a 7.2 kW Solar Simulator

Journal of Solar Energy Engineering, Transactions of the ASME

Boubault, Antoine; Yellowhair, Julius; Ho, Clifford K.

A 7.2 kW (electric input) solar simulator was designed in order to perform accelerated testing on absorber materials for concentrating solar power (CSP) technologies. COMPUTER-AIDED DESIGN (CAD) software integrating a ray-Tracing tool was used to select appropriate components and optimize their positioning in order to achieve the desired concentration. The simulator comprises four identical units, each made out of an ellipsoidal reflector, a metal halide lamp, and an adjustable holding system. A single unit was characterized and shows an experimental average irradiance of 257 kWm-2 on a 25.4mm (1 in) diameter spot. Shape, spot size, and average irradiance are in good agreement with the model predictions, provided the emitting arc element model is realistic. The innovative four-lamp solar simulator potentially demonstrates peak irradiance of 1140kWm-2 and average irradiance of 878kWm-2 over a 25.4mm diameter area. The electric-To-radiative efficiency is about 0.86. The costs per radiative and electric watt are calculated at $2.31 W-1 and $1.99 W-1, respectively. An upgraded installation including a sturdier structure, computer-controlled lamps, a more reliable lamp holding system, and safety equipment yields a cost per electric watt of about $3.60 W-1 excluding labor costs.

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Enhanced Kinetics of Electrochemical Hydrogen Uptake and Release by Palladium Powders Modified by Electrochemical Atomic Layer Deposition

ACS Applied Materials and Interfaces

Benson, David M.; Tsang, Chu F.; Sugar, Joshua D.; Jagannathan, Kaushik; Robinson, David B.; El Gabaly, Farid; Cappillino, Patrick J.; Stickney, John L.

Electrochemical atomic layer deposition (E-ALD) is a method for the formation of nanofilms of materials, one atomic layer at a time. It uses the galvanic exchange of a less noble metal, deposited using underpotential deposition (UPD), to produce an atomic layer of a more noble element by reduction of its ions. This process is referred to as surface limited redox replacement and can be repeated in a cycle to grow thicker deposits. It was previously performed on nanoparticles and planar substrates. In the present report, E-ALD is applied for coating a submicron-sized powder substrate, making use of a new flow cell design. E-ALD is used to coat a Pd powder substrate with different thicknesses of Rh by exchanging it for Cu UPD. Cyclic voltammetry and X-ray photoelectron spectroscopy indicate an increasing Rh coverage with increasing numbers of deposition cycles performed, in a manner consistent with the atomic layer deposition (ALD) mechanism. Cyclic voltammetry also indicated increased kinetics of H sorption and desorption in and out of the Pd powder with Rh present, relative to unmodified Pd.

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Centrifugal Microfluidic Platform for Rapid, Multiplexed Detection of TB and HIV Biomarkers in Whole Blood Samples

Journal of Bioengineering & Biomedical Science

Litvinov, Julia; Moen, Scott T.; Koh, Chung Y.; Singh, Anup K.

Infection with Mycobacterium Tuberculosis represents a significant threat to people with immune disorders, such as HIV-positive individuals, and can result in significant health complications or death if not diagnosed and treated early. We present a centrifugal microfluidic platform for multiplexed detection of tuberculosis and HIV biomarkers in human whole blood with minimal sample preparation and a sample-to-answer time of 30 minutes. This multiplexed assay was developed for the detection of two M.tuberculosis secreted proteins, whose secretion represents an active and ongoing infection, as well as detection of HIV p24 protein and human anti-p24 antibodies. The limit of detection for this multiplex assay is in the pg/mL range for both HIV and M.tuberculosis proteins, making this assay potentially useful in the clinical diagnosis of both HIV and Tuberculosis proteins indicative of active infection. Antigen detection for the HIV assay sensitivity was 89%, the specificity 85%. Serological detection had 100% sensitivity and specificity for the limited sample pool. The centrifugal microfluidic platform presented here offers the potential for a portable, fast and inexpensive multiplexed diagnostic device that can be used in resource-limited settings for diagnosis of TB and HIV.

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Silicon photonic transceiver circuit for highspeed polarization-based discrete variable quantum key distribution

Optics Express

Cai, Hong; Long, Christopher M.; Derose, Christopher T.; Boynton, Nicholas; Urayama, Junji; Camacho, Ryan C.; Pomerene, Andrew; Starbuck, Andrew L.; Trotter, Douglas C.; Davids, Paul; Lentine, Anthony L.

We demonstrate a silicon photonic transceiver circuit for high-speed discrete variable quantum key distribution that employs a common structure for transmit and receive functions. The device is intended for use in polarization-based quantum cryptographic protocols, such as BB84. Our characterization indicates that the circuit can generate the four BB84 states (TE/TM/45°/135° linear polarizations) with >30 dB polarization extinction ratios and gigabit per second modulation speed, and is capable of decoding any polarization bases differing by 90° with high extinction ratios.

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Designing graphene absorption in a multispectral plasmon-enhanced infrared detector

Optics Express

Goldflam, Michael; Fei, Zhe; Ruiz, Isaac; Howell, Stephen W.; Davids, Paul; Peters, David; Bays, Nathan R.

We have examined graphene absorption in a range of graphene-based infrared devices that combine either monolayer or bilayer graphene with three different gate dielectrics. Electromagnetic simulations show that the optical absorption in graphene in these devices, an important factor in a functional graphene-based detector, is strongly dielectricdependent. These simulations reveal that plasmonic excitation in graphene can significantly influence the percentage of light absorbed in the entire device, as well as the graphene layer itself, with graphene absorption exceeding 25% in regions where plasmonic excitation occurs. Notably, the dielectric environment of graphene has a dramatic influence on the strength and wavelength range over which the plasmons can be excited, making dielectric choice paramount to final detector tunability and sensitivity.

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Imaging the Impact of Proton Irradiation on Edge Terminations in Vertical GaN pin Diodes

IEEE Electron Device Letters

Celio, Kimberlee C.; King, Michael P.; Dickerson, Jeramy; Vizkelethy, Gyorgy; Armstrong, Andrew A.; Fischer, Arthur J.; Allerman, Andrew A.; Kaplar, Robert J.; Aktas, Ozgur; Kizilyalli, Isik C.; Talin, Albert A.; Leonard, Francois

Devices based on GaN have shown great promise for high power electronics, including their potential use as radiation tolerant components. An important step to realizing high power diodes is the design and implementation of an edge termination to mitigate field crowding, which can lead to premature breakdown. However, little is known about the effects of radiation on edge termination functionality. We experimentally examine the effects of proton irradiation on multiple field ring edge terminations in high power vertical GaN pin diodes using in operando imaging with electron beam induced current (EBIC). We find that exposure to proton irradiation influences field spreading in the edge termination as well as carrier transport near the anode. By using depth-dependent EBIC measurements of hole diffusion length in homoepitaxial n-GaN we demonstrate that the carrier transport effect is due to a reduction in hole diffusion length following proton irradiation.

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Phonon scattering mechanisms dictating the thermal conductivity of lead zirconate titanate (PbZr1-xTixO3) thin films across the compositional phase diagram

Journal of Applied Physics

Ihlefeld, Jon F.; Paisley, Elizabeth; Diantonio, Christopher; Chavez, Thomas P.; Bays, Nathan R.; Brennecka, Geoff; Foley, Brian M.; Gaskins, John T.; Hopkins, Patrick E.

This work represents a thorough investigation of the thermal conductivity (κ) in both thin film and bulk PbZr1-xTixO3 (PZT) across the compositional phase diagram. Given the technological importance of PZT as a superb piezoelectric and ferroelectric material in devices and systems impacting a wide array of industries, this research serves to fill the gap in knowledge regarding the thermal properties. The thermal conductivities of both thin film and bulk PZT are found to vary by a considerable margin as a function of composition x. Additionally, we observe a discontinuity in κ in the vicinity of the morphotropic phase boundary (MPB, x = 0.48) where there is a 20%-25% decrease in κ in our thin film data, similar to that found in literature data for bulk PZT. The comparison between bulk and thin film materials highlights the sensitivity of κ to size effects such as film thickness and grain size even in disordered alloy/solid-solution materials. A model for the thermal conductivity of PZT as a function of composition (κ (x)) is presented, which enables the application of the virtual crystal approximation for alloy-type material systems with very different crystals structures, resulting in differing temperature trends for κ. We show that in the case of crystalline solid-solutions where the thermal conductivity of one of the parent materials exhibits glass-like temperature trends the compositional dependence of thermal conductivity is relatively constant for most values of x. This is in stark contrast with the typical trends of thermal conductivity with x in alloys, where the thermal conductivity increases dramatically as the composition of the alloy or solid-solution approaches that of a pure parent materials (i.e., as x = 0 or 1).

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Scalable focused ion beam creation of nearly lifetime-limited single quantum emitters in diamond nanostructures

Nature Communications

Bielejec, Edward S.

The controlled creation of defect centre - nanocavity systems is one of the outstanding challenges for efficiently interfacing spin quantum memories with photons for photon-based entanglement operations in a quantum network. Here we demonstrate direct, maskless creation of atom-like single silicon vacancy (SiV) centres in diamond nanostructures via focused ion beam implantation with ∼32 nm lateral precision and <50 nm positioning accuracy relative to a nanocavity. We determine the Si+ ion to SiV centre conversion yield to be ∼2.5% and observe a 10-fold conversion yield increase by additional electron irradiation. Low-temperature spectroscopy reveals inhomogeneously broadened ensemble emission linewidths of ∼51 GHz and close to lifetime-limited single-emitter transition linewidths down to 126±13 MHz corresponding to ∼1.4 times the natural linewidth. This method for the targeted generation of nearly transform-limited quantum emitters should facilitate the development of scalable solid-state quantum information processors.

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Thermodynamic assessment of an electrically-enhanced thermochemical hydrogen production (EETHP) concept for renewable hydrogen generation

International Journal of Hydrogen Energy

Babiniec, Sean M.; Ambrosini, Andrea; Miller, James E.

A novel concept for coupling a thermochemical cycle with an electrochemical separation device for the generation of hydrogen from steam is reported and a thermodynamic analysis of the system is presented. In a conventional thermochemical cycle, an oxygen carrier material is thermally reduced, cooled, and then reoxidized in steam thereby generating hydrogen. However, this process often requires high temperatures (>1700 K) and/or low oxygen partial pressures (<0.001 atm) in order to meet thermodynamic requirements. Such extreme conditions can adversely affect the stability of the reactive oxides, reactor materials, and system efficiency. In our proposed technology, we seek to decrease the required reduction temperature by several hundred degrees Kelvin by relaxing the requirement for spontaneous oxidation reaction at atmospheric pressure. This is accomplished by incorporating a proton-conducting membrane (PCM) to separate hydrogen produced at equilibrium concentrations from reactant steam. We also suggest the use of mixed ionic-electronic conducting (MIEC) oxygen carrier materials that reduce through a continuum of oxidation states at lower temperatures (∼1200 °C). This concept allows the generation of a high-quality hydrogen stream while avoiding the challenging high temperatures/low partial pressures required in conventional water-splitting reaction schemes.

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Method for Determining the Sensitivity of a Physical Security System

Risk Analysis

Speed, Ann E.; Gauthier, John H.; Hoffman, Matthew J.; Wachtel, Amanda; Kittinger, Robert; Munoz-Ramos, Karina

Modern systems, such as physical security systems, are often designed to involve complex interactions of technological and human elements. Evaluation of the performance of these systems often overlooks the human element. A method is proposed here to expand the concept of sensitivity—as denoted by d’—from signal detection theory (Green & Swets 1966; Macmillan & Creelman 2005), which came out of the field of psychophysics, to cover not only human threat detection but also other human functions plus the performance of technical systems in a physical security system, thereby including humans in the overall evaluation of system performance. New in this method is the idea that probabilities of hits (accurate identification of threats) and false alarms (saying “threat” when there is not one), which are used to calculate d’ of the system, can be applied to technologies and, furthermore, to different functions in the system beyond simple yes-no threat detection. At the most succinct level, the method returns a single number that represents the effectiveness of a physical security system; specifically, the balance between the handling of actual threats and the distraction of false alarms. The method can be automated, and the constituent parts revealed, such that given an interaction graph that indicates the functional associations of system elements and the individual probabilities of hits and false alarms for those elements, it will return the d’ of the entire system as well as d’ values for individual parts. The method can also return a measure of the response bias* of the system. One finding of this work is that the d’ for a physical security system can be relatively poor in spite of having excellent d’s for each of its individual functional elements.

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Electron Turbulence at Nanoscale Junctions

Nano Letters

Bushong, Neil; Bays, Nathan R.; Di Ventra, Massimiliano

Electron transport through a nanostructure can be characterized in part using concepts from classical fluid dynamics. Hence, it is natural to ask how far the analogy can be taken and whether the electron liquid can exhibit nonlinear dynamical effects such as turbulence. Here we present an ab initio study of the electron dynamics in nanojunctions which reveals that the latter indeed exhibits behavior quite similar to that of a classical fluid. In particular, we find that a transition from laminar to turbulent flow occurs with increasing current, corresponding to increasing Reynolds numbers. These findings reveal unexpected features of electron dynamics and shed new light on our understanding of transport properties of nanoscale systems.

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Molecular dynamics studies of defect formation during heteroepitaxial growth of InGaN alloys on (0001) GaN surfaces

Journal of Applied Physics

Zhou, Xiaowang; Jones, Reese E.; Gruber, J.; Lee, Stephen R.; Tucker, G.J.

We investigate the formation of extended defects during molecular-dynamics (MD) simulations of GaN and InGaN growth on (0001) and ( 11 2 ¯ 0 ) wurtzite-GaN surfaces. The simulated growths are conducted on an atypically large scale by sequentially injecting nearly a million individual vapor-phase atoms towards a fixed GaN surface; we apply time-and-position-dependent boundary constraints that vary the ensemble treatments of the vapor-phase, the near-surface solid-phase, and the bulk-like regions of the growing layer. The simulations employ newly optimized Stillinger-Weber In-Ga-N-system potentials, wherein multiple binary and ternary structures are included in the underlying density-functional-theory training sets, allowing improved treatment of In-Ga-related atomic interactions. To examine the effect of growth conditions, we study a matrix of >30 different MD-growth simulations for a range of InxGa1-xN-alloy compositions (0 ≤ x ≤ 0.4) and homologous growth temperatures [0.50 ≤ T/T*m(x) ≤ 0.90], where T*m(x) is the simulated melting point. Growths conducted on polar (0001) GaN substrates exhibit the formation of various extended defects including stacking faults/polymorphism, associated domain boundaries, surface roughness, dislocations, and voids. In contrast, selected growths conducted on semi-polar ( 11 2 ¯ 0 ) GaN, where the wurtzite-phase stacking sequence is revealed at the surface, exhibit the formation of far fewer stacking faults. We discuss variations in the defect formation with the MD growth conditions, and we compare the resulting simulated films to existing experimental observations in InGaN/GaN. While the palette of defects observed by MD closely resembles those observed in the past experiments, further work is needed to achieve truly predictive large-scale simulations of InGaN/GaN crystal growth using MD methodologies.

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Numeric invariants from multidimensional persistence

Journal of Applied and Computational Topology

Skryzalin, Jacek; Carlsson, Gunnar

In this paper, we analyze the space of multidimensional persistence modules from the perspectives of algebraic geometry. We first build a moduli space of a certain subclass of easily analyzed multidimensional persistence modules, which we construct specifically to capture much of the information which can be gained by using multidimensional persistence over one-dimensional persistence. We argue that the global sections of this space provide interesting numeric invariants when evaluated against our subclass of multidimensional persistence modules. Lastly, we extend these global sections to the space of all multidimensional persistence modules and discuss how the resulting numeric invariants might be used to study data.

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Co-Planning of Investments in Transmission and Merchant Energy Storage

IEEE Transactions on Power Systems

Dvorkin, Yury; Fernandez-Blanco, Ricardo; Wang, Yishen; Xu, Bolun; Kirschen, Daniel S.; Pandzic, Hrvoje; Watson, Jean-Paul; Silva-Monroy, Cesar A.

We observe suitably located energy storage systems are able to collect significant revenue through spatiotemporal arbitrage in congested transmission networks. However, transmission capacity expansion can significantly reduce or eliminate this source of revenue. Investment decisions by merchant storage operators must, therefore, account for the consequences of potential investments in transmission capacity by central planners. This paper presents a tri-level model to co-optimize merchant electrochemical storage siting and sizing with centralized transmission expansion planning. The upper level takes the merchant storage owner's perspective and aims to maximize the lifetime profits of the storage, while ensuring a given rate of return on investments. The middle level optimizes centralized decisions about transmission expansion. The lower level simulates market clearing. The proposed model is recast as a bi-level equivalent, which is solved using the column-and-constraint generation technique. A case study based on a 240-bus, 448-line testbed of the Western Electricity Coordinating Council interconnection demonstrates the usefulness of the proposed tri-level model.

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A Comprehensive Set of Impact Data for Common Aerospace Metals

Journal of Computational and Nonlinear Dynamics

Brake, Matthew; Reu, P.L.; Aragon, Dannelle S.

Our results for the two sets of impact experiments are reported here. In order to assist with model development using the impact data reported, the materials are mechanically characterized using a series of standard experiments. The first set of impact data comes from a series of coefficient of restitution experiments, in which a 2 meter long pendulum is used to study "in context" measurements of the coefficient of restitution for eight different materials (6061-T6 Aluminum, Phosphor Bronze alloy 510, Hiperco, Nitronic 60A, Stainless Steel 304, Titanium, Copper, and Annealed Copper). The coefficient of restitution is measured via two different techniques: digital image correlation and laser Doppler vibrometry. Due to the strong agreement of the two different methods, only results from the digital image correlation are reported. The coefficient of restitution experiments are "in context" as the scales of the geometry and impact velocities are representative of common features in the motivating application for this research. Finally, a series of compliance measurements are detailed for the same set of materials. Furthermore, the compliance measurements are conducted using both nano-indentation and micro-indentation machines, providing sub-nm displacement resolution and uN force resolution. Good agreement is seen for load levels spanned by both machines. As the transition from elastic to plastic behavior occurs at contact displacements on the order of 30 nm, this data set provides a unique insight into the transitionary region.

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Improved moving window cross-spectral analysis for resolving large temporal seismic velocity changes in permafrost

Geophysical Research Letters

James, S.R.; Knox, Hunter A.; Abbott, Robert; Screaton, E.J.

Cross correlations of seismic noise can potentially record large changes in subsurface velocity due to permafrost dynamics and be valuable for long-term Arctic monitoring. We applied seismic interferometry, using moving window cross-spectral analysis (MWCS), to 2 years of ambient noise data recorded in central Alaska to investigate whether seismic noise could be used to quantify relative velocity changes due to seasonal active-layer dynamics. The large velocity changes (>75%) between frozen and thawed soil caused prevalent cycle-skipping which made the method unusable in this setting. We developed an improved MWCS procedure which uses a moving reference to measure daily velocity variations that are then accumulated to recover the full seasonal change. This approach reduced cycle-skipping and recovered a seasonal trend that corresponded well with the timing of active-layer freeze and thaw. This improvement opens the possibility of measuring large velocity changes by using MWCS and permafrost monitoring by using ambient noise.

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Modeling charge collection efficiency degradation in partially depleted GaAs photodiodes using the 1- and 2-carrier Hecht equations

Nuclear Instruments and Methods in Physics Research, Section B: Beam Interactions with Materials and Atoms

Vizkelethy, Gyorgy; Serkland, Darwin K.; Bossert, David; Doyle, Barney L.

The Hecht equation can be used to model the nonlinear degradation of charge collection efficiency (CCE) in response to radiation-induced displacement damage in both fully and partially depleted GaAs photodiodes. CCE degradation is measured for laser-generated photocurrent as a function of fluence and bias in Al0.3Ga0.7As/GaAs/Al0.25Ga0.75As p-i-n photodiodes which have been irradiated with 12 MeV C and 7.5 MeV Si ions. CCE is observed to degrade more rapidly with fluence in partially depleted photodiodes than in fully depleted photodiodes. When the intrinsic GaAs layer is fully depleted, the 2-carrier Hecht equation describes CCE degradation as photogenerated electrons and holes recombine at defect sites created by radiation damage in the depletion region. If the GaAs layer is partially depleted, CCE degradation is more appropriately modeled as the sum of the 2-carrier Hecht equation applied to electrons and holes generated within the depletion region and the 1-carrier Hecht equation applied to minority carriers that diffuse from the field-free (non-depleted) region into the depletion region. Enhanced CCE degradation is attributed to holes that recombine within the field-free region of the partially depleted intrinsic GaAs layer before they can diffuse into the depletion region.

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High speed ultra-broadband amplitude modulators with ultrahigh extinction >65 dB

Optics Express

Liu, Sheng; Cai, Hong; Derose, Christopher T.; Davids, Paul; Pomerene, Andrew; Starbuck, Andrew L.; Trotter, Douglas C.; Camacho, Ryan C.; Urayama, Junji; Lentine, Anthony L.

We experimentally demonstrate ultrahigh extinction ratio (>65 dB) amplitude modulators (AMs) that can be electrically tuned to operate across a broad spectral range of 160 nm from 1480-1640 nm and 95 nm from 1280-1375 nm. Our on-chip AMs employ one extra coupler compared with conventional Mach-Zehnder interferometers (MZI), thus form a cascaded MZI (CMZI) structure. Either directional or adiabatic couplers are used to compose the CMZI AMs and experimental comparisons are made between these two different structures. We investigate the performance of CMZI AMs under extreme conditions such as using 95:5 split ratio couplers and unbalanced waveguide losses. Electro-optic phase shifters are also integrated in the CMZI AMs for high-speed operation. Finally, we investigate the output optical phase when the amplitude is modulated, which provides us valuable information when both amplitude and phase are to be controlled. Our demonstration not only paves the road to applications such as quantum information processing that requires high extinction ratio AMs but also significantly alleviates the tight fabrication tolerance needed for large-scale integrated photonics.

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Experimental Demonstration of a Cheap and Accurate Phase Estimation

Physical Review Letters

Rudinger, Kenneth M.; Kimmel, Shelby; Lobser, Daniel; Maunz, Peter L.W.

We demonstrate an experimental implementation of robust phase estimation (RPE) to learn the phase of a single-qubit rotation on a trapped Yb+ ion qubit. We show this phase can be estimated with an uncertainty below 4×10-4 rad using as few as 176 total experimental samples, and our estimates exhibit Heisenberg scaling. Unlike standard phase estimation protocols, RPE neither assumes perfect state preparation and measurement, nor requires access to ancillae. We crossvalidate the results of RPE with the more resource-intensive protocol of gate set tomography.

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Initiation reactions in acetylene pyrolysis

Journal of Physical Chemistry. A, Molecules, Spectroscopy, Kinetics, Environment, and General Theory

Zador, Judit; Fellows, Madison D.; Miller, James A.

In gas-phase combustion systems the interest in acetylene stems largely from its role in molecular weight growth processes. The consensus is that above 1500 K acetylene pyrolysis starts mainly with the homolytic fission of the C–H bond creating an ethynyl radical and an H atom. However, below ~1500 K this reaction is too slow to initiate the chain reaction. It has been hypothesized that instead of dissociation, self-reaction initiates this process. Nevertheless, rigorous theoretical or direct experimental evidence is lacking, to an extent that even the molecular mechanism is debated in the literature. In this work we use rigorous ab initio transition-state theory master equation methods to calculate pressure- and temperature-dependent rate coefficients for the association of two acetylene molecules and related reactions. We establish the role of vinylidene, the high-energy isomer of acetylene in this process, compare our results with available experimental data, and assess the competition between the first-order and second-order initiation steps. As a result, we also show the effect of the rapid isomerization among the participating wells and highlight the need for time-scale analysis when phenomenological rate coefficients are compared to observed time scales in certain experiments.

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Ancilla-driven quantum computation for qudits and continuous variables

Physical Review A

Proctor, Timothy J.; Giulian, Melissa; Korolkova, Natalia; Andersson, Erika; Kendon, Viv

Although qubits are the leading candidate for the basic elements in a quantum computer, there are also a range of reasons to consider using higher-dimensional qudits or quantum continuous variables (QCVs). In this paper, we use a general "quantum variable" formalism to propose a method of quantum computation in which ancillas are used to mediate gates on a well-isolated "quantum memory" register and which may be applied to the setting of qubits, qudits (for d>2), or QCVs. More specifically, we present a model in which universal quantum computation may be implemented on a register using only repeated applications of a single fixed two-body ancilla-register interaction gate, ancillas prepared in a single state, and local measurements of these ancillas. In order to maintain determinism in the computation, adaptive measurements via a classical feed forward of measurement outcomes are used, with the method similar to that in measurement-based quantum computation (MBQC). We show that our model has the same hybrid quantum-classical processing advantages as MBQC, including the power to implement any Clifford circuit in essentially one layer of quantum computation. In some physical settings, high-quality measurements of the ancillas may be highly challenging or not possible, and hence we also present a globally unitary model which replaces the need for measurements of the ancillas with the requirement for ancillas to be prepared in states from a fixed orthonormal basis. Finally, we discuss settings in which these models may be of practical interest.

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Write-optimized skip lists

Proceedings of the ACM SIGACT-SIGMOD-SIGART Symposium on Principles of Database Systems

Bender, Michael A.; Farach-Colton, Martin; Johnson, Rob; Mauras, Simon; Mayer, Tyler; Phillips, Cynthia A.; Xu, Helen

The skip list is an elegant dictionary data structure that is commonly deployed in RAM. A skip list with N elements supports searches, inserts, and deletes in O (log N) operations with high probability (w.h.p.) and range queries returning K elements in O(log N + K) operations w.h.p. A seemingly natural way to generalize the skip list to external memory with block size B is to "promote" with probability 1/B, rather than 1/2. However, there are practical and theoretical obstacles to getting the skip list to retain its efficient performance, space bounds, and high-probability guarantees. We give an external-memory skip list that achieves write-optimized bounds. That is, for 0 < ϵ < 1, range queries take O(logBϵ N + K/B) I/Os w.h.p. and insertions and deletions take O((logBϵ N)/B1-ϵ) amortized I/Os w.h.p. Our write-optimized skip list inherits the virtue of simplicity from RAM skip lists. Moreover, it matches or beats the asymptotic bounds of prior write-optimized data structures such as Bϵ trees or LSM trees. These data structures are deployed in high-performance databases and file systems. The main technical challenge in proving our bounds comes from the fact that there are so few levels in the skip list, an aspect of the data structure that is essential to getting strong external-memory bounds. We use extremal-graph coloring to show that it is possible to decompose paths in the skip list into uncorrelated groups, regardless of the insertion/deletion pattern. Thus, we achieve our bounds by averaging over these uncorrelated paths rather than by averaging over uncorrelated levels, as in the standard skip list.

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Reaction Mechanisms on Multiwell Potential Energy Surfaces in Combustion (and Atmospheric) Chemistry

Annual Review of Physical Chemistry

Osborn, David L.

Chemical reactions occurring on a potential energy surface with multiple wells are ubiquitous in low-temperature combustion and in the oxidation of volatile organic compounds in Earth's atmosphere. The rich variety of structural isomerizations that compete with collisional stabilization makes characterizing such complex-forming reactions challenging. This review describes recent experimental and theoretical advances that deliver increasingly complete views of their reaction mechanisms. New methods for creating reactive intermediates coupled with multiplexed measurements provide many experimental observables simultaneously. Automated methods to explore potential energy surfaces can uncover hidden reactive pathways, and master equation methods enable a holistic treatment of both sequential and well-skipping pathways. Our ability to probe and understand nonequilibrium effects and reaction sequences is increasing. These advances provide the fundamental science base for predictive models of combustion and the atmosphere that are crucial to address global challenges.

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The SLH framework for modeling quantum input-output networks

Advances in Physics: X

Combes, Joshua; Kerckhoff, Joseph; Sarovar, Mohan

Many emerging quantum technologies demand precise engineering and control over networks consisting of quantum mechanical degrees of freedom connected by propagating electromagnetic fields, or quantum input-output networks. Here we review recent progress in theory and experiment related to such quantum input-output networks, with a focus on the SLH framework, a powerful modeling framework for networked quantum systems that is naturally endowed with properties such as modularity and hierarchy. We begin by explaining the physical approximations required to represent any individual node of a network, e.g. atoms in cavity or a mechanical oscillator, and its coupling to quantum fields by an operator triple (S,L,H). Then we explain how these nodes can be composed into a network with arbitrary connectivity, including coherent feedback channels, using algebraic rules, and how to derive the dynamics of network components and output fields. The second part of the review discusses several extensions to the basic SLH framework that expand its modeling capabilities, and the prospects for modeling integrated implementations of quantum input-output networks. In addition to summarizing major results and recent literature, we discuss the potential applications and limitations of the SLH framework and quantum input-output networks, with the intention of providing context to a reader unfamiliar with the field.

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2017 Workshop Summary: MHK Environmental Compliance Cost Reduction Strategies Workshop

West, Anna; Kramer, Sharon; Bar, Zach; Roberts, Jesse D.

This three year effort started in FY17 with the objectives of capturing environmental compliance costs and lessons learned from MHK developments that have gone through the permitting and compliance process. The goal is to find ways to improve the efficiency and effectiveness of the permitting and compliance process and reduce costs to encourage investment in MHK projects. The project team is composed of Sandia National Laboratories, Integral Consulting, Kearns & West, and H. T. Harvey & Associates. Step one of the project process, collect data to determine permitting and compliance costs, is currently underway. Step two of the project process, identify cost reduction pathways and step three, develop cost reduction strategies, will follow and are envisioned as an iterative approach to best meet the project goal.

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A practitioner-driven research agenda for syndromic surveillance

Online Journal of Public Health Informatics

Finley, Patrick D.; Hopkins, Richard S.; Tong, Catherine; Burkom, Howard; Akkina, Judy; Berezowski, John; Shigematsu, Mika; Painter, Ian; Gamache, Roland; Del Rio Vilas, Victor; Streichert, Laura

The objective here is to obtain feedback and seek future directions for an ISDS initiative to establish and update research questions in Informatics, Analytics,Communications, and Systems Research with the greatest perceived impact for improving surveillance practice.Introduction Over the past fifteen years, syndromic surveillance (SyS) has evolved from a set of ad hoc methods used mostly in post-disaster settings, then expanded with broad support and development because of bioterrorism concerns, and subsequently evolved to a mature technology that runs continuously to detect and monitor a wide range of health issues. Continued enhancements needed to meet the challenges of novel health threats with increasingly complex information sources will require technical advances focused on day-to-day public health needs.Since its formation in 2005, the International Society for Disease Surveillance (ISDS) has sought to clarify and coordinate global priorities in surveillance research. As part of a practitioner-driven initiative to identify current research priorities in SyS, ISDS polled its members about capabilities needed by SyS practitioners that could be improved as a result of research efforts. A taskforce of the ISDS Research Committee, consisting of national and global subject matter experts (SMEs) in SyS and ISDS professional staff, carried out the project. This panel will discuss the results and the preferred means to determine and communicate priorities in the future.

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Complete prevalence of malignant primary brain tumors registry data in the United States compared with other common cancers, 2010

Neuro-Oncology

Zhang, Adah; Ostrom, Quinn T.; Kruchko, Carol; Rogers, Lisa; Peereboom, David M.; Barnholtz-Sloan, Jill S.

Background. Complete prevalence proportions illustrate the burden of disease in a population. This study estimates the 2010 complete prevalence of malignant primary brain tumors overall and by Central Brain Tumor Registry of the United States (CBTRUS) histology groups, and compares the brain tumor prevalence estimates to the complete prevalence of other common cancers as determined by the Surveillance, Epidemiology, and End Results Program (SEER) by age at prevalence (2010): children (0-14 y), adolescent and young adult (AYA) (15-39 y), and adult (40+ y). Methods. Complete prevalence proportions were estimated using a novel regression method extended from the Completeness Index Method, which combines survival and incidence data from multiple sources. In this study, two datasets, CBTRUS and SEER, were used to calculate complete prevalence estimates of interest. Results. Complete prevalence for malignant primary brain tumors was 47.59/100000 population (22.31, 48.49, and 57.75/100000 for child, AYA, and adult populations). The most prevalent cancers by age were childhood leukemia (36.65/100000), AYA melanoma of the skin (66.21/100000), and adult female breast (1949.00/100000). The most prevalent CBTRUS histologies in children and AYA were pilocytic astrocytoma (6.82/100000, 5.92/100000), and glioblastoma (12.76/100000) in adults. Conclusions. The relative impact of malignant primary brain tumors is higher among children than any other age group; it emerges as the second most prevalent cancer among children. Complete prevalence estimates for primary malignant brain tumors flls a gap in overall cancer knowledge, which provides critical information toward public health and health care planning, including treatment, decision making, funding, and advocacy programs.

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Transient current induced in thin film diamonds by swift heavy ions

Diamond and Related Materials

Vizkelethy, Gyorgy; Sato, Shin I.; Makino, Takahiro; Ohshima, Takeshi; Kamiya, Tomihiro; Kada, Wataru; Hanaizumi, Osamu; Grilj, Veljko; Skukan, Natko; Sudic, Ivan; Jaksic, Milko; Pomorski, Michal

Single crystal diamond is a suitable material for the next generation particle detectors because of the superior electrical properties and the high radiation tolerance. In order to investigate charge transport properties of diamond particle detectors, transient currents generated in diamonds by single swift heavy ions (26 MeV O5 + and 45 MeV Si7 +) are investigated. Two dimensional maps of transient currents by single ion hits are also measured. In the case of 50 μm-thick diamond, both the signal height and the collected charge are reduced by the subsequent ion hits and the charge collection time is extended. These results are thought to be attributable to the polarization effect in diamond and it appears only when the transient current is dominated by hole current. In the case of 6 μm-thick diamond membrane, an “island” structure is found in the 2D map of transient currents. Signals in the islands shows different applied bias dependence from signals in other regions, indicating different crystal and/or metal contact quality. Simulation study of transient currents based on the Shockley-Ramo theorem clarifies that accumulation of space charges changes distribution of electric field in diamond and causes the polarization effect.

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Monte Carlo simulation of proton track structure in biological matter

European Physical Journal D

Quinto, Michele A.; Monti, Juan M.; Weck, Philippe F.; Fojon, Omar A.; Hanssen, Jocelyn; Rivarola, Roberto D.; Senot, Philippe; Champion, Christophe

Abstract: Understanding the radiation-induced effects at the cellular and subcellular levels remains crucial for predicting the evolution of irradiated biological matter. In this context, Monte Carlo track-structure simulations have rapidly emerged among the most suitable and powerful tools. However, most existing Monte Carlo track-structure codes rely heavily on the use of semi-empirical cross sections as well as water as a surrogate for biological matter. In the current work, we report on the up-to-date version of our homemade Monte Carlo code TILDA-V – devoted to the modeling of the slowing-down of 10 keV–100 MeV protons in both water and DNA – where the main collisional processes are described by means of an extensive set of ab initio differential and total cross sections. Graphical abstract: [Figure not available: see fulltext.].

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Synthesis and characterization of novel phosphate glass matrix nanocomposites containing polyhedral oligomeric silsesquioxane with improved properties

Journal of Non-Crystalline Solids

Alam, Todd M.; Kim, Kyoungtae; Lichtenhan, Joseph D.; Otaigbe, Joshua U.

The preparation and characterization of novel tin fluorophosphate glass (Pglass) matrix nanocomposite materials containing nanoscale trisilanolphenyl polyhedral oligomeric silsesquioxane (POSS) prepared via classical glass synthesis was investigated to accelerate efforts to develop novel hybrid Pglass/POSS nanocomposites with enhanced benefits in suitable diverse applications. The glass transition temperatures (Tg) of the obtained nanocomposites ranged from 121.6° to 147.6 °C to an extent that depends on the nano-POSS concentrations (≤ 10 wt% POSS) in the nanocomposites. The obtained scanning electron microscopy with energy-dispersive x-ray spectroscopy and atomic force microscopy results confirmed the homogeneous molecular level dispersion of the POSS cages in the continuous Pglass matrix of the nanocomposite. Chemical reaction (or bonding) between the constituents of the nanocomposites was confirmed by Fourier transform infrared spectroscopy, X-ray photoelectron spectroscopy, and nuclear magnetic resonance spectroscopy. The rheological (storage and loss modulus) and nanomechanical (elastic modulus) properties of the nanocomposites significantly improved with increasing nano-POSS concentrations up to 10 wt% POSS. The molecular dispersion of the POSS and its strong physicochemical interaction with the continuous Pglass matrix can be tailored to satisfy requirements of a number of optomechanical applications where the pure glass is not useable.

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The role of ceramic and glass science research in meeting societal challenges: Report from an NSF-sponsored workshop

Journal of the American Ceramic Society

Tikare, Veena

Under the sponsorship of the U.S. National Science Foundation, a workshop on emerging research opportunities in ceramic and glass science was held in September 2016. Reported here are proceedings of the workshop. The report details eight challenges identified through workshop discussions: Ceramic processing: Programmable design and assembly; The defect genome: Understanding, characterizing, and predicting defects across time and length scales; Functionalizing defects for unprecedented properties; Ceramic flatlands: Defining structure-property relations in free-standing, supported, and confined two-dimensional ceramics; Ceramics in the extreme: Discovery and design strategies; Ceramics in the extreme: Behavior of multimaterial systems; Understanding and exploiting glasses and melts under extreme conditions; and Rational design of functional glasses guided by predictive modeling. It is anticipated that these challenges, once met, will promote basic understanding and ultimately enable advancements within multiple sectors, including energy, environment, manufacturing, security, and health care.

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Simulations of realistic multifunctional nanoantenna enabled detectors

2017 International Applied Computational Electromagnetics Society Symposium - Italy, ACES 2017

Campione, Salvatore; Warne, Larry K.; Jorgenson, Roy E.; Davids, Paul; Peters, David

The goal of this paper is to investigate full-wave simulations of realistic implementations of multifunctional nanoantenna enabled detectors (NEDs). We realize a 2×2 pixelated array structure that supports two wavelengths of operation. After designing each resonating structure independently using full-wave simulations with periodic boundary conditions mimicking the whole infinite array, we construct a supercell made of a 2×2 pixelated array with periodic boundary conditions mimicking the full NED. In the NED, each pixel comprises 10-20 nanoantennas. Our simulations account for the cross-talk between contiguous pixels. We observe that, even though there are finite extent effects, the pixels work as designed, each responding at the respective wavelength of operation. We want to stress that realistic simulations of multifunctional NEDs need to be performed to verify the design functionality by taking into account finite extent and cross-talk effects.

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Does risk aversion affect transmission and generation planning? A Western North America case study

Energy Economics

Watson, Jean-Paul; Munoz, Francisco D.; Van Der Weijde, Adriaan H.; Hobbs, Benjamin F.

We investigate the effects of risk aversion on optimal transmission and generation expansion planning in a competitive and complete market. To do so, we formulate a stochastic model that minimizes a weighted average of expected transmission and generation costs and their conditional value at risk (CVaR). We show that the solution of this optimization problem is equivalent to the solution of a perfectly competitive risk-averse Stackelberg equilibrium, in which a risk-averse transmission planner maximizes welfare after which risk-averse generators maximize profits. This model is then applied to a 240-bus representation of the Western Electricity Coordinating Council, in which we examine the impact of risk aversion on levels and spatial patterns of generation and transmission investment. Although the impact of risk aversion remains small at an aggregate level, state-level impacts on generation and transmission investment can be significant, which emphasizes the importance of explicit consideration of risk aversion in planning models.

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DE-FOA-EE0005502 Advanced Percussive Drilling Technology for Geothermal Exploration and Development Phase II Report

Su, Jiann-Cherng; Raymond, David W.; Prasad, Somuri V.

Percussive hammers are a promising advance in drilling technology for geothermal since they rely upon rock reduction mechanisms that are well-suited for use in the hard, brittle rock characteristic of geothermal formations. The project research approach and work plan includes a critical path to development of a high-temperature (HT) percussive hammer using a two- phase approach. The work completed in Phase I of the project demonstrated the viability of percussive hammers and that solutions to technical challenges in design, material technology, and performance are likely to be resolved. Work completed in Phase II focused on testing the findings from Phase I and evaluating performance of the materials and designs at high- operating temperatures. A high-operating temperature (HOT) drilling facility was designed, built, and used to test the performance of the DTH under extreme conditions. Results from the testing indicate that a high-temperature capable hammer can be developed and is a viable alternative for user in the driller's toolbox.

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Sandia Dynamic Materials Program Strategic Plan

Flicker, Dawn; Bays, Nathan R.; Desjarlais, Michael P.; Knudson, Marcus D.; Leifeste, Gordon T.; Lemke, Raymond W.; Mattsson, Thomas; Wise, Jack L.

Materials in nuclear and conventional weapons can reach multi-megabar pressures and 1000s of degree temperatures on timescales ranging from microseconds to nanoseconds. Understanding the response of complex materials under these conditions is important for designing and assessing changes to nuclear weapons. In the next few decades, a major concern will be evaluating the behavior of aging materials and remanufactured components. The science to enable the program to underwrite decisions quickly and confidently on use, remanufacturing, and replacement of these materials will be critical to NNSA’s new Stockpile Responsiveness Program. Material response is also important for assessing the risks posed by adversaries or proliferants. Dynamic materials research, which refers to the use of high-speed experiments to produce extreme conditions in matter, is an important part of NNSA’s Stockpile Stewardship Program.

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Thermocouple Errors when Mounted on Cylindrical Surfaces in Abnormal Thermal Environments

Nakos, James T.; Suo-Anttila, Jill M.; Zepper, Ethan T.; Koenig, Jerry J.; Valdez, Vincent A.

Mineral-insulated, metal-sheathed, Type-K thermocouples are used to measure the temperature of various items in high-temperature environments, often exceeding 1000degC (1273 K). The thermocouple wires (chromel and alumel) are protected from the harsh environments by an Inconel sheath and magnesium oxide (MgO) insulation. The sheath and insulation are required for reliable measurements. Due to the sheath and MgO insulation, the temperature registered by the thermocouple is not the temperature of the surface of interest. In some cases, the error incurred is large enough to be of concern because these data are used for model validation, and thus the uncertainties of the data need to be well documented. This report documents the error using 0.062" and 0.040" diameter Inconel sheathed, Type-K thermocouples mounted on cylindrical surfaces (inside of a shroud, outside and inside of a mock test unit). After an initial transient, the thermocouple bias errors typically range only about +-1-2% of the reading in K. After all of the uncertainty sources have been included, the total uncertainty to 95% confidence, for shroud or test unit TCs in abnormal thermal environments, is about +-2% of the reading in K, lower than the +-3% typically used for flat shrouds. Recommendations are provided in Section 6 to facilitate interpretation and use of the results. .

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Modification of the SAS4A Safety Analysis Code for Integration with the ADAPT Discrete Dynamic Event Tree Framework

Jankovsky, Zachary K.; Denman, Matthew R.

It is difficult to assess the consequences of a transient in a sodium-cooled fast reactor (SFR) using traditional probabilistic risk assessment (PRA) methods, as numerous safety-related sys- tems have passive characteristics. Often there is significant dependence on the value of con- tinuous stochastic parameters rather than binary success/failure determinations. One form of dynamic PRA uses a system simulator to represent the progression of a transient, tracking events through time in a discrete dynamic event tree (DDET). In order to function in a DDET environment, a simulator must have characteristics that make it amenable to changing physical parameters midway through the analysis. The SAS4A SFR system analysis code did not have these characteristics as received. This report describes the code modifications made to allow dynamic operation as well as the linking to a Sandia DDET driver code. A test case is briefly described to demonstrate the utility of the changes.

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Strategic Stability in South Asia: An Indian?s Perspective

Kanwal, Gurmeet

The security environment in South Asia has been marked by instability for several decades. The foremost causes of regional instability are the nuclear weapons-cum-missile development program of China, North Korea and Pakistan, the strident march of Islamist fundamentalism, the diabolical nexus between narcotics trafficking and terrorism, the proliferation of small arms and the instability inherent in the rule of despotic regimes. Instability on the Indian sub-continent is manifested, first and foremost, in the continuing conflict in Afghanistan, its tense relations with Iran and the Central Asian Republics (CARs); Pakistan’s struggle against the Taliban, the emerging fissiparous tendencies in Balochistan and Pakhtoonkhwa, the rise of Jihadi Islam and what some fear is Pakistan’s gradual slide towards becoming a ‘failed state’ despite some economic gains in the last five years. Also symptomatic of an unstable and uncertain security environment in the South Asian region are what some see as Sri Lanka’s inability to find a lasting solution to its internal challenges; the potential for Bangladesh’s gradual emergence as the new hub of Islamist fundamentalist terrorism and its struggle for economic upliftment to subsistence levels; the continuing negative impact of Maoist insurgency on Nepal’s fledgling democracy; the simmering discontent in Tibet and Xinjiang and what some see as a low-key uprising against China’s regime; and, the Myanmar peoples’ nascent movement for democracy. In all these countries, socio-economic development has been slow and, consequently, per capita income is alarmingly low. Transborder narcotics trafficking – the golden triangle lies to the east of South Asia and the golden crescent to its west – and the proliferation of small arms, make a potent cocktail. Ethnic tensions and fairly widespread radicalization, worsened by the advent of the vicious ideology of the Islamic state, add further to regional instability.

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The Gothic shale of the Pennsylvanian Paradox Formation Greater Aneth Field (Aneth Unit) Southeastern Utah U.S.A.: Seal for Hydrocarbons and Carbon Dioxide Storage

Heath, Jason E.; Dewers, Thomas; Chidsey, Thomas C.; Carney, Stephanie M.; Bereskin, S.R.

Greater Aneth oil field, Utah’s largest oil producer, was discovered in 1956 and has produced over 483 million barrels of oil. Located in the Paradox Basin of southeastern Utah, Greater Aneth is a stratigraphic trap producing from the Pennsylvanian (Desmoinesian) Paradox Formation. Because Greater Aneth is a mature, major oil field in the western U.S., and has a large carbonate reservoir, it was selected to demonstrate combined enhanced oil recovery and carbon dioxide storage. The Aneth Unit in the northwestern part of the field has produced over 160 million barrels of the estimated 386 million barrels of original oil in place—a 42% recovery rate. The large amount of remaining oil made the Aneth Unit ideal to enhance oil recovery by carbon dioxide flooding and demonstrate carbon dioxide storage capacity.

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Results 37401–37600 of 101,000
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