Publications

Abstract not provided.

In response to personal protective equipment (PPE) shortages in the United States due to the Coronavirus Disease 2019, two models of N95 respirators were evaluated for reuse after gamma radiation sterilization. Gamma sterilization is attractive for PPE reuse because it can sterilize large quantities of material through hermetically sealed packaging, providing safety and logistic benefits. The Gamma Irradiation Facility at Sandia National Laboratories was used to irradiate N95 filtering facepiece respirators to a sterilization dose of 25 kGy(tissue). Aerosol particle filtration performance testing and electrostatic field measurements were used to determine the efficacy of the respirators after irradiation. Both respirator models exhibited statistically significant decreases in particle filtering efficiencies and electrostatic potential after irradiation. The largest decrease in capture efficiency was 40–50% and peaked near the 200 nm particle size. The key contribution of this effort is correlating the electrostatic potential change of individual filtration layer of the respirator with the decrease filtration efficiency after irradiation. This observation occurred in both variations of N95 respirator that we tested. Electrostatic potential measurement of the filtration layer is a key indicator for predicting filtration efficiency loss.

This study evaluated gamma irradiation for sterilization and reuse of two models of N95 respirators after gamma radiation sterilization as a method to increase availability of N95 respirators during a shortage. The Sandia National Laboratories Gamma Irradiation Facility was used to irradiate two different models of N95 filtering facepiece respirators at doses ranging from 0 kGy(tissue) to 50 kGy(tissue). The following tests were used to determine the efficacy of the respirator after irradiation sterilization: Ambient Aerosol Condensation Nuclei Counter Quantitative Fit Test, tensile test, strain cycling, oscillatory dynamic mechanical analysis, microscopic image analysis of fiber layers, and electrostatic field measurements. Both of the respirator models exhibited statistically significant changes after gamma irradiation as shown by the Quantitative Fit Test, electrostatic testing and the aerosol testing. The change in electrostatic charge of the filter was correlated with a reduction in capturing particles near the 200 nm size by approximately 40-50%. Both tested respirators showed statistically significant changes associated with gamma sterilization. However, our results indicate that choices in materials and manufacturing methods to achieve N95 filtration lead to different magnitudes of damage when exposed to gamma radiation at sterilization relevant doses. This damage results in lower filtration performance. While our sample size (2 different types of respirators) was small, we did observe a change in electrostatic properties on a filter layer that coincided with the failure on the Quantitative Fit Test and reduction in aerosol filtering efficiency. Key Words: N95 respirators, respirators, airborne transmission, pandemic prevention, COVID-19, gamma sterilization

This study evaluated gamma irradiation for sterilization and reuse of two models of N95 respirators after gamma radiation sterilization as a method to increase availability of N95 respirators during a shortage. The Sandia National Laboratories Gamma Irradiation Facility was used to irradiate two different models of N95 filtering facepiece respirators at doses ranging from 0 kGy(tissue) to 50 kGy(tissue). The following tests were used to determine the efficacy of the respirator after irradiation sterilization: Ambient Aerosol Condensation Nuclei Counter Quantitative Fit Test, tensile test, strain cycling, oscillatory dynamic mechanical analysis, microscopic image analysis of fiber layers, and electrostatic field measurements. Both of the respirator models exhibited statistically significant changes after gamma irradiation as shown by the Quantitative Fit Test, electrostatic testing and the aerosol testing. The change in electrostatic capability of the filter reduced the efficiency of challenging particles near the 200 nm size by approximately 40-50%. Both tested respirators showed statistically significant changes associated with gamma sterilization. However, our results indicate that choices in materials and manufacturing methods to achieve N95 filtration lead to different magnitudes of damage when exposed to gamma radiation at sterilization relevant doses. This damage results in lower filtration performance. While our sample size (2 different types of respirators) was small, we did observe a change in electrostatic properties on a filter layer that coincided with the failure on the Quantitative Fit Test.

Neutron dosimetry monitors should be used during all irradiations in the Annular Core Research Reactor. This report provides the recommended conversion factors that should be used to translate the monitor dosimeter read-outs into the damage metrics that are typically used by experimenters to assess the results of their experiment. These conversion factors are based upon the use of the latest least-squares adjusted neutron spectrum determination to describe the Sandia National Laboratories reference neutron fields and the latest International Atomic Energy Agency recommended dosimetry cross sections to capture the response of the dosimeter. The resulting conversion factors are built into the dosimetry results routinely provided by the Radiation Metrology Laboratory.

The process of determining the uncertainty in the neutron fluence from the measured activity of a dosimetry monitor is reviewed and the importance of treating the energy-dependent correlation is illustrated using several representative neutron fields. The process of determining the uncertainty in the neutron fluence when a transfer calibration is used is then detailed. The conversion factor, when a transfer calibration is used, has a term that has an integral over the cross section appearing in both the numerator and the denominator. This term introduces a nonlinear dependence on the cross section within the conversion factor and an explicit correlation between the terms appearing in the numerator and denominator of the conversion factor. A method for rigorously treating this nonlinear uncertainty propagation is presented. This method is based upon utilizing the covariance matrix for the cross section and utilizing a statistical sampling approach based on a Cholesky transformation of this covariance matrix. This methodology is then applied to the determination of the uncertainty from a transfer calibration for a set of nine neutron spectra based upon using the 32S(n,p)32P reaction and a transfer calibration in a 2 5 2Cf standard benchmark neutron field. A very strong correlation is found in the cross-section terms as they appear in the numerator and in the denominator. When a rigorous treatment is used to propagate the uncertainty due to the cross section for the dosimetry monitor, the uncertainty in the conversion factor is reduced by a factor of more than ten times from a worst-case approach that treats the uncertainty components in the numerator and denominator as uncorrelated. This ten times difference is also seen when the comparison is made between a rigorous treatment and a treatment of the cross-section contributions where the numerator and denominator are treated as uncorrelated (i.e., when compared to a root-mean-square approach).

The measurement of photon dose in pure gamma-ray and mixed (neutron/ gamma) field environments relies heavily on calibration of thermoluminescent dosimeters (TLDs) in cobalt-60 (Co-60) gamma irradiation environments. One of the principal means of reducing the gamma dose measurement uncertainty in Sandia National Laboratories' reactor environments is careful calibration of the CaF2:Mn TLDs used in the test environment. One issue that arises is that Co-60 gamma fields used for calibration universally have a low energy photon component. The scattered photons that make up the low energy photon component are a principal source of measurement error for the TLD calibration. ASTM E1249, Standard Practice for Minimizing Dosimetry Errors in Radiation Hardness Testing of Silicon Electronic Devices Using Co-60 Sources, describes a method that utilizes photon spectrum filter boxes to enclose devices under test that can reduce the measurement error during TLD calibration as well as during normal radiation testing of electronic components in the gamma field. Using a silicon sensor representative of a CMOS-7 technology, a series of calculations was performed for single-layer, two-layer, and three-layer filters to identify a filter box that improves the silicon dose-to-kerma ratio (that is, the filter reduces the low energy photon component in the Co-60 radiation field) in the sensor over the current filter box design. The results of the parameter study in this paper will be used to plan experimental studies in the Co-60 gamma fields used for calibration.

This document presents the facility - recommended characterization of the neutron, prompt gamma - ray, and delayed gamma - ray radiation fields in the Annular Core Research Reactor ( ACRR ) Fueled - Ring External Cavity II (FREC - II) for the free - field environment at the core centerline. The designation for this environment is ACRR - FRECII - FF - cl. The neutron, prompt gamma - ray, and delayed gamma - ray energy spectra, uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma - ray fluence profiles within the experiment area of the cavity. Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulse operations are presented with conversion examples.

Abstract not provided.

Abstract not provided.

This document presents the facility-recommended characterization of the neutron, prompt gamma-ray, and delayed gamma-ray radiation fields in the Annular Core Research Reactor (ACRR) for the cadmium-polyethylene (CdPoly) bucket in the central cavity on the 32-inch pedestal at the core centerline. The designation for this environment is ACRR-CdPoly-CC-32-cl. The neutron, prompt gamma-ray, and delayed gamma-ray energy spectra, uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma-ray fluence profiles within the experiment area of the bucket. Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulse operations are presented with conversion examples. Acknowledgements The authors wish to thank the Annular Core Research Reactor staff and the Radiation Metrology Laboratory staff for their support of this work. Also thanks to Drew Tonigan for helping field the activation experiments in ACRR, David Samuel for helping to finalize the drawings and get the parts fabricated, and Elliot Pelfrey for preparing the active dosimetry plots.

Abstract not provided.

Characterization of the neutron environment in the central cavity of the Sandia National Laboratories' Annular Core Research Reactor (ACRR) is important in order to provide experimenters with the most accurate spectral information and maintain a high degree of fidelity in performing reactor experiments. Characterization includes both modeling and experimental efforts. Building accurate neutronic models of the ACRR and the central cavity "bucket" environments that can be used by experimenters is important in planning and designing experiments, as well as assessing the experimental results and quantifying uncertainties. Neutron fluence characterizations of two bucket environments, LB44 and PLG, are presented. These two environments are used frequently and represent two extremes in the neutron spectrum. The LB44 bucket is designed to remove the thermal component of the neutron spectrum and significantly attenuate the gamma-ray fluence. The PLG bucket is designed to enhance the thermal component of the neutron spectrum and attenuate the gamma-ray fluence. The neutron characterization for each bucket was performed by irradiating 20 different activation foil types, some of which were cadmium covered, resulting in 37 different reactions at the peak axial flux location in each bucket. The dosimetry results were used in the LSL-M2 spectrum adjustment code with a 640-energy group MCNP-generated trial spectrum, self-shielding correction factors, the SNLRML or IRDFF dosimetry cross-section library, trial spectrum uncertainty, and trial covariance matrix, to generate a least-squares adjusted neutron spectrum, spectrum uncertainty, and covariance matrix. Both environment character-izations are well documented and the environments are available for use by experimenters.

The IRDFF cross section library provides the highest fidelity cross section characterization and is the recommended data library to be used for dosimetry in support of reactor pressure vessel surveillance programs. In order to support this critical application, quantified validation evidence is required for the cross section library. Results are reported here on the use of various advanced approaches to uncertainty quantification using metrics relevant to spectrum characterization applications. The use of a quantified least squares approach, combining a consistent treatment of uncertainty from the spectral characterizations, the dosimetry cross sections, and measured activation products, is identified as one of the most sensitive metrics by which to report validation evidence. Using this metric the status of the validation of the IRDFF library was investigated. This analysis began with a consideration of the best characterized 252Cf spontaneous fission standard neutron benchmark field. Good validation evidence is found for 39 of the 79 IRDFF reactions. The 235U thermal fission reference neutron field was then investigated, and found to yield good validation evidence for an additional 10 of the IRDFF reactions. Extending the analysis further to include four different reactor-based reference neutron benchmark fields, ranging from fast burst reactors to well-moderated pool-type reactors, yielded good validation evidence for an additional 6 IRDFF reactions. In total, evidence is reported here for 55 of the 79 reactions in the IRDFF library.

Abstract not provided.

This document presents the facilit y - recommended characteri zation o f the neutron, prompt gamma - ray, and delayed gamma - ray radiation fields in the Annular Core Research Reactor ( ACRR ) for the cen tral cavity free - field environment with the 32 - inch pedestal at the core centerline. The designation for this environmen t is ACRR - FF - CC - 32 - cl. The neutron, prompt gamma - ray , and delayed gamma - ray energy spectra , uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma - ray fluence profiles within the experiment area of the cavity . Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulse operations are presented with conversion examples . Acknowledgements The authors wish to th ank the Annular Core Research Reactor staff and the Radiation Metrology Laboratory staff for their support of this work . Also thanks to David Ames for his assistance in running MCNP on the Sandia parallel machines.

This report was put together to support the International Atomic Energy Agency (IAEA) REAL- 2016 activity to validate the dosimetry community’s ability to use a consistent set of activation data and to derive consistent spectral characterizations. The report captures details of integral measurements taken in the Annular Core Research Reactor (ACRR) central cavity with the Polyethylene-Lead-Graphite (PLG) bucket, reference neutron benchmark field. The field is described and an “a priori” calculated neutron spectrum is reported, based on MCNP6 calculations, and a subject matter expert (SME) based covariance matrix is given for this “a priori” spectrum. The results of 37 integral dosimetry measurements in the neutron field are reported.

This report was put together to support the International Atomic Energy Agency (IAEA) REAL- 2016 activity to validate the dosimetry community’s ability to use a consistent set of activation data and to derive consistent spectral characterizations. The report captures details of integral measurements taken in the Annular Core Research Reactor (ACRR) central cavity with the 44 inch Lead-Boron (LB44) bucket, reference neutron benchmark field. The field is described and an “a priori” calculated neutron spectrum is reported, based on MCNP6 calculations, and a subject matter expert (SME) based covariance matrix is given for this “a priori” spectrum. The results of 31 integral dosimetry measurements in the neutron field are reported.

This report was put together to support the International Atomic Energy Agency (IAEA) REAL- 2016 activity to validate the dosimetry community’s ability to use a consistent set of activation data and to derive consistent spectral characterizations. The report captures details of integral measurements taken in the Annular Core Research Reactor (ACRR) central cavity free-field reference neutron benchmark field. The field is described and an “a priori” calculated neutron spectrum is reported, based on MCNP6 calculations, and a subject matter expert (SME) based covariance matrix is given for this “a priori” spectrum. The results of 31 integral dosimetry measurements in the neutron field are reported.

This document presents the facility-recommended characterization of the neutron, prompt gamma-ray, and delayed gamma-ray radiation fields in the Annular Core Research Reactor (ACRR) for the polyethylene-lead-graphite (PLG) bucket in the central cavity on the 32-inch pedestal at the core centerline. The designation for this environment is ACRR-PLG-CC-32-cl. The neutron, prompt gamma-ray, and delayed gamma-ray energy spectra, uncertainties, and covariance matrices are presented as well as radial and axial neutron and gamma-ray fluence profiles within the experiment area of the bucket. Recommended constants are given to facilitate the conversion of various dosimetry readings into radiation metrics desired by experimenters. Representative pulse operations are presented with conversion examples. Acknowledgements The authors wish to thank the Annular Core Research Reactor staff and the Radiation Metrology Laboratory staff for their support of this work. Also thanks to David Ames for his assistance in running MCNP on the Sandia parallel machines.

Abstract not provided.

In 1992 the Radiation Metrology Laboratory (RML) at Sandia National Laboratories implemented EPR/Alanine capabilities for use in routine and calibration activities at its Co-60 and pulsed-power facilities. At that time it also investigated the usefulness of the system for measurement of absorbed dose in the mixed neutron/photon environments of reactors such as the Sandia Pulsed Reactor and the Annular Core Research Reactor used for hardness testing of electronics. The RML concluded that the neutron response of alanine was a sufficiently high fraction of the overall dosimeter response that the resulting uncertainties in the photon dose would be unacceptably large for silicon-device testing. However, it also suggested that non-hydrogenous materials such as polytetrafluoroethylene (PTFE) would exhibit smaller neutron response and might be useful in mixed environments. Preliminary research with PTFE in photon environments indicated considerable promise, but further development was not pursued at that time. Because of renewed interest in absorbed dose measurements that could better define the individual contributions of photon and neutron components to the overall dose delivered to a test object, the RML has re-initiated the development of an EPR/PTFE dosimetry system. This paper presents a summary of the research, a description of the EPR/PTFE dosimetry system, and recommendations for preparation and fielding of the dosimetry in photon and mixed neutron/photon environments. Copyright © 2012 by ASTM International.

Abstract not provided.

Abstract not provided.

Abstract not provided.