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Energetics of Sn2+ isomorphic substitution into hydroxylapatite: first-principles predictions

RSC Advances

Weck, Philippe F.; Kim, Eunja

The energetics of Sn2+ substitution into the Ca2+ sublattice of hydroxylapatite (HA), Ca10(PO4)6(OH)2, has been investigated within the framework of density functional theory. Calculations reveal that Sn2+ incorporation via coupled substitutions at Ca(ii) sites is energetically favourable up to a composition of Sn6Ca4(PO4)6(OH)2, and further substitutions at Ca(i) sites proceed once full occupancy of Ca(ii) sites by Sn2+ is achieved. Compositions of SnxCa10−x(PO4)6(OH)2 (x = 4-9) are predominant, with an optimal stoichiometry of Sn8Ca2(PO4)6(OH)2, and Sn-substituted HA follows approximately Vegard's law across the entire composition range.

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Fluid-structure interactions using controlled disturbances on a slender cone at Mach 8

54th AIAA Aerospace Sciences Meeting

Casper, Katya M.; Beresh, Steven J.; Henfling, John F.; Spillers, Russell; Hunter, Patrick

Fluid-structure interactions were studied on a 7° half-angle cone in the Sandia Hypersonic Wind Tunnel at Mach 8 over a range of freestream Reynolds numbers between 3.3 and 14.5 × 106/m. A thin panel with tunable structural natural frequencies was integrated into the cone and exposed to naturally developing boundary layers. An elevated panel response was measured during boundary-layer transition at frequencies corresponding to the turbulent burst rate, and lower vibrations were measured under a turbulent boundary layer. Controlled perturbations from an electrical discharge were then introduced into the boundary layer at varying frequencies corresponding to the structural natural frequencies of the panel. The perturbations were not strong enough to drive a panel response exceeding that due to natural transition. Instead at high repetition rates, the perturber modified the turbulent burst rate and intermittency on the cone and therefore changed the conditions for when an elevated transitional panel vibration response occurred.

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Nanoporous-carbon as a potential host material for reversible Mg ion intercalation

Journal of the Electrochemical Society

Siegal, Michael P.; Yelton, W.G.; Perdue, Brian R.; Gallis, Dorina F.S.; Schwarz, Haiqing L.

We study nanoporous-carbon (NPC) grown via pulsed laser deposition (PLD) as an electrically conductive anode host material for Mg2+ intercalation. NPC has high surface area, and an open, accessible pore structure tunable via mass density that can improve diffusion. We fabricate 2032 coin cells using NPC coated stainless-steel disk anodes, metallic Mg cathodes, and a Grignardbased electrolyte. NPC mass density is controlled during growth, ranging from 0.06-1.3 g/cm3. The specific surface area of NPC increases linearly from 1,000 to 1,700 m2/g as mass density decreases from 1.3 to 0.26 g/cm3, however, the surface area falls off dramatically at lowermass densities, implying a lack of mechanical integrity in such nanostructures. These structural characterizations correlate directly with coin cell electrochemical measurements. In particular, cyclic voltammetry (CV) scans for NPC with density ∼0.5 g/cm3 and BET surface area ∼1500 m2/g infer the possibility of reversible Mg-ion intercalation. Higher density NPC yields capacitive behavior, most likely resulting from the smaller interplanar spacings between graphene sheet fragments and tighter domain boundaries; lower density NPC results in asymmetrical CV scans, consistent with the likely structural degradation resulting from mass transport through soft, low-density carbon materials.

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Curve reconstruction with many fewer samples

Eurographics Symposium on Geometry Processing

Ohrhallinger, S.; Mitchell, Scott A.; Wimmer, M.

We consider the problem of sampling points from a collection of smooth curves in the plane, such that the CRUST family of proximity-based reconstruction algorithms can rebuild the curves. Reconstruction requires a dense sampling of local features, i.e., parts of the curve that are close in Euclidean distance but far apart geodesically. We show that e < 0:47-sampling is sufficient for our proposed HNN-CRUST variant, improving upon the state-of-the-art requirement of e < 13-sampling. Thus we may reconstruct curves with many fewer samples. We also present a new sampling scheme that reduces the required density even further than e < 0:47-sampling. We achieve this by better controlling the spacing between geodesically consecutive points. Our novel sampling condition is based on the reach, the minimum local feature size along intervals between samples. This is mathematically closer to the reconstruction density requirements, particularly near sharp-angled features. We prove lower and upper bounds on reach r-sampling density in terms of lfs e-sampling and demonstrate that we typically reduce the required number of samples for reconstruction by more than half.

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Particle resuspension simulation capability to substantiate DOE-HDBK-3010 Data

Transactions of the American Nuclear Society

Voskuilen, Tyler; Pierce, Flint; Brown, Alexander L.; Gelbard, Fred M.; Foulk, James W.

In this work we have presented a particle resuspension model implemented in the SNL code SIERRA/Fuego, which can be used to model particle dispersal and resuspension from surfaces. The method demonstrated is applicable to a class of particles, but would require additional parametric fits or physics models for extension to other applications, such as wetted particles or walls. We have demonstrated the importance of turbulent variations in the wall shear stress when considering resuspension, and implemented both shear stress variation models and stochastic resuspension models (not shown in this work). These models can be used in simulations with of physically realistic scenarios to augment lab-scale DOE Handbook data for airborne release fractions and respirable fractions in order to provide confidences for safety analysts and facility designers to apply in their analyses at DOE sites. Future work on this topic will involve validation of the presented model against experimental data and extension of the empirical models to be applicable to different classes of particles and surfaces.

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Why do electricity policy and competitive markets fail to use advanced PV systems to improve distribution power quality?

Journal of Solar Energy

Johnson, Jay

The increasing pressure for network operators to meet distribution network power quality standards with increasing peak loads, renewable energy targets, and advances in automated distributed power electronics and communications is forcing policy-makers to understand new means to distribute costs and benefits within electricity markets. Discussions surrounding how distributed generation (DG) exhibits active voltage regulation and power factor/reactive power control and other power quality capabilities are complicated by uncertainties of baseline local distribution network power quality and to whom and how costs and benefits of improved electricity infrastructure will be allocated. DG providing ancillary services that dynamically respond to the network characteristics could lead to major network improvements. With proper market structures renewable energy systems could greatly improve power quality on distribution systems with nearly no additional cost to the grid operators. Renewable DG does have variability challenges, though this issue can be overcome with energy storage, forecasting, and advanced inverter functionality. This paper presents real data from a large-scale grid-connected PV array with large-scale storage and explores effective mitigation measures for PV system variability. As a result, we discuss useful inverter technical knowledge for policy-makers to mitigate ongoing inflation of electricity network tariff components by new DG interconnection requirements or electricity markets which value power quality and control.

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Use of Al2O3 layers for higher laser damage threshold at 22.5° incidence, S polarization of a 527 nm/1054 nm dichroic coating

Proceedings of SPIE - The International Society for Optical Engineering

Bellum, John C.; Field, Ella; Kletecka, Damon; Rambo, Patrick K.; Smith, Ian C.

We have designed and reported on a dichroic beam combiner coating consisting of HfO2/SiO2 layer pairs to provide high transmission at 527 nm and high reflection at 1054 nm for 22.5° angle of incidence (AOI) in S polarization (Spol). The laser-induced damage threshold (LIDT) of this first coating at the use AOI and polarization with 3.5 nanosecond (ns) pulses at 532 nm is 7 J/cm2, and only marginally adequate for our beam combining application. In this paper, we describe the use of a combination of Al2O3 and HfO2 high index layers to modify the first as well as a second dichroic coating in two different ways, which results in a higher LIDT of 10 J/cm2 for 3.5 ns pulses at 532 nm and 22.5° AOI, Spol for the second dichroic coating, and in the same 7 J/cm2 LIDT for the first dichroic coating.

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CASL COBRA-TF improvements for PWR DNB analysis

Top Fuel 2016: LWR Fuels with Enhanced Safety and Performance

Sung, Yixing; Cao, Liping; Kucukboyaci, Vefa; Gordon, Natalie; Salko, Robert; Tatli, Emre

COBRA-TF (CTF) is a thermal hydraulic (T/H) subchannel code using either three-dimensional (3D) Cartesian or subchannel coordinate formulations for two-phase fluid flow and heat transfer solutions. CTF has been improved under the Consortium for Advanced Simulation of Light Water Reactors (CASL) program for Pressurized Water Reactor (PWR) applications, including software optimization, new closure models, pre- and post-processing and parallelization for modeling full reactor core T/H responses under normal operating and accident conditions. As a result of collaboration among CASL partners including the Westinghouse Electric Company, the Oak Ridge National Laboratory (ORNL), and the Sandia National Laboratories, additional modeling improvements were made to CTF specifically for PWR Departure from Nucleate Boiling (DNB) analysis, including a code option to evaluate fuel thermal margin in terms of DNB Ratio (DNBR) and an axial shape factor to account for effect of non-uniform axial power distribution on DNB. Multiple DNB correlations are now linked with CTF for different applications, including the Westinghouse proprietary WRB-1 correlation for fuel designs containing mixing vane grid spacers. The improved CTF code with the WRB-1 correlation (CTF/WRB-1) was validated using the DNB data from the PWR Subchannel Bundle Tests (PSBT). In addition to the comparison with the test data, the CTF/WRB-1 DNBR results and the associated local fluid conditions were compared to the results of the Westinghouse T/H design code, VIPRE-W, which is an enhanced version of the VIPRE-01 code originally developed by the Electric Power Research Institute (EPRI). The comparisons showed that CTF/WRB-1 DNBR predictions are in good agreement with the VIPRE-W results within the applicable range of the DNB correlation. A model sensitivity study was performed to confirm that the CTF void drift model had an insignificant effect on DNBR under the steam line break (SLB) low pressure condition.

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Experimental and computational investigations into the effect of process induced stresses on the mode I fracture toughness of composite materials

CAMX 2016 - Composites and Advanced Materials Expo

Nelson, Stacy M.; Werner, Brian T.

Process induced residual stresses commonly occur in composite structures composed of dissimilar materials. These residual stresses form due to differences in the composite materials' coefficients of thermal expansion as well as the cure shrinkage exhibited by polymer matrix materials. These residual stresses can have a profound effect on the measured performance of a loaded composite structure. A material property of particular interest when modeling the formation of damage in composite materials is the mode I fracture toughness. Currently, the standard method of measuring the mode I fracture toughness involves a double cantilever beam (DCB) experiment, where a pre-crack is introduced into a laminate and subsequently opened under tension. The resulting apparent fracture toughness from the DCB experiment may depend upon a coupled interaction between a material property, the mode I energy release rate, and the effect of residual stresses. Therefore, in this study, a series of DCB experiments are completed in conjunction with the solution of representative finite element models to quantify and understand the effect of process-induced residual stresses and temperature variations on the apparent fracture toughness. Specifically, double cantilever beam experiments are completed at three temperatures to characterize three types of specimens composed of carbon fiber/epoxy and glass fiber/epoxy materials: carbon bonded to carbon, glass bonded to glass, and carbon bonded to glass. The carbon-to-carbon and glass-to-glass specimens provide estimates of the composite's fracture toughness in the absence of significant residual stresses and the carbon-to-glass specimens indicate the effect of measurable process induced stresses. Upon completion of testing, the measured results and observations are used to develop high-fidelity finite element models simulating the residual stresses formed throughout the manufacturing process and the subsequent DCB testing of a laminate composed of the carbon/epoxy and glass/epoxy materials. The stress fields and delamination behavior predicted through simulation assist in understanding the trends observed during the DCB experiments and demonstrate the important relationship between experimental and computational efforts.

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Intermittent computation without hardware support or programmer intervention

Proceedings of the 12th USENIX Symposium on Operating Systems Design and Implementation, OSDI 2016

Van Der Woude, Joel; Hicks, Matthew

As computation scales downward in area, the limitations imposed by the batteries required to power that computation become more pronounced. Thus, many future devices will forgo batteries and harvest energy from their environment. Harvested energy, with its frequent power cycles, is at odds with current models of long-running computation. To enable the correct execution of long-running applications on harvested energy-without requiring specialpurpose hardware or programmer intervention-we propose Ratchet. Ratchet is a compiler that adds lightweight checkpoints to unmodified programs that allow existing programs to execute across power cycles correctly. Ratchet leverages the idea of idempotency, decomposing programs into a continuous stream of re-executable sections connected by lightweight checkpoints, stored in non-volatile memory. We implement Ratchet on top of LLVM, targeted at embedded systems with highperformance non-volatile main memory. Using eight embedded systems benchmarks, we show that Ratchet correctly stretches program execution across frequent, random power cycles. Experimental results show that Ratchet enables a range of existing programs to run on intermittent power, with total run-time overhead averaging below 60%-comparable to approaches that require hardware support or programmer intervention.

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Complex geometry effects on cavity resonance

AIAA Journal

Casper, Katya M.; Beresh, Steven J.; Henfling, John F.; Spillers, Russell; Pruett, Brian; Wagner, Justin L.

The flow over an aircraft bay is often represented using a rectangular cavity; however, this simplification neglects many features of actual flight geometry that could affect the unsteady pressure field and resulting loading in the bay. To address this shortcoming, a complex cavity geometry was developed to incorporate more realistic aircraft-bay features including shaped inlets, internal cavity structure, and doors. A parametric study of these features was conducted based on fluctuating pressure measurements at subsonic and supersonic Mach numbers. Resonance frequencies and amplitudes increased in the complex geometry compared to a simple rectangular cavity that could produce severe loading conditions for store carriage. High-frequency content and dominant frequencies were generated by features that constricted the flow such as leading-edge overhangs, internal cavity variations, and the presence of closed doors. Broadband frequency components measured at the aft wall of the complex cavities were also significantly higher than in the rectangular geometry. These changes highlight the need to consider complex geometric effects when predicting the flight loading of aircraft bays.

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Cobalt phosphide based nanostructures as bifunctional electrocatalysts for low temperature alkaline water splitting

ECS Transactions

Lambert, Timothy N.; Vigil, Julian A.; Christensen, Ben

Cobalt phosphide based thin films and nanoparticles were prepared by the thermal phosphidation of spinel Co3O4 precursor films and nanoparticles, respectively. CoP films were prepared with overall retention of the Co3O4 nanoplatelet morphology while the spherical/cubic Co3O4 and Ni0.15Co2.85O4 nanoparticles were converted to nanorods or nanoparticles, respectively. The inclusion of nickel in the nanoparticles resulted in a 2.5 fold higher surface area leading to higher gravimetric performance. In each case high surface area structures were obtained with CoP as the primary phase. All materials were found to act as effective bifunctional electrocatalysts for both the HER and the OER and compared well to commercial precious metal benchmark materials in alkaline electrolyte. A symmetrical water electrolysis cell prepared from the CoP-based film operated at a low overpotential of 0.41-0.51 V.

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Direct RF to Optical Link Based on Film Bulk Acoustic Wave Resonators (FBAR)

Optics InfoBase Conference Papers

Siddiqui, Aleem; Moore, Jeremy; Stanfield, Paul S.; Camacho, Ryan; Eichenfield, Matt

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Why Peridynamics?

Handbook of Peridynamic Modeling

Silling, Stewart

Therefore, to design a building or a bridge that stands up and is safe, one might assume that engineers must need to know a lot about these tensor fields and stress potentials, in all their mathematical glory. If not, then surely they must depend on specialists in continuum mechanics for guidance. Right?

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Real-time digital simulation to improve advanced microgrid design

Proposed Journal Article, unpublished

Schenkman, Benjamin L.; Chae, Suyong; Oh, Seaseung; Jensen, Richard P.; Hightower, Marion M.

In this study, there are several ways to address energy reliability concerns during an extended power outage. This can include hardening the energy infrastructure to reduce potential loss of power, adding redundant backup systems with larger fuel tanks, and improving generator reliability through better maintenance. While each is valid, they are often expensive to adequately implement. The traditional emergency power approach for decades has been the use of building-tied emergency generators to start up and supply emergency power until the utility can come back on line. Unfortunately, operational experience from many recent extended power outages has shown that emergency backup generators are often mismatched in size with the building energy load, under-maintained such that their operational reliability is well below expected values, and have insufficient fuel to operate for the entire power outage. Here we describe how energy reliability and security can be enhanced with the use of Advanced Microgrids.

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Exploring magnetized liner inertial fusion with a semi-analytic model

Physics of Plasmas

Mcbride, Ryan; Slutz, Stephen A.; Vesey, Roger A.; Gomez, Matthew R.; Sefkow, Adam B.; Hansen, Stephanie B.; Knapp, P.F.; Schmit, Paul; Geissel, Matthias; Harvey-Thompson, Adam J.; Jennings, Christopher A.; Harding, Eric H.; Awe, Thomas J.; Rovang, Dean C.; Hahn, Kelly; Martin, Matthew R.; Cochrane, Kyle; Peterson, K.J.; Rochau, G.A.; Porter, John L.; Stygar, William A.; Campbell, Edward M.; Nakhleh, Charles W.; Herrmann, Mark C.; Cuneo, Michael E.; Sinars, Daniel

In this study, we explore magnetized liner inertial fusion (MagLIF) [S. A. Slutz et al., Phys. Plasmas 17, 056303 (2010)] using a semi-analytic model [R. D. McBride and S. A. Slutz, Phys. Plasmas 22, 052708 (2015)]. Specifically, we present simulation results from this model that: (a) illustrate the parameter space, energetics, and overall system efficiencies of MagLIF; (b) demonstrate the dependence of radiative loss rates on the radial fraction of the fuel that is preheated; (c) explore some of the recent experimental results of the MagLIF program at Sandia National Laboratories [M. R. Gomez et al., Phys. Rev. Lett. 113, 155003 (2014)]; (d) highlight the experimental challenges presently facing the MagLIF program; and (e) demonstrate how increases to the preheat energy, fuel density, axial magnetic field, and drive current could affect future MagLIF performance.

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Pt and Pd catalyzed oxidation of Li2O2 and DMSO during Li–O2 battery charging

ChemComm

Gittleson, Forrest S.; Ryu, Won-Hee; Schwab, Mark; Tong, Xiao; Taylor, Andre D.

Rechargeable Li-O2 and Li-air batteries require electrode and electrolyte materials that synergistcally promote long-term cell operation. We investigate the role of noble metals Pt and Pd as catalysts for the Li-O2 oxidation process and their compatibility with a dimethyl sulfoxide (DMSO) based electrolyte. Lastly, we identify a basis for low potential Li2O2 evolution followed by oxidative decomposition of the electrolyte to form carbonate side products.

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Spark Breakdown Threshold in Non-Uniform Fields

Warne, Larry K.; Jorgenson, Roy E.; Martinez, Leonard E.; Coats, Rebecca S.; Jojola, John M.; Kunhardt, Erich E.

We develop a criterion for spark breakdown in non-uniform field geometries with positive polarity and small electrode separations so that breakdown evolves without the formation of a leader. We arrive at the spark-breakdown criterion by framing it in terms of gain and instability conditions, whose relative importance are established from an analysis of the experimental breakdown characteristics and correlations with streamer behavior in short gaps. Results are presented in the context of two generic geometries having coaxial and point-plane electrodes. For nearly uniform field situations, we re-confirm that the breakdown criterion obtained by the usual extension of either the Townsend or Meek criteria satisfactorily predicts the experimental results. On the other hand, for increasing non-uniformity, the results for the corona and spark branches of the breakdown characteristics are shown inconsistent with a breakdown criterion solely based on either the Townsend or streamer mechanisms. In particular, the avalanche gain factor, the primary component of the Townsend and streamer criteria does not determine the spark breakdown criterion. Streamers can cross the gap for a significantly wide range of applied voltages without triggering a spark. We find that it is the instability condition, derived from a relation between the minimum Laplacian field in the gap and the local streamer body field (which we relate to the streamer sustaining field), that is sufficient for determining the spark threshold thereby yielding a breakdown criterion. We examine the physics of the discharge occurring in the several parts of the nonuniform field gap to elucidate the underpinning of the threshold criterion. These include streamer stability and branching in the stressed electrode region, cathode fall setup near the planar-type electrode, and importantly, the renewed ionization of the discharge resulting from neutral expansion of the gas discharge driven by currents, which are critically dependent on the minimum field level in the gap. We also discuss experiments which were carried out to examine instabilities associated with the streamer breakdown of uniform gaps with triggering.

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Programmable Nanocomposite Membranes for Ion-Based Electrical Energy Storage

Spoerke, Erik D.; Small, Leo J.; Vandelinder, Virginia; Rempe, Susan; Wheeler, David R.; Bachand, George D.; Brumbach, Michael T.; Mckenzie, Bonnie

This report describes a new, bio-inspired approach to electrical energy storage, based on the generation, maintenance, and discharge of ion concentration gradients. This approach was investigated as part of a Laboratory Directed Research and Development program at Sandia National Laboratories in Albuquerque, NM between October 2012 and September 2015. In particular, this report describes the development of ion-selective nanoporous membranes, controlled through pore morphology and Sandia-developed electrochemical functionalization. In addition, it describes a potential avenue to functionalize synthetic polymer membranes in a way that facilitates oriented ion pump binding to polymer surfaces. Finally, it highlights a number of new computational findings central to the understanding and ultimate design of synthetic ion channels and ion gates needed for biomimetic ion-based electrochemical energy storage.

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Cost estimation inputs for spent nuclear fuel geologic disposal concepts (Revision 1)

Hardin, Ernest; Kalinina, Elena A.

A set of 16 geologic disposal concepts is described in sufficient detail for rough-order-of-magnitude repository cost estimates, for disposal of spent nuclear reactor fuel in generic crystalline, argillaceous, and salt host geologic media. The description includes total length, diameter, and volume for all underground shafts, ramps, drifts and large-diameter borings. Basic types of ground support are specified. Total repository capacity is assumed to be approximately 140,000 MT of spent fuel, but concepts are described in terms of modular panels each containing 10,000 MT. Waste packaging is described, and the materials and outer dimensions for disposal overpacks are given. The manner of emplacement is specified, with any additional fixturing, lining, buffer materials, and backfill needed. Thermal limits for waste package emplacement or repository closure are given, as appropriate for enclosed and open emplacement modes, respectively. The 16 disposal concepts are based on disposal concept studies performed for the Used Fuel Disposition R&D program between 2011 and 2014, and the accompanying engineering analyses. Revision 1 results from review and checking of repository spacings, drift length estimates, repository plan area estimates, closure power limits, and estimates of fuel age at closure.

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Sandia SWiFT Facility Site Operations Manual

White, Jonathan R.

The Scaled Wind Farm Technology (SWiFT) site, operated by Sandia National Laboratories for the U.S. Department of Energy’s Wind and Water Power Program, was commissioned in 2013 as a research facility with multiple wind turbines at a scale useful for the experimental study of wake dynamics, advanced rotor development, turbine control, and advanced sensing at production-scale wind farms. This manual provides an overview of facility operations, hazards and safety controls, and emergency response procedures at the site and is required reading for all SWiFT staff and Sandia workers, collaborators, and contractors who perform work on the site.

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Description and Analysis of the Hardware Safety Systems for the DOE/SNL SWiFT Wind Turbines

Leblanc, Bruce P.; Paquette, Joshua A.

This report covers the design and analysis of the hardware safety systems of the DOE/SNL Scaled Wind Farm Technology facility wind turbines. An analysis of the stopping capability of the turbines in multiple scenarios is presented. Included are calculations of braking torque, simulations of high wind speed emergency stops including multiple fault scenarios, and comparisons of predicted turbine performance to the relevant design standards.

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Thermal conductivity of tubrostratic carbon nanofiber networks

Journal of Heat Transfer

Foulk, James W.; Leseman, Zayd C.; Saltonstall, Christopher B.; Bauer, Matthew L.; Hopkins, Patrick E.; Norris, Pamela M.

Composite material systems composed of a matrix of nano materials can achieve combinations of mechanical and thermophysical properties outside the range of traditional systems. While many reports have studied the intrinsic thermal properties of individual carbon fibers, to be useful in applications in which thermal stability is critical, an understanding of heat transport in composite materials is required. In this work, air/ carbon nano fiber networks are studied to elucidate the system parameters influencing thermal transport. Sample thermal properties are measured with varying initial carbon fiber fill fraction, environment pressure, loading pressure, and heat treatment temperature through a bidirectional modification of the 3ω technique. The nanostructures of the individual fibers are characterized with small angle x-ray scattering and Raman spectroscopy providing insight to individual fiber thermal conductivity. Measured thermal conductivity varied from 0.010 W/(m K) to 0.070 W/(m K). An understanding of the intrinsic properties of the individual fibers and the interactions of the two phase composite is used to reconcile low measured thermal conductivities with predictive modeling. This methodology can be more generally applied to a wide range of fiber composite materials and their applications.

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Multi-Objective Advanced Inverter Controls to Dispatch the Real and Reactive Power of Many Distributed PV Systems

Seuss, John; Reno, Matthew J.; Lave, Matt; Broderick, Robert J.; Grijalva, Santiago

The research presented in this report compares several real - time control strategies for the power output of a large number of PV distributed throughout a large distribution feeder circuit. Both real and reactive power controls are considered with the goal of minimizing network over - voltage violations caused by large amounts of PV generation. Several control strategies are considered under various assumptions regarding the existence and latency of a communication network. The control parameters are adjusted to maximize the effectiveness of each control. The controls are then compared based on their ability to achieve multiple objectiv es. These objectives include minimizing the total number of voltage violations , minimizing the total amount of PV energy curtailed or reactive power generated, and maximizing the fairness of any control action among all PV systems . The controls are simulat ed on the OpenDSS platform using time series load and spatially - distributed irradiance data.

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Analysis of Alternatives (AoA) of Open Colllaboration and Research Capabilities Collaboratipon in Research and Engineering in Advanced Technology and Education and High-Performance Computing Innovation Center (HPCIC) on the LVOC

Vrieling, P.D.

The Livermore Valley Open Campus (LVOC), a joint initiative of the National Nuclear Security Administration (NNSA), Lawrence Livermore National Laboratory (LLNL), and Sandia National Laboratories (SNL), enhances the national security missions of NNSA by promoting greater collaboration between world-class scientists at the national security laboratories, and their partners in industry and academia. Strengthening the science, technology, and engineering (ST&E) base of our nation is one of the NNSA’s top goals. By conducting coordinated and collaborative programs, LVOC enhances both the NNSA and the broader national science and technology base, and helps to ensure the health of core capabilities at LLNL and SNL. These capabilities must remain strong to enable the laboratories to execute their primary mission for NNSA.

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Quantum Oscillations in an Interfacial 2D Electron Gas

Zhang, Bingop; Lu, Ping; Liu, Henan; Lin, Jiao; Ye, Zhenyu; Jaime, Marcelo; Balakirev, Fedor F.; Yuan, Huiqiu; Wu, Huizhen; Pan, Wei; Zhang, Yong

Recently, it has been predicted that topological crystalline insulators (TCIs) may exist in SnTe and Pb1-xSnxTe thin films [1]. To date, most studies on TCIs were carried out either in bulk crystals or thin films, and no research activity has been explored in heterostructures. We present here the results on electronic transport properties of the 2D electron gas (2DEG) realized at the interfaces of PbTe/ CdTe (111) heterostructures. Evidence of topological state in this interfacial 2DEG was observed.

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Collaboration in Research and Engineering for Advanced Technology

Vrieling, P.D.

SNL/CA proposes the Collaboration in Research and Engineering for Advanced Technology and Education (CREATE) facility to support customer-driven national security mission requirements while demonstrating a fiscally responsible approach to cost-control. SNL/CA realizes that due to the current backlog of capital projects in NNSA that following the normal Line Item process to procure capital funding is unlikely and therefore SNL/CA will be looking at all options including Alternative Financing.

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Extended-Term Dynamic Simulations with High Penetrations of Photovoltaic Generation

Concepcion, Ricky; Elliott, Ryan T.

The uncontrolled intermittent availability of renewable energy sources makes integration of such devices into today's grid a challenge. Thus, it is imperative that dynamic simulation tools used to analyze power system performance are able to support systems with high amounts of photovoltaic (PV) generation. Additionally, simulation durations expanding beyond minutes into hours must be supported. This report aims to identify the path forward for dynamic simulation tools to accom- modate these needs by characterizing the properties of power systems (with high PV penetration), analyzing how these properties affect dynamic simulation software, and offering solutions for po- tential problems. We present a study of fixed time step, explicit numerical integration schemes that may be more suitable for these goals, based on identified requirements for simulating high PV penetration systems. We also present the alternative of variable time step integration. To help determine the characteristics of systems with high PV generation, we performed small signal sta- bility studies and time domain simulations of two representative systems. Along with feedback from stakeholders and vendors, we identify the current gaps in power system modeling including fast and slow dynamics and propose a new simulation framework to improve our ability to model and simulate longer-term dynamics.

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Final Technical Report: Low-Cost Solar Variability Sensors for Ubiquitous Deployment

Lave, Matt

In this project, an integrated solution to measuring and collecting solar variability data called the solar variability datalogger (SVD) was developed, tested, and the value of its data to distribution grid integration studies was demonstrated. This work addressed the problem that high-frequency solar variability is rarely measured – due to the high cost and complex installation of existing solar irradiance measuring pyranometers – but is critical to the accurate determination of the impact of photovoltaics to electric grid operation. For example, up to a 300% difference in distribution grid voltage regulator tap change operations (a measure of the impact of PV) [1] has been observed due solely to different solar variability profiles.

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Pickless event detection and location: The waveform correlation event detection system (WCEDS) revisited

Bulletin of the Seismological Society of America

Arrowsmith, Stephen J.; Young, Christopher J.; Ballard, Sanford; Slinkard, Megan E.

The standard paradigm for seismic event monitoring breaks the event detection problem down into a series of processing stages that can be categorized at the highest level into station-level processing and network-level processing algorithms (e.g., Le Bras and Wuster (2002)). At the station-level, waveforms are typically processed to detect signals and identify phases, which may subsequently be updated based on network processing. At the network-level, phase picks are associated to form events, which are subsequently located. Furthermore, waveforms are typically directly exploited only at the station-level, while network-level operations rely on earth models to associate and locate the events that generated the phase picks.

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A Modal Model to Simulate Typical Structural Dynamic Nonlinearity [PowerPoint]

Mayes, Randall L.; Pacini, Benjamin R.; Roettgen, Dan

Some initial investigations have been published which simulate nonlinear response with almost traditional modal models: instead of connecting the modal mass to ground through the traditional spring and damper, a nonlinear Iwan element was added. This assumes that the mode shapes do not change with amplitude and there are no interactions between modal degrees of freedom. This work expands on these previous studies. An impact experiment is performed on a structure which exhibits typical structural dynamic nonlinear response, i.e. weak frequency dependence and strong damping dependence on the amplitude of vibration. Use of low level modal test results in combination with high level impacts are processed using various combinations of modal filtering, the Hilbert Transform and band-pass filtering to develop response data that are then fit with various nonlinear elements to create a nonlinear pseudo-modal model. Simulations of forced response are compared with high level experimental data for various nonlinear element assumptions.

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Highly stretchable miniature strain sensor for large dynamic strain measurement

Proceedings of the Society for Experimental Mechanics Series

Song, Bo; Yao, Shurong; Nie, Xu; Yu, Xun; Blecke, Jill

In this paper, a new type of highly stretchable strain sensor was developed to measure large strains. The sensor was based on the piezo-resistive response of carbon nanotube (CNT)/polydimethylsiloxane (PDMS) composite thin films. The piezo-resistive response of CNT composite gives accurate strain measurement with high frequency response, while the ultra-soft PDMS matrix provides high flexibility and ductility for large strain measurement. Experimental results show that the CNT/PDMS sensor measures large strains (up to 8 %) with an excellent linearity and a fast frequency response. The new miniature strain sensor also exhibits much higher sensitivities than the conventional foil strain gages, as its gauge factor is 500 times of that of the conventional foil strain gages.

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Light-emitting diode technology status and directions: Opportunities for horticultural lighting

Acta Horticulturae

Tsao, Jeffrey Y.; Pattison, P.M.; Krames, Michael R.

Here, light-emitting diode (LED) technology has advanced rapidly over the last decade, primarily driven by display and general illumination applications ("solid-state lighting (SSL) for humans"). These advancements have made LED lighting technically and economically advantageous not only for these applications, but also, as an indirect benefit, for adjacent applications such as horticultural lighting ("SSL for plants"). Moreover, LED technology has much room for continued improvement. In the near-term, these improvements will continue to be driven by SSL for humans (with indirect benefit to SSL for plants), the most important of which can be anticipated.

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One-pot bioconversion of algae biomass into terpenes for advanced biofuels and bioproducts

Algal Research

Davis, Ryan W.

In this study, rising demand for transportation fuels, diminishing reserved of fossil oil, and the concerns with fossil fuel derived environmental pollution as well as the green-house gas emission derived climate change have resulted in the compelling need for alternative, sustainable new energy sources(1). Algae-based biofuels have been considered one of the promising alternatives to fossil fuels as they can overcome some of these issues (2-4). The current state-of-art of algal biofuel technologies have primarily focused on biodiesel production through prompting high algal lipid yields under the nutrient stress conditions. There are less interests of using algae-based carbohydrate and proteins as carbon sources for the fermentative production of liquid fuel compounds or other high-value bioproducts(5-7).

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A Comparison of Reduced Order Modeling Techniques Used in Dynamic Substructuring [PowerPoint]

Roettgen, Dan; Seeger, Benjamin; Tai, Wei; Baek, Seunghun; Dossogne, Tilan; Allen, Matthew S.; Kuether, Robert J.; Brake, M.R.W.; Mayes, Randall L.

Experimental dynamic substructuring is a means whereby a mathematical model for a substructure can be obtained experimentally and then coupled to a model for the rest of the assembly to predict the response. Recently, various methods have been proposed that use a transmission simulator to overcome sensitivity to measurement errors and to exercise the interface between the substructures; including the Craig-Bampton, Dual Craig-Bampton, and Craig-Mayes methods. This work compares the advantages and disadvantages of these reduced order modeling strategies for two dynamic substructuring problems. The methods are first used on an analytical beam model to validate the methodologies. Then they are used to obtain an experimental model for structure consisting of a cylinder with several components inside connected to the outside case by foam with uncertain properties. This represents an exceedingly difficult structure to model and so experimental substructuring could be an attractive way to obtain a model of the system.

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PV Systems Reliability Final Technical Report: Ground Fault Detection

Lavrova, Olga; Flicker, Jack D.; Johnson, Jay

We have examined ground faults in PhotoVoltaic (PV) arrays and the efficacy of fuse, current detection (RCD), current sense monitoring/relays (CSM), isolation/insulation (Riso) monitoring, and Ground Fault Detection and Isolation (GFID) using simulations based on a Simulation Program with Integrated Circuit Emphasis SPICE ground fault circuit model, experimental ground faults installed on real arrays, and theoretical equations.

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Permafrost Active Layer Seismic Interferometry Experiment (PALSIE)

Abbott, Robert; Knox, Hunter A.; James, Stephanie; Lee, Rebekah; Cole, Chris

We present findings from a novel field experiment conducted at Poker Flat Research Range in Fairbanks, Alaska that was designed to monitor changes in active layer thickness in real time. Results are derived primarily from seismic data streaming from seven Nanometric Trillium Posthole seismometers directly buried in the upper section of the permafrost. The data were evaluated using two analysis methods: Horizontal to Vertical Spectral Ratio (HVSR) and ambient noise seismic interferometry. Results from the HVSR conclusively illustrated the method's effectiveness at determining the active layer's thickness with a single station. Investigations with the multi-station method (ambient noise seismic interferometry) are continuing at the University of Florida and have not yet conclusively determined active layer thickness changes. Further work continues with the Bureau of Land Management (BLM) to determine if the ground based measurements can constrain satellite imagery, which provide measurements on a much larger spatial scale.

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Plasma sprayed coatings for containment of Cu-Mg-Si metallic phase change material

Surface and Coatings Technology

Withey, Elizabeth A.; Kruizenga, Alan M.; Andraka, Charles E.; Gibbs, Paul J.

In this study, the performance of Y2O3-stabilized ZrO2 (YSZ), Y2O3, and Al2O3 plasma sprayed coatings are investigated for their ability to prevent attack of Haynes 230 by a near-eutectic Cu-Mg-Si metallic phase change material (PCM) in a closed environment at 820 °C. Areas where coatings failed were identified with optical and scanning electron microscopy, while chemical interactions were clarified through elemental mapping using electron microprobe analysis. Despite its susceptibility to reduction by Mg, the Al2O3 coating performed well while the YSZ and Y2O3 coating showed clear areas of attack. These results are attributed to the evolution of gaseous Mg at 820 °C leading to the formation of MgO and MgAl2O4.

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Results 44301–44400 of 99,299
Results 44301–44400 of 99,299