Publications

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The Materials Chemistry Department 1846 has developed a lab-scale chem-prep process for the synthesis of PNZT 95/5, referred to as the ''SP'' process (Sandia Process). This process (TSP) has been successfully transferred to and scaled-up by Department 14192 (Ceramics and Glass Department), producing the larger quantities of PZT powder required to meet the future supply needs of Sandia for neutron generator production. The particle size distributions of TSP powders routinely have been found to contain a large particle size fraction that was absent in development (SP) powders. This SAND report documents experimental studies focused on characterizing these particles and assessing their potential impact on material performance. To characterize these larger particles, fractionation of several TSP powders was performed. The ''large particle size fractions'' obtained were characterized by particle size analysis, SEM, and ICP analysis and incorporated into compacts and sintered. Large particles were found to be very similar in structure and composition as the bulk of the powder. Studies showed that the large-size fractions of the powders behave similarly to the non-fractionated powder with respect to the types of microstructural features once sintered. Powders were also compared that were prepared using different post-synthesis processing (i.e. differences in precipitate drying). Results showed that these powders contained different amounts and sizes of porous inclusions when sintered. How this affects the functional performance of the PZT 95/5 material is the subject of future investigations.

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This report describes development of a system that provides high-speed, real-time downhole data while drilling. Background of the project, its benefits, major technical challenges, test planning, and test results are covered by relatively brief descriptions in the body of the report, with some topics presented in more detail in the attached appendices.

The Salt Valve and Instrumentation Test was done to provide data on equipment performance in high temperature environments similar to that expected in the next large scale application of that technology. The experiment tested three different valves: (1) a valve with the standard valve body and standard high temperature self-packing material; (2) a valve with the standard valve body and stainless steel O-rings; and (3) a magnetic valve that uses a high temperature coil and no packing material. The first valve, which was used at Solar Two, performed sufficiently throughout the test with only a small leak from the split-body, not the packing material, on the 6th day of testing on the long-term test. The second valve, with the stainless steel O-rings, developed a small leak on the last run of the third test at the bonnet (packing material), at which point it was noted to watch if it got worse and the test continued. By the 6th day of the long-term test, the leak was significant (up to 3 cups per day) and the test was terminated. The magnetic valve failed when exposed to a relatively low temperature of 500 F. According to the manufacturer, it was expected to survive up to temperatures of 600 F. Two different pressure transducers were tested and compared, Taylor and Dynisco. The Taylor pressure transducer was used and proven successful at Solar Two. However, they are no longer made. Therefore the experiment tested a new pressure transducer from Dynisco and compared the results to that of the Taylor. The Dynisco pressure transducer performed inaccurately from the beginning. The pressure transducer was affected by an increase in temperature when the pressure remained the same. Dynisco agreed to recalibrate the pressure transducer and/or send us a new one if the piece was faulty. However, in the process of removing the piece from the system, due to the high temperatures used, the piece had gulled with the stainless-steel piping and broke. Flared fittings versus Swagelock fittings were tested in the experiment as well. Both fittings showed no signs of any leakage when exposed to the high temperatures and corrosive environment. The existing test set-up for the Nagle Long Shafted Pump was used in this experiment and additional test hours were obtained on the pump bearings. However, only 132 hours (5 1/2 days) of the 5000 hours (208 days) were performed due to a salt leak, which required removal of insulation. The experiment had to be terminated prior to removal of the insulation.

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SNL is developing intense sources for flash x-ray radiography. The goals of the experiments presented here were to assess power flow issues and to help benchmark the LSP particle-in-cell code used to design the experiment. Comparisons between LSP simulations and experimental data are presented.

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A new laser trigger system (LTS) has been installed on Z that benefits the experimenter with reduced temporal jitter on the x-ray output, the confidence to use command triggers for time sensitive diagnostics and the ability to shape the current pulse at the load. This paper presents work on the pulse shapping aspects othe the new LTS.

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The use of laser diodes in devices to ignite pyrotechnics provides unique new capabilities including the elimination of electrostatic discharge (ESD) pulses entering the device. The Faraday cage formed by the construction of these devices removes the concern of inadvertent ignition of the energetic material. However, the laser diode itself can be damaged by ESD pulses, therefore, to enhance reliability, some protection of the laser diode is necessary. The development of the MC4612 Optical Actuator has included a circuit to protect the laser diode from ESD pulses including the ''Fisher'' severe human body ESD model. The MC4612 uses a laser diode and is designed to replace existing hot-wire actuators. Optical energy from a laser diode, instead of electrical energy, is used to ignite the pyrotechnic. The protection circuit is described along with a discussion of how the circuit design addresses and circumvents the historic 1Amp/1Watt requirement that has been applicable to hot-wire devices.

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Development in the field of destructive single-event effects over the last 40 years are reviewed. Single-event latchup, single-event burnout, single-event gate rupture, and single-event snap-back are discussed beginning with the first observation of each effect, its phenomenology, and the development of present day understanding of the mechanisms involved.

This report describes a workshop on self-healing infrastructures conducted jointly by Sandia National Laboratories, Infrastructure & Information Division, and the Massachusetts Institute of Technology, Engineering Systems Division. The workshop was held in summer, 2002 and funded under Laboratory-Directed Research and Development (LDRD) No.5 1540. The purpose of the workshop was to obtain a working definition of a self-healing infrastructure, explore concepts for self-healing infrastructures systems, and to propose engineering studies that would lay the foundation for the realization of such systems. The workshop produced a number of useful working documents that clarified the concept of self-healing applied to large-scale system-of-systems exemplified by the US National Critical Infrastructure. The workshop eventually resulted in a joint proposal to the National Science Foundation and a continuing collaboration on intelligent agent based approaches to coordination of infrastructure systems in a self-healing regime.

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Glass can have lethal effects including fatalities and injuries when it breaks and then flies through the air under blast loading (''the glass problem''). One goal of this program was to assess the glass problem and solutions being pursued to mitigate it. One solution to the problem is the development of new glass technology that allows the strength and fragmentation to be controlled or selected depending on the blast performance specifications. For example the glass could be weak and fail, or it could be strong and survive, but it must perform reliably. Also, once it fails it should produce fragments of a controlled size. Under certain circumstances it may be beneficial to have very small fragments, in others it may be beneficial to have large fragments that stay together. The second goal of this program was to evaluate the performance (strength, reliability, and fragmentation) of Engineered Stress Profile (ESP) glass under different loading conditions. These included pseudo-static strength and pressure tests and free-field blast tests. The ultimate goal was to provide engineers and architects with a glass whose behavior under blast loading is less lethal. A near-term benefit is a new approach for improving the reliability of glass and modifying its fracture behavior.

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A prototype design for a plutonium air transport package capable of carrying 7.6 kg of plutonium oxide and surviving a ''worst-case'' plane crash has been developed by Sandia National Laboratories (SNL) for the Japan Nuclear Cycle Development Institute (JNC). A series of impact tests were conducted on half-scale models of this design for side, end, and comer orientations at speeds close to 282 m/s onto a target designed to simulate weathered sandstone. These tests were designed to evaluate the performance of the overpack concept and impact-limiting materials in critical impact orientations. The impact tests of the Perforated Metal Air Transportable Package (PMATP) prototypes were performed at SNL's 10,000-ft rocket sled track. This report describes test facilities calibration and environmental testing methods of the PMATP under specific test conditions. The tests were conducted according to the test plan and procedures that were written by the authors and approved by SNL management and quality assurance personnel. The result of these tests was that the half-scale PMATP survived the ''worst-case'' airplane crash conditions, and indicated that a full-scale PMATP, utilizing this overpack concept and these impact-limiting materials, would also survive these crash conditions.

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High-quality-factor microcavities in two-dimensional photonic crystals at optical frequencies have a number of technological applications, such as cavity quantum electrodynamics, optical switching, filtering, and wavelength multiplexing. For such applications, it is useful to have a simple approach to tune the microcavity resonant wavelength. In this letter, we propose a microcavity design by which we can tune the resonant wavelength by changing the cavity geometry while still obtaining a high quality factor.

We have investigated in situ and in real time vapor-phase self-assembly of 1-decene on Si, using attenuated total reflection Fourier transform infrared spectroscopy (ATR-FTIRS). The adsorption of 1-decene on hydrogenated Si(100) results in a decane-terminated hydrophobic surface, indicated by the sessile-drop water contact angle at 107 {+-} 2. This maximum contact angle is achieved at 160 C under 30 mTorr of vapor-phase 1-decene. The fractional surface coverage of decane, calculated from the IR absorbance of C-H stretching vibrational modes near 2900 cm{sup -1}, follows a Langmuir isotherm. The absolute surface coverage calculated from the IR absorbance saturates at 3.2 x 10{sup 14} cm{sup -2}. On the basis of this isotherm, the empirical rate constant (k{prime}{sub 2}) that governs the rate-limiting step in 1-decene adsorption on HF-treated Si(100) is (3.3 {+-} 0.7) x 10{sup -2} min{sup -1}. The thickness and cant angle of the decane monolayer at the saturation coverage are calculated from angle resolved X-ray photoelectron spectroscopy (AR-XPS). The calculated thickness ranges from 8.4 to 18 {angstrom} due to the uncertainty in the attenuation lengths of C(1s) and Si(2p) photoelectrons through the decane layer. For the same uncertainty, the calculated cant angle ranges from 0 to 55{sup o}. Spectroscopic ellipsometry is independently used to approximate the film thickness at 16 {angstrom}. Monitoring the decane monolayer over a period of 50 days using AR-XPS indicates that the Si surface underneath the decane monolayer gets oxidized with time, leading to the degradation of the decane layer.

We demonstrate that when vertical threading dislocations in (0001) GaN are imaged in plan-view by transmission electron microscopy, a surface-relaxation contrast operates in addition to that due to the strain fields of dislocations passing through the specimen. We show that all three dislocation types (edge, screw, and mixed) can be detected in the same image using g = (11{bar 2}0) and 18{sup o} specimen tilt from [0001], allowing total densities to be assessed properly. The type of an individual dislocation can also be readily identified.

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In this paper we consider the problem of automatically determining whether regions in an outdoor environment can be traversed by a mobile robot. We propose a two-level classifier that uses data from a single color image to make this determination. At the low level, we have implemented three classifiers based on color histograms, directional filters and local binary patterns. The outputs of these low level classifiers are combined using a voting scheme that weights the results of each classifier using an estimate of its error probability. We present results from a large number of trials using a database of representative images acquired in real outdoor environments.

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Wireless networking using the IEEE 802.11standards is a viable alternative for data communications in safeguards applications. This paper discusses the range of 802.11-based networking applications, along with their advantages and disadvantages. For maximum performance, safety, and security, Wireless networking should be implemented only after a comprehensive site survey has determined detailed requirements, hazards, and threats.

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The propagation of electromagnetic waves through dispersive media forms the basis for a wide variety of applications. Rapid advances in materials have produced new products with tailored responses across frequency bands. Many of these new materials, such as radar absorbing material and photonic crystals, are dispersive in nature. This, in turn, has opened up the possibility for the exploitation of these dispersive dielectric properties for a variety of applications. Thus, it is desirable to know the electromagnetic properties of both man-made and natural materials across a wide frequency range. With the advent of transient pulsers with sub-nanosecond risetimes and rates of voltage rise approaching 10**16 V/s, the frequencies of interest in the transient response extend to approximately the 2 GHz range. Although a network analyzer can provide either frequency- or time-domain data (by inverse transform), common TEM cells are only rated to 0.5 to 1.5 GHz--significantly below the maximum frequency of interest. To extend the frequency range to include 2 GHz, a TEM cell was characterized and a deembedding algorithm was applied to account, in part, for the limitations of the cell. The de-embedding technique is described along with such measurement issues such as clear time and sneak around. Measurements of complex permittivity of common drinking water are shown. This frequency extension will lead to more expansive testing of dielectric materials of interest.

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The Multispectral Thermal Imager Satellite (MTI) has been used to test a sub-pixel sampling technique in an effort to obtain higher spatial frequency imagery than that of its original design. The MTI instrument is of particular interest because of its infrared detectors. In this spectral region, the detector size is traditionally the limiting factor in determining the satellite's ground sampling distance (GSD). Additionally, many over-sampling techniques require flexible command and control of the sensor and spacecraft. The MTI sensor is well suited for this task, as it is the only imaging system on the MTI satellite bus. In this super-sampling technique, MTI is maneuvered such that the data are collected at sub-pixel intervals on the ground. The data are then processed using a deconvolution algorithm using in-scene measured point spread functions (PSF) to produce an image with synthetically-boosted GSD.

The Digital Elevation Model (DEM) extraction process traditionally uses a stereo pair of aerial photographs that are sequentially captured using an airborne metric camera. Standard DEM extraction techniques have been naturally extended to utilize satellite imagery. However, the particular characteristics of satellite imaging can cause difficulties in the DEM extraction process. The ephemeris of the spacecraft during the collects, with respect to the ground test site, is the most important factor in the elevation extraction process. When the angle of separation between the stereo images is small, the extraction process typically produces measurements with low accuracy. A large angle of separation can cause an excessive number of erroneous points in the output DEM. There is also a possibility of having occluded areas in the images when drastic topographic variation is present, making it impossible to calculate elevation in the blind spots. The use of three or more images registered to the same ground area can potentially reduce these problems and improve the accuracy of the extracted DEM. The pointing capability of the Multispectral Thermal Imager (MTI) allows for multiple collects of the same area to be taken from different perspectives. This functionality of MTI makes it a good candidate for the implementation of DEM extraction using multiple images for improved accuracy. This paper describes a project to evaluate this capability and the algorithms used to extract DEMs from multi-look MTI imagery.

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Coupled double quantum well field-effect transistors with a grating gate exhibit a terahertz ({approx}600 GHz) photoconductive response that resonates with standing two dimensional plasma oscillations under the gate and may be the basis for developing a fast, tunable terahertz detector. The application of a precisely aligned in-plane magnetic field produces no detectable change in the device DC conductance but produces a dramatic inversion, growth of the terahertz photoconductive response and frequency shift of the standing plasmon resonances. The frequency shift can be described by a significant mass increase produced by the in-plane field. The mass increase is substantially larger than that calculated from a single well and we presume that a proper treatment of the coupled double quantum well may resolve this discrepancy.

Fe nanoparticles prepared by iron carbonyl decomposition using different methods are compared structurally, chemically, and magnetically. The specific magnetization of the particles was determined from the magnetic moment, the particle size observed by transmission electron microscopy, and the total iron concentration found from calibrated X-ray fluorescence. The volume fraction of oxide is reported for particles of different sizes and for particles made by slightly different techniques.

The conductivity of extremely high mobility dilute two-dimensional holes in GaAs changes linearly with temperature in the insulating side of the metal-insulator transition. Hopping conduction, characterized by an exponentially decreasing conductivity with decreasing temperature, is not observed when the conductivity is smaller than e{sup 2}/h. We suggest that strong interactions in a regime close to the Wigner crystallization must be playing a role in the unusual transport.

Experiments using high-resolution size exclusion chromatography (HRSEC), dynamic light scattering, and transmission electron microscopy are conducted to investigate the effects of aging of Au nanoclusters in the presence of surfactant ligands. It is observed that contrary to the expectation that aging in solution will always broaden the size dispersion and increase the average size (Ostwald ripening), a narrowing of the size dispersion and change in average size can occur with time under ambient conditions.

Transport measurements of high-mobility two-dimensional electron systems at low temperatures have revealed a large resistance anisotropy around half-filling of excited Landau levels. These results have been attributed to electronic stripe-phase formation with spontaneously broken orientational symmetry. Mechanisms which are known to break the orientational symmetry include poorly-understood crystal structure effects and an in-plane magnetic field, B{sub {parallel}}. Here we report that a large B{sub {parallel}} also causes the transport anisotropy to persist up to much higher temperatures. In this regime, we find that the anisotropic resistance scales sublinearly with B{sub {parallel}}/T. These observations support the proposal that the transition from anisotropic to isotropic transport reflects a liquid crystal phase transition where local stripe order persists even in the isotropic regime.

The metallic conductivity of dilute two-dimensional holes in a GaAs HIGFET (Heterojunction Insulated-Gate Field-Effect Transistor) with extremely high mobility and large r{sub s} is found to have a linear dependence on temperature, consistent with the theory of interaction corrections in the ballistic regime. Phonon scattering contributions are negligible in the temperature range of our interest, allowing comparison between our measured data and theory without any phonon subtraction. The magnitude of the Fermi liquid interaction parameter F{sub 0}{sup {sigma}} determined from the experiment, however, decreases with increasing r{sub s} for r{sub s} {approx}> 22, a behavior unexpected from existing theoretical calculations valid for small r{sub s}.

The Multispectral Thermal Imager Satellite (MTI), launched on March 12, 2000, has now surpassed its one-year mission requirement and its three-year mission goal. Primary and secondary program objectives regarding the development and evaluation of space-based multispectral and thermal imaging technology for nonproliferation treaty monitoring and other national security and civilian application have been met. Valuable lessons have also been learned, both from things that worked especially well and from shortcomings and anomalies encountered. This paper addresses lessons associated with the satellite, ground station and system operations, while companion papers address lessons associated with radiometric calibration, band-to-band registration and scientific processes and results. Things addressed in this paper that went especially well include overall satellite design, ground station design, system operations, and integration and test. Anomalies and other problems addressed herein include gyro and mass storage unit failures, battery under-voltage trips, a blown fuse, unexpected effects induced by communication link noise, ground station problems, and anomalies resulting from human error. In spite of MTI's single-string design, the operations team has been successful in working around these problems, and the satellite continues to collect valuable mission data.

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The existing IEEE stationary battery maintenance and testing standards fall into two basic categories: those associated with grid-tied standby applications and those associated with stand-alone photovoltaic cycling applications. These applications differ in several significant ways, which in turn influence their associated standards. A review of the factors influencing the maintenance and testing of stationary battery systems provides the reasons for the differences between these standards and some of the hazards of using a standard inappropriate to the application. This review also provides a background on why these standards will need to be supplemented in the future to support emerging requirements of other applications, such as grid-tied cycling and photovoltaic hybrid applications.

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This paper describes preliminary results of a dynamic system model for a closed-loop Brayton-cycle that is coupled to a nuclear reactor. The current model assumes direct coupling between the reactor and the Brayton-cycle, however only minor additions are required to couple the Brayton-cycle through a heat exchanger to either a heat pipe reactor or a liquid metal cooled reactor. Few reactors have ever been coupled to closed Brayton-cycle systems. As such their behavior under dynamically varying loads, startup and shut down conditions, and requirements for safe and autonomous operation are largely unknown. Sandia National Laboratories has developed steady-state and dynamic models for closed-loop turbo-compressor systems (for space and terrestrial applications). These models are expected to provide a basic understanding of the dynamic behavior and stability of the coupled reactor and power generation loop. The model described in this paper is a lumped parameter model of the reactor, turbine, compressor, recuperator, radiator/waste-heat-rejection system and generator. More detailed models that remove the lumped parameter simplifications are also being developed but are not presented here. The initial results of the model indicate stable operation of the reactor-driven Brayton-cycle system and its ability to load-follow. However, the model also indicates some counter-intuitive behavior for the complete coupled system. This behavior will require the use of a reactor control system to select an appropriate reactor operating temperature that will optimize the performance of the complete spacecraft system. We expect this model and subsequent versions of it to provide crucial information in developing procedures for safe start up, shut down, safe-standby, and other autonomous operating modes. Ultimately, Sandia hopes to validate these models and to perform nuclear ground tests of reactor-driven closed Brayton-cycle systems in our nuclear research facilities.

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