Publications

Abstract not provided.

Smokes are frequently used as visual obscurants in access delay applications. A new generation of low temperature pyrotechnic smokes is being developed. Terephthalic Acid (TPA) smoke was developed by the U.S. Army and Sebacic Acid (SA) smoke is being developed by Thiokol Corp. The advantages these smokes offer over traditional pyrotechnic smokes include; low generation temperature (approximately 450{degree}C), lower toxicity, and lower corrosivity. The low generation temperature reduces smoke layering effects and allows the addition of sensory irritants, such as o-Chlorobenzylidene Malononitrile (CS), to the formulation. Some advantages low temperature pyrotechnic smokes offer over nonpyrotechnic smokes include; low cost, simplicity, compactness, light weight, long storage life, and orientation insensitive operation. Low cost permits distribution of multiple units for reduced vulnerability and refill flexibility. Some disadvantages may include the combustibility of the smoke particulate; however, the published lower explosive limit of the mentioned materials is approximately ten times greater than the concentration required for effective obscuration. The TPA smoke cloud contains small quantities of benzene, formaldehyde, and carbon monoxide; no benzene or formaldehyde was identified during preliminary SA smoke analyses performed by Thiokol Corp. Sandia performed tests and analyses on TPA smoke to determine the smoke cloud composition, the quantity of particulate produced per canister, and the relationship between airborne particulate concentration and measured optical density values. Current activities include characterization of SA smoke.

One decade ago, Sandia National Laboratories designed and developed a nonpyrotechnic smoke generator capable of producing large quantities of low corrosivity, low toxicity chemical smoke to be used as a visual obscurant in access delay applications. Utilizing the same chemistry, a proof-of-concept advanced smoke generator is presently being tested. The testing is being conducted to evaluate two new concepts providing unique capabilities. Hemispherical stainless steel bladders are installed in spherically shaped chemical storage reservoirs. This provides positive displacement of the chemicals and permits orientation insensitive operation. Also, a specially designed nozzle/valve is being evaluated as a means of providing a multiple initiation capability. Cyclic operation could be accomplished via time delay circuitry, sensor input, or on demand from the control console. These new capabilities provide distinct advantages. Some advantages may be longer obscuration times, optimal volume obscuration, easier facility sizing, no organic seals in contact with the stored chemicals, and elimination of the requirement to use ultrahigh purity nitrogen as a propellant.