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Lateral organization of cholesterol molecules in lipid-cholesterol assemblies

Proposed for publication in Physical Review E.

Slepoy, Alexander S.

We present results of an off-lattice simulation of a two-component planar system, as a model for lateral organization of cholesterol molecules in lipid-cholesterol assemblies. We explore the existence of 'superlattice' structures even in fluid systems, in the absence of an underlying translational long-range order, and study their coupling to hexatic or bond-orientational order. We discuss our results in context of geometric superlattice theories and 'condensation complexes' in understanding a variety of experiments in artificial lipid-cholesterol assemblies.

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Single-quantum-well grating-gated terahertz plasmon detectors

Proposed for publication in Applied Physics Letters.

Shaner, Eric A.; Lee, Mark L.; Wanke, Michael W.; Grine, Albert D.; Reno, J.L.

A grating-gated field-effect transistor fabricated from a single-quantum well in a high-mobility GaAs-AlGaAs heterostructure is shown to function as a continuously electrically tunable photodetector of terahertz radiation via excitation of resonant plasmon modes in the well. Different harmonics of the plasmon wave vector are mapped, showing different branches of the dispersion relation. As a function of temperature, the resonant response magnitude peaks at around 30 K. Both photovoltaic and photoconductive responses have been observed under different incident power and bias conditions.

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Computing the mobility of grain boundaries

Proposed for publication in Nature Materials.

Janssens, Koenraad G.; Holm, Elizabeth A.; Foiles, Stephen M.; Plimpton, Steven J.

As current experimental and simulation methods cannot determine the mobility of flat boundaries across the large misorientation phase space, we have developed a computational method for imposing an artificial driving force on boundaries. In a molecular dynamics simulation, this allows us to go beyond the inherent timescale restrictions of the technique and induce non-negligible motion in flat boundaries of arbitrary misorientation. For different series of symmetric boundaries, we find both expected and unexpected results. In general, mobility increases as the grain boundary plane deviates from (111), but high-coincidence and low-angle boundaries represent special cases. These results agree with and enrich experimental observations.

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Condition monitoring through advanced sensor and computational technology : final report (January 2002 to May 2005)

Luk, Vincent K.

The overall goal of this joint research project was to develop and demonstrate advanced sensors and computational technology for continuous monitoring of the condition of components, structures, and systems in advanced and next-generation nuclear power plants (NPPs). This project included investigating and adapting several advanced sensor technologies from Korean and US national laboratory research communities, some of which were developed and applied in non-nuclear industries. The project team investigated and developed sophisticated signal processing, noise reduction, and pattern recognition techniques and algorithms. The researchers installed sensors and conducted condition monitoring tests on two test loops, a check valve (an active component) and a piping elbow (a passive component), to demonstrate the feasibility of using advanced sensors and computational technology to achieve the project goal. Acoustic emission (AE) devices, optical fiber sensors, accelerometers, and ultrasonic transducers (UTs) were used to detect mechanical vibratory response of check valve and piping elbow in normal and degraded configurations. Chemical sensors were also installed to monitor the water chemistry in the piping elbow test loop. Analysis results of processed sensor data indicate that it is feasible to differentiate between the normal and degraded (with selected degradation mechanisms) configurations of these two components from the acquired sensor signals, but it is questionable that these methods can reliably identify the level and type of degradation. Additional research and development efforts are needed to refine the differentiation techniques and to reduce the level of uncertainties.

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Guidelines to improve airport preparedness against chemical and biological terrorism

Edwards, Donna M.; Gordon, Susanna P.

Guidelines to Improve Airport Preparedness Against Chemical and Biological Terrorism is a 100-page document that makes concrete recommendations on improving security and assessing vulnerable areas and helps its readers understand the nature of chemical and biological attacks. The report has been turned over to Airports Council International (ACI) and the American Association of Airport Executives (AAAE), two organizations that together represent the interests of thousands of airport personnel and facilities in the U.S. and around the world.

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SNL/CA Environmental Planning and Ecology Annual Program Report for Calendar Year 2005

Larsen, Barbara L.

The annual program report provides detailed information about all aspects of the SNL/CA Environmental Planning and Ecology Program for a given calendar year. It functions as supporting documentation to the SNL/CA Environmental Management System Program Manual. The 2005 program report describes the activities undertaken during the past year, and activities planned in future years to implement the Planning and Ecology Program, one of six programs that supports environmental management at SNL/CA.

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What do you want? : how perceivers use cues to make goal inferences about others

Proposed for publication in Cognitive Psychology.

Forsythe, James C.

Variables influencing inferences about a stranger's goal during an unsolicited social interaction were explored. Experiment 1 developed a procedure for identifying cues. Experiments 2 and 3 assessed the relative importance of various cues (space, time, characteristics of oneself, characteristics of the stranger, and the stranger's behavior) for goal judgments. Results indicated that situational context cues informed goal judgments in ways that were consistent with diagnosticity ratings and typicality ratings of those cues. Stranger characteristics and stranger behaviors affected goal judgments more than would be expected from these quantitative measures of their informativeness. Nonetheless, the results are consistent with a mental model view that assumes perceivers monitor situational cues present during interactions and that goal inferences are guided by the informativeness of these cues.

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Results from Sandia National Laboratories/Lockheed Martin Electromagnetic Missile Launcher (EMML)

Aubuchon, Matthew S.; Lockner, Thomas L.; Turman, Bobby N.

Sandia national laboratories (SNL) and lockheed martin MS2 are designing an electromagnetic missile launcher (EMML) for naval applications. The EMML uses an induction coilgun topology with the requirement of launching a 3600 lb. missile up to a velocity of 40 m/s. To demonstrate the feasibility of the electromagnetic propulsion design, a demonstrator launcher was built that consists of approximately 10% of the propulsion coils needed for a tactical design. The demonstrator verified the design by launching a 1430 lb weighted sled to a height of 24 ft in mid-December 2004 (Figure 1). This paper provides the general launcher design, specific pulsed power system component details, system operation, and demonstration results.

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Tribological properties of alkylsilane self-assembled monolayers

Proposed for publication in Langmuir.

Lorenz, Christian D.; Chandross, M.; Grest, Gary S.; Stevens, Mark J.; Webb, Edmund B.

In this study, we perform molecular dynamics simulations of adhesive contact and friction between alkylsilane Si(OH){sub 3}(CX{sub 2}){sub 10}CX{sub 3} and alkoxylsilane Si(OH){sub 2}(CX{sub 2}){sub 10}CX{sub 3} (where X = H or F) self-assembled monolayers (SAMs) on an amorphous silica substrate. The alkylsilane SAMs are primarily hydrogen-bonded or physisorbed to the surface. The alkoxylsilane SAMs are covalently bonded or chemisorbed to the surface. Previously, we studied the chemisorbed systems. In this work, we study the physisorbed systems and compare the tribological properties with the chemisorbed systems. Furthermore, we examine how water at the interface of the SAMs and substrate affects the tribological properties of the physisorbed systems. When less than a third of a monolayer is present, very little difference in the microscopic friction coefficient {mu} or shear stresses is observed. For increasing amounts of water, the values of {mu} and the shear stresses decrease; this effect is somewhat more pronounced for fluorocarbon alkylsilane SAMs than for the hydrocarbon SAMs. The observed decrease in friction is a consequence of a slip plane that occurs in the water as the amount of water is increased. We studied the frictional behavior using relative shear velocities ranging from v = 2 cm/s to 2 m/s. Similar to previously reported results for alkoxylsilane SAMs, the values of the measured stress and {mu} for the alkylsilane SAM systems decrease monotonically with v.

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Morphology of evaporated multiblock co-polymer membranes studied by molecular dynamics simulations

Proposed for publication in Macromolecules.

Tsige, Mesfin T.; Grest, Gary S.; Mattsson, Thomas M.

We present extensive simulations modeling the casting of multiblock polymer films by evaporation. The domain structure of the resulting film is strongly affected by varying the relative stiffness of the coblocks. The morphology changes from a bicontinuous lamellar phase when both blocks are flexible to a small-scale phase-separated phase with isolated domains as the stiffness of one of the blocks increases. As the relative stiffness of the blocks changes, the rate of evaporation, interfacial width, and morphology of the system changes. The findings can be used to tailor membrane morphology of interest to fuel-cell applications where the morphology is important for proton conduction.

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New facets of the STS polytope generated from known facets of the ATS polytope

Proposed for publication in the Journal of the Discrete Optimization.

Carr, Robert D.

While it had been known for a long time how to transform an asymmetric traveling salesman (ATS) problem on the complete graph with n vertices into a symmetric traveling salesman (STS) problem on an incomplete graph with 2n vertices, no method was available for using this correspondence to derive facets of the symmetric polytope from facets of the asymmetric polytope until the work of E. Balas and M. Fischetti in [Lifted cycle inequalities for the asymmetric traveling salesman problem, Mathematics of Operations Research 24 (2) (1999) 273-292] suggested an approach. The original Balas-Fischetti method uses a standard sequential lifting procedure for the computation of the coefficient of the edges that are missing in the incomplete STS graph, which is a difficult task when addressing classes of (as opposed to single) inequalities. In this paper we introduce a systematic procedure for accomplishing the lifting task. The procedure exploits the structure of the tight STS tours and organizes them into a suitable tree structure. The potential of the method is illustrated by deriving large new classes of facet-defining STS inequalities.

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Distributed-feedback terahertz quantum-cascade lasers using laterally corrugated metal waveguides

Proposed for publication in Optics Letters.

Reno, J.L.

We report the demonstration of distributed-feedback terahertz quantum-cascade lasers based on a first-order grating fabricated via a lateral corrugation in a double-sided metal ridge waveguide. The phase of the facet reflection was precisely set by lithographically defined facets by dry etching. Single-mode emission was observed at low to moderate injection currents, although multimode emission was observed far beyond threshold owing to spatial hole burning. Finite-element simulations were used to calculate the modal and threshold characteristics for these devices, with results in good agreement with experiments.

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Staggered-grid finite-difference acoustic modeling with the Time-Domain Atmospheric Acoustic Propagation Suite (TDAAPS)

Symons, Neill P.; Aldridge, David F.

This document is intended to serve as a users guide for the time-domain atmospheric acoustic propagation suite (TDAAPS) program developed as part of the Department of Defense High-Performance Modernization Office (HPCMP) Common High-Performance Computing Scalable Software Initiative (CHSSI). TDAAPS performs staggered-grid finite-difference modeling of the acoustic velocity-pressure system with the incorporation of spatially inhomogeneous winds. Wherever practical the control structure of the codes are written in C++ using an object oriented design. Sections of code where a large number of calculations are required are written in C or F77 in order to enable better compiler optimization of these sections. The TDAAPS program conforms to a UNIX style calling interface. Most of the actions of the codes are controlled by adding flags to the invoking command line. This document presents a large number of examples and provides new users with the necessary background to perform acoustic modeling with TDAAPS.

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X-ray absorption spectroscopy to probe surface composition and surface deprotection in photoresist films

Langmuir

Lenhart, Joseph L.; Fischer, Daniel A.; Sambasivan, Sharadha; Lin, Eric K.; Jones, Ronald L.; Soles, Christopher L.; Wu, Wen L.; Goldfarb, Dario L.; Angelopoulos, Marie

Near-edge X-ray absorption fine structure spectroscopy (NEXAFS) is utilized to provide insight into surface chemical effects in model photoresist films. First, NEXAFS was used to examine the resist/air interface including surface segregation of a photoacid generator (PAG) and the extent of surface deprotection in the film. The concentration of PAG at the resist-air interface was higher than the bulk concentration, which led to a faster deprotection rate at that interface. Second, a NEXAFS depth profiling technique was utilized to probe for compositional gradients in model resist line edge regions. In the model line edge region, the surface composition profile for the developed line edge was dependent on the post exposure bake time. © 2005 American Chemical Society.

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Characterization of adsorption sites on aggregate soil samples using synchrotron X-ray computerized microtomography

Environmental Science and Technology

Altman, Susan J.; Rivers, Mark L.; Reno, Marissa D.; Cygan, Randall T.; Mclain, Angela A.

Synchrotron-source X-ray computerized microtomography (CMT) was used to evaluate the adsorptive properties of aggregate soil samples. A linear relationship between measured mean mass attenuation coefficient (σ) and mass fraction iron was generated by imaging mineral standards with known iron contents. On the basis of reported stoichiometries of the clay minerals and identifications of iron oxyhydroxides (1), we calculated the mass fraction iron and iron oxyhydroxide in the intergranular material. The mass fractions of iron were estimated to range from 0.17 to 0.22 for measurements made at 18 keV and from 0.18 to 0.21 for measurements made at 26 keV. One aggregate sample also contained regions within the intergranular material with mass fraction iron ranging from 0.29 to 0.31 and from 0.33 to 0.36 for the 18 and 26 keV measurements, respectively. The mass fraction iron oxyhydroxide ranged from 0.18 to 0.35 for the low-iron intergranular material and from 0.40 to 0.59 for the high-iron intergranular material. Using absorption edge difference imaging with CMT, we visualized cesium on the intergranular material, presumably because of adsorption and possible exchange reactions. By characterizing the mass fraction iron, the mass fraction iron oxyhydroxide, and the adsorptive capacity of these soil mineral aggregates, we provide information useful for conceptualization, development, and parametrization of transport models. © 2005 American Chemical Society.

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Using triaxial magnetic fields to create optimal particle composites

Composites Part A: Applied Science and Manufacturing

Martin, James E.

The properties of a particle composite can be controlled by organizing the particles into assemblies. The properties of the composite will depend on the structure of the particle assemblies, and for any give property there is some optimal structure. Through simulation and experiment we show that the application of heterodyned triaxial magnetic or electric fields generates structures that optimize the magnetic and dielectric properties of particle composites. We suggest that optimizing these properties optimizes other properties, such as transport properties, and we give as one example of this optimization the magnetostriction of magnetic particle composites formed in a silicone elastomer. © 2005 Elsevier Ltd. All rights reserved.

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Microporous sol-gel derived aminosilicate membrane for enhanced carbon dioxide separation

Separation and Purification Technology

Xomeritakis, George; Tsai, Chung Y.; Brinker, C.J.

A new aminosilicate, sol-gel derived microporous inorganic membrane has been developed for enhanced CO2 separation in applications such as removal of metabolic CO2 from the breathing loop of the NASA extravehicular mobility unit (EMU), natural gas purification, or CO2 capture from coal-fired power plant emissions. This membrane consists of an inorganic, amorphous silica matrix of pore size 4-5 Å, containing randomly dispersed amine (NH2) functional groups in order to enhance its CO2 selectivity, due to preferential adsorption of CO 2 in the membrane pore walls and simultaneous blocking of permeation of other gases (O2, N2 and CH4). It is found that the gas feed condition during permeation (partial pressure of CO 2, relative humidity), post-synthetic treatments and aging, affect significantly the separation performance of the membranes. At this stage of development, with feeds of 1-20 vol.% CO2 and 0-40% relative humidity at 22 °C, the highest CO2:N2 separation factor was in the range 100-200, while the CO2 permeance was in the range 0.1-1.5 cm3 (STP)/(cm2 min atm). The results suggest that controlling the membrane pore size and method of activation of amine groups are the most critical factors for improving the CO 2-permselectivity of the membrane. © 2004 Elsevier B.V. All rights reserved.

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Pulse shaping techniques for testing elastic-plastic materials with a split Hopkinson pressure bar

Experimental Mechanics

Frew, Danny J.; Forrestal, M.J.; Chen, W.

We present pulse shaping techniques to obtain compressive stress - strain data for elastic - plastic materials with a split Hopkinson pressure bar. The conventional split Hopkinson pressure bar apparatus is modified by placing a combination of copper and steel pulse shapers on the impact surface of the incident bar. After impact by the striker bar, the copper - steel pulse shaper deforms plastically and spreads the pulse in the incident bar so that the sample is nearly in dynamic stress equilibrium and has a nearly constant strain rate in the plastic response region. We present analytical models and data that show a broad range of incident strain pulses can be obtained by varying the pulse shaper geometry and striking velocity. For an application, we present compressive stress - strain data for 4340 Rc 43 steel. © 2005 Society for Experimental Mechanics.

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A finite element multiscale capability for nonlinear quasistatic stress analysis

Finite Elements in Analysis and Design

Heinstein, Martin W.

Failure modeling is inherently a multi length scale phenomenon that requires a failure model and a computational method that solves for stress/strain gradients at interesting locations. Focusing on the computational method, we recognize that the mesh resolution must be relatively fine in regions where failure is expected and relatively coarse elsewhere. Furthermore, in some modeling approaches the topology in the structural model is different than that required in the fine scale model where failure is to be predicted. This necessarily precludes approaches such as h-adaptivity. We are therefore led to consider multiscale approaches to solve these problems.This work describes an approach to solve multiple (a reference scale and fine scale) coupled boundary value problems for the purpose of nonlinear quasistatic stress analysis. Two examples are included: one example illustrates the multiscale solution strategy to perform quasistatic stress analysis and the other demonstrates the computational beginnings of the ability to model material failure. © 2005 Elsevier B.V. All rights reserved.

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Final LDRD report : design and fabrication of advanced device structures for ultra high efficiency solid state lighting

Fischer, Arthur J.; Crawford, Mary H.; Koleske, Daniel K.; Allerman, A.A.; Bogart, Katherine B.; Wendt, J.R.; Shul, Randy J.

The goal of this one year LDRD was to improve the overall efficiency of InGaN LEDs by improving the extraction of light from the semiconductor chip. InGaN LEDs are currently the most promising technology for producing high efficiency blue and green semiconductor light emitters. Improving the efficiency of InGaN LEDs will enable a more rapid adoption of semiconductor based lighting. In this LDRD, we proposed to develop photonic structures to improve light extraction from nitride-based light emitting diodes (LEDs). While many advanced device geometries were considered for this work, we focused on the use of a photonic crystal for improved light extraction. Although resonant cavity LEDs and other advanced structures certainly have the potential to improve light extraction, the photonic crystal approach showed the most promise in the early stages of this short program. The photonic crystal (PX)-LED developed here incorporates a two dimensional photonic crystal, or photonic lattice, into a nitride-based LED. The dimensions of the photonic crystal are selected such that there are very few or no optical modes in the plane of the LED ('lateral' modes). This will reduce or eliminate any radiation in the lateral direction so that the majority of the LED radiation will be in vertical modes that escape the semiconductor, which will improve the light-extraction efficiency. PX-LEDs were fabricated using a range of hole diameters and lattice constants and compared to control LEDs without a photonic crystal. The far field patterns from the PX-LEDs were dramatically modified by the presence of the photonic crystal. An increase in LED brightness of 1.75X was observed for light measured into a 40 degree emission cone with a total increase in power of 1.5X for an unencapsulated LED.

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Emphasis/Nevada STDEM : user's guide : version 1.0

Coats, Rebecca S.; Pasik, Michael F.; Seidel, David B.

STDEM is the structured mesh time-domain electromagnetic and plasma physics component of Emphasis/Nevada. This report provides a guide on using STDEM. Emphasis, the electromagnetic physics analysis system, is a suite of codes for the simulation of electromagnetic and plasma physics phenomena. The time-dependent components of Emphasis have been implemented using the Nevada framework [1]. The notation Emphasis/Nevada is used to highlight this relationship and/or distinguish the time-dependent components of Emphasis. In theory the underlying framework should have little influence on the user's interaction with the application. In practice the framework tends to be more invasive as it provides key services such as input parsing and defines fundamental concepts and terminology. While the framework offers many technological advancements from a software development point of view, from a user's perspective the key benefits of the underlying framework are the common interface for all framework physics modules as well as the ability to perform coupled physics simulations. STDEM is the structured time-domain electromagnetic and plasma physics component of Emphasis/Nevada. STDEM provides for the full-wave solution to Maxwell's equations on multi-block three-dimensional structured grids using finite-difference time-domain (FDTD) algorithms. Additionally STDEM provides for the fully relativistic, self-consistent simulation of charged particles using particle-in-cell (PIC) algorithms.

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Dynamic compaction of tungsten carbide powder

Hall, Clint A.

The shock compaction behavior of a tungsten carbide powder was investigated using a new experimental design for gas-gun experiments. This design allows the Hugoniot properties to be measured with reasonably good accuracy despite the inherent difficulties involved with distended powders. The experiments also provide the first reshock state for the compacted powder. Experiments were conducted at impact velocities of 245, 500, and 711 m/s. A steady shock wave was observed for some of the sample thicknesses, but the remainder were attenuated due to release from the back of the impactor or the edge of the sample. The shock velocity for the powder was found to be quite low, and the propagating shock waves were seen to be very dispersive. The Hugoniot density for the 711 m/s experiment was close to ambient crystal density for tungsten carbide, indicating nearly complete compaction. When compared with quasi-static compaction results for the same material, the dynamic compaction data is seen to be significantly stiffer for the regime over which they overlap. Based on these initial results, recommendations are made for improving the experimental technique and for future work to improve our understanding of powder compaction.

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Statistical validation of engineering and scientific models : bounds, calibration, and extrapolation

Dowding, Kevin J.

Numerical models of complex phenomena often contain approximations due to our inability to fully model the underlying physics, the excessive computational resources required to fully resolve the physics, the need to calibrate constitutive models, or in some cases, our ability to only bound behavior. Here we illustrate the relationship between approximation, calibration, extrapolation, and model validation through a series of examples that use the linear transient convective/dispersion equation to represent the nonlinear behavior of Burgers equation. While the use of these models represents a simplification relative to the types of systems we normally address in engineering and science, the present examples do support the tutorial nature of this document without obscuring the basic issues presented with unnecessarily complex models.

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Dismantlement and Radioactive Waste Management of DPRK Nuclear Facilities

Baldwin, George T.

One critical aspect of any denuclearization of the Democratic People’s Republic of Korea (DPRK) involves dismantlement of its nuclear facilities and management of their associated radioactive wastes. The decommissioning problem for its two principal operational plutonium facilities at Yongbyun, the 5MWe nuclear reactor and the Radiochemical Laboratory reprocessing facility, alone present a formidable challenge. Dismantling those facilities will create radioactive waste in addition to existing inventories of spent fuel and reprocessing wastes. Negotiations with the DPRK, such as the Six Party Talks, need to appreciate the enormous scale of the radioactive waste management problem resulting from dismantlement. The two operating plutonium facilities, along with their legacy wastes, will result in anywhere from 50 to 100 metric tons of uranium spent fuel, as much as 500,000 liters of liquid high-level waste, as well as miscellaneous high-level waste sources from the Radiochemical Laboratory. A substantial quantity of intermediate-level waste will result from disposing 600 metric tons of graphite from the reactor, an undetermined quantity of chemical decladding liquid waste from reprocessing, and hundreds of tons of contaminated concrete and metal from facility dismantlement. Various facilities for dismantlement, decontamination, waste treatment and packaging, and storage will be needed. The shipment of spent fuel and liquid high level waste out of the DPRK is also likely to be required. Nuclear facility dismantlement and radioactive waste management in the DPRK are all the more difficult because of nuclear nonproliferation constraints, including the call by the United States for “complete, verifiable and irreversible dismantlement,” or “CVID.” It is desirable to accomplish dismantlement quickly, but many aspects of the radioactive waste management cannot be achieved without careful assessment, planning and preparation, sustained commitment, and long completion times. The radioactive waste management problem in fact offers a prospect for international participation to engage the DPRK constructively. DPRK nuclear dismantlement, when accompanied with a concerted effort for effective radioactive waste management, can be a mutually beneficial goal.

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Conversion of the Bryan Mound geological site characterization reports to a three-dimensional model

Stein, Joshua S.

The Bryan Mound salt dome, located near Freeport, Texas, is home to one of four underground crude oil-storage facilities managed by the U. S. Department of Energy Strategic Petroleum Reserve (SPR) Program. Sandia National Laboratories, as the geotechnical advisor to the SPR, conducts site-characterization investigations and other longer-term geotechnical and engineering studies in support of the program. This report describes the conversion of two-dimensional geologic interpretations of the Bryan Mound site into three-dimensional geologic models. The new models include the geometry of the salt dome, the surrounding sedimentary units, mapped faults, and the 20 oil-storage caverns at the site. This work provides an internally consistent geologic model of the Bryan Mound site that can be used in support of future work.

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Leadership development study :success profile competencies and high-performing leaders at Sandia National Laboratories

Crowder, Stephen V.

Sandia is undergoing tremendous change. Sandia's executive management recognized the need for leadership development. About ten years ago the Business, Leadership, and Management Development department in partnership with executive management developed and implemented the organizational leadership Success Profile Competencies to help address some of the changes on the horizon such as workforce losses and lack of a skill set in the area of interpersonal skills. This study addresses the need for the Business, Leadership, and Management Development department to provide statistically sound data in two areas. One is to demonstrate that the organizational 360-degree success profile assessment tool has made a difference for leaders. A second area is to demonstrate the presence of high performing leaders at the Labs. The study utilized two tools to address these two areas. Study participants were made up of individuals who have solid data on Sandia's 360-degree success profile assessment tool. The second assessment tool was comprised of those leaders who participated in the Lockheed Martin Corporation Employee Preferences Survey. Statistical data supports the connection between leader indicators and the 360-degree assessment tool. The study also indicates the presence of high performing leaders at Sandia.

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Detonation tube impulse in sub-atmospheric environments

Proposed for publication in AIAA Journal of Propulsion and Power.

Cooper, Marcia A.

The thrust from a multi-cycle, pulse detonation engine operating at practical flight altitudes will vary with the surrounding environment pressure. We have carried out the first experimental study using a detonation tube hung in a ballistic pendulum arrangement within a large pressure vessel in order to determine the effect that the environment has on the single-cycle impulse. The air pressure inside the vessel surrounding the detonation tube varied between 100 and 1.4 kPa while the initial pressure of the stoichiometric ethylene-oxygen mixture inside the tube varied between 100 and 30 kPa. The original impulse model (Wintenberger et al., Journal of Propulsion and Power, Vol. 19, No. 1, 2002) was modified to predict the observed increase in impulse and blow down time as the environment pressure decreased below one atmosphere. Comparisons between the impulse from detonation tubes and ideal, steady flow rockets indicate incomplete expansion of the detonation tube exhaust, resulting in a 37% difference in impulse at a pressure ratio (ratio of pressure behind the Taylor wave to the environment pressure) of 100.

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Smart materials for Gossamer spacecraft : performance limitations

Chaplya, Pavel; Assink, Roger A.

Smart polymeric materials, such as piezoelectric polymers which deform by application of an electric field, are of interest for use in controllable mirrors as large, lightweight space optics. An important consideration when using any organic material in a space application is their extreme vulnerability to the space environment. In LEO the presence of atomic oxygen, large thermal extremes, hard vacuum, short wavelength ultraviolet and particulate radiation can result in erosion, cracking and outgassing of most polymers. While much research has been performed examining the physical and chemical changes incurred by polymers exposed to actual and simulated LEO environments, little work has focused on the effects of the space environment on the performance of piezoelectric polymers. The most widely used piezoelectric polymers are those based on poly(vinylidene fluoride) (PVDF) and include copolymers synthesized from vinylidene fluoride and trifluoroethylene, hexafluoropropylene or chlorotrifluoroethylene. The presence of a comonomer group can greatly influence on the crystalline phase, melting point, Curie point, modulus and processing required for piezoelectricity. After a rigorous pre-selection process only two polymers, namely the PVDF homopolymer and a TrFE copolymer (80% comonomer content), satisfied most of the requirements for operation in the temperature/radiation environment of LEO. Based on this initial materials selection, we have now performed a detailed study of the effects of temperature, atomic oxygen and vacuum UV radiation simulating low Earth orbit conditions on these two polymers. Both polymers exhibited diminished but very stable piezoelectric performance up to 130 C despite the upper use temperatures suggested by industry of 80 C (PVDF) and 100 C (P(VDF-TrFE)). We believe that the loss of piezoelectric response in samples conditioned at 130 C compared with non-exposed samples is partly due to the depoling process which occurs when the highly stressed films undergo contraction via relaxation. The TrFE copolymer, which does not need to be stretched for the polar phase to be present, has better retention of piezoelectric properties at 130 C compared with the highly oriented homopolymer. AO/VUV exposure caused significant surface erosion and pattern development for both polymers. Erosion yields were 2.8 x 10{sup -24} cm{sup 3}/atom for PVDF and 2.5 x 10{sup -24} cm{sup 3}/atom for P(VDF-TrFE). The piezoelectric properties of the residual material for both polymers were largely unchanged after exposure, although a slight shift in the Curie transition of the P(VDF-TrFE) was observed. A lightly crosslinked network was formed in the copolymer, presumably due to penetrating VUV radiation, while the homopolymer remained uncrosslinked. These differences were attributed to different levels of crystallinity and increased VUV absorption by P(VDF-TrFE) over PVDF. In this paper a summary of the performance limiting effects of temperature, radiation, atomic oxygen and VUV on the piezoelectric response of PVDF based polymers will be presented.

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Analysis of a distributed algorithm to determine multiple routes with path diversity in ad hoc networks

Mueller, Stephen M.

With multipath routing in mobile ad hoc networks (MANETs), a source can establish multiple routes to a destination for routing data. In MANETs, mulitpath routing can be used to provide route resilience, smaller end-to-end delay, and better load balancing. However, when the multiple paths are close together, transmissions of different paths may interfere with each other, causing degradation in performance. Besides interference, the physical diversity of paths also improves fault tolerance. We present a purely distributed multipath protocol based on the AODV-Multipath (AODVM) protocol called AODVM with Path Diversity (AODVM/PD) that finds multiple paths with a desired degree of correlation between paths specified as an input parameter to the algorithm. We demonstrate through detailed simulation analysis that multiple paths with low degree of correlation determined by AODVM/PD provides both smaller end-to-end delay than AODVM in networks with low mobility and better route resilience in the presence of correlated node failures.

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Results 84801–84900 of 96,771
Results 84801–84900 of 96,771