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An Inertial-Fusion Z-Pinch Power Plant Concept

Nuclear Fusion

Derzon, Mark S.; Rochau, Gary E.; Olson, Craig L.; Slutz, Stephen A.; Zamora, Antonio J.

With the promising new results of fast z-pinch technology developed at Sandia National Laboratories, we are investigating using z-pinch driven high-yield Inertial Confinement Fusion (ICF) as a fusion power plant energy source. These investigations have led to a novel fusion system concept based on an attempt to separate many of the difficult fusion engineering issues and a strict reliance on existing technology, or a reasonable extrapolation of existing technology, wherever possible. In this paper, we describe the main components of such a system with a focus on the fusion chamber dynamics. The concept works with all of the electrically-coupled ICF proposed fusion designs. It is proposed that a z-pinch driven ICF power system can be feasibly operated at high yields (1 to 30 GJ) with a relatively low pulse rate (0.01-0.1 Hz). To deliver the required current from the rep-rated pulse power driver to the z-pinch diode, a Recyclable Transmission Line (RTL) and the integrated target hardware are fabricated, vacuum pumped, and aligned prior to loading for each power pulse. In this z-pinch driven system, no laser or ion beams propagate in the chamber such that the portion of the chamber outside the RTL does not need to be under vacuum. Additionally, by utilizing a graded-density solid lithium or fluorine/lithium/beryllium eutectic (FLiBe) blanket between the source and the first-wall the system can breed its own fuel absorb a large majority of the fusion energy released from each capsule and shield the first-wall from a damaging neutron flux. This neutron shielding significantly reduces the neutron energy fluence at the first-wall such that radiation damage should be minimal and will not limit the first-wall lifetime. Assuming a 4 m radius, 8 m tall cylindrical chamber design with an 80 cm thick spherical FLiBe blanket, our calculations suggest that a 20 cm thick 6061-T6 Al chamber wall will reach the equivalent uranium ore radioactivity level within 100 years after a 30 year plant operation. The implication of this low radioactivity is that a z-pinch driven power plant may not require deep geologic waste storage.

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Statistical Properties of Antenna Impedance in an Electrically Large Cavity

IEEE Transactions on Antennas and Propagation

Warne, Larry K.; Hudson, H.G.; Johnson, William A.; Jorgenson, Roy E.; Stronach, Stephen L.

This paper presents models and measurements of antenna input impedance in resonant cavities at high frequencies.The behavior of input impedance is useful in determining the transmission and reception characteristics of an antenna (as well as the transmission characteristics of certain apertures). Results are presented for both the case where the cavity is undermoded (modes with separate and discrete spectra) as well as the over moded case (modes with overlapping spectra). A modal series is constructed and analyzed to determine the impedance statistical distribution. Both electrically small as well as electrically longer resonant and wall mounted antennas are analyzed. Measurements in a large mode stirred chamber cavity are compared with calculations. Finally a method based on power arguments is given, yielding simple formulas for the impedance distribution.

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Hexahedral Mesh Untangling

Engineering with Computers

Knupp, Patrick K.

We investigate a well-motivated mesh untangling objective function whose optimization automatically produces non-inverted elements when possible. Examples show the procedure is highly effective on simplicial meshes and on non-simplicial (e.g., hexahedral) meshes constructed via mapping or sweeping algorithms. The current whisker-weaving (WW) algorithm in CUBIT usually produces hexahedral meshes that are unsuitable for analyses due to inverted elements. The majority of these meshes cannot be untangled using the new objective function. The most likely source of the difficulty is poor mesh topology.

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Quantitative Temperature Imaging in Gas-Phase Turbulent Thermal Convection by Laser-Induced Fluorescence of Acetone

Kearney, Sean P.; Reyes, Felipe V.

In this paper, an acetone planar laser-induced fluorescence (PLIF) technique for nonintrusive, temperature imaging is demonstrated in gas-phase (Pr = 0.72) turbulent Rayleigh-Benard convection at Rayleigh number, Ra = 1.3 x 10{sup 5}. The PLIF technique provides quantitative, spatially correlated temperature data without the flow intrusion or time lag associated with physical probes and without the significant path averaging that plagues most optical heat-transfer diagnostic tools, such as the Mach-Zehnder interferometer, thus making PLIF an attractive choice for quantitative thermal imaging in easily perturbed, complex three-dimensional flow fields. The instantaneous (20-ns integration time) thermal images presented have a spatial resolution of 176 x 176 x 500 {micro}m and a single-pulse temperature measurement precision of {+-}5.5 K, or 5.4 % of the total temperature difference. These images represent a 2-D slice through a complex, 3-D flow allowing for the thermal structure of the turbulence to be quantified. Statistics such as the horizontally averaged temperature profile, rms temperature fluctuation, two-point spatial correlations, and conditionally averaged plume structures are computed from an ensemble of 100 temperature images. The profiles of the mean temperature and rms temperature fluctuation are in good agreement with previously published data, and the results obtained from the two-point spatial correlations and conditionally averaged temperature fields show the importance of large-scale coherent structures in this turbulent flow.

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Hall-Petch hardening in pulsed laser deposited nickel and copper thin films

Materials Research Society Symposium - Proceedings

Knapp, J.A.; Follstaedt, David M.; Banks, James C.; Myers, Samuel M.

Very fine-grained Ni and Cu films were formed using pulsed laser deposition onto fused silica substrates. The grain sizes in the films were characterized by electron microscopy, and the mechanical properties were determined by ultra-low load indentation, with finite-element modeling used to evaluate the properties of the layers separately from those of the substrate. Some Ni films were also examined after annealing to 350 and 450 °C to enlarge the grain sizes. These preliminary results show that the observed hardnesses are consistent with a simple extension of the Hall-Petch relationship to grain sizes as small as 11 nm for Ni and 32 nm for Cu.

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Analysis of Patent Databases Using VxInsight

Boyack, Kevin W.; Wylie, Brian N.; Davidson, George S.; Johnson, David L.

We present the application of a new knowledge visualization tool, VxInsight, to the mapping and analysis of patent databases. Patent data are mined and placed in a database, relationships between the patents are identified, primarily using the citation and classification structures, then the patents are clustered using a proprietary force-directed placement algorithm. Related patents cluster together to produce a 3-D landscape view of the tens of thousands of patents. The user can navigate the landscape by zooming into or out of regions of interest. Querying the underlying database places a colored marker on each patent matching the query. Automatically generated labels, showing landscape content, update continually upon zooming. Optionally, citation links between patents may be shown on the landscape. The combination of these features enables powerful analyses of patent databases.

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Diffusion Kinetics in the Pd/Cu(001) Surface Alloy

Physical Review Letters

Swartzentruber, Brian; Bartelt, Norman C.

We use atom-tracking scanning tunneling microscopy to study the diffusion of Pd in the Pd/Cu(001) surface alloy. By following the motion of individual Pd atoms incorporated in the surface, we show that Pd diffuses by a vacancy-exchange, mechanism. We measure an effective activation energy for the diffusion of incorporated Pd atoms of 0.88 eV, which is consistent with an ab initio calculated barrier of 0.94 eV.

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The Stimulation of Hydrocarbon Reservoirs with Subsurface Nuclear Explosions

Oil Industry History Journal

Lorenz, John C.

Between 1965 and 1979 there were five documented and one or more inferred attempts to stimulate the production from hydrocarbon reservoirs by detonating nuclear devices in reservoir strata. Of the five documented tests, three were carried out by the US in low-permeability, natural-gas bearing, sandstone-shale formations, and two were done in the USSR within oil-bearing carbonates. The objectives of the US stimulation efforts were to increase porosity and permeability in a reservoir around a specific well by creating a chimney of rock rubble with fractures extending beyond it, and to connect superimposed reservoir layers. In the USSR, the intent was to extensively fracture an existing reservoir in the more general vicinity of producing wells, again increasing overall permeability and porosity. In both countries, the ultimate goals were to increase production rates and ultimate recovery from the reservoirs. Subsurface explosive devices ranging from 2.3 to about 100 kilotons were used at depths ranging from 1208 m (3963 ft) to 2568 m (8427 ft). Post-shot problems were encountered, including smaller-than-calculated fracture zones, formation damage, radioactivity of the product, and dilution of the BTU value of tie natural gas with inflammable gases created by the explosion. Reports also suggest that production-enhancement factors from these tests fell short of expectations. Ultimately, the enhanced-production benefits of the tests were insufficient to support continuation of the pro-grams within increasingly adversarial political, economic, and social climates, and attempts to stimulate hydrocarbon reservoirs with nuclear devices have been terminated in both countries.

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Representation of Random Shock via the Karhunen Loeve Expansion

Paez, Thomas L.

Shock excitations are normally random process realizations, and most of our efforts to represent them either directly or indirectly reflect this fact. The most common indirect representation of shock sources is the shock response spectrum. It seeks to establish the damage-causing potential of random shocks in terms of responses excited in linear, single-degree-of-freedom systems. This paper shows that shock sources can be represented directly by developing the probabilistic and statistical structure that underlies the random shock source. Confidence bounds on process statistics and probabilities of specific excitation levels can be established from the model. Some numerical examples are presented.

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The Study of Phosphors Efficiency and Homogeneity using a Nuclear Microprobe

Doyle, B.L.

Ion Beam Induced Luminescence (IBIL) and Ion Beam Induced Charge Collection (IBICC) have been applied in the study of the luminescence emission efficiency and investigation of the homogeneity of the luminescence emission in phosphors. The IBIL imaging was performed by using sharply focused ion beams or broad/partially-focused ion beams. The luminescence emission homogeneity in samples was examined to reveal possible distributed crystal-defects that may lead to the inhomogeneity of the luminescence emission in samples.The purpose of the study is to search for suitable luminescent thin films that have high homogeneity of luminescence emission, large IBIL efficiency under heavy ion excitation, and can be placed as a thin layer on the top of microelectronic devices to be analyzed with Ion Photon Emission Microscopy (IPEM). The emission yield was found to be low for organic materials, due to saturation of the light output dependence on the energy deposition of heavy ions. The emission yield of a typical Bicron plastic scintillator is about 70 photons/ion/micron. Inorganic materials may have higher IBIL yield under high-energy and heavy-ion excitation, but the challenging problem is the inhomogeneity of the IBIL emission. The IBIL image techniques are applied in the investigation of the homogeneity of a GaN epitaxial thin film, a zircon single crystal and a thin layer coated by Thiogallate(EuII) ceramic.

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Experimental Results on Statistical Approaches to Page Replacement Policies

Leung, Vitus J.

This paper investigates the questions of what statistical information about a memory request sequence is useful to have in making page replacement decisions: Our starting point is the Markov Request Model for page request sequences. Although the utility of modeling page request sequences by the Markov model has been recently put into doubt, we find that two previously suggested algorithms (Maximum Hitting Time and Dominating Distribution) which are based on the Markov model work well on the trace data used in this study. Interestingly, both of these algorithms perform equally well despite the fact that the theoretical results for these two algorithms differ dramatically. We then develop succinct characteristics of memory access patterns in an attempt to approximate the simpler of the two algorithms. Finally, we investigate how to collect these characteristics in an online manner in order to have a purely online algorithm.

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The Xyce Parallel Electronic Simulator - An Overview

Hutchinson, Scott A.; Keiter, Eric R.; Hoekstra, Robert J.; Watts, Herman A.; Waters, Lon J.; Schells, Regina L.; Wix, Steven D.

The Xyce{trademark} Parallel Electronic Simulator has been written to support the simulation needs of the Sandia National Laboratories electrical designers. As such, the development has focused on providing the capability to solve extremely large circuit problems by supporting large-scale parallel computing platforms (up to thousands of processors). In addition, they are providing improved performance for numerical kernels using state-of-the-art algorithms, support for modeling circuit phenomena at a variety of abstraction levels and using object-oriented and modern coding-practices that ensure the code will be maintainable and extensible far into the future. The code is a parallel code in the most general sense of the phrase--a message passing parallel implementation--which allows it to run efficiently on the widest possible number of computing platforms. These include serial, shared-memory and distributed-memory parallel as well as heterogeneous platforms. Furthermore, careful attention has been paid to the specific nature of circuit-simulation problems to ensure that optimal parallel efficiency is achieved even as the number of processors grows.

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Recent Advances in AC-DC Transfer Measurements Using Thin-Film Thermal Converters

Wunsch, Thomas F.; Manginell, Ronald; Solomon, Otis M.

New standards for ac current and voltage measurements, thin-film multifunction thermal converters (MJTCS), have been fabricated using thin-film and micro-electro-mechanical systems (MEMS) technology. Improved sensitivity and accuracy over single-junction thermoelements and targeted performance will allow new measurement approaches in traditionally troublesome areas such as the low frequency and high current regimes. A review is presented of new microfabrication techniques and packaging methods that have resulted from a collaborative effort at Sandia National Laboratories and the National Institute of Standards and Technology (MHZ).

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Optical spectroscopy of ingan epilayers in the low indium composition regime

Materials Research Society Symposium - Proceedings

Crawford, M.H.; Han, J.; Banas, M.A.; Myers, Samuel M.; Peterscn, G.A.; Figiel, Jeffrey J.

Photoluminescence (PL) spectroscopy was carried out on a series of Si-doped bulk InGaN films in the low indium (In) composition regime. Room temperature PL showed a factor of 25 increase in integrated intensity as the In composition was increased from 0 to 0.07. Temperature dependent PL data was fit to an Arrhenius equation to reveal an increasing activation energy for thermal quenching of the PL intensity as the In composition is increased. Time resolved PL measurements revealed that only the sample with highest In ( x=0.07) showed a strong spectral variation in decay time across the T=4K PL resonance, indicative of recombination from localized states at low temperatures. The decay times at room temperature were non-radiatively dominated for all films, and the room temperature (non-radiative) decay times increased with increasing In, from 50-230 psec for x=0-0.07. Our data demonstrate that non-radiative recombination is less effective with increasing In composition. © 2000 Materials Research Society.

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On the late-time behavior of tracer test breakthrough curves

Water Resources Research

Mckenna, Sean A.; Meigs, Lucy C.

We investigated the late-time (asymptotic) behavior of tracer test breakthrough curves (BTCs) with rate-limited mass transfer (e.g., in dual-porosity or multiporosity systems) and found that the late-time concentration c is given by the simple expression c = tad{c0g - [m0(∂g/∂t)]}, for t ≫ tad and tα ≫ tad, where tad is the advection time, c0 is the initial concentration in the medium, m0 is the zeroth moment of the injection pulse, and tα is the mean residence time in the immobile domain (i.e., the characteristic mass transfer time). The function g is proportional to the residence time distribution in the immobile domain; we tabulate g for many geometries, including several distributed (multirate) models of mass transfer. Using this expression, we examine the behavior of late-time concentration for a number of mass transfer models. One key result is that if rate-limited mass transfer causes the BTC to behave as a power law at late time (i.e., c ̃ t-k), then the underlying density function of rate coefficients must also be a power law with the form αk-3 as α → 0. This is true for both density functions of first-order and diffusion rate coefficients. BTCs with k < 3 persisting to the end of the experiment indicate a mean residence time longer than the experiment, and possibly an infinite residence time, and also suggest an effective rate coefficient that is either undefined or changes as a function of observation time. We apply our analysis to breakthrough curves from single-well injection-withdrawal tests at the Waste Isolation Pilot Plant, New Mexico. We investigated the late-time (asymptotic) behavior of tracer test breakthrough curves (BTCs) with rate-limited mass transfer (e.g., in dual-porosity or multiporosity systems) and found that the late-time concentration c is given by the simple expression c = tad{c0g - [m0(∂g/∂t)]}, for t ≫ tad and tα ≫ t ad, where tad is the advection time, c0 is the initial concentration in the medium, m0 is the zeroth moment of the injection pulse, and tα is the mean residence time in the immobile domain (i.e., the characteristic mass transfer time). The function g is proportional to the residence time distribution in the immobile domain; we tabulate g for many geometries, including several distributed (multirate) models of mass transfer. Using this expression, we examine the behavior of late-time concentration for a number of mass transfer models. One key result is that if rate-limited mass transfer causes the BTC to behave as a power law at late time (i.e., c t-k), then the underlying density function of rate coefficients must also be a power law with the form αk-3 as α → 0. This is true for both density functions of first-order and diffusion rate coefficients. BTCs with k < 3 persisting to the end of the experiment indicate a mean residence time longer than the experiment, and possibly an infinite residence time, and also suggest an effective rate coefficient that is either undefined or changes as a function of observation time. We apply our analysis to breakthrough curves from single-well injection-withdrawal tests at the Waste Isolation Pilot Plant, New Mexico.

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Null-steering viewpoint of interferometric SAR

International Geoscience and Remote Sensing Symposium (IGARSS)

Bickel, Douglas L.

Interferometric synthetic aperture radar (IFSAR) extends the two-dimensional imaging capability of traditional synthetic aperture radar to three-dimensions by using an aperture in the elevation plane to estimate the 3-D structure of the target. The operation of this additional aperture can be viewed from a null-steering point of view rather than the traditional phase determination point of view. Knowing that IFSAR can be viewed from the null-steering perspective allows us to take advantage of the mathematical foundation developed for null-steering arrays. In addition, in some problems of interest in IFSAR the null-steering perspective provides better intuition and suggests alternative solutions. One example is the problem of estimating building height where layover is present.

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Properties of low residual stress silicon oxynitrides used as a sacrificial layer

Materials Research Society Symposium - Proceedings

Habermehl, Scott D.; Glenzinski, A.K.; Halliburton, W.M.; Sniegowski, Jeffry J.

Low residual stress silicon oxynitride thin films are investigated for use as a replacement for silicon dioxide (SiO2) as sacrificial layer in surface micromachined microelectrical-mechanical systems (MEMS). It is observed that the level of residual stress in oxynitrides is a function of the nitrogen content in the film. MEMS film stacks are prepared using both SiO2 and oxynitride sacrificial layers. Wafer bow measurements indicate that wafers processed with oxynitride release layers are significantly flatter. Polycrystalline Si (poly-Si) cantilevers fabricated under the same conditions are observed to be flatter when processed with oxynitride rather than SiO2 sacrificial layers. These results are attributed to the lower post-processing residual stress of oxynitride compared to SiO2.

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Selective W for coating and releasing MEMS devices

Materials Research Society Symposium - Proceedings

Mani, Seethambal; Fleming, J.G.; Sniegowski, Jeffry J.; De Boer, Maarten P.; Irwin, L.W.; Walraven, Jeremy; Tanner, Danelle M.; La Van, D.A.

Two major problems associated with Si-based MEMS (MicroElectroMechanical Systems) devices are stiction and wear. Surface modifications are needed to reduce both adhesion and friction in micromechanical structures to solve these problems. In this paper, we will present a CVD (Chemical Vapor Deposition) process that selectively coats MEMS devices with tungsten and significantly enhances device durability. Tungsten CVD is used in the integrated-circuit industry, which makes this approach manufacturable. This selective deposition process results in a very conformal coating and can potentially address both stiction and wear problems confronting MEMS processing. The selective deposition of tungsten is accomplished through the silicon reduction of WF6. The self-limiting nature of this selective. We deposition process ensures the consistency necessary for process control. The tungsten is deposited after the removal of the sacrificial oxides to minimize stress and process integration problems. Tungsten coating adheres well and is hard and conducting, requirements for device performance. Furthermore, since the deposited tungsten infiltrates under adhered silicon parts and the volume of W deposited is less than the amount of Si consumed, it appears to be possible to release stuck parts that are contacted over small areas such as dimples. The wear resistance of selectively coated W parts has been shown to be significantly improved on microengine test structures.

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Development of one-equation transition / turbulence models (AIAA Paper 2000-0133)

38th Aerospace Sciences Meeting and Exhibit

Roy, Christopher J.; Blottner, Frederick G.

This paper reports on the development of a unified,one-equation model for the prediction of transitional and turbulent flows. An eddy viscosity - transport equation for nonturbulent fluctuation growth based on that proposed by Warren and Hassan (Journal of Aircraft, Vol. 35, No. 5) is combined with the Spalart-Allmaras one-equation model for turbulent fluctuation growth. Blending of the two equations is accomplished through a multidimensional intermittency function based on the work of Dhawan and Narasimha (Journal of Fluid Mechanics, Vol. 3, No. 4). The model predicts both the onset and extent of transition. Lowspeed test cases include transitional flow over a Aat plate, a single element airfoil, and a multielement airfoil in landing configuration. Highspeed test cases include transitional Mach 3.5 flow over a 5° cone and Mach 6 flow over a flaredcone configuration. Results are compared with experimental data, and the grid-dependence of selected predictions is analyzed. © 1999 by the American Institute of Aeronautics and Astronautics, Inc. All rights reserved.

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Torsional ratcheting actuating system

2000 International Conference on Modeling and Simulation of Microsystems - MSM 2000

Barnes, Stephen M.; Miller, Samuel L.; Rodgers, M.S.; Bitsie, Fernando

A new type of surface micromachined ratcheting actuation system has been developed at the Microelectronics Development Laboratory at Sandia National Laboratories. The actuator uses a torsional electrostatic comb drive that is coupled to an external ring gear through a ratcheting scheme. The actuator can be operated with a single square wave, has minimal rubbing surfaces, maximizes comb finger density, and can be used for open-loop position control. The prototypes function as intended with a minimum demonstrated operating voltage of 18V. The equations of motion are developed for the torsional electrostatic comb drive. The resonant frequency, voltage vs. displacement and force delivery characteristics are predicted and compared with the fabricated device's performance.

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Laser injection optics for high-intensity transmission in multimode fibers

Proceedings of SPIE - The International Society for Optical Engineering

Setchell, Robert E.

An increasing number of applications are requiring fiber transmission of high-intensity laser pulses. Our particular interests have led us to examine carefully the fiber transmission of Q-switched pulses from multimode Nd:YAG lasers at their fundamental wavelength. The maximum pulse energy that can be transmitted through a particular fiber is limited by the onset of laser-induced breakdown and damage mechanisms. Laser breakdown at the fiber entrance face is often the first limiting process to be encountered, but other mechanisms can result in catastrophic damage at either fiber face, within the initial `entry' segment of the fiber, and at other internal sites along the fiber path. In the course of our studies we have examined a number of factors that govern the relative importance of different mechanisms, including laser characteristics, the design and alignment of injection optics, fiber end-face preparation, and fiber routing. The present study emphasizes the important criteria for injection optics in high-intensity fiber transmission, and illustrates the opportunities that now exist for innovative designs of optics to meet these criteria. Our consideration of diffractive optics to achieve desired injection criteria began in 1993, and we have evaluated a progression of designs since that time. In the present study, two recent designs for injection optics are compared by testing a sufficient number of fibers with each design to establish statistics for the onset of laser-induced breakdown and damage. In this testing we attempted to hold constant other factors that can influence damage statistics. Both designs performed well, although one was less successful in meeting all injection criteria and consequently showed a susceptibility to a particular damage process.

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SEM/EDX spectrum imaging and statistical analysis of a metal/ceramic braze

Materials Research Society Symposium - Proceedings

Kotula, Paul G.; Keenan, Michael R.

Energy dispersive x-ray (EDX) spectrum imaging has been performed in a scanning electron microscope (SEM) on a metal/ceramic braze to characterize the elemental distribution near the interface. Statistical methods were utilized to extract the relevant information (i.e., chemical phases and their distributions) from the spectrum image data set in a robust and unbiased way. The raw spectrum image was over 15 Mbytes (7500 spectra) while the statistical analysis resulted in five spectra and five images which describe the phases resolved above the noise level and their distribution in the microstructure. © 2001 Materials Research Society.

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Computational fluid dynamics modeling of proton exchange membrane fuel cells

Journal of the Electrochemical Society

Chen, Ken S.

A transient, multidimensional model has been developed to simulate proton exchange membrane fuel cells. The model accounts simultaneously for electrochemical kinetics, current distribution, hydrodynamics, and multicomponent transport. A single set of conservation equations valid for flow channels, gas-diffusion electrodes, catalyst layers, and the membrane region are developed and numerically solved using a finite-volume-based computational fluid dynamics technique. The numerical model is validated against published experimental data with good agreement. Subsequently, the model is applied to explore hydrogen dilution effects in the anode feed. The predicted polarization curves under hydrogen dilution conditions are in qualitative agreement with recent experiments reported in the literature. The detailed two-dimensional electrochemical and flow/transport simulations further reveal that in the presence of hydrogen dilution in the fuel stream, hydrogen is depleted at the reaction surface, resulting in substantial anode mass transport polarization and hence a lower current density that is limited by hydrogen transport from the fuel stream to the reaction site. Finally, a transient simulation of the cell current density response to a step change in cell voltage is reported.

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Oxidative alteration of spent fuel in a silica-rich environment: SEM/AEM investigation and geochemical modeling

Materials Research Society Symposium - Proceedings

Wang, Yifeng

Correctly identifying the possible alteration products and accurately predicting their occurrence in a repository-relevant environment are the key for source-term calculations in a repository performance assessment. Uraninite in uranium deposits has long been used as a natural analog to spent fuel in a repository because of their chemical and structural similarity. In this paper, a SEM/AEM investigation has been conducted on a partially alterated uraninite sample from a uranium ore deposit of Shinkolobwe of Congo. The mineral formation sequences were identified: uraninite→uranyl hydrates→uranyl silicates→Ca-uranyl silicates or uraninite→uranyl silicates→Ca-uranyl silicates. Reaction-path calculations were conducted for the oxidative dissolution of spent fuel in a representative Yucca Mountain groundwater. The predicted sequence is in general consistent with the SEM observations. The calculations also show that uranium carbonate minerals are unlikely to become major solubility-controlling mineral phases in a Yucca Mountain environment. Some discrepancies between model predictions and field observations are observed. Those discrepancies may result from poorly constrained thermodynamic data for uranyl silicate minerals.

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Thermodynamic stability of actinide pyrochlore minerals in deep geologic repository environments

Materials Research Society Symposium - Proceedings

Wang, Yifeng

Crystalline phases of pyrochlore (e.g., CaPuTi2O7, CaUTi2O7) have been proposed as a durable ceramic waste form for disposal of high level radioactive wastes including surplus weapons-usable plutonium. In this paper, we use a linear free energy relationship to predict the Gibbs free energies of formation of pyrochlore phases (CaMTi2O7). The Pu-pyrochlore phase is predicted to be stable with respect to PuO2, CaTiO3, and TiO2 at room temperatures. Pu-pyrochlore is expected to be stable in a geologic repository where silica and carbonate components are absent or limited. We suggest that a repository in a salt formation be an ideal environment for disposal of high level, pyrochlore-based ceramic wastes. In such environment, adding CaO as a backfill will make pyrochlore minerals thermodynamically stable and therefore effectively prevents actinide release from these mineral phases.

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On the influence of applied fields on spinel formation

Materials Research Society Symposium - Proceedings

Michael, Joseph R.

Interfaces play an important role in determining the effect of electric fields on the mechanism of the formation of spinel by solid-state reaction. The reaction occurs by the movement of phase boundaries but the rate of this movement can be affected by grain boundaries in the reactants or in the reaction product. Only by understanding these relationships will it be possible to engineer their behavior. As a particular example of such a study, MgIn2O4 can be formed by the reaction between single-crystal MgO substrate and a thin film of In2O3 with or without an applied electric field. High-resolution backscattered electron (BSE) imaging and electron backscattered diffraction (EBSD) in a scanning electron microscope (SEM) has been used to obtain complementary chemical and crystallographic information.

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Semiconductor e-h plasma lasers

Conference Digest - IEEE International Semiconductor Laser Conference

Zutavern, Fred J.; Baca, Albert G.; Chow, Weng W.; Hafich, Michael J.; Hjalmarson, Harold P.; Loubriel, Guillermo M.; Mar, Alan; O'Malley, Martin W.; Vawter, Gregory A.

A new class of semiconductor lasers that can potentially produce much more short pulse energy is presented. This new laser is not limited in volume or aspect ratio by the depth of a p-n junction and are created from current filaments in semi-insulating GaAs. A current filament semiconductor lasers (CFSL) that have produced 75 nJ of 890 nm radiation in 1.5 ns were tested. A filaments as long as 3.4 cm and several hundred microns in diameter in high gain GaAs photoconductive switches were observed. Their smallest dimension can be more than 100 times the carrier diffusion length in GaAs. The spectral narrowing, lasing thresholds, beam divergence, temporal narrowing and energies which imply lasing for several configurations of CFSL are reported.

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Failure analysis of tungsten coated polysilicon micromachined microengines

Proceedings of SPIE - The International Society for Optical Engineering

Walraven, Jeremy; Mani, Seethambal; Fleming, J.G.; Headley, Thomas J.; Kotula, Paul G.; Pimentel, Alejandro A.; Rye, Michael J.; Tanner, Danelle M.; Smith, Norman F.

Failure analysis (FA) tools have been applied to analyze tungsten coated polysilicon microengines. These devices were stressed under accelerated conditions at ambient temperatures and pressure. Preliminary results illustrating the failure modes of microengines operated under variable humidity and ultra-high drive frequency will also be shown. Analysis of tungsten coated microengines revealed the absence of wear debris in microengines operated under ambient conditions. Plan view imaging of these microengines using scanning electron microscopy (SEM) revealed no accumulation of wear debris on the surface of the gears or ground plane on microengines operated under standard laboratory conditions. Friction bearing surfaces were exposed and analyzed using the focused ion beam (FIB). These cross sections revealed no accumulation of debris along friction bearing surfaces. By using transmission electron microscopy (TEM) in conjunction with electron energy loss spectroscopy (EELS), we were able to identify the thickness, elemental analysis, and crystallographic properties of tungsten coated MEMS devices. Atomic force microscopy was also utilized to analyze the surface roughness of friction bearing surfaces.

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High-power single mode operation of hybrid ion-implanted/selectively-oxidized VCSELs

Conference Proceedings - Lasers and Electro-Optics Society Annual Meeting-LEOS

Hadley, G.R.; Choquette, Kent D.; Fischer, Arthur J.; Geib, Kent M.; Allerman, A.A.; Hindi, J.J.

One method of providing the mode selectivity necessary to insure single mode operation in a large diameter VCSEL is to independently control the size of the gain region and that of the optical mode. Numerical simulations quantity this approach by predicting lateral mode discrimination for different sized gain apertures. Calculations are experimentally confirmed by the fabrication and testing of 850 nm VCSELs employing hybrid ion implantation/selective oxidation that produce a single-mode output of more than 5 mW.

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Paul Bunyan's brachistochrone and tautochrone

Advances in the Astronautical Sciences

Hurtado, John E.

In this paper we concern ourselves with modified versions of the traditional brachistochrone and tautochrone problems. In the modified version of each problem the constant gravity model is replaced with an attractive inverse square law, consequently we name these the 1/r2 brachistochrone and 1/r2 tautochrone problems. With regard to the 1/r2 brachistochrone problem, we show that the shape of the minimizing curve is formally constructed from an infinite series of elliptic integrals, and we use a numerical optimal control technique to generate the trajectories. The 1/r2 tautochrone problem is solved using fractional calculus techniques and we show that the solution satisfies Lagrange's rule for tautochronous curves.

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Electrostatic discharge/electrical overstress susceptibility in MEMS: A new failure mode

Proceedings of SPIE - The International Society for Optical Engineering

Walraven, Jeremy; Soden, Jerry M.; Tanner, Danelle M.; Tangyunyong, Paiboon; Colr, Edward I.; Anderson, Richard E.; Irwin, Lloyd W.

Electrostatic discharge (ESD) and electrical overstress (EOS) damage of Micro-Electro-Mechanical Systems (MEMS) has been identified as a new failure mode. This failure mode has not been previously recognized or addressed primarily due to the mechanical nature and functionality of these systems, as well as the physical failure signature that resembles stiction. Because many MEMS devices function by electrostatic actuation, the possibility of these devices not only being susceptible to ESD or EOS damage but also having a high probability of suffering catastrophic failure due to ESD or EOS is very real. Results from previous experiments have shown stationary comb fingers adhered to the ground plane on MEMS devices tested in shock, vibration, and benign environments. Using Sandia polysilicon microengines, we have conducted tests to establish and explain the ESD/EOS failure mechanism of MEMS devices. These devices were electronically and optically inspected prior to and after ESD and EOS testing. This paper will address the issues surrounding MEMS susceptibility to ESD and EOS damage as well as describe the experimental method and results found from ESD and EOS testing. The tests were conducted using conventional IC failure analysis and reliability assessment characterization tools. In this paper we will also present a thermal model to accurately depict the heat exchange between an electrostatic comb finger and the ground plane during an ESD event.

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Application of TIVA in Design Debug

Conference Proceedings from the International Symposium for Testing and Failure Analysis

Colr, Edward I.

Thermally-Induced Voltage Alteration (TIVA) is a relatively new technique for locating electrical defects in integrated circuits [1,2]. This paper describes a novel application of TIVA, to locate design anomalies. A newly designed integrated circuit with high and inconsistent Quiescent Power Supply Current (IDDQ) was initially diagnosed with limited success using various failsite isolation techniques. The TIVA technique was successful in accurately locating design anomalies. Results from TIVA identified a spurious ring oscillator in the design. Design modifications carried out using a focussed ion beam (FIB), verified the accuracy of the results from TIVA. This study clearly extends the use of TIVA beyond that of locating electrical defects and anomalies into the realm of design debugging.

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Origins of total-dose response variability in linear bipolar microcircuits

IEEE Transactions on Nuclear Science

Shaneyfelt, Marty R.

LM111 voltage comparators exhibit a wide range of total-dose-induced degradation. Simulations show this variability may be a natural consequence of the low base doping of the substrate PNP (SPNP) input transistors. Low base doping increases the SPNPs collector to base breakdown voltage, current gain, and densities. The build-up of oxide trapped charge (N OT) and interface traps (N IT) is shown to be a function of pre-irradiation bakes. Experimental data indicate that, despite its structural similarities to the LM111, irradiated input transistors of the LM124 operational amplifier do not exhibit the same sensitivity to variations in pre-irradiation thermal cycles. Further disparities in LM111 and LM124 responses may result from a difference in the oxide defect build-up in the two part types. Variations in processing, packaging, and circuit effects are suggested as potential explanations.

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5.2 mW single-mode power from a coupled-resonator vertical-cavity laser

Conference Proceedings - Lasers and Electro-Optics Society Annual Meeting-LEOS

Fischer, Arthur J.; Choquette, Kent D.; Chow, Weng W.; Allerman, A.A.; Geib, Kent M.

A record high fundamental-mode power of 5.1 mW was achieved from coupled-resonator vertical-cavity lasers (CRVCLs). In conventional VCSELs, the extent to which the gain volume may be increased is limited by the onset of multi-mode operation. Results indicate that this limitation is circumvented in a coupled-resonator device allowing high power fundamental-mode operation.

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Risk assessment methodology for protecting our critical physical infrastructures

Risk-Based Decisionmaking in Water Resources IX

Biringer, Betty E.; Danneels, Jeffrey J.

Critical infrastructures are central to our national defense and our economic well being, but many are taken for granted. Presidential Decision Directive (PDD) 63 highlights the importance of eight of our critical infrastructures and outlines a plan for action. Greatly enhanced physical security systems will be required to protect these national assets from new and emerging threats. Sandia National Laboratories has been the lead laboratory for the Department of Energy (DOE) in developing and deploying physical security systems for the past twenty-five years. Many of the tools, processes, and systems employed in the protection of high-consequence facilities can be adapted to the civilian infrastructure.

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The development of confidence limits for fatigue strength data

2000 ASME Wind Energy Symposium

Sutherland, Herbert J.; Veers, Paul S.

Over the past several years, extensive databases have been developed for the S-N behavior of various mate&& used in wind turbine blades, primarily fiberglass composites. These data are typically presented both in their "raw" form and curve fit to define their average properties. For design, confidence limits must be placed on these descriptions. In particular, most designs call for the "95195" design values; namely, with a 95 percent level of confidence, thedesiguerisassuredthat95percentofthematerial will 'meet or exceed the design value. For such material properties as the ultimate streng& the procedures for estimating its value at a particular confidence level is wellffiedifthemeasured values follow a normal or a log-normal distribution. Namely, based upon the number of sample points and their standard deviation, a commonly-found table may be used to determine the survival percentagea t a particular confidencel evel with respect to its mean value. The same is true for fatigue data at a constaut stress level (the number of cycles to failure N at stress level SI). However, when the stress level is allowed to vary, as with a typical S-N fatigue curve, the proceduresf or determmingc onfidencel imits are not as well delked. This paper outlines techn.iques for determimng confklence limits of fatigue data Different approachesto estimating the 95195l evel are compared. Data from the MSUIDOE and the FACT fatigue databam are used to illustrate typical results.

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Lattice location of deuterium in plasma and gas charged Mg doped GaN

Materials Research Society Symposium - Proceedings

Wampler, William R.; Barbour, J.C.; Seager, Carleton H.; Myers, Samuel M.; Wright, Alan F.; Han, J.

We have used ion channeling to examine the lattice configuration of deuterium in Mg doped GaN grown by MOCVD. The deuterium is introduced by exposure to gas phase or ECR plasmas. A density functional approach including lattice relaxation, was used to calculate total energies for various locations and charge states of hydrogen in the wurtzite Mg doped GaN lattice. Results of channeling measurements are compared with channeling simulations for hydrogen at lattice locations predicted by density functional theory. © 2000 Materials Research Society.

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Electron backscatter diffraction: A powerful tool for phase identification in the SEM

Materials Research Society Symposium - Proceedings

Michael, Joseph R.; Goehner, Raymond P.

EBSD in the SEM has been developed into a tool that can provide identification of unknown crystalline phases with a spatial resolution that is better than one micrometer. This technique has been applied to a wide range of materials. Use of the HOLZ rings in the EBSD patterns has enabled the reduced unit cell to be determined from unindexed EBSD patterns. This paper introduces EBSD for phase identification and illustrates the technique with examples from metal joining and particle analysis. Reduced unit cell determination from EBSD patterns is then discussed. © 2001 Materials Research Society.

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Friction measurement in MEMS using a new test structure

Materials Research Society Symposium - Proceedings

De Boer, Maarten P.; Redmond, James M.; Michalske, Terry A.

A MEMS test structure capable of measuring friction between polysilicon surfaces under a variety of test conditions has been refined from previous designs. The device is applied here to measuring friction coefficients of polysilicon surfaces under different environmental, loading, and surface conditions. Two methods for qualitatively comparing friction coefficients (μ) using the device are presented. Samples that have been coated with a self-assembled monolayer of the lubricating film perfluorinated-decyltrichlorosilane (PFTS) have a coefficient of friction that is approximately one-half that of samples dried using super-critical CO2 (SCCO2) drying. Qualitative results indicate that μ is independent of normal pressure. Wear is shown to increase μ for both supercritically dried samples and PFTS coated samples, though the mechanisms appear to be different. Super critically dried surfaces appear to degrade continuously with increased wear cycles, while PFTS coated samples reach a steady state friction value after about 105 cycles.

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Pulsed Power Peer Review Committee Report

Bloomquist, Douglas D.

In 1993, the Government Performance and Results Act (GPRA, PL 103-62) was enacted. GPRA, which applies to all federal programs, has three components: strategic plans, annual performance plans, and metrics to show how well annual plans are being followed. As part of meeting the GRPA requirement in FY2000, a 14-member external peer review panel (the Garwin Committee) was convened on May 17-19, 2000 to review Sandia National Laboratories' Pulsed Power Programs as a component of the Performance Appraisal Process negotiated with the Department of Energy (DOE). The scope of the review included activities in inertial confinement fission (ICF), weapon physics, development of radiation sources for weapons effects simulation, x-ray radiography, basic research in high energy density physics (HEDP), and pulsed power technology research and development. In his charge to the committee, Jeffrey Quintenz, Director of Pulsed Power Sciences (1600) asked that the review be based on four criteria (1) quality of science, technology, and engineering, (2) programmatic performance, management, and planning, (3) relevance to national needs and agency missions, and (4) performance in the operation and construction of major research facilities. In addition, specific programmatic questions were posed by the director and by the DOE-Defense Programs (DP). The accompanying report, produced as a SAND document, is the report of the committee's findings.

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Results 90501–90550 of 99,299
Results 90501–90550 of 99,299