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Modeling gravity-driven fingering in rough-walled fractures using modified percolation theory

Glass, R.J.

Pore scale invasion percolation theory is modified for imbibition of.wetting fluids into fractures. The effects of gravity, local aperture field geometry, and local in-plane air/water interfacial curvatureare included in the calculation of aperture filling potential which controls wetted structure growth within the fracture. The inclusion of gravity yields fingers oriented in the direction of the gravitational gradient. These fingers widen and tend to meander and branch more as the gravitational gradient decreases. In-plane interfacial curvature also greatly affects the wetted structure in both horizontal and nonhorizontal fractures causing the formation of macroscopic wetting fronts. The modified percolation model is used to simulate imbibition into an analogue rough-walled fracture where both fingering and horizontal imbibition experiments were previously conducted. Comparison of numerical and experimental results showed reasonably good agreement. This process oriented physical and numerical modeling is-a necessary step toward including gravity-driven fingering in models of flow and transport through unsaturated, fractured rock.

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Investigation of fracture-matrix interaction: Preliminary experiments in a simple system

Foltz, S.D.; Tidwell, V.C.; Glass, R.J.; Sobolik, S.R.

Paramount to the modeling of unsaturated flow and transport through fractured porous media is a clear understanding of the processes controlling fracture-matrix interaction. As a first step toward such an understanding, two preliminary experiments have been performed to investigate the influence of matrix imbibition on water percolation through unsaturated fractures in the plane normal to the fracture. Test systems consisted of thin slabs of either tuff or an analog material cut by a single vertical fracture into which a constant fluid flux was introduced. Transient moisture content and solute concentration fields were imaged by means of x-ray absorption. Flow fields associated with the two different media were significantly different owing to differences in material properties relative to the imposed flux. Richards` equation was found to be a valid means of modeling the imbibition of water into the tuff matrix from a saturated fracture for the current experiment.

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Recent developments in stochastic modeling and upscaling of hydrologic properties in tuff

Rautman, Christopher A.

A set of detailed geostatistical simulations of porosity has been produced for a layered stratigraphic sequence of welded and nonwelded volcanic tuffs at Yucca Mountain, Nevada. The simulations are produced using a composite. model of spatial continuity and they are highly conditioned to abundant drill hole (core) information. A set of derivative simulations of saturated hydraulic conductivity has been produced, in the absence of conditioning data, using a cross-variable relationship developed from similar data elsewhere. The detailed simulations reproduce both the major stratigraphic units and finer scale layering indicated by the drill hole data. These simulations have been scaled up several order of magnitude to represent block-scale effective hydrologic properties suitable for use in numerical modeling of groundwater flow and transport. The upscaling process involves the reformulation of a previously reported method that iteratively adapts an initial arbitrary grid to ``homogenize`` the detailed hydraulic properties contained within the adjusted cell limits and to minimize the size of cell in highly heterogeneous regions. Although the computation of the block-effective property involves simple numerical averaging, the blocks over which these averages are computed are relatively homogeneous, which reduces the numerical difficulties involved in averaging non-additive properties, such as permeability. The entire process of simulation and upscaling is rapid and computationally efficient compared with alterative techniques. It is thus suitable for the Monte Carlo evaluation of the uncertainty in site characterization as it affects the results of groundwater flow and transport calculations.

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Influence of deterministic geologic trends on spatial variability of hydrologic properties in volcanic tuff

Rautman, Christopher A.

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Rock mass mechanical property estimation strategy for the Yucca Mountain Site Characterization Project

Bauer, Stephen

This paper presents a method of estimating the rock mass properties for the welded and nonwelded tuffs based on currently available information on intact rock and joint characteristics at the Yucca Mountain site. Variability of the expected ground conditions at the potential repository horizon (the TSw2 thermomechanical unit) and in the Calico Hills nonwelded tuffs is accommodated by defining five rock mass quality categories in each unit based upon assumed and observed distributions of the data.

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Is it possible to demonstrate compliance with the regulations for high-level-waste repositories?

Bingham, F.W.

The regulations that currently govern repositories for spent fuel and high-level waste require demonstrations that are sometimes described as impossible to make. To make them will require an understanding of the current and the future phenomena at repository sites; it will also require credible estimates of the probabilities that the phenomena will occur in the distant future. Experts in many fields{emdash}earth sciences, statistics, numerical modeling, and the law{emdash}have questioned whether any amount of data collection can allow modelers to meet these requirements with enough confidence to satisfy the regulators. In recent years some performance assessments have begun to shed light on this question because they use results of actual site investigations. Although these studies do not settle the question definitively, a review of a recent total-system assessment suggests that compliance may be possible to demonstrate. The review also suggests, however, that the demonstration can be only at the ``reasonable`` levels of assurance mentioned, but not defined, in the regulations.

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Characterization of porosity in support of mechanical property analysis

Price, Ronald H.

Previous laboratory investigations of tuff have shown that porosity has a dominant, general effect on mechanical properties. As a result, it is very important for the interpretation of mechanical property data that porosity is measured on each sample tested. Porosity alone, however, does not address all of the issues important to mechanical behavior. Variability in size and distribution of pore space produces significantly different mechanical properties. A nondestructive technique for characterizing the internal structure of the sample prior to testing is being developed and the results are being analyzed. The information obtained from this technique can help in both qualitative and quantitative interpretation of test results.

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Instrumentation requirements for the ESF thermomechanical experiments

Pott, John

In situ thermomechanical experiments are planned as part of the Yucca Mountain Site Characterization Project that require instruments to measure stress and displacement at temperatures that exceed the typical specifications of existing geotechnical instruments. A high degree of instrument reliability will also be required to satisfy the objectives of the experiments, therefore a study was undertaken to identify areas where improvement in instrument performance was required. A preliminary list of instruments required for the experiments was developed, based on existing test planning and analysis. Projected temperature requirements were compared to specifications of existing instruments to identify instrumentation development needs. Different instrument technologies, not currently employed in geotechnical instrumentation, were reviewed to identify potential improvements of existing designs for the high temperature environment. Technologies with strong potentials to improve instrument performance with relatively high reliability include graphite fiber composite materials, fiber optics, and video imagery.

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Sensitivity analyses for total-system performance assessment

Wilson, M.L.

As a follow-on to Sandia`s 1991 preliminary total-system performance assessment of the Yucca Mountain site, this paper presents results of some sensitivity analyses that were done using results from the 1991 study. Two conceptual models of unsaturated-zone flow and transport at Yucca Mountain were included in the study, including both aqueous and gaseous releases. The sensitivities are quite different for the two models. For the composite-porosity model, the results are most sensitive to groundwater percolation flux, gaseous transport time, container lifetime, and fuel-matrix-alteration rate. For the weeps model, the results are most sensitive to parameters used to characterize fracture flow (fracture aperture and fracture connectivity) and infiltration (percolation flux and weep-episode factor).

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A working definition of scenario and a method of scenario construction

Barr, George E.

The event-tree method of scenario construction has been chosen for the Yucca Mountain performance assessment. Its applicability and suitability to the problem are discussed and compared with those of the Nuclear Regulatory Commission (NRC) method. The event-tree method is appropriate for an incompletely characterized site, where there must be an evolving understanding, over time, of the processes at work, for a site that may require analysis of details in specific context, and when the scenario functions to guide site characterization. Anticipating the eventual requirement for using the NRC method, we show that the event-tree method can be translated to the NRC format after final scenario screening.

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Chemical vapor deposition sciences

Ho, Pauline H.

Chemical vapor deposition (CVD) is a widely used method for depositing thin films of a variety of materials. Applications of CVD range from the fabrication of microelectronic devices to the deposition of protective coatings. New CVD processes are increasingly complex, with stringent requirements that make it more difficult to commercialize them in a timely fashion. However, a clear understanding of the fundamental science underlying a CVD process, as expressed through computer models, can substantially shorten the time required for reactor and process development. Research scientists at Sandia use a wide range of experimental and theoretical techniques for investigating the science of CVD. Experimental tools include optical probes for gas-phase and surface processes, a range of surface analytic techniques, molecular beam methods for gas/surface kinetics, flow visualization techniques and state-of-the-art crystal growth reactors. The theoretical strategy uses a structured approach to describe the coupled gas-phase and gas-surface chemistry, fluid dynamics, heat and mass transfer of a CVD process. The software used to describe chemical reaction mechanisms is easily adapted to codes that model a variety of reactor geometries. Carefully chosen experiments provide critical information on the chemical species, gas temperatures and flows that are necessary for model development and validation. This brochure provides basic information on Sandia`s capabilities in the physical and chemical sciences of CVD and related materials processing technologies. It contains a brief description of the major scientific and technical capabilities of the CVD staff and facilities, and a brief discussion of the approach that the staff uses to advance the scientific understanding of CVD processes.

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Aging and condition monitoring of Class 1E cables

Jacobus, M.J.

This paper presents a brief summary of condition monitoring results from an NRC-sponsored test program on aging, condition monitoring, and accident testing of Class 1E cables. In addition, since the program has been completed and the final reports have been published, this paper presents a list of references, along with abstracts for each reference. This list can serve as a guide for finding references to any desired information on the test program in varying levels of detail. The major conclusions of the test program with regard to condition monitoring were as follows: (a) of the parameters tested, elongation at break had the best correlation with aging for the most cable types; (b) hardness and indenter modulus (performed using the cable indenter developed under Electric Power Research Institute (EPRI) sponsorship) measurements both increased with aging for some of the materials, especially the jacket materials, and the modulus measurements were significantly more sensitive to aging than the hardness measurements; (c) where indenter modulus was sensitive to aging, it was most sensitive in the later stages of aging, after the elongation had reached nearly 0%; (d) density generally increased with aging for most materials, but some changes were inconsistent; and (e) with only a few exceptions, tensile strength and a number of different electrical measurements did not correlate well with aging.

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Comparison of predicted far-field temperatures for discrete and smeared heat sources

Ryder, Eric E.

A fundamental concern in the design of the potential repository at Yucca Mountain. Nevada is the response of the host rock to the emplacement of heat-generating waste. The thermal perturbation of the rock mass has implications regarding the structural, hydrologic. and geochemical performance of the potential repository. The phenomenological coupling of many of these performance aspects makes repository thermal modeling a difficult task. For many of the more complex, coupled models, it is often necessary to reduce the geometry of the potential repository to a smeared heat-source approximation. Such simplifications have impacts on induced thermal profiles that in turn may influence other predicted responses through one- or two-way thermal couplings. The effect of waste employment layout on host-rock thermal was chosen as the primary emphasis of this study. Using a consistent set of modeling and input assumptions, far-field thermal response predictions made for discrete-source as well as plate source approximations of the repository geometry. Input values used in the simulations are consistent with a design-basis a real power density (APD) of 80 kW/acre as would be achieved assuming a 2010 emplacement start date, a levelized receipt schedule, and a limitation on available area as published in previous design studies. It was found that edge effects resulting from general repository layout have a significant influence on the shapes and extents of isothermal profiles, and should be accounted for in far-field modeling efforts.

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Stress relaxation of braze joints

American Society of Mechanical Engineers, EEP

Stephens, J.J.; Burchett, S.N.; Jones, W.B.

Calculations of residual stresses in braze joints are required to validate designs for a variety of metal/ceramic joining applications. In particular, finite element analysis (FEA) codes have the capability of incorporating either elastic-plastic or minimum creep rate constitutive models for the braze material. This paper presents both elevated temperature mechanical properties correlations for the eutectic Ag-Cu alloy, along with FEA results which use this data in calculating residual stresses in a generic metal/ceramic ``shear'' type braze joint. Three constitutive relations have been developed for eutectic Ag-Cu alloy: (i) an elastic/plastic correlation incorporating temperature-dependent yield stress and work hardening data, (ii) a high temperature minimum creep rate correlation with a temperature-dependent stress exponent and (iii) a minimum creep rate correlation using the Garofalo hyperbolic sine (sinh) equation. FEA calculations are presented for a eutectic Ag-Cu braze joint between metallized alumina ceramic and either Fe-29Ni-17Co or Fe-27Ni-25Co alloys using the three different constitutive relations for the brazement. The two creep correlations, since they are time-dependent, permit a study of the effect of various cooldown cycles on the maximum residual stress in the alumina ceramic. For the cooldown profiles studied in this paper, lower residual stresses are predicted in the ceramic-relative to the elastic-plastic model - when either of the two creep models are used as the constitutive law for the eutectic Ag-Cu braze joint. A second important result is that the simulations which incorporate the Fe-29-Ni-17Co alloy show higher peak stresses than the Fe-27Ni-25Co alloy at 420°C, along with much lower peak stresses compared to Fe-27Ni-25Co alloy at room temperature. The reason for this somewhat surprising behavior can be understood in terms of the coefficient of thermal expansion for the two Fe-Ni-Co alloys.

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Control of photoluminescence from porous silicon

Nanotechnology

Barbour, J.C.

A description of ion-irradiation-induced reduction in the photoluminescence (PL) signal from porous silicon is given and a simple model which is consistent with a nanocrystalline Si structure is presented. Ion irradiation with 250 keV Ne is used to controllably reduce the integrated PL signal by 20% after a fluence of 4*1012 Ne cm-2 and completely eliminate the PL signal after a fluence of 4*1013 Ne cm-2. The use of vacuum and air annealing to recover ion-induced damage is also described, but the high temperatures for annealing cause elimination of the PL signal.

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Observations of the shock response of specific piezo resistive accelerometers

Proceedings, Annual Technical Meeting - Institute of Environmental Sciences

Benham, R.A.; Duggins, B.D.

Pyro shock loads are generated in many missile or rocket systems when stages are separated or shrouds are removed. These shocks are localized, of short rise time (10's of ns) and of very high stress level. This paper will document some anomalous behavior that occurs when pyro shock accelerometers (Endevco 7270A) are exposed to levels of high frequency shock that is higher than the manufacturer's recommended limits. Such shocks occur in many pyro shock events. Standard, accepted recording techniques can produce totally erroneous data with no obvious indicator that the data is in error. Wide band data recording, along with Fourier Analysis of the data, and dynamic analysis, made by the gage manufacturer of the transducer, allow recognition of some of the non-standard response modes excited but no method of quantifying the corrupted data has been developed. Wide band recording, which will preserve the data in the gage resonance range and above, are required to insure understanding of these pyro shock events.

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Calibration of CR-39 for detecting fusion neutrons

Review of Scientific Instruments

Leeper, Ramon J.

We have measured the efficiency (tracks per incident neutron) of pure CR-39 for detecting DD and DT neutrons. Neutrons having average energies of 2.9 MeV (DD) and 14.8 MeV (DT) were produced by a 200-keV electrostatic accelerator and the neutron yields were measured using the associated particle counting technique. All CR-39 samples irradiated by DD or DT neutrons were etched for 2 h in a 70°, 6.25-N- NaOH bath. For bare CR-39, the efficiencies for detecting 2.9- and 14.8-MeV neutrons were found to be (1.3±0.4)×10 -4 and (5.0±1.8)×10-5, respectively. We also investigated using CR-39 and polyimide as proton radiators. For detecting 2.9-MeV neutrons, the radiators had no significant effect on efficiency; but for detecting 14.8-MeV neutrons the polyimide radiator increased the efficiency to (7.8±2.8)×10-5.

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Absolute calibration of a total yield indium activation detector for DD and DT neutrons

Review of Scientific Instruments

Ruiz, Carlos L.

Progress in Z-pinch experiments at Sandia's Saturn facility have underscored a need for an absolute yield measurement for DD fusion neutrons. The technique chosen for making this absolute yield measurement was neutron activation of indium metal samples. To calibrate the technique, a 175-keV deuteron beam was allowed to impinge on a 3.0-μm-thick erbium deuteride target, producing neutrons through the 2H(d,n)3He fusion reaction. The neutron flux produced at 0° and incident on nominal 5-g indium samples was determined by the associated particle method. This method employed protons measured from the 2H(d,p)3H reaction to infer the neutron flux produced. After neutron irradiation, the activity of the indium samples was measured with a Ge gamma-ray detector. The total activity of the metastable state 115mIn (336.23 keV) was measured, compared with the total incident flux, and a calibration factor (indium counts/neutron/gram of indium) determined. For completeness, a calibration factor for DT neutrons from the 3H(d,n)4He fusion reaction was also obtained through the measured activity of the metastable state 114mIn(190.29 keV). The experiment and the measured calibration factors for both reactions are described in the paper.

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Range and straggling effects on CR-39/range-filter ion energy measurements

Review of Scientific Instruments

Bailey, James E.

The CR-39/range-filter technique measures ion energy by determining the maximum filter thickness which ions can penetrate. CR-39 located behind the filter records the ions. This method is used to measure peak voltage in pulsed power accelerators. We investigated range and straggling effects in this diagnostic by exposing it to 8- and 15-MeV protons for both Al and Ta filters. The range agreed with published values to better than ±6%. The range straggling decreased for higher incident ion energy and lower atomic number, as expected, although there were differences up to a factor of 1.7 between the experimental values and predictions. The dependence of the track diameter distribution on ion energy enabled us to establish a signature which is characteristic of ions which penetrate a filter, via straggling. These results can be used to evaluate the errors present when this diagnostic is used to measure accelerator voltage.

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Proton beam targets shot on PBFA-II

Review of Scientific Instruments

Wiemann, Dora K.

In recent proton beam experiments on PBFA-II, foam-filled gold targets and gas-filled spherical exploding pushers were shot as physics targets. Surrounding these targets were gold foils used to characterize the beam. The target fabrication and characterization are presented in this paper.

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Cautions in using x-ray measurements derived from broad spectral response functions to determine the peak voltage of flash bremsstrahlung sources

Review of Scientific Instruments

Fehl, David L.

Because a direct measurement of the voltage (V) in pulsed power bremsstrahlung sources can be difficult, the energy spectrum of x rays emitted is sometimes used to infer V. Both the voltage and current in such sources vary with time. Moreover, for modern x-ray simulators with multiple cathodes, multiple voltages may exist simultaneously. We demonstrate here how such sources lead to systematic errors in several types of simple-to-field x-ray voltage measurements, especially those with broad spectral response functions, when calibrated against constant-potential bremsstrahlung spectra.

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Spectroscopic characterization of LEVIS active ion source on PBFA II

Beams 92 - Proceedings of the 9th International Conference on High-Power Particle Beams

Filuk, A.B.

The laser-initiated LEVIS source is intended to provide an active source in the PBFA II ion diode by generation of a preformed lithium anode plasma. Visible spectra recorded with a streaked spectrograph are used to help evaluate the source performance. The absence of Stark shifting of the Li I 2p-3d and 2s-2p light confirms that a plasma is created over the anode surface. At lower LEVIS laser intensities this plasma erodes back toward the anode as the ion beam current grows. Considerable improvements in anode plasma purity have been noted when the anode is heated for several hours. The LEVIS source microdivergence estimated from the carbon ion transverse energy is less than 14 mrad, meeting the near term requirements for PBFA II target experiments. © 1992 National Technical Information Service.

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Summary of results from the TEXTOR helium self-pumping experiment

Journal of Nuclear Materials

Doyle, Barney L.

Helium removal experiments were conducted in TEXTOR with a small helium self-pumping module located in a modified ALT-I limiter head. The module contained two heated nickel alloy trapping plates, a nickel deposition filament array, a Langmuir probe, flux probe, and thermocouples. The experiment examined plasma helium removal via trapping of helium ions in the deposited nickel surfaces. Such helium removal was successfully observed, with about 10% of the helium in a 10% He/D plasma being removed in a ∼1 s period. The module was found to be compatible with overall tokamak operation with essentially no sputtered nickel entering the core plasma. The temperature rise on the ion-exposed inner trapping plate, during a plasma shot, is consistent with a local sheath potential of ∼3kTe. Post-tokamak test examination of the trapping plates shows helium atom concentrations in the deposited nickel consistent with the observed helium removal, and shows very small D concentrations. © 1992 Elsevier Science Publishers B.V. All rights reserved.

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Operation of a high impedance applied-B extraction ion diode on the SABRE positive polarity linear induction accelerator

Beams 92 - Proceedings of the 9th International Conference on High-Power Particle Beams

Hanson, D.L.; Cuneo, M.E.; Mckay, P.F.; Maenchen, J.E.; Coats, R.S.; Poukey, J.W.; Rosenthal, S.E.; Fowler, W.E.; Wenger, D.F.; Bernard, M.; Chavez, J.R.; Stearns, W.F.

We present results from initial experiments with a high impedance applied-B extraction diode on the SABRE ten stage linear induction accelerator (6 MV, 300 kA). We have demonstrated efficient coupling of power from the accelerator through an extended MTTL (Magnetically Insulated Transmission Line) into a high intensity ion beam. Both MITL electron flow in the diode region and ion diode behavior, including ion source turn-on, virtual cathode formation and evolution, enhancement delay, and ion coupling efficiency, are strongly influenced by the geometry of the diode insulating magnetic field. For our present diode electrode geometry, electrons from the cathode feed play a large role in the evolution of the virtual cathode. Both experimental data and particle-in-cell numerical simulations show that a uniform radial distribution of these feed electrons is required for uniform ion emission and efficient diode operation. © 1992 National Technical Information Service.

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Laser formation of lithium plasma ion sources for applied-B ion diodes on the PBFA-II accelerator

Beams 92 - Proceedings of the 9th International Conference on High-Power Particle Beams

Tisone, G.C.; Renk, T.J.; Johnson, D.J.; Gerber, R.A.; Adams, R.G.

An active ion source, LEVIS (Laser Evaporation Ion Source), using a short pulsed Nd laser (1.06 m, 8ns) to form a thin Li vapor layer and a tuned dye laser (670.8nm, μsec) for ionization is being developed at Sandia. The LEVIS process has been developed and characterized in the laboratory. Initial experiments using these ion sources on PBFA-II produced ion beams with a low fraction of lithium ions and with low voltages. Recent experiments using improved distribution optics and anode cleaning techniques are described. © 1992 National Technical Information Service.

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Progress in lithium beam focusing and beam-target interaction experiments at Sandia National Laboratories

Beams 92 - Proceedings of the 9th International Conference on High-Power Particle Beams

Mehlhorn, Thomas A.

Significant progress in the generation and focusing of ion beams generated by PBFA-II has enabled us to begin experiments in ion beam coupling and target physics. Data from these experiments indicates that we can reproducibly deliver 50 KJ of 5 MeV protons at an average power intensity of 3.5 TW/cm 2 to a 6 mm diameter by 6 mm tall cylindrical target. The implosion of spherical exploding pusher targets and the radiation production from foam-filled cylindrical thermal targets were studied in these experiments. They demonstrated that high quality target data can be obtained on PBFA-II. Specific deposition rates of about 100 TW/g were achieved in these experiments. This deposition rate marks the boundary between the regime where enhanced ion deposition and equation-of-state (EOS) physics are studied (10-100 TW/g) and the regime where radiation-conversion and radiation-transport physics are studied (100-1000 TW/g). Experiments in the radiation-conversion regime are now of primary importance in our program because these experiments will test the target physics basis for ion-driven ICE Experiments using a thin film LiF source have produced an intensity of 1 TW/cm 2 of lithium ions. This beam has a potential specific deposition rate of 300-400 TW/g in hydrocarbon foams. However, radiation conversion experiments will require an increased total energy content of this beam in order to overcome the specific internal energy of the foam. Further increases in ion beam intensity and energy content are being pursued in a multi-pronged attack. Understanding and controlling ion beam divergence is the highest program priority. Present understanding indicates that instabilities in the electron sheath cause significant ion beam divergence. Our understanding suggests that this contribution to the ion divergence can be decreased by operating the diode at a low enhancement through the use of high applied magnetic fields or by modifying the electron distribution near the anode via electron limiters. The new 9 cm radius Compact Diode has the capability of generating 8 T applied magnetic fields which will enable divergence experiments in the low-enhancement, high-B regime. Experiments with the LEVIS (Laser Evaporation Ion Source) lithium source have demonstrated the existence of a preformed plasma, as determined by visible-emission spectroscopy of the anode plasma. Work on improving lithium purity with this source is in progress. This active anode plasma will be used in experiments testing the effectiveness of electron limiters in controlling ion beam divergence. We are also working to understand the interrelation between accelerator coupling, diode physics, and ion beam focusing in order to optimize the diode configuration to maximize the power intensity on target. Success in these experiments will provide an adequate lithium beam for performing target experiments exploring radiation conversion and radiation transport physics in ion-driven ICF. © 1992 National Technical Information Service.

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A five-channel, diamond photoconducting x-ray detector array for z-pinch experiments

Review of Scientific Instruments

Spielman, Rick

We have built a five-channel, x-ray detector array based on diamond photoconducting detectors (PCDs). The diamond elements have dimensions of 3 mm × 1 mm × 1 mm (or 0.5 mm). We use diamond PCDs for their stability, flat spectral response, and low leakage currents. The good time response of diamond PCDs is due to the 100-ps electron/hole recombination time. Filters were designed to give information in the 1-10-keV spectral region. Calibration of the diamond PCDs showed sensitivities between 4 and 7 × 10-4 A/W for a bias of 100 V. We shall present data from z-pinch experiments on Saturn.

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Numerical simulations of steel plate perforation

American Society of Mechanical Engineers, Pressure Vessels and Piping Division (Publication) PVP

Chen, Er-Ping

Numerical simulations of perforation in steel plates involve the treatment of material failure during the perforation process. One way to model physical material separation is to delete failed elements from the analysis based on an appropriate failure criterion. Different algorithms were used in different transient finite element codes to delete failed elements. This investigation compares the results of PRONTO 2D and LS-DYNA2D codes for a specific steel plate perforation problem. Influences of the deletion algorithms on material parameters are discussed.

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Thermodynamically consistent theories for elastoplasticity coupled with damage

American Society of Mechanical Engineers, Applied Mechanics Division, AMD

Hansen, Ned R.

A framework for coupled elastoplastic and damage theories is developed, following a rigorous thermodynamic procedure. This framework is sufficiently general to include anisotropic plasticity and damage formulations. Both the plastic yield and damage functions are constructed using homogeneous functions of degree one. The principle of maximum dissipation or maximum entropy production is used to derive the evolution relations together with the loading and unloading conditions. In addition, the convexity of the undamaging elastic domain is shown. For plasticity the resulting evolution of the plastic strains corresponds to an associative flow. This general framework is shown to be sufficiently general to describe several popular theories for both plasticity and damage. Limitations of some existing damage theories are discussed.

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Bifurcations in elastic-damaging materials

American Society of Mechanical Engineers, Applied Mechanics Division, AMD

Neilsen, Michael K.

Continuum damage theories describe the progressive reduction in stiffness and strength of brittle materials resulting from the initiation and growth of microcracks and microvoids. When brittle materials are loaded into the nonlinear regime, they often exhibit localized zones of intense deformation and the eventual formation of macrocracks. Criteria for diffuse and discontinuous bifurcations have previously been developed and used to study the initiation of necking and localization in elastic-plastic materials. In this investigation, the same bifurcation criteria are applied to continuum damage theories. Since the bifurcation criteria depend on the fourth-order tangent modulus tensor, the first step in this investigation is the derivation of the tangent modulus tensor for a general continuum damage theory. An eigenanalysis of the symmetric part of the tangent modulus tensor is then shown to fully characterize the potential diffuse and discontinuous bifurcations associated with a given continuum damage theory.

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Results from the US/USSR exchange for heat load material studies of simulated disruptions

Journal of Nuclear Materials

Mcdonald, Jimmie M.

The motivation behind exchange I.2 of the USSR/US exchange program of cooperation for magnetic confinement fusion is to more closely simulate tokamak disruptions with a variety of plasma devices within the Soviet Union and the United States and to characterize the effect these simulated disruptions have on candidate PFC materials. Earlier work conducted in the Soviet Union by a team of Soviet and American researchers showed ablation of graphites exposed to a disruption like heat flux from a plasma flow was significantly less than that previously expected [J.M. Gahl et al., Proc. ICFRM-5, J. Nucl. Mater. 191-194 (1992) 454]. Work has continued and results from recent work at the University of New Mexico are in general agreement with earlier results from the Soviet Union. New results from work in the United States and the Soviet Union will be presented. © 1992 Elsevier Science Publishers B.V. All rights reserved.

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Decision making under uncertainty: An investigation into the application of formal decision-making methods to safety issue decisions

Bohn, M.P.

As part of the NRC-sponsored program to study the implications of Generic Issue 57, Effects of Fire Protection System Actuation on Safety-Related Equipment,'' a subtask was performed to evaluate the applicability of formal decision analysis methods to generic issues cost/benefit-type decisions and to apply these methods to the GI-57 results. In this report, the numerical results obtained from the analysis of three plants (two PWRs and one BWR) as developed in the technical resolution program for GI-57 were studied. For each plant, these results included a calculation of the person-REM averted due to various accident scenarios and various proposed modifications to mitigate the accident scenarios identified. These results were recomputed to break out the benefit in terms of contributions due to random event scenarios, fire event scenarios, and seismic event scenarios. Furthermore, the benefits associated with risk (in terms of person-REM) averted from earthquakes at three different seismic ground motion levels were separately considered. Given this data, formal decision methodologies involving decision trees, value functions, and utility functions were applied to this basic data. It is shown that the formal decision methodology can be applied at several different levels. Examples are given in which the decision between several retrofits is changed from that resulting from a simple cost/benefit-ratio criterion by virtue of the decision-makinger's expressed (and assumed) preferences.

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Manufacturing technology: A Sandia Technology Bulletin, November 1992

Leonard, J.A.; Floyd, H.L.; Parrott, L.; Goetsch, B.; Doran, L.

This issue describes several innovative technologies in modern manufacturing. Methods in which the HIRCIS sensor may cut costs in precision machining are described. Computer models and experimental methods aid in the chemical vapor deposition of high-temperature coatings. Shared computer networks provide communication for interactive collaboration. Sol-gel processing of tailored thin films furnish low cost, high quality glass coatings at room temperature. Integrated circuit characterization tools and expertise are available to improve quality and reliability in the microelectronic industry.

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E-beam radiolysis for oil spill clean up

Patterson, E.L.; Jackson, N.B.; Thornberg, S.M.; Samlin, G.E.

This paper describes preliminary experiments to investigate electron-beam radiolysis of model compounds appropriate for crude oil spills on water or soil. Since no previous work in this area is known to exist, the rate of destruction of such concentrated organic materials in aqueous media is not known. The experiments conducted here were designed to provide preliminary estimates of the destruction rate and the estimated costs. Samples of model compounds were irradiated to dose levels up to 700 Mrad (H{sub 2}0) and the change in chemical composition was determined by mass spectrometry/gas chromatography and Fourier transform infrared spectroscopy. It was found that a dose of 700 Mrads reduced the liquid volume of the model compound by 60% and that the major effect of irradiation was the formation of long chain alkanes and dimethyl and ethyl benzenes. Under certain conditions a solid polymer was found to form. When alcohol was present in the model compound, additional products included small quantities of ethane diodic acid, butanol, butanediol, and various other alcohols. Further research is recommended to obtain a better analysis of the products, better values for the destruction rates, and better understanding of dose rate effects.

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A review of the experience gained in 10 years operation of Gould`s solar industrial process heat system

Knipfer, D.C.; Menicucci, D.

For nearly 10 years, the Gould Electronics, Incorporated manufacturing plant in Chandler, Arizona, has been a model of how medium-temperature solar thermal energy systems can produce economical industrial process heat (IPH). In 1982, a solar IPH system was designed and built on the site by Solar Kinetics, Inc. The system has remained in operation and continues to provide economical process heat for Gould`s copper foil manufacturing operation. System performance and availability has fluctuated over the years, reaching a low point in early 1990 when the system was nearly inoperative because of equipment reliability problems. Gould teamed with engineers from Sandia National Laboratories` (Sandia) Solar Thermal Design Assistance Center to develop a plan to solve the technical problems and refurbish the field. The IPH system is currently operating at over 90-percent equipment availability, returning to Gould a net energy cost savings on the order of $7,500 per month. This paper presents the history and operation of the system from the perspective of the end user and describes the phased upgrade program undertaken with Sandia to refurbish the system.

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A modal test of a space-truss for structural parameter identification

Carne, Thomas G.

The Jet Propulsion Laboratory is developing a large space-truss to support a micro-precision interferometer. A finite element model will be used to design and place passive and active elements in the truss to suppress vibration. To improve the model`s predictive capability, it is desirable to identify uncertain structural parameters in the model by utilizing experimental modal data. Testing of both the components and the system was performed to obtain the data necessary to identify the structural parameters. Extracting a modal model, absent of bias errors, from measured data requires great care in test design and implementation. Testing procedures that are discussed include: verification of non-constraining shaker attachment, quantification of the non-linear structural response, and the design and effects of suspension systems used to simulate a free structure. In addition to these procedures, the accuracy of the measured frequency response functions are evaluated by comparing functions measured with random excitation, using various frequency resolutions, and with step sine excitation.

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PVDF water-shock pressure transducer with 200-ns response

Johnson, D.E.; Hogeland, S.R.; Nelson, L.S.

The design, calibration, and preliminary test results for an underwater shock gauge are presented. The active element is a 25-{mu}m thick polyvinylidene fluoride shock sensor providing rise times as short as 50 ns. Fast rise time is essential to accurate recording of shock pulses with durations of only a few microseconds. The piezoelectric polymer provides a self-generating pressure sensor requiring neither amplification nor additional active electronic circuitry. The gauge package is designed to minimize electromagnetic interference from the high-voltage fire set used to power the exploding bridge wire pressure source. The gauge package is constructed to withstand the initial water shock as well as subsequent reactions in the water that result in strong water motion and bubble generation. Thin-film diaphragm sensors are not sturdy enough to withstand this environment. Initial tests show that the gauge responds in 200 ns in water and that low-frequency response is sufficient to allow recording for at least 40 {mu}s after the initial shock arrival.

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Network storage service usage characteristics

Haynes, R.A.

Performance and functionality increases in network environments have in the need for readily accessible mass storage. UNIX{reg_sign}-based networks and mass storage systems are providing the required connectivity and interoperability, however, how UNIX-based mass storage systems are being used is not well documented. This paper describes a study of the usage of the UNIX-based Network Storage Service at Sandia National Laboratories.

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Momentum transfer from flowing explosive gases to spherical particles during computer simulation of blasting-induced rock motion

Preece, Dale S.

A discrete element computer program, DMC (Distinct-Motion Code), has been used for several years to simulate blasting-induced rock motion. Recent enhancements of DMC`s capabilities have included addition of an algorithm that couples together rock motion and gas flow. This allows the user to specify a particular explosive which also specifies equation-of-state and other parameters necessary to model explosive gas flow from the blastwell. Rock loading by the flowing gas is calculated automatically. The mechanism for calculating the rock loading is the subject of this paper. The rock motion effects the gas flow calculation by changing the porosity. DMC is currently being used on a SLTN SPARCstation 2 computer workstation.

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Effects of simulated storage on the solder wettability of inhibited substrates

Hosking, F.M.; Sorensen, N.R.

Solder wettability of Class II environmentally exposed Cu substrates coated with an organic solderability preservative (OSP) is being investigated. The OSP coatings slightly retarded the wetting behavior of 60Sn-40Pb solder during baseline testing of unaged coupons. A nominal increase in wetting angle, or decrease in wettability, was observed on the inhibited surfaces, particularly when less active fluxes were used. Small increases in the wetting time and decreases in the wetting rate were also measured. Simulated accelerated aging tests are underway to determine the effects of aging in a typical indoor industrial environment on the solder wettability of OSP coated Cu.

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A guide to Division 2000`s capabilities and expertise in component development and engineering support

Dellin, Theodore A.

Sandia operated by AT&T for the US Department of Energy. Sandia has a billion dollar annual budget and over 8,000 employees. Sandia`s main sites are in Albuquerque, New Mexico; Livermore, California; and Tonopah, Nevada. Sandia has a broad base of engineering and scientific skills that supports the whole product cycle from advanced R&D through manufacturing and end-user support. Sandia`s original mission was to develop the non-nuclear portion of nuclear weapons. In the 1970s, the mission was expanded to include technical work on conventional and alternative energy sources. Recently, the mission was further expanded to include technology transfer and US competitiveness. This report describes the activities in the Component Development and Engineering Support Division 2000 (indicated by the bold lines on the organization chart). Division 2000 develops electrical, electronic, optical, explosive, mechanical, and other components that are the core products of Sandia systems. The Division also develops advanced capabilities in CAD/CAE, test, nondestructive test, programming, reliability, failure analysis, and simulation that are part of the core services required by Sandia systems. For each of the core products and services described in this brochure, there is a corresponding set of science and engineering capabilities that are Sandia`s core competencies. Also, there are systems groups that use these core products and services to develop ultra-reliable systems for Sandia`s customers. Most of these groups have literature available describing their capabilities and expertise.

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Risk evaluation for a General Electric BWR, effects of fire protection system actuation on safety-related equipment

Lambright, J.

Nuclear power plants have experienced actuations of fire protection systems (FPSs) under conditions for which these systems were not intended to actuate. They have also experienced advertent actuations with the presence of a fire. These actuations have often damaged nearby plant equipment. A review of past occurrences of both types of such events on nuclear power plant safety has been performed. Thirteen different scenarios leading to actuation of fire protection systems due to a variety of causes were identified. These scenarios range from inadvertant actuation caused by human errors to hardware failures and include seismic root causes and seismic/fire interactions. A quantification of these thirteen scenarios, where applicable, was performed on a BWR4/MKI. This report estimates the contribution of FPS actuations to core damage frequency and to risk.

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Geochemical Evaluation (Room G): In situ data report, December 1984-- November 1990. Waste Isolation Pilot Plant (WIPP) Thermal/Structural Interactions Program

Munson, Darrell E.

Data are presented from the Geomechanical Evaluation (first phase), a very large scale in situ test fielded underground at the Waste Isolation Pilot Plant (WIPP). These data include selected fielding information, test configuration, instrumentation activities, and comprehensive results from a large number of gages. Construction of the test began in December 1984 and the test has been in operation since that time; gage data in this report cover the period from December 1984 through November 1990.

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Evaluation of Generic Issue 57: Effects of fire protection system actuation on safety-related equipment. Volume 2, Appendices A, B, and C

Lambright, J.

Nuclear power plants have experienced actuations of fire protection systems (FPSs) under conditions for which these systems were not intended to actuate and also have experienced advertent actuations with the presence of a fire. These actuations have often damaged safety-related equipment. A review of the impact of past occurrences of both types of such events and their impact on plant safety systems, an analysis of the risk impacts of such events on nuclear power plant safety, and a cost-benefit analysis of potential corrective measures have been performed. Thirteen different scenarios leading to actuation of fire protection systems due to a variety of causes were identified. These scenarios ranged from inadvertent actuation caused by human error to hardware failure, and include seismic root causes and seismic/fire interactions. A quantification of these thirteen root causes, where applicable, was performed on generically applicable scenarios. This document, Volume 2, contains appendices A,B, and C of this report.

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Risk evaluation for a Westinghouse PWR, effects of fire protection systems actuation on safety-related equipment. Evaluation of Generic Issue 57

Lambright, J.

Nuclear power plants have experienced actuations of fire protection systems (FPSs) under conditions for which these systems were not intended to actuate and also have experienced advertent actuations with the presence of a fire. These actuations have often damaged nearby plant equipment. A review of the impact of past occurrences of both types of such events, a quantification of the risk of FPS actuation, a sensitivity study of the quantification of the risk of FPS actuation and risk calculations in terms of person-REM have been performed. Thirteen different scenarios leading to actuation of fire protection systems due to a variety of causes were identified. A quantification of these thirteen scenarios, where applicable, was performed on a 3-loop Westinghouse Pressurized water Reactor (PWR). These scenarios ranged from inadvertent actuation caused by human error to hardware failures, and include seismic root causes and seismic/fire interaction. This report estimates the contribution of FPS actuations to core damage frequency and risk.

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VICTORIA: A mechanistic model of radionuclide behavior in the reactor coolant system under severe accident conditions. Revision 1

Heams, T.J.

The VICTORIA model of radionuclide behavior in the reactor coolant system (RCS) of a light water reactor during a severe accident is described. It has been developed by the USNRC to define the radionuclide phenomena and processes that must be considered in systems-level models used for integrated analyses of severe accident source terms. The VICTORIA code, based upon this model, predicts fission product release from the fuel, chemical reactions involving fission products, vapor and aerosol behavior, and fission product decay heating. Also included is a detailed description of how the model is implemented in VICTORIA, the numerical algorithms used, and the correlations and thermochemical data necessary for determining a solution. A description of the code structure, input and output, and a sample problem are provided.

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Brine inflow sensitivity study for Waste Isolation Pilot Plant boreholes: Results of one-dimensional simulations

Webb, Stephen W.

Brine inflow to the Waste Isolation Pilot Plant is important in assessing the performance of the repository, and a mechanistic model is needed for performance calculations. Brine inflow experiments are being conducted, and formation parameters such as the permeability and diffusivity are inferred from these data using a simplified one-dimensional radial, uniform property, single-phase Darcy flow model. This model has met with limited success in interpreting some of the recent data. Much of the data could not be satisfactorily fit with the above model because the brine inflow rate increases with time, so a more mechanistic model is being developed based on the TOUGH and TOUGH2 computer codes. These codes are much more complex than the simplified model and include a number of parameters that have not been measured. Therefore, a one-dimensional brine inflow sensitivity study has been undertaken to evaluate the importance of a number of these parameters in influencing the behavior of brine inflow to open boreholes. In addition, two-phase conditions have been included in the study, and the sensitivity of gas inflow rates and the formation pressure and saturation distributions after 1 year are examined. These results should be helpful in determining what additional measurements are necessary to assist in the development of a more mechanistic brine inflow model.

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Precision Linear Shaped Charge designs for severance of aluminum materials

Vigil, Manuel G.

The Precision Linear Shaped Charge (PLSC) design concept involves the independent fabrication and assembly of the liner (wedge of PLSC), the tamper/confinement, and explosive. The liner is the most important part of an LSC and should be fabricated by a more quality controlled, precise process than the tamper material. Also, this concept allows the liner material to be different from the tamper material. The explosive can be loaded between the liner and tamper as the last step in the assembly process rather than the first step as in conventional LSC designs. PLSC designs are shown to produce increased jet penetrations in given targets, more reproducible jet penetration, and more efficient explosive cross sections using a minimum amount of explosive. The Linear Explosive Shaped Charge Analysis (LESCA) code developed at SandiaNational Laboratories has been used to assist in the design of PLSCs. LESCA predictions for PLSC jet penetration in aluminum targets, jet tip velocities and jet-target impact angles are compared to measured data.

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Local lightning early warning system (LLEWS), Phase 1

Fisher, R.J.

Results are presented of a detailed survey of the present state of scientific understanding of cloud electrification processes and lightning warning technology. A review is given of the principles of operation and demonstrated performance factors of lightning strike location technologies and associated commercial products. Emphasis is given to the local lightning warning problem, which is divided into two categories: detection and tracking of active storms that originate outside of and move into the declared safety zone, and early detection of cloud electrification that initiates within the zone. A prototype single-station warning system design is presented that is intended to accumulate data simultaneously from a complement of different types of sensors during intervals immediately preceding the onset of lightning conditions within the area of coverage. The resultant data base will be analyzed statistically to identify the most promising combinations of early warning indicators and to quantify their reliability as a function of the warning intervals they provide.

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Statistical process control for charting multiple sources of variation with an application to neutron tube production

Spencer, Floyd W.

Multiple sources of variation will often affect the stability of a manufacturing process. Items from different batches may vary because of variation both within a batch and among different batches. Potential sources of variation include within run, run-to-run and week-to-week differences in a manufacturing process. If multiple sources of variation are present, traditional control chart methods may not be appropriate. In this report we develop control charts for monitoring these sources of variation as well as the process average. An example of how to use the control charts is given, using Field 89 data from functional testing of the MC3854 neutron tube.

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Chemically prepared Pb(Zr,Ti)O{sub 3} thin films: The effects of orientation and stress

Tuttle, Bruce

We have determined the effects that orientation and stress have on chemically prepared Pb(Zr,Ti)0{sub 3} (PZT) film properties. Systematic modification of the underlying substrate technology has permitted us to fabricate suites of films that have various degrees of orientation at a constant stress level, and to also fabricate films that are in different states of stress, but have similar orientation. We have fabricated highly oriented films of the following compositions: PZT 60/40, PZT 40/60 and PZT 20/80. Remanent polarizations ({approx}60 {mu}C/cm{sup 2}) greater than the best bulk polycrystalline ferroelectrics were obtained for PZT 40/60 films that were under compression and highly (001) oriented. While we show that systematically varying orientation influences ferroelectric properties, film stress also has a considerable effect. Perhaps the most important concept presented in this paper is that the sign of the film stress at the Curie point controls the type of ferroelectric behavior exhibited by PZT thin films. Further, our stress measurements as a function of thermal history indicate that the coefficient of thermal expansion of the paraelectric state is critical in determining the type of film ferroelectric behavior.

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Process quality management for Data Analysis Department 2722

Mccartney, Lawrence J.

A Quality Management System was defined by Sub-Process teams within Data Analysis Department 2722. Each of the processes is concerned with a different phase of work for intemal customers (members of the Department) and for external customers (Sandians external to the Department, or agencies outside of Sandia). This report identifies and defines the crucial Work Processes of the Department, where each Process is documented in a separate ``Chapter.`` This report documents the effort of the Data Analysis Department to effectively provide services to its customers and to assess/improve these services. Thus this report is intended to be a ``living document`` for the Department and each member of the Department is expected to follow its guidelines.

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A heat transfer analysis of a mobile vehicle radiation-shielded operator compartment

Snyder, K.W.

Solar heat gain inside a radiation-shielded forklift operator compartment can be a significant problem due to the ``greenhouse effect``. Battery power prohibits the use of a refrigerant type of air-conditioning system, which limits the interior temperature to be approximately equal to the outside ambient temperature through alternative cooling methods. A heat transfer analysis is performed to determine the amount of solar heat gain in this type of mobile vehicle shelter. Various results are presented that depend on exterior surface finish and temperature difference between inside and outside ambient. An amount of forced air flow along with several design recommendations are then specified to rid the compartment of this excess heat.

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Primary Standards Laboratory report, first half 1992

Levy, W.G.T.

Sandia National Laboratories operates the Primary Standards Laboratory for the Department of Energy, Albuquerque Operations Office (DOE/AL). This report summarizes metrology activities that received emphasis in the first half of 1992 and provides information pertinent to the operation of the DOE/AL system wide Standards and Calibration Program.

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Aprepro: An algebraic preprocessor for parameterizing finite element analyses

Sjaardema, Gregory D.

Aprepro is an algebraic preprocessor that reads a file containing both general text and algebraic, string, or conditional expressions. It interprets the expressions and outputs them to the output file along with the general text. The syntax used in Aprepro is such that all expressions between the delimiters and are evaluated and all other text is simply echoed to the output file. Aprepro contains several mathematical functions, string functions, and flow control constructs. In addition, functions are included that, with some additional files, implement a units conversion system and a material database lookup system. Aprepro was written primarily to simplify the preparation of parameterized input files for finite element analyses at Sandia National Laboratories; however, it can process any text file that does not use the characters.

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GJOIN: A program for merging two or more GENESIS databases

Sjaardema, Gregory D.

GJOIN is a two- or three-dimensional mesh combination program. GJOIN combines two or more meshes written in the GENESIS mesh database format into a single GENESIS mesh. Selected nodes in the two meshes that are closer than a specified distance can be combined The geometry of the mesh databases can be modified by scaling, offsetting, revolving, and mirroring. The combined meshes can be further modified by deleting, renaming, or combining material blocks, sideset identifications, or nodeset identifications. GJOIN is one of the mesh generation tools in the Sandia National Laboratories Engineering Analysis Code Access System (SEACAS). GJOIN is typically used with the other SEACAS mesh generation codes GEN3D, GENSHELL, GREPOS, and Aprepro.

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Long-term gas and brine migration at the Waste Isolation Pilot Plant: Preliminary sensitivity analyses for post-closure 40 CFR 268 (RCRA), May 1992

Butcher, Barry M.

This report describes preliminary probabilistic sensitivity analyses of long term gas and brine migration at the Waste Isolation Pilot Plant (WIPP). Because gas and brine are potential transport media for organic compounds and heavy metals, understanding two-phase flow in the repository and the surrounding Salado Formation is essential to evaluating long-term compliance with 40 CFR 268.6, which is the portion of the Land Disposal Restrictions of the Hazardous and Solid Waste Amendments to the Resource Conservation and Recovery Act that states the conditions for disposal of specified hazardous wastes. Calculations described here are designed to provide guidance to the WIPP Project by identifying important parameters and helping to recognize processes not yet modeled that may affect compliance. Based on these analyses, performance is sensitive to shaft-seal permeabilities, parameters affecting gas generation, and the conceptual model used for the disturbed rock zone surrounding the excavation. Brine migration is less likely to affect compliance with 40 CFR 268.6 than gas migration. However, results are preliminary, and additional iterations of uncertainty and sensitivity analyses will be required to provide the confidence needed for a defensible compliance evaluation. Specifically, subsequent analyses will explicitly include effects of salt creep and, when conceptual and computational models are available, pressure-dependent fracturing of anhydrite marker beds.

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The use of expert judgment to quantify uncertainty in solubility and sorption parameters for Waste Isolation Pilot Plant performance assessment

Trauth, K.M.

Iterative, annual performance-assessment calculations are being performed for the Waste Isolation Pilot Plant (WIPP), which is a planned underground repository in southeastern New Mexico for the disposal of transuranic radioactive waste. The performance-assessment calculations estimate long-term (10,000-year) radionuclide releases from the disposal system to the accessible environment. The estimation of the releases is probabilistic in nature, requiring system parameters to be described with probability distributions. Because direct experimental data in some areas are presently insufficient or unavailable to form the required distributions, researchers at Sandia National Laboratories have used a formalized expert-judgment elicitation procedure to determine the state of knowledge in these areas. Expert judgment was used to estimate the concentrations of specific radionuclides in a repository brine that might be forced up an intruding borehole, and also to estimate the distribution coefficients to determine the retardation of radionuclides in the overlying Culebra Dolomite. The variables representing these concentrations and coefficients have been shown by 1990 sensitivity analyses to be among the set of parameters making the greatest contribution to the uncertainty in WIPP performance assessment predictions. Using available information, the experts (one expert panel addressed concentrations and a second panel addressed retardation) were briefed on the problem of insufficient experimental data and were formally elicited to obtain probability distributions that characterize the uncertainty in fixed, but unknown, quantities. The probability distributions developed by the experts were incorporated into the 1991 and 1992 performance-assessment calculations.

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Arms control compliance: Information value of verification measures

Gough, R.G.

Using concepts of decision analysis, this paper examines how government policy makers might consider and evaluate the contribution of additional inspection, openness, and confidence-building measures to diplomatic questions involving compliance with arms control agreements. During the current debate among parties to the Biological Weapons Convention as to what constitutes effective verification of compliance with that Convention, these analytical concepts were employed to evaluate some proposed inspection or confidence-building measures. Some of the salient points not bound up in the confidentiality of on-going negotiations will be summarized here.

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Very high coercivity magnetic stripes produced by particle rotation

Naylor, R.B.

This paper describes a current research program at Sandia National Laboratories whereby magnetic stripes are produced through the use of a new particle rotation technology. This new process allows the stripes to be produced in bulk and then held in a latent state so that they may be encoded at a later date. Since particle rotation is less dependent on the type of magnetic particle used, very high coercivity particles could provide a way to increase both magnetic tamper-resistance and accidental erasure protection. This research was initially funded by the Department of Energy, Office of Safeguard and Security as a portion of their Science and Technology Base Development, Advanced Security Concepts program. Current program funding is being provided by Sandia National Laboratories as part of their Laboratory Directed Research and Development program.

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Evaluation of alternatives for high-level and transuranic radioactive- waste disposal standards

Klett, R.D.

The remand of the US Environmental Protection Agency`s long-term performance standards for radioactive-waste disposal provides an opportunity to suggest modifications that would make the regulation more defensible and remove inconsistencies yet retain the basic structure of the original rule. Proposed modifications are in three specific areas: release and dose limits, probabilistic containment requirements, and transuranic-waste disposal criteria. Examination of the modifications includes discussion of the alternatives, demonstration of methods of development and implementation, comparison of the characteristics, attributes, and deficiencies of possible options within each area, and analysis of the implications for performance assessments. An additional consideration is the impact on the entire regulation when developing or modifying the individual components of the radiological standards.

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Finding minimum-quotient cuts in planar graphs

Park, J.K.; Phillips, C.A.

Given a graph G = (V, E) where each vertex v {element_of} V is assigned a weight w(v) and each edge e {element_of} E is assigned a cost c(e), the quotient of a cut partitioning the vertices of V into sets S and {bar S} is c(S, {bar S})/min{l_brace}w(S), w(S){r_brace}, where c(S, {bar S}) is the sum of the costs of the edges crossing the cut and w(S) and w({bar S}) are the sum of the weights of the vertices in S and {bar S}, respectively. The problem of finding a cut whose quotient is minimum for a graph has in recent years attracted considerable attention, due in large part to the work of Rao and Leighton and Rao. They have shown that an algorithm (exact or approximation) for the minimum-quotient-cut problem can be used to obtain an approximation algorithm for the more famous minimumb-balanced-cut problem, which requires finding a cut (S,{bar S}) minimizing c(S,{bar S}) subject to the constraint bW {le} w(S) {le} (1 {minus} b)W, where W is the total vertex weight and b is some fixed balance in the range 0 < b {le} {1/2}. Unfortunately, the minimum-quotient-cut problem is strongly NP-hard for general graphs, and the best polynomial-time approximation algorithm known for the general problem guarantees only a cut whose quotient is at mostO(lg n) times optimal, where n is the size of the graph. However, for planar graphs, the minimum-quotient-cut problem appears more tractable, as Rao has developed several efficient approximation algorithms for the planar version of the problem capable of finding a cut whose quotient is at most some constant times optimal. In this paper, we improve Rao`s algorithms, both in terms of accuracy and speed. As our first result, we present two pseudopolynomial-time exact algorithms for the planar minimum-quotient-cut problem. As Rao`s most accurate approximation algorithm for the problem -- also a pseudopolynomial-time algorithm -- guarantees only a 1.5-times-optimal cut, our algorithms represent a significant advance.

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Gating geometry studies of thin-walled 17-4PH investment castings

Maguire, Michael C.

The ability to design gating systems that reliably feed and support investment castings is often the result of ``cut-and-try`` methodology. Factors such as hot tearing, porosity, cold shuts, misruns, and shrink are defects often corrected by several empirical gating design iterations. Sandia National Laboratories is developing rules that aid in removing the uncertainty involved in the design of gating systems for investment castings. In this work, gating geometries used for filling of thin walled investment cast 17-4PH stainless steel flat plates were investigated. A full factorial experiment evaluating the influence of metal pour temperature, mold preheat temperature, and mold channel thickness were conducted for orientations that filled a horizontal flat plate from the edge. A single wedge gate geometry was used for the edge-gated configuration. Thermocouples placed along the top of the mold recorded metal front temperatures, and a real-time x-ray imaging system tracked the fluid flow behavior during filling of the casting. Data from these experiments were used to determine the terminal fill volumes and terminal fill times for each gate design.

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Truncation effects on control design models

Allen, James J.

This paper studied the behavior of retained system poles and transmission zeros in a control design model when the model is truncated. The sensitivity of the transmission zeros due to the tuncation of system dynamics was analytically obtained. The sensitivity of system poles to the truncation of system dynamics was shown to be zero as expected. The effects of actuator-sensor type and location was also studied. The results were illustrated with two example problems. The effect of transmission zero shifts in control design models and the controllers designed from them was illustrated with an example.

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Cooperation of mobile robots for accident scene inspection

Byrne, Raymond H.

A telerobotic system demonstration was developed for the Department of Energy`s Accident Response group to highlight the applications of telerobotic vehicles to accident site inspection. The proof-of- principle system employs two mobile robots, Dixie and RAYBOT, to inspect a simulated accident site. Both robots are controlled serially from a single driving station, allowing an operator to take advantage of having multiple robots at the scene. The telerobotic system is described and some of the advantages of having more than one robot present are discussed. Future plans for the system are also presented.

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Transient dynamics capability at Sandia National Laboratories

Attaway, Stephen W.

This report will present a brief overview of the transient dynamics capabilities at Sandia National Laboratories, with an emphasis on recent new developments and current research. In addition, the Sandia National Laboratories (SNL) Engineering Analysis Code Access System (SEACAS), which is a collection of structural and thermal codes and utilities used by analysts at SNL, will be described. The SEACAS system includes pre- and post-processing codes, analysis codes, database translation codes, support libraries, Unix shell scripts for execution, and an installation system. SEACAS is used at SNL on a daily basis as a production, research, and development system for the engineering analysts and code developers. Over the past year, approximately 190 days of CPU time have been used by SEACAS codes on jobs running from a few seconds up to two and one-half days of CPU time. SEACAS is running on several different systems at SNL including Cray Unicos, Hewlett Packard HP-UX, Digital Equipment Ultrix, and Sun SunOS. An overview of SEACAS, including a short description of the codes in the system, will be presented. Abstracts and references for the codes are listed at the end of the report.

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A simple, approximate model of parachute inflation

Macha, John M.

A simple, approximate model of parachute inflation is described. The model is based on the traditional, practical treatment of the fluid resistance of rigid bodies in nonsteady flow, with appropriate extensions to accommodate the change in canopy inflated shape. Correlations for the steady drag and steady radial force as functions of the inflated radius are required as input to the dynamic model. In a novel approach, the radial force is expressed in terms of easily obtainable drag and reefing fine tension measurements. A series of wind tunnel experiments provides the needed correlations. Coefficients associated with the added mass of fluid are evaluated by calibrating the model against an extensive and reliable set of flight data. A parameter is introduced which appears to universally govern the strong dependence of the axial added mass coefficient on motion history. Through comparisons with flight data, the model is shown to realistically predict inflation forces for ribbon and ringslot canopies over a wide range of sizes and deployment conditions.

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Quality assurance procedures for parameter selection and use of expert judgment panels supporting performance assessments of the Waste Isolation Pilot Plant

Rechard, Robert P.

This document presents the quality assurance (QA) procedures for Parameter Selection and Expert Judgment Panels used by the performance Assessment Department of Sandia National Laboratories, which directly supports the Waste Isolation Pilot Plant (WIPP). Parameter Selection QA procedures described herein will be incorporated into the general Performance Assessment Quality Assurance Procedures, QAP 2-3; the Expert Judgment Panel procedures will be incorporated into QAP 2-6. Both sets of procedures will apply to all Sandia and Sandia contractor activities related to performance assessment (except where the contractor has its own approved QA procedures). This report presents the philosophy behind the QA procedures, provides the standards adopted for performance assessment Parameter Selection and Expert Judgment Panels, and discusses the implementation of these standards.

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1991 Environmental monitoring report Sandia National Laboratories, Albuquerque, New Mexico

Culp, Todd A.

This 1991 report contains monitoring data from routine radiological and nonradiological environmental surveillance activities. Summaries of significant environmental compliance programs in progress such as National Environmental Policy Act (NEPA) documentation, environmental permits, environmental restoration (ER), and various waste management programs for Sandia National Laboratories in Albuquerque (SNL, Albuquerque) are included. The maximum offsite dose impact was calculated to be 1.3 {times} 10{sup {minus}3} mrem. The total population within a 50-mile radius of SNL, Albuquerque, received a collective dose of 0.53 person-rem during 1991 from SNL, Albuquerque, operations. As in the previous year, the 1991 operations at SNL, Albuquerque, had no discernible impact on the general public or on the environment.

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Nuclear thermal rocket entry heating and thermal response preliminary analysis

Potter, D.L.; Connell, L.W.; Wong, C.C.; Kniskern, M.W.

This preliminary study analyzes the atmospheric entry of a solid core nuclear thermal rocket (NTR) engine under three accidental entry scenarios. Depending on the scenario, results of the analysis showed that, without external thermal protection, an aluminum pressure vessel will fail at altitudes ranging 25 to 73 km. subsequent release the core materials occurs. The graphitic based core materials will undergo partial ablation, with the percent mass loss depending on the geometry of the fuel elements. A carbon-phenolic thermal protection system was sized to prevent pressure vessel aerothermal failure. It was found to increase the mass of the NTR by approximately 15 percent.

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A method for determining the spent-fuel contribution to transport cask containment requirements

Sanders, Thomas L.

This report examines containment requirements for spent-fuel transport containers that are transported under normal and hypothetical accident conditions. A methodology is described that estimates the probability of rod failure and the quantity of radioactive material released from breached rods. This methodology characterizes the dynamic environment of the cask and its contents and deterministically models the peak stresses that are induced in spent-fuel cladding by the mechanical and thermal dynamic environments. The peak stresses are evaluated in relation to probabilistic failure criteria for generated or preexisting ductile tearing and material fractures at cracks partially through the wall in fuel rods. Activity concentrations in the cask cavity are predicted from estimates of the fraction of gases, volatiles, and fuel fines that are released when the rod cladding is breached. Containment requirements based on the source term are calculated in terms of maximum permissible volumetric leak rates from the cask. Calculations are included for representative cask designs.

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Specification of an IF1 to PG translator for the Epsilon-2 dataflow machine

Boehm, W.; Hoch, J.E.

This report describes a mechanism for compiling the functional language SISAL for Sandia`s Epsilon-2 hybrid dataflow machine. The strategy couples the front-end of the standard SISAL compiler (which generates a data dependence graph intermediate form called IF1) with an optimizing code-generator for Epsilon-2. The Epsilon-2 code-generator is the back-end of a compiler for the functional language Id. It translates a data dependence graph intermediate form called Program Graphs into Epsilon-2 machine code. This report describes a translation path from IF1 graphs to Program Graphs. This report also comments on the relative merits of the IF1 and Program Graph representations.

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Gauge calibration using the vacuum station

Rebarchik, F.N.

This memorandum is a synopsis of the description and operation of the equipment used and the events accuring during the calibration of gauges on the vacuum station over the range of 0.0001 to 650 torr.

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1991 Environmental Monitoring Report Tonopah Test Range, Tonopah, Nevada

Culp, Todd A.

This report summarizes the environmental surveillance activities conducted by the US Environmental Protection Agency (EPA) and Reynolds Electrical and Engineering Company (REECO) for the Tonopah Test Range (TTR) operated by Sandia National Laboratories (SNL). Other environmental compliance programs such as the National Environmental Policy Act of 1969 (NEPA), environmental permits, environmental restoration, and waste management programs are also included. The 1991 SNL, TTR, operations had no discernible impact on the general public or the environment. This report 3-s prepared for the US Department of Energy (DOE) in compliance with DOE Order 5400.1.

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Development of CPG dish-Stirling systems for remote power applications

Kubo, I.; Diver, R.B.

Through a program sponsored by the US Department of Energy (DOE), Cummins Power Generation, Inc. (CPG) and Sandia National Laboratories (SNL) have entered into a joint venture to develop and commercialize economically competitive dish-Stirling systems for remote power applications. Sixteen systems, representing three generations of technology, will be developed, fielded, and tested in the Dish-Stirling Joint Venture Program (JVP). The JVP is funded equally by a consortium led by CPG and by the DOE. After completion of the program, CPG`s commercialization effort will continue with limited production expected to start in 1996. In this paper, the program plan and the technology used in the JVP are outlined. ne current status of the key system components, and the initial results of a system optimization study including current cost and performance estimates, are also provided.

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Solar reforming applications study summary

Tyner, Craig E.

Research in recent years has demonstrated the efficient use of solar thermal energy for driving endothermic chemical reforming reactions in which hydrocarbons are reacted to form syngas. Closed-loop reforming/methanation systems can be used for storage and transport of process heat and for short-term storage for peaking power generation. Open-loop reforming and gasification systems can be used for direct fuel production; for production of syngas feedstock for further processing to bulk ammonia, hydrogen, and liquid fuels; and for destruction of hazardous organic materials. To help identify the most promising areas for future development of this technology, we discuss in this paper the market potential of these applications.

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Rapid mesh generation for finite element analysis of investment castings

Lober, R.R.; Bohnhoff, W.J.; Meyers, R.J.

FASTCAST is a Sandia National Laboratories program to produce investment cast prototypical hardware faster by integrating experimental and computational technologies into the casting process. FASTCAST uses the finite element method to characterize the metal flow and solidification processes to reduce uncertainty in the mold design. For the casting process to benefit from finite element analysis, analysis results must be available in a very short time frame. By focusing on the bottleneck of finite element model creation, automated mesh generation can drastically reduce the time span between geometry definition (design) and accurate analysis results. The increased availability of analysis results will diminish the need for trial and error approaches to acquiring production worthy mold and gating systems for investment casting. The CUBIT meshing tool kit is being developed to address the need for rapid mesh generation. CUBIT is being designed to effectively automate the generation of quadrilateral and hexahedral elements. It is a solid-modeler based, two- and three-dimensional preprocessor that prepares solid models for finite element analysis. CUBIT contains several meshing algorithms including two- and three-dimensional mapping, two- and three-dimensional paving (patented), and a general two and one-half dimensional sweeper based upon the plastering algorithm. This paper describes progress in the development of the CUBIT meshing toolkit.

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Entry/exit control components for physical protection systems

Holmes, J.P.; Kenna, B.T.; Murray, D.W.

The purpose of this NUREG is to provide technical information on the major components of entry control systems: identity verifiers, weapons detectors, explosives detectors, and special nuclear material (SNM) detectors. For each type of device, information is presented on principles of operation, hardware features, recommended installation, testing methods, and operational procedures. Applications to personnel, handcarried packages, bulk items, and vehicles are addressed.

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Chemistry of copper CVD precursors on a Pt(111) surface

Parmeter, John

We have investigated the chemistry of Cu(hfac){sub 2}, (hfac)Cu(VTMS), (hfac)Cu(2-butyne), and hfach on a Pt(111) surface. In contrast to what is observed on copper surfaces. Cu(hfac)2 and hfach lead to the formation of distinctly different adsorbed hfac species on Pt(111). This shows the importance of the copper atoms themselves in determining the surface chemistry of copper {beta}-diketonate CVD precursors. The hfac species on Pt(111) are considerably less stable than hfac on copper, suggesting that unimolecular decomposition may lead to impurity incorporation in the interfacial region when copper is deposited onto a more reactive substrate. In situ CVD studies with Cu(I) {beta}-diketonates show that the bimolecular disproportionation reaction leading to copper CVD is favored over unimolecular precursor decomposition at pressures above approximately 10{sup {minus}5} torr.

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Experimental results of an integral effects test in a zion-like geometry to investigate the effect of a classically inert atmosphere on direct containment heating: The IET-5 experiment

Allen, Mark S.

The fifth experiment of the Integral Effects Test (IET-5) series was conducted to investigate the effects of high pressure melt ejection on direct containment heating. Scale models of the Zion reactor pressure vessel (RPV), cavity, instrument tunnel, and subcompartment structures were constructed in the Surtsey Test Facility at Sandia National Laboratories. The RPV was modeled with a melt generator that consisted of a steel pressure barrier, a cast MgO crucible, and a thin steel inner liner. The melt generator/crucible had a hemispherical bottom head containing a graphite limiter plate with a 4-cm exit hole to simulate the ablated hole in the RPV bottom head that would be formed by ejection of an instrument guide tube in a severe nuclear power plant accident. The cavity contained 3.48 kg of water, and the basement floor inside the crane wall contained 71 kg of water, which corresponded to condensate levels in the Zion plant. A 43-kg initial charge of iron oxide/aluminium/chromium thermite was used to simulate corium debris on the bottom head of the RPV. Molten them-lite was ejected by 6.0 MPa of steam into the reactor cavity.

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Locking systems for physical protection and control

Gee, K.T.

The purpose of this NUREG is to present technical information that should be useful for understanding and applying locking systems for physical protection and control. There are major sections on hardware for locks, vaults, safes, and security containers. Other topics include management of lock systems and safety considerations. this document also contains notes on standards and specifications and a glossary.

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Indicator tests for the creep of rock salt from borehole Moss Bluff 2, Moss Bluff Dome, Texas

Wawersik, W.R.

Creep tests were performed on a representative sample of rock salt from borehole Moss Bluff 2 (MB2), Moss Bluff dome near Houston, Texas. Moss Bluff 2 is located at the site of a compressed gas storage cavern of Tejas Power Corporation. Four triaxial experiments were conducted at two values of principal stress difference and two representative temperatures. The minimum observed creep rates at the end of each test varied between 5.2{times}10{sup {minus}9} 1/s and 2.14{times}10{sup {minus}8} 1/s. Comparisons of the present results with existing data for rock salt from other locations suggest that the steadystate creep characteristics of MB2 salt, depth 3349 ft (1098.8 m), are intermediate to those measured for the US Strategic Petroleum Reserve at West Hackberry and Bryan Hound, which included the most creep resistant rock salt ever tested at Sandia National Laboratories. Creep parameters are suggested for first-order sensitivity calculations.

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Evaluation of a no-clean soldering process designed to eliminate the use of ozone depleting chemicals

Iman, R.L.

The destruction of the Earth`s protective ozone layer is one of today`s largest environmental concerns. Solvent emissions released during the cleaning of printed wiring boards (PWBs) have been identified as a primary contributor to ozone destruction. No-clean soldering (sometimes referred to as self-cleaning) processes represent an ideal solution since they eliminate the need for cleaning after soldering. Elimination of solvent cleaning operations significantly reduces the emissions of ozone depleting chemicals (ODCs), reduces energy consumption, and reduces product costs. Several no-clean soldering processes have been developed over the past few years. The program`s purpose was to evaluate the no-clean soldering process and to determine if hardware produced by the process is acceptable for military applications. That is, determine if the no-clean process produces hardware that is as reliable as that soldered with the existing rosin-based flux solvent cleaning process.

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Vibration and shock test report for the H1616-1 container and the Savannah River Hydride Transport Vessel

York II, A.R.; Joseph, B.J.

Sandia National Laboratories performed random vibration and shock tests on a tritium hydride transport vessel that was packaged in an H1616-1 container. The objective of the tests was to determine if the hydride transport vessel remains leaktight under vibration and shock normally incident to transport, which is a requirement that the hydride transport vessel must meet to be shipped in the H1616-1. Helium leak tests before and after the vibration and shock tests showed that the hydride transport vessel remained leaktight under the specified conditions. There were no detrimental effects on the containment vessel of the H1616-1.

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Treatment of human-computer interface in a decision support system

Cox, Roger G.

One of the most challenging applications facing the computer community is development of effective adaptive human-computer interface. This challenge stems from the complex nature of the human part of this symbiosis. The application of this discipline to the environmental restoration and waste management is further complicated due to the nature of environmental data. The information that is required to manage environmental impacts of human activity is fundamentally complex. This paper will discuss the efforts at Sandia National Laboratories in developing the adaptive conceptual model manager within the constraint of the environmental decision-making. A computer workstation, that hosts the Conceptual Model Manager and the Sandia Environmental Decision Support System will also be discussed.

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Conceptual models of VOC migration in the vadose zone using soil gas sampling data collected from existing ground water monitoring wells

Lindgren, Eric

Choosing the appropriate conceptual model of contaminant transport from a hazardous waste site to the underlying aquifer will assist in designing efficient site investigation and remediation strategies. One method of collecting data to support a conceptual model is by comparing ground water sampling results to soil gas sampling results that are collected through existing monitoring wells. This underutilized data collection technique is quick, easy, and inexpensive. Comparing the soil gas results to ground water results can assist in supporting or refuting a conceptual model selection. In addition, soil gas sampling from existing monitoring wells may provide an early warning detection technique to impending ground water contamination. This approach is being implemented at the Chemical Waste Landfill at Sandia National Laboratories in Albuquerque, New Mexico.

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Beam transport physics issues for the recirculating linear accelerator

Shokair, Isaac R.

The Recirculating Linear Accelerator (RLA) utilizes the Ion Focused Regime (IFR) of beam transport plus a ramped bending field to guide the beam around the curved sections. Several issues of beam transport are considered. Beam transverse perturbations that could result in growth of the ion hose instability are analyzed. It is found that transverse kicks due to bending field errors, energy mismatches and fringe fields are the most important. The scaling of these perturbations with beam and channel parameters is derived. The effect of ramping of the bending field on the preformed plasma channel is then considered. For RLA experimental parameters the effect is found to be very small. For high energies however, in addition to axial heating, it is found that ramping the field causes compression of the plasma channel along the radius of curvature. This compression results in a quasi-equilibrium plasma electron temperature along the field lines which leads to collisionless transport towards the walls. The analysis of compression is done in an approximate way using a single particle picture and the channel expansion is analyzed using an envelope solution which gives a simple expression for the expansion time. This solution is then verified by Buckshot simulations. For a bending field of 2 kG ramped in 2 {mu}-secs and an argon channel (RLA parameters) we estimate that the channel radius doubling time (along field lines) is of the order of 0.5 {mu}-secs. Finally the effect of electron impact ionization due to axially heated electrons by the action of the inductive field is estimated. It is found that in Argon gas the electron avalanche time could be as low as 0.5 {mu}-sec which is smaller than the field ramp time.

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Plans for containment bellows testing under extreme loads

Spletzer, Barry L.

Piping penetrations in nuclear power plant steel containments are surrounded by flexible metal bellows. The purpose of the bellows is to maintain the containment pressure boundary integrity while permitting relative movement between the piping and the containment wall. In a severe accident, bellows may be subjected to high temperatures, pressure, and combinations of lateral and axial deflections. Sandia National Laboratories (SNL), under sponsorship of the Nuclear Regulatory Commission (NRC), is performing a series of tests to investigate the performance of containment bellows under severe accident conditions.

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Use of a commercial heat transfer code to predict horizontally oriented spent fuel rod temperatures

Koski, Jorman A.

Radioactive spent fuel assemblies are a source of hazardous waste that will have to be dealt with in the near future. It is anticipated that the spent fuel assemblies will be transported to disposal sites in spent fuel transportation casks. In order to design a reliable and safe transportation cask, the maximum cladding temperature of the spent fuel rod arrays must be calculated. The maximum rod temperature is a limiting factor in the amount of spent fuel that can be loaded in a transportation cask. The scope of this work is to demonstrate that reasonable and conservative spent fuel rod temperature predictions can be made using commercially available thermal analysis codes. The demonstration is accomplished by a comparison between numerical temperature predictions, with a commercially available thermal analysis code, and experimental temperature data for electrical rod heaters simulating a horizontally oriented spent fuel rod bundle.

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Piezoelectric response of precisely poled PVDF to shock compression greater than 10 GPa

Graham, R.A.

Prior work has shown that the piezoelectric response of shock-compressed PVDF film prepared with attention to mechanical and electrical processing exhibits precise, well-defined, reproducible behavior to 10 GPa. Higher pressure response continues to pressures approaching 50 GPa, and appears to provide a basis for a very high pressure stress-rate gauge. Previous work shows that differences in response were sometimes observed. The present report describes studies in progress undertaken to increase the precision of the polarization of the PVDF and to develop optimum sensors and shock gauge package designs. Results obtained on such careful prepared PVDF shock gauges show that differences in electrical charge response less than few percent are observed between 10 and 25 GPa.

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Computer-aided design of molecular catalysts for alkane oxidation using dodeca-substituted iron porphyrins

Shelnutt, John A.

Recent progress in the design, synthesis, and activity testing of catalysts for partial oxidation of light alkanes is described. The first testing results for the designed halogenated dodeca-substituted iron-porphyrin catalysts are presented. The results validate the design goals selected and suggest improvements to the current catalyst designs.

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Radionuclide inventories for short run-time space nuclear reactor systems

Coats, Richard L.

Space Nuclear Reactor Systems, especially those used for propulsion, often have expected operation run times much shorter than those for land-based nuclear power plants. This produces substantially different radionuclide inventories to be considered in the safety analyses of space nuclear systems. This presentation describes an analysis utilizing ORIGEN2 and DKPOWER to provide comparisons among representative land-based and space systems. These comparisons enable early, conceptual considerations of safety issues and features in the preliminary design phases of operational systems, test facilities, and operations by identifying differences between the requirements for space systems and the established practice for land-based power systems. Early indications are that separation distance is much more effective as a safety measure for space nuclear systems than for power reactors because greater decay of the radionuclide activity occurs during the time to transport the inventory a given distance. In addition, the inventories of long-lived actinides are very low for space reactor systems.

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Effluent treatment options for nuclear thermal propulsion system ground tests

Shipers, Larry R.

A variety of approaches for handling effluent from nuclear thermal propulsion system ground tests in an environmentally acceptable manner are discussed. The functional requirements of effluent treatment are defined and concept options are presented within the framework of these requirements. System concepts differ primarily in the choice of fission-product retention and waste handling concepts. The concept options considered range from closed cycle (venting the exhaust to a closed volume or recirculating the hydrogen in a closed loop) to open cycle (real time processing and venting of the effluent). This paper reviews the strengths and weaknesses of different methods to handle effluent from nuclear thermal propulsion system ground tests.

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Development and testing of a Science and Engineering Fair Self-Help Development Program: Results of the pilot program in three middle schools

Menicucci, D.F.

This report details the Science Fair Self-Help Development Program, which was initiated in a pilot project at three middle schools in Albuquerque, NM, during school year 1991-1992. The purpose of the program was to provide guidance to schools in developing their own parental and community resources into a sustainable support group whose major function would be to assist the school's science teachers and administration in all aspects of the science fair. The report documents the development of the Self-Help Program and the results of the pilot testing.

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Quality assurance procedures for analyses and report reviews supporting performance assessments of the Waste Isolation Pilot Plant

Rechard, Robert P.

This document presents the quality assurance (QA) philosophy and procedures for analyses and report reviews used by the Performance Assessment Department of Sandia National Laboratories, which directly supports the Waste Isolation Pilot Plant (WIPP). Analysis procedures described herein will be incorporated into the Performance Assessment Analysis Quality Assurance Procedures (QAP 2-4), and report review procedures will be incorporated into QAP 2-5; both will apply to all Sandia and Sandia contractor activities related to performance assessment (except where the contractor has its own approved QA procedures). This report presents the philosophy behind the OA procedures, provides the standards adopted for performance assessment analysis and report review, discusses the implementation of these standards, and summarizes the software executive package, CAMCON, which aids in implementing the standards.

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Delivery of very high bandwidth with ATM switches and SONET

Gossage, S.A.

The choice of technologies for the delivery of very high bandwidth throughout a facility capable of ultimately achieving gigabits per second performance, is a crucial one for any high technology facility. The components of a high bandwidth delivery system include high performance sources and sinks in the form of central facilities (major mainframes, large file storage and specialized peripherals) and powerful, full bandwidth distributed local area networks (LANs). In order to deliver bandwidth among the sources and sinks, a ubiquitous inter-/intra-building cable plant consisting of single mode and multimode fiber as well as twisted pair copper is required. The selection of the ``glue`` to transport and interconnect the LANs with the central facility over the pervasive cable plant is the focus of this paper. A design philosophy for high performance communications systems is proposed. A description of the traditional problems that must be overcome to provide very high bandwidth beyond the narrow confines of a computer center is given. The advantages of ATM switching and SONET physical transport are explored in the structured design presentation. The applicability of Asynchronous Transfer Mode (ATM) switching (interconnection) and Synchronous Optical NETwork (SONET) (transport) for high bandwidth delivery is described using the environment and requirements of Sandia National Laboratories as a context to examine the suitability of those technologies. The synergy and utility of ATM and SONET in the campus network are explored. Other methods for distributing high data rates are compared and contrasted to ATM and SONET with respect to cable plant impact, reliability/availability, maintainability, and capacity. Sandia is implementing a standards based foundation utilizing a pervasive single mode fiber cable plant, SONET transport, and ATM switching to meet the goals of gigabit networking.

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Pyroshock simulation for satellite components using a tunable resonant fixture, Phase 1

Davie, Neil T.

Aerospace components are often subjected to pyroshock events during flight and deployment, and must be qualified to this frequently severe environment. Laboratory simulation of pyroshock using a mechanically excited resonant fixture, has gained favor at Sandia for testing small (<8 inch cube) weapon components. With this method, each different shock environment required a different resonant fixture that was designed such that it`s response matched the environment. A new test method has been developed which eliminates the need to have a different resonant fixture for each test requirement. This is accomplished by means of a tunable resonant fixture that has a response which is adjustable over a wide frequency range. The adjustment of the fixture`s response is done in a simple and deterministic way. This report covers the first phase of this research, which includes design conception through fabrication and evaluation of hardware capable of testing components with up to a 10 inch {times} 10 inch base. This method will ultimately allow the testing of much larger items, perhaps as large as entire small satellites.

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Finite element methods in heat transfer

Gartling, David K.

The application of the finite element method to problems in conduction and convection heat transfer is described. The formulation of the basic equations is presented for nonisothermal, incompressible, viscous flows and nonisothermal flows in porous media; typical solution algorithms for both transient and time-independent problems are described. Example analyses are included for problems in heat conduction, forced convection and free convection.

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Exact analysis of a two-dimensional model for brine flow to a borehole in a disturbed rock zone

Gelbard, Fred M.

An exact two-dimensional solution is derived for determining the fluid flow rates into a borehole and to the surface from which the borehole was drilled. The solution is for a single fluid phase in a disturbed rock zone (DRZ) that surrounds the borehole with a radius specified to be either finite or infinite. The solution is restricted to constant homogeneous rock and fluid properties in the DRZ, and pressures in the borehole and at the surface of the drift that are maintained constant at ambient conditions. A major objective of the work is to provide a benchmark for more detailed numerical calculations that include variable physical properties and an arbitrary DRZ geometry. However in addition, this work extends previous exact solutions for one-dimensional flow by: (1) allowing for a DRZ of finite but arbitrary extent, (2) accounting for depressurization due to mining the drift before drilling the borehole, and (3) accounting for two-dimensional variations of the fluid pressure caused by simultaneous fluid flow to the drift and to the borehole.

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The ES&H Training Department Standards and Procedures Manual

Ehart, Linda L.

This Manual was established in October 1992 to document the business processes used by the environment, safety, and health (ES&H) Training Department (7524) in providing services to internal Sandia National Laboratories (SNL) customers and to meet Tiger Team findings and milestones. This documentation will be revised as the department improves its processes. This manual implements the processes and procedures followed by the ES&H Training Department in support of the ES&H Training Program. The first part of the manual describes the corporate wide administrative process; the second part describes the department wide administrative process; and parts three, four, and five describe workgroup processes. Terms are defined in the Glossary at the back of the manual.

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Finite element methods for non-Newtonian flows

Gartling, David K.

The application of the finite element method to problems in non-Newtonian fluid mechanics is described. The formulation of the basic equations is presented for both inelastic and viscoelastic constitutive models. Solution algorithms for treating the material nonlinearities associated with inelastic fluids are described; typical solution procedures for the implicit stress-rate equations of viscoelastic fluids are also presented. Methods for the simulation of various types of free-surface flows are also outlined. Simple example analyses are included for both types of fluid models.

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Automated glovebox bagout

Morimoto, A.K.

In FY91, the Intelligent Machines Technologies Group at Sandia National Laboratories (SNL) developed a robotic prototype system that automates the removal of nuclear material from gloveboxes (called bagout) at Rocky Flats Plant (RFP). This work was funded by RFP and the Office of Security and Safeguards (OSS) at the Department of Energy (DOE) through the Facility Systems Engineering Department. With increasing concerns of dose reduction to meet ever-changing environmental, safety, and health (ES&H) standards, the need for an automated process to handle high-dose operations will increase. By removing the operators from the ``hands-on`` operation of bagout, the automated glovebox bagout (AGB) system reduces the dose. The automated platform uses a commercially available robot in combination with automated fixturing and computer control to provide a system that removes the material from the glovebox through the bag, seals the bag, and stores the bagged material into containers. Material waste is reduced by modifying the bagging process using an rf sealer instead of the conventional ``twist and tape`` method and by reducing the bag diameter used for bagout. Security and safeguards is achieved primarily by relieving the operator of handling the material. In addition, accountability for the special nuclear materials is achieved through verification of the procedure. Security measures designed against insider threat have also been developed.

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A simplified model of aerosol scrubbing by a water pool overlying core debris interacting with concrete. Draft report for comment

Powers, Dana A.

A classic model of aerosol scrubbing from bubbles rising through water is applied to the decontamination of gases produced during core debris interactions with concrete. The model, originally developed by Fuchs, describes aerosol capture by diffusion, sedimentation, and inertial impaction. This original model for spherical bubbles is modified to account for ellipsoidal distortion of the bubbles. Eighteen uncertain variables are identified in the application of the model to the decontamination of aerosols produced during core debris interactions with concrete by a water pool of specified depth and subcooling. These uncertain variables include properties of the aerosols, the bubbles, the water and the ambient pressure. Ranges for the values of the uncertain variables are defined based on the literature and experience. Probability density functions for values of these uncertain variables are hypothesized. The model of decontamination is applied in a Monte Carlo sampling of the decontamination by pools of specified depth and subcooling. Results are analyzed using a nonparametric, order statistical analysis that allows quantitative differentiation of stochastic and phenomenological uncertainty. The sampled values of the decontamination factors are used to construct estimated probability density functions for the decontamination factor at confidence levels of 50%, 90% and 95%. The decontamination factors for pools 30, 50, 100, 200, 300, and 500 cm deep and subcooling levels of 0, 2, 5, 10, 20, 30, 50, and 70{degree}C are correlated by simple polynomial regression. These polynomial equations can be used to estimate decontamination factors at prescribed confidence levels.

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UniTree, a mass storage solution at Sandia National Laboratories

Kelly, S.M.

Sandia National Laboratories has recently placed into production a mass storage system based on the UniTree{sup TM} Central File Manager software. this paper describes the current status of the system. Background information on the selection criteria is given and the hardware and software configurations are shown. The system has been in production since April, 1992 and the usage and performance statistics, as obtained thus far, are presented.

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Phenomenological direct containment heating models in CONTAIN and their assessment against experimental data

Washington, Kenneth

In previous years, a suite of interim models had been developed for the CONTAIN code for analyzing direct containment heating (DCH) accidents. The initial development and application of these DCH models are described in a previous WRS paper. While useful, these interim models were incomplete and were highly parametric. The parametric nature of the interim CONTAIN DCH models was necessary at the time because of the lack of relevant DCH experimental data, and to facilitate sensitivity studies aimed at improving our understanding of the most important governing processes in a DCH event. However, today our understanding of DCH phenomenology is significantly improved from when the interim DCH models were developed. This understanding largely stems from recently completed NRC-sponsored DCH experiments at Sandia National Laboratories and Argonne National Laboratory. New models have been developed and added to the CONTAIN code for modeling DCH events to reflect this improvement in our understanding of DCH. The purpose of this paper is to describe the new DCH models in CONTAIN. A demonstration of the new models by comparing simplified calculations against relevant DCH test data will also be presented in this paper. This paper is an extension of the preliminary descriptions of the DCH model improvements presented in the 19th WRS paper. The new models that have been added to CONTAIN for analyzing DCH are briefly discussed below. The following paragraphs also include brief discussions of the motivation and/or basis for the developed improvement. The models are described in greater detail in the full paper.

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Design and development of an IBM/VM menu system

Cazzola, D.J.

This report describes a full screen menu system developed using IBM`s Interactive System Productivity Facility (ISPF) and the REXX programming language. The software was developed for the 2800 IBM/VM Electrical Computer Aided Design (ECAD) system. The system was developed to deliver electronic drawing definitions to a corporate drawing release system. Although this report documents the status of the menu system when it was retired, the methodologies used and the requirements defined are very applicable to replacement systems.

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System model development for nuclear thermal propulsion

Dobranich, Dean

A critical enabling technology in the evolutionary development of nuclear thermal propulsion (NTP) is the ability to predict the system performance under a variety of operating conditions. Since October 1991, US (DOE), (DOD) and NASA have initiated critical technology development efforts for NTP systems to be used on Space Exploration Initiative (SEI) missions to the Moon and Mars. This paper presents the strategy and progress of an interagency NASA/DOE/DOD team for NTP system modeling. It is the intent of the interagency team to develop several levels of computer programs to simulate various NTP systems. An interagency team was formed for this task to use the best capabilities available and to assure appropriate peer review. The vision and strategy of the interagency team for developing NTP system models will be discussed in this paper. A review of the progress on the Level 1 interagency model is also presented.

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Diagnostic behavior of the Wire Arc Plasma spray process

Smith, Mark F.

Laser two-focus (L2F) velocimetry has been used to measure particle velocities in the Wire Arc Plasma spray process. Particle velocities were measured for aluminum, stainless steel, and copper feedstock with wire diameters of 1.6 mm and 0.9 mm. The Wire Arc Plasma gun was operated in both a single-gas mode, using air, and in a two-gas mode, using a mixture of argon/35% hydrogen as the primary plasma gas with pure argon as the secondary gas. The results indicate that maximum particle velocities are as high as 180 m/s for aluminum sprayed using air and 130 m/s using the argon/hydrogen mixture. The results also show that arc current and wire feed rate have little effect on particle velocity; however, particle velocities increase significantly with decreasing wire diameter and with decreasing density of the feedstock material.

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Verification of the computer programs SLAAP and DATA

Cawlfield, J.L.

The computer programs SLAAP and DATA are currently being used by Division 2743 for data analysis. These programs had not been previously verified to determine if they were producing correct results. The objective of the study described in this report was to verify these programs by comparing their results to those obtained with GRAFAID, a verified data analysis program. To accomplish this, five acceleration-time histories were selected. For each time history, the shock response spectrum, integral, double integral, derivative and Fourier transform were computed using SLAAP, DATA and GRAFAID. The results of each operation for each time history were overlay plotted for comparison. The results show only minor differences in some cases. These differences are deterministic and are due to differences in the algorithms or block size restrictions of the three programs.

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Modeling of the vacuum plasma spray process

Smith, Mark F.

Experimental and analytical studies have been conducted to investigate gas, particle, and coating dynamics in the vacuum plasma spray (VPS) process for a tungsten powder. VPS coatings were examined metallographically and the results compared with the model`s predictions. The plasma was numerically modeled from the cathode tip to the spray distance in the free plume for the experimental conditions of this study. This information was then used as boundary conditions to solve the particle dynamics. The predicted temperature and velocity of the powder particles at standoff were then used as initial conditions for a coating dynamics code. The code predicts the coating morphology for the specific process parameters. The predicted characteristics exhibit good correlation with the observed coating properties.

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Description and validation of ERAD: An atmospheric dispersion model for high explosive detonations

Boughton, Bruce A.

The Explosive Release Atmospheric Dispersion (ERAD) model is a three-dimensional numerical simulation of turbulent atmospheric transport and diffusion. An integral plume rise technique is used to provide a description of the physical and thermodynamic properties of the cloud of warm gases formed when the explosive detonates. Particle dispersion is treated as a stochastic process which is simulated using a discrete time Lagrangian Monte Carlo method. The stochastic process approach permits a more fundamental treatment of buoyancy effects, calm winds and spatial variations in meteorological conditions. Computational requirements of the three-dimensional simulation are substantially reduced by using a conceptualization in which each Monte Carlo particle represents a small puff that spreads according to a Gaussian law in the horizontal directions. ERAD was evaluated against dosage and deposition measurements obtained during Operation Roller Coaster. The predicted contour areas average within about 50% of the observations. The validation results confirm the model`s representation of the physical processes.

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Probabilistic analysis of manipulation tasks: A research agenda

Brost, Randolph

This paper addresses the problem of manipulation planning in the presence of uncertainty. We begin by reviewing the worst-case planning techniques introduced in and show that these methods are hampered by an information gap inherent to worst-case analysis techniques. As the task uncertainty increases, these methods fail to produce useful information even though a high-quality plan may exist. To fill this gap, we present the probabilistic backprojection, which describes the likelihood that a given action will achieve the task goal from a given initial state. We provide a constructive definition of the probabilistic backprojection and related probabilistic models of manipulation task mechanics, and show how these models unify and enhance several past results in manipulation planning. These models capture the fundamental nature of the task behavior, but appear to be very complex. Methods for computing these models are sketched, but efficient computational methods remain unknown.

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One-class classifiers and their application to synthetic aperture radar target recognition

Moya, Mary M.

Target recognition requires the ability to distinguish targets from non-targets, a capability called one-class generalization. To function as a one-class classifier, a neural network must have three types of generalization: within-class, between-class, and out-of-class. We discuss these three types of generalization and identify neural network architectures that meet these requirements. We have applied our one-class classifier ideas to the problem of automatic target recognition in synthetic aperture radar. We have compared three neural network algorithms: Carpenter and Grossberg`s algorithmic version of the Adaptive Resonance Theory (ART-2A), Kohonen`s Learning Vector Quantization (LVQ), and Reilly and Cooper`s Restricted Columb Energy network (RCE). The ART 2-A neural network has given the best results, with 100% within-class, and out-of-class generalization. Experiments show that the network`s performance is sensitive to vigilance and number of training set presentations.

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Effects of anomalous salt features on caverns in Gulf Coast domes

Neal, James T.

Early solution miners encountered occasional difficulties with nonsymmetric caverns (including ``wings`` and ``chimneys``), gas releases, insoluble stringers, and excessive anhydrite ``sands.`` Apparently there was no early recognition of trends for these encounters, although certain areas were avoided after problems appeared consistently within them. Solution mining has now matured, and an accumulation of experience indicates that anomalous salt features occur on a number of Gulf Coast domes. Trends incorporating concentrations of anomalous features will be referred to as ``anomalous zones,`` or AZs (after Kupfer). The main objective of this Project is to determine the effects of AZ encounters on solution-mined caverns and related storage operations in domes. Geological features of salt domes related directly to cavern operations and AZs will be described briefly, but discussions of topics related generally to the evolution of Gulf Coast salt structures are beyond the scope of this Project.

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Pressure as a probe of deep levels and defects in semiconductors: GaAs, GaP and their alloys

Samara, George A.

Measurements of the effects of pressure on the thermal electron emission rate and capture cross section for a variety of deep electronic levels in GaAs, GaP and their alloys have yielded the pressure dependences of the energies of these levels in the bandgaps, allowed evaluation of the breathing mode lattice relaxations accompanying carrier emission or capture by these levels and revealed trends which lead to new insights into the nature of the responsible defects. Emphasis is on deep levels believed to be associated with simple defects. Specifically, results will be summarized for the donor levels of the dominant native defect known as EL2 in CAM, which is believed to be associated with the arsenic antisite, and on the radiation-induced El and E2 levels in GaAs, GaP and their alloys, which are believed to be due to arsenic (or phosphorous) vacancies. The results are discussed in terms of models for the defects responsible for these deep levels.

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Characterization of solidification and weldability of Fe-29Ni-17Co alloys

Robino, Charles V.

Applications for the controlled thermal expansion alloy Fe-29Ni-17Co often require joining by fusion welding processes. In addition, these applications usually require hermetic and high reliability joints. The small size of typical components normally dictates the use of autogenous welding processes, so that the hot cracking tendency of Fe-29Ni-17Co is of concem. The solidification behavoir and hot cracking tendency of commercial Fe-29Ni-17Co has been evaluated using diffcrential thermal analysis (DTA), Varestraint testing, light and electron microscopy, and laser welding trials. DTA and microstructural analysis indicated that the solidification of Fe-29Ni-17Co occurs as single phase austenite, does not exhibit the formation of terminal solidification phases, and results in only minimal segregation of major alloying elements. Varestraitit testing indicated that the hot cracking behavior of Fe-29Ni-17Co is similar to, though somewhat more pronounced than, 304L and 316 stainless steels. Relative to other Fe-Ni-Co and Ni-based alloys, however, the hot cracking response of this alloy is fiverable. Pulsed laser welding trials indicated that the phosphorus and sulfur levels in this heat of Fe-29Ni-17Co were insufficient to pmmote cracking in bead-on-plate welds.

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Fundamentals of high energy electron beam generation

Turman, B.N.

High energy electron beam accelerator technology has been developed over the past three decades in response to military and energy-related requirements for weapons simulators, directed-energy weapons, and inertially-confined fusion. These applications required high instantaneous power, large beam energy, high accelerated particle energy, and high current. These accelerators are generally referred to as ``pulsed power`` devices, and are typified by accelerating potential of millions of volts (MV), beam current in thousands of amperes (KA), pulse duration of tens to hundreds of nanoseconds, kilojoules of beam energy, and instantaneous power of gigawatts to teffawatts (10{sup 9} to 10{sup 12} watts). Much of the early development work was directed toward single pulse machines, but recent work has extended these pulsed power devices to continuously repetitive applications. These relativistic beams penetrate deeply into materials, with stopping range on the order of a centimeter. Such high instantaneous power deposited in depth offers possibilities for new material fabrication and processing capabilities that can only now be explored. Fundamental techniques of pulse compression, high voltage requirements, beam generation and transport under space-charge-dominated conditions will be discussed in this paper.

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The Remote Security Station (RSS) final report

Pletta, J.B.

The Remote Security Station (RSS) was developed by Sandia National Laboratories for the Defense Nuclear Agency to investigate issues pertaining to robotics and sensor fusion in physical security systems. This final report documents the status of the RSS program at its completion in April 1992. The RSS system consists of the Man Portable Security Station (MaPSS) and the Telemanaged Mobile Security Station (TMSS), which are integrated by the Operator`s Control Unit (OCU) into a flexible exterior perimeter security system. The RSS system uses optical, infrared, microwave, and acoustic intrusion detection sensors in conjunction with sensor fusion techniques to increase the probability of detection and to decrease the nuisance alarm rate of the system. Major improvements to the system developed during the final year are an autonomous patrol capability, which allows TMSS to execute security patrols with limited operator interaction, and a neural network approach to sensor fusion, which significantly improves the system`s ability to filter out nuisance alarms due to adverse weather conditions.

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In situ permeable flow sensors at the Savannah River Integrated Demonstration: Phase 1 results

Ballard, Sanford

The In Situ Permeable Flow Sensor, a new technology which uses a thermal perturbation technique to directly measure the 3-dimensional groundwater flow velocity vector at a point in permeable, unconsolidated geologic formations, has been used to monitor changes in the groundwater flow regime around an experimental air stripping waste remediation activity. While design flaws in the first version of the technology, which were used during the experiment being reported here, precluded measurements of the horizontal component of the flow velocity, measurements of the vertical component of the flow velocity were obtained. Results indicate that significant changes in the vertical flow velocity were induced by the air injection system. One flow sensor, MHM6, measured a vertical flow velocity of 4 m/yr or less when the air injection system was not operating and 25 m/yr when the air injection system was on. This may be caused by air bubbles moving past the probes or may be the result of the establishment of a more widespread flow regime in the groundwater induced by the air injection system. In the latter case, significantly more groundwater would be remediated by the air stripping operation since groundwater would be circulated through the zone of influence of the air injection system. Newly designed flow sensors, already in the ground at Savannah River to monitor Phase II of the project, are capable of measuring horizontal as well as vertical components of flow velocity.

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Durability of carbon-plastic electrodes for zinc/bromine storage batteries

Arnold Jr., C.

In previous work, failure of early versions of the zinc/bromine battery was traced to degradation and warpage of the carbon-plastic electrode. These electrodes were fabricated from copolymers of ethylene and propylene (EP) containing structures that were found to be susceptible to degradation by the electrolyte. In this work, we evaluated two developmental electrodes from Johnson Controls Battery Group, Inc., in which the EP copolymer was replaced with a high-density polyethylene (HDPE) that contained glass-fiber reinforcing fillers. The glass fiber content of these two electrodes was different (19% vs. 31%). We determined the effect of electrolyte on sorption behavior, dimensional stability, chemical stability, and thermal, mechanical, and electrical properties under real-time and accelerated aging conditions. We also characterized unaged samples of both electrodes to determine their chemical composition and physical structure. We found that high glass content in the electrode minimizes sorption and increases dimensional stability. Both high and low glass content electrodes were found to be chemically and thermally stable toward the electrolyte. A slight decrease in the storage modulus (G{prime}) of both electrodes was attributed to sorption of non-ionic and hydrophobic ingredients in the electrolyte. The electrical conductivity of both electrodes appeared to improve (increase) upon exposure to the electrolyte. No time or temperature trends were observed for the chemical, thermal, or mechanical properties of electrodes made from HDPE. Since decreases in these properties were noted for electrodes made from EP copolymers under similar conditions, it appears that the HDPE-based electrodes have superior long-term stability in the ZnBr{sub 2} environment.

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Hydrostatic and triaxial compression experiments on unpoled PZT 95/5-2Nb ceramic: The effects of shear stress on the F{sub R1} {yields} A{sub O} polymorphic phase transformation

Zeuch, David H.

Hydrostatic and constant-stress-difference (CSD) experiments were conducted at RT on 3 different sintering runs of unpoled, Nb-doped lead-zirconate-titanate ceramic (PZT 95/5-2Nb) in order to quantify influence of shear stress on displacive, martensitic-like, first-order, rhombohedral {r_arrow} orthorhombic phase transformation. In hydrostatic compression at RT, the transformation began at about 260 MPa, and was usually incompletely reversed upon return to ambient. Strains associated with the transformation were isotropic, both on first and subsequent hydrostatic cycles. Results for CSD tests were quite different. First, the confining pressure and mean stress at which the transition begins decreased linearly with increasing stress difference. Second, the rate of transformation decreased with increasing shear stress and the accompanying purely elastic shear strain. This contrasts with the typical observation that shear stresses increase reaction and transformation kinetics. Third, strain was not isotropic during the transformation: axial strains were greater and lateral strains smaller than for the hydrostatic case, though volumetric strain behavior was comparable for the two types of tests. However, this effect does not appear to be an example of true transformational plasticity: no additional unexpected strains accumulated during subsequent cycles through transition under nonhydrostatic loading. If subsequent hydrostatic cycles were performed on samples previously run under CSD conditions, strain anisotropy was again observed, indicating that the earlier superimposed shear stress produced a permanent mechanical anisotropy in the material. The mechanical anisotropy probably results from a ``one-time`` crystallographic preferred orientation that developed during the transformation under shear stress. Finally, in a few specimens from one particular sintering run, sporadic evidence for a ``shape memory effect`` was observed.

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The use of sequential indicator simulation to characterize geostatistical uncertainty; Yucca Mountain Site Characterization Project

Hansen, K.M.

Sequential indicator simulation (SIS) is a geostatistical technique designed to aid in the characterization of uncertainty about the structure or behavior of natural systems. This report discusses a simulation experiment designed to study the quality of uncertainty bounds generated using SIS. The results indicate that, while SIS may produce reasonable uncertainty bounds in many situations, factors like the number and location of available sample data, the quality of variogram models produced by the user, and the characteristics of the geologic region to be modeled, can all have substantial effects on the accuracy and precision of estimated confidence limits. It is recommended that users of SIS conduct validation studies for the technique on their particular regions of interest before accepting the output uncertainty bounds.

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A fast portable implementation of the Secure Hash Algorithm, III

Mccurley, Kevin S.

In 1992, NIST announced a proposed standard for a collision-free hash function. The algorithm for producing the hash value is known as the Secure Hash Algorithm (SHA), and the standard using the algorithm in known as the Secure Hash Standard (SHS). Later, an announcement was made that a scientist at NSA had discovered a weakness in the original algorithm. A revision to this standard was then announced as FIPS 180-1, and includes a slight change to the algorithm that eliminates the weakness. This new algorithm is called SHA-1. In this report we describe a portable and efficient implementation of SHA-1 in the C language. Performance information is given, as well as tips for porting the code to other architectures. We conclude with some observations on the efficiency of the algorithm, and a discussion of how the efficiency of SHA might be improved.

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Test facilities for evaluating nuclear thermal propulsion systems

Beck, David F.

Interagency panels evaluating nuclear thermal propulsion (NTP) development options have consistently recognized the need for constructing a major new ground test facility to support fuel element and engine testing. This paper summarizes the requirements, configuration, and baseline performance of some of the major subsystems designed to support a proposed ground test complex for evaluating nuclear thermal propulsion fuel elements and engines being developed for the Space Nuclear Thermal Propulsion (SNTP) program. Some preliminary results of evaluating this facility for use in testing other NTP concepts are also summarized.

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UNICOS{reg_sign} security system

Vandevender, W.H.

Developing security plans and supporting security tests is a very important part of the Department of Energy accreditation process. This paper will discuss the general testing methodology that was used to achieve DOE accreditation of the Secure UNICOS environment at Sandia National Laboratories, Albuquerque. In addition, some specific security testing procedures, test and problem areas will be described.

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Thermo-visco-inelasticity in large deformations

Herrmann, W.

A formulation is given of constitutive equations valid for large deformations for materials with elastic range and internal state variables intended to describe the internal structure of the material. A material description is used to construct a purely mechanical theory which largely follows that of Carroll. The assumption that the work done in finite closed cycles of homogeneous deformation is non-negative leads to an elastic potential and a dissipation inequality which, in turn, implies a normality condition, by an argument adapted from that of Lin and Naghdi. When the theory is generalized to include temperature dependence, the Clausius-Duhem inequality leads by well-known arguments to an elastic potential and nonnegative dissipation. Rate effects are included by assuming that the inelastic strain rate is a function of the dynamic overstress, but the results of the work assumption or the thermodynamic argument are unchanged. Some remarks regarding implications for stability are made.

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Handling effluent from nuclear thermal propulsion system ground tests

Shipers, Larry R.

A variety of approaches for handling effluent from nuclear thermal propulsion system ground tests in an environmentally acceptable manner are discussed. The functional requirements of effluent treatment are defined and concept options are presented within the framework of these requirements. System concepts differ primarily in the choice of fission-product retention and waste handling concepts. The concept options considered range from closed cycle (venting the exhaust to a closed volume or recirculating the hydrogen in a closed loop) to open cycle (real time processing and venting of the effluent). This paper reviews the different methods to handle effluent from nuclear thermal propulsion system ground tests.

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Analysis and measurement of thermal resistance in a 3-dimensional silicon multichip module populated with assembly test chips

Sweet, James N.

Three dimensional multichip modules (MCMS) present an unusual challenge to the thermal designer. For example, high thermal resistance between upper planes of the MCM and the thermally anchored bottom plane can lead to the development of excessive temperatures. As new designs emerge, it becomes desirable to have methods of experimentally determining interior temperatures in the module in order to validate complex finite element calculations. In order to develop methods for assessing the thermal performance of a 3D MCM, we have developed a test module with three planes or slices. In this paper, we report on some initial calculations and measurements for the 3D MCM. In addition, we discuss the improvement in thermal performance obtained by replacing the top slice with a diamond substrate. Finite element method (FEM) thermal calculations have been done with both the workstation based analyzer P/Thermal from PDA Engineering and the PC program, Inertia from Modern Computer Aided Engineering. These analyses have assumed no heat losses by radiation or convection.

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Loaded cavity-backed slot (LCBS) antennas for Reentry Vehicles

Sena, M.D.

This report describes the linearly-polarized, loaded cavity-backed slot (LCBS) antenna developed for Reentry Vehicles (RVs) and the development process used by the Antenna Development Department. It includes typical antenna engineering design considerations or requirements, fabrication/assembly process, and performance characteristics. Antenna design theory is reduced to the basic concepts useful in designing LCBS antennas for reentry vehicles.

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Video animation system operators manual

Mareda, John F.

This document describes the components necessary to put together a video animation system. It is primarily intended for use at Sandia National Laboratories as it describes the components used in systems at Sandia. The main document covers the operation of the equipment in some detail and is intended for either the system maintainer or an advanced user. There is an appendix for each of the three systems in use by the Engineering Sciences Directorate which contain instructions for the general user.

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Whipple bumper shield results and CTH simulations at velocities in excess of 10 km/s

Chhabildas, L.C.

A series of experiments has been performed on the Sandia HyperVelocity Launcher (HVL) to evaluate the effectiveness of a Whipple bumper shield to orbital space debris at impact velocities in excess of 10 km/s. Upon impact by a 0.67 g (0.87 mm thick) flier plate, the thin aluminum bumper shield disintegrates into a debris cloud. The debris cloud front propagates axially at velocities of {approximately}14 km/s and expands radially at a velocity of {approximately}7 km/s. Subsequent loading on a 3.2 mm thick aluminum substructure by the debris penetrates the substructure completely. However, when the mass of the flier plate is reduced to 0.33 g, the substructure, although damaged, is not perforated over the duration of the experiment. Numerical simulations performed using the multi-dimensional hydrodynamics code CTH also predict complete penetration of the substructure by the subsequent debris cloud for a 0.87 g flier plate. The numerical simulations for a 0.33 g flier plate show a strong dependence on assumed impact geometry. For the assumption of a spherical projectile impact geometry, perforation of the substructure by the subsequent debris cloud is not predicted by CTH.

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Shock characterization of Diallyl Phthalate (DAP)

Weirick, L.J.

This study involved the shock characterization of Diallyl Phthalate (DAP), in particular, the equation of state as measured by the shock Hugoniot. Tests were done between 1 and 11 GPa impact shock pressure. The Hugoniot parameters were determined to be: {rho}{sub 0}= 1.743, C{sub 0} = 2.20, and S = 2.33.

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Risk evaluation for a B&W Pressurized Water Reactor, effects of fire protection system actuation on safety-related equipment. Evaluation of Generic Issue 57

Lambright, J.

Nuclear power plants have experienced inadvertent actuations of fire protection systems (FPS) under conditions for which these systems were not intended to actuate. They have also experienced advertent actuations with the presence of a fire. These actuations have often damaged plant equipment. This document provides a review of the impact of past occurrences of both types of such events on nuclear power plant safety. Thirteen different scenarios leading to actuation of fire protection systems due to a variety of causes were identified. These scenarios ranged from inadvertent actuation caused by human error to hardware failure and includes seismic root causes and seismic/fire interaction. A quantification of these thirteen scenarios, where applicable, was performed on a Babcock and Wilcox Pressurized Water Reactor (lowered loop design). This report estimates the contribution of FPS actuations to core damage frequency and to risk.

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An improved spectral graph partitioning algorithm for mapping parallel computations

Hendrickson, Bruce A.

Efficient use of a distributed memory parallel computer requires that the computational load be balanced across processors in a way that minimizes interprocessor communication. We present a new domain mapping algorithm that extends recent work in which ideas from spectral graph theory have been applied to this problem. Our generalization of spectral graph bisection involves a novel use of multiple eigenvectors to allow for division of a computation into four or eight parts at each stage of a recursive decomposition. The resulting method is suitable for scientific computations like irregular finite elements or differences performed on hypercube or mesh architecture machines. Experimental results confirm that the new method provides better decompositions arrived at more economically and robustly than with previous spectral methods. We have also improved upon the known spectral lower bound for graph bisection.

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Revised nomenclature for defects at or near the Si/SiO{sub 2} interface

Fleetwood, Daniel M.

A revised nomenclature for defects in MOS devices is described which clearly distinguishes the language used to describe the physical location of defects from that used to describe their electrical response. ``Oxide traps`` are simply defects in the SiO{sub 2} layer, and ``interface traps`` are defects at the Si/SiO{sub 2} interface; nothing is presumed about how either communicates with the underlying Si. ``Fixed states`` are defined electrically as trap levels that do not communicate with the Si on the time scale, but ``switching states`` can exchange charge with the Si. Fixed states presumably are oxide traps, but switching states can either be interface traps or near-interfacial oxide traps that can communicate with the Si, i.e. ``border traps.`` Thus the term ``traps`` is reserved for defect location, and the term ``states`` for electrical response. This defect picture is used to provide new insight into the response of MOS capacitors with 45-nm radiation-hardened oxides to electrical stress and annealing; capacitance-voltage and thermally-stimulated-current measurements are used. 2 figs, 14 refs. (DLC)

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The formal use of expert judgments in environmental management

Bonano, Evaristo J.

The solution of ER/WM problems will rely on the use of expert judgments. These judgments should be able to withstand the same rigorous scrutiny as the decisions made to solve these problems. Therefore, those judgments that are likely to have a significant impact on the solution of ER/WM problems should be elicited and used in a formal manner. In this paper, we discuss the key areas of environmental management where expert judgments are expected to be crucial, as well as the process to formalize them. This process is a generic one and should only be construed as a roadmap; specific aspects of the process need to be tailored to address the problem at hand. By employing this process, the quality of the judgments is enhanced, and therefore, the likelihood that the solution of ER/WM problems will be a sound and defensible one is considerably increased.

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Discrepancies between charge-pumping, dual-transistor, and midgap measurements of D{sub it}

Schwank, James R.

Several different techniques are used to electrically characterize defects at or near the Si/SiO{sub 2} interface. Three common methods are the charge-pumping, midgap, and dual-transistor techniques. Each of these techniques offer advantages and disadvantages compared to the others. For instance, charge-pumping measurements are not significantly affected by charge lateral non-uniformities and can provide high-sensitivity measurements of the average density of interface traps. However, charge-pumping measurements cannot provide accurate measurements of the number of charged oxide traps. In contrast both the dual-tranistor and midgap techniques can provide good estimates for threshold-voltage shifts due to oxide traps and interface traps, but these estimates can break down when significant charge lateral non-uniformities are present in the oxide. Considering the widespread use of these, techniques, it is of practical and theoretical importance to quantitatively compare them. At the SISC, we will present a detailed comparison of the charge-pumping, midgap, and dual-tranistor techniques. Values for the density of interface traps measured using the three techniques will be compared for n- and P-channel transistors fabricated using several different process technologies, and under different process technologies, and under different irradiation and anneal conditions. Discrepancies between the different techniques are observed. Causes for the discrepancies will be explored at the SISC.

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Decision making, risk assessment, and uncertainty analysis in environmental management

Bonano, Evaristo J.

Environmental management involves making decisions that will lead to the solution of environmental restoration and waste management (ER/WM) problems. Not only are ER/WM problems technologically challenging, but they must be dealt with under politically and emotionally charged conditions. Furthermore, these decisions must be made based on less than certain information. Therefore, environmental managers must consider the sources of uncertainty that will impact the results of the decision-making process, treat them in an explicit manner, and assess their impact on the decision. Consequently, the process must be a defensible, objective, and transparent one; otherwise the foundation for solving ER/WM problems will not be sufficiently solid to survive the criticisms that such solutions are likely to be subjected to. The use of risk assessment and decision analysis tools helps the environmental manager achieve this goal. It is also important that these decisions consider the array of risk-related issues associated with ER/WM problems, which include the risk to the health and safety of the public as well as other risks such as economic risk. The solution of ER/WM problems must obtain and maintain a proper balance between all these issues. It is also crucial that the multiple stakeholders having an interest in the solution of ER/WM problems be involved in the decision-making process.

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Core-concrete interactions using molten urania with zirconium on a limestone concrete basemat

Copus, E.R.

An inductively heated experiment SURC-1, using UO[sub 2]-ZrO[sub 2] material, was executed to measure and assess the thermal, gas, and aerosol source terms produced during core debris/concrete interactions. The SURC-1 experiment eroded a total of 27 cm of limestone concrete during 130 minutes of sustained interaction using 204.2 kg of molten prototypic UO[sub 2]-ZrO[sub 2] core debris material that included 18 kg of zr metal and 3.4 kg of fission product simulants. The melt pool temperature ranged from 2100 to 2400[degrees]C during the first 50 minutes of the test, followed by steady temperatures of 2000 to 2100[degrees]C during the middle portion of the test and temperatures of 1800 to 2000[degrees]C during the final 50 minutes of testing. The total erosion during the first 50 minutes was 16 cm with an additional 2 cm during the middle part of the test and 9 cm of ablation during the final 50 minutes. Aerosols were continuously released in concentrations ranging from 30 to 200 g/m[sup 3]. Comprehensive gas flow rates, gas compositions, and aerosol compositions were also measured during the SURC-1 test.

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Market hub technology in the domestic natural gas distribution system. A panel discussion

Turnley, Jessica G.

This document describes a panel discussion held on March 18, 1992 as part of a conference entitled ``Market Hub Technology`` . The purpose of the conference was to stimulate dialogue among various segments of the natural gas industry on the technology limits of an economic policy issue that has the potential to significantly alter the structure and functioning of the natural gas industry. Attendees included key US gas industry representatives, Federal Energy Regulatory Commission (FERC) commissioners, and others. The conference explored the concept of market centers, or hubs, and related technologies. It covered the technology currently available for the establishment of an integrated system of physical market hubs, and explored technology requirements for the further development of useful and efficient hubs. The discussion identified two primary barriers to the acceptance and implementation of a market center distribution system for natural gas. The first barrier is the potential change in the configuration of the market such a system would introduce and the resistance various industry segments would mount to such change. The second is the lack of industry standardization in the physical and business infrastructures.

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PVUSA EMT-1 ENTECH photovoltaic concentrator module test report

Hund, Thomas D.

A single EMCH concentrator module for the Photovoltaics for Utility Scale Application (PVUSA), Emerging Technologies-1 (EMT-1) program has been electrically and environmentally tested to the requirements in Sandia`s SAND86-2743 document ``Qualification Tests for Photovoltaic Concentrator Cell Assemblies; and Modules.`` Module testing was divided into three parts: (1) initial characterization, (2) environmental testing, and (3) supplemental testing. Testing began with module inspection for damage, adequate name plate information, grounding off-axis beam damage, and baseline electrical performance. The included thermal cycling, humidity/freeze cycling, rainwater intrusion, and hail impact, and hi-pot testing. After both thermal cycling and environmental testing, the module was electrically tested. The supplemental testing not required by the Sandia qualification document was conducted for engineering evaluation. These tests included wet insulation resistance measurements and cell temperature measurements after installation of heat sink fin extensions. The test sequence revealed some module deficiencies which include RTV adhesive/sealant problems, high cell temperatures, off-track beam damage, and low wet insulation resistance values.

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Latent image exposure monitor using scatterometry

Draper, Bruce L.

We discuss the use of light scattered from a latent image to control photoresist exposure dose and focus conditions which results in improved control of the critical dimension (CD) of the developed photoresist. A laser at a non-exposing wavelength is used to illuminate a latent image grating. The light diffracted from the grating is directly related to the exposure dose and focus and thus to the resultant CD in the developed resist. Modeling has been done using rigorous coupled wave analysis to predict the diffraction from a latent image as a function of the substrate optical properties and the photoactive compound (PAC) concentration distribution inside the photoresist. It is possible to use the model to solve the inverse problem: given the diffraction, to predict the parameters of the latent image and hence the developed pattern. This latent image monitor can be implemented in a stepper to monitor exposure in situ, or prior to development to predict the developed CD of a wafer for early detection of bad devices. Experimentation has been conducted using various photoresists and substrates with excellent agreement between theoretical and experimental results. The technique has been used to characterize a test pattern with a focused spot as small as 36{mu}m in diameter. Using diffracted light from a simulated closed-loop control of exposure dose, CD control was improved by as much as 4 times for substrates with variations in underlying film thickness, compared to using fixed exposure time. The latent image monitor has also been applied to wafers with rough metal substrates and focus optimization.

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Energy and Environment, August 1992. A Sandia Technology Bulletin

Parrott, Lori K.

A brief overview of selected programs at Sandia is presented. This issue contains high-lights on the following: Reducing risk in nuclear reactors; energy and environment news in brief; eliminating bottlenecks in plastics recycling; new technologies remedy old waste problems; new technologies remedy old waste problems; safe disposal of military components; and heat pipes for stirling engine testing.

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The estimation of electrical cable fire-induced damage limits

Nowlen, Steven P.

Sandia National Laboratories has, for several years, been engaged in the performance of both fire safety and electrical equipment qualification research under independent programs sponsored by the US Nuclear Regulatory Commission. Recent comparisons between electrical cable thermal damageability data gathered independently in these two efforts indicate that a direct correlation exists between certain of the recent cable thermal vulnerability information gathered under equipment qualification conditions and thermal damageability in a fire environment. This direct correlation allows for a significant expansion of the data base on estimated cable thermal vulnerability limits in a fire environment because of the wide range of cable types and products that have been evaluated as a part of the equipment qualification research. This paper provides a discussion of the basis for the derived correlation, and presents estimated cable thermal damage limits for a wide range of generic cable types and specific cable products. The supposition that a direct correlation exists is supported through direct comparisons of the test results for certain specific cable products. The proposed supplemental cable fire vulnerability data gained from examination of the equipment qualification results is presented. These results should be of particular interest to those engaged in the evaluation of fire risk for industrial facilities, including nuclear power plants.

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Optimization of expressions involving array classes

Budge, Kent G.

C++ is rapidly gaining in popularity as a scientific programming language. The data encapsulation inherent in the class concept and the availability of operator overloading for compact representation of operations make it an ideal language for translating concepts in mathematical physics into computer code. Furthermore, its strong type checking and memory management features facilitate correct coding of algorithms. Unfortunately, C++ code which is written in the true spirit of the language is often very inefficient under current compiler implementations. Many of the inefficiency issues, such as unnecessary copy operations or proliferation of temporaries, have been well-characterized. Some may be alleviated by clever C++ coding, but others cannot be alleviated except by writing C-like code that sacrifices one or more of the best features of the language. This document describes a major source of efficiency problems in expressions using overloaded operators on array classes, and proposes certain minor modifications to the C++ language standard which will facilitate optimization of these expressions.

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SAFSIM input manual: A computer program for the engineering simulation of flow systems

Dobranich, Dean

SAFSIM (System Analysis Flow SIMulator) is a FORTRAN computer program to simulate the integrated performance of systems involving fluid mechanics, heat transfer, and reactor dynamics. SAFSIM provides sufficient versatility to allow the engineering simulation of almost any system, from a backyard sprinkler system to a clustered nuclear reactor propulsion system. In addition to versatility, speed and robustness are primary goals of SAFSIM. SAFSIM contains three basic physics modules: (1) a one-dimensional finite element fluid mechanics module with multiple flow network capability; (2) a one-dimensional finite element structure heat transfer module with multiple convection and radiation exchange surface capability; and (3) a point reactor dynamics module with reactivity feedback and decay heat capability. SAFSIM can be used for gas (compressible) or liquid (incompressible) single-phase flow systems with primary emphasis on gases (or supercritical fluids). This document contains a description of all the information required to create an input file for SAFSIM execution.

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Automated dry powder dispenser for explosive components

Garcia, P.; Salmonson, J.C.

Sandia and Mound are developing a workcell that will automate the assembly of explosive components. Sandia is responsible for the automated powder dispenser subsystem. Automated dispensing of explosive powders in the past resulted in separation or segregation of powder constituents. The Automated Dry Powder Dispenser designed by Sandia achieves weight tolerances of {plus_minus}0.1 mg while keeping powderoxidizer separation to a minimum. A software control algorithm compensates fore changes in powder flow due to lot variations, temperature, humidity, and the amount of powder left in the system.

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Prompt critical control of the ACRR using a linear quadratic regulator design

Gilkey, Jeffrey C.

This paper describes the application of linear control design techniques to the problem of nuclear reactor control. The control algorithm consists of generating a nominal trajectory within the control authority of the reactor rod drives, and then following this trajectory with a gain scheduled linear quadratic regulator (LQR). A controller based on this algorithm has generated power pulses up to 100 MW on Sandia`s Annular Core Research Reactor (ACRR). Prompt critical control at $1.02 net reactivity and controlled start up rates over 350 DPM have also been demonstrated using tills controller.

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Energy distribution of trapped holes in irradiated SiO{sub 2}

Fleetwood, Daniel M.

There is a discrepancy between literature estimates of trapped-hole energies in irradiated SiO{sub 2} obtained via thermal and optical methods (0.6-1.4 eV and 3 eV, respectively). A method has been developed for obtaining an improved estimate of the energy distribution of trapped holes in irradiated SiO{sub 2}, which brings thermal and optical estimates into much closer agreement. Experimental and theoretical TSC (thermally stimulated current) spectra are shown for a soft MOS capacitor with a 350-nm oxide cycled through 4 irradiations (10 keV x rays) and TSC measurements. Four trap-energy distributions were also independently derived from TSC at different ramp rates for a 45-nm radiation-hardened oxide. The trap distributions inferred from TSC for the 45-nm hard oxide agree with each other and with that inferred for the soft 350-nm oxide. 2 figs, 8 refs. (DLC)

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Fine-particle iron catalysts: Testing program at Sandia National Laboratories

Stohl, F.V.

The use of fine-particle size (<40 nm) unsupported catalysts in the solubilization step of direct coal liquefaction may result in improved economics for direct coal liquefaction due to the possible enhanced yields of desired products, the potential for decreasing reaction severity, and the possibility of using less supported catalyst during liquefaction processing. To guide the research and development efforts for these new unsupported catalysts, it is necessary to evaluate the catalyst performance under standard test conditions so that the impacts of catalyst formulations from different laboratories can be compared. The objectives of this work are to develop standard coal liquefaction test procedures and to perform the testing of the novel fine-particle size liquefaction catalysts being developed in the DOE/PETC AR Coal Liquefaction program. As part of this effort, we have developed a factorial experimental design to enable evaluation of the catalysts over ranges of temperature, time, and catalyst loading. The standard test procedure uses DECS-17 Blind Canyon Coal and 9,10-dihydrophenanthrene (DHP) as the hydrogen donor. Product analyses include tetrahydrofuran (THF) conversion, heptane conversion, DHP recovery, and gas analyses. THF and heptane insoluble materials are analyzed for carbon, hydrogen, nitrogen and sulfur contents. Testing is performed in batch microautoclave reactors. The experimental design and test procedures are being evaluated using {minus}100 mesh pyrite as a catalyst.

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Monolithic, series connected GaAs photovoltaic power converters for optoelectronic component applications

Rose, B.H.

This report describes the features of monolithic, series connected photovoltaic converters which have been developed for applications where voltages are required that are higher than available using conventional single junction solar cells. These devices are intended to play a significant role in advanced weapon systems development. They are also appropriate for any other applications where electric power is needed in remote regions and electrical connection to the region is deemed detrimental for whatever reasons. Development of this technology at two outside contractors has been accomplished through competitive procurement in response to an internally generated Statement of Work. Detailed comparisons are made of data taken from converters of each type from both contractors. The primary advantage of these converters is that they are high voltage/low current devices compared to conventional single junction solar cells. This allows them to directly drive a wider range of loads without the necessity of power conditioning, such as provided by a transformer. Discussions of load analysis for given applications are included.

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Software security for a network storage service

Haynes, R.A.

In 1991, Sandia National Laboratories acquired a Network Storage Service (NSS) as a result of a fully competitive procurement. The Network Storage Service, which provides access to over a terabyte of data storage in a two-tiered hierarchy, had minimal software security features. Before the NSS could be placed into production, it had to be accredited by the Department of Energy, Sandia`s accrediting authority. Sandia was faced with implementing security features to allow the NSS to be operated in its secure computing network, which is a single security clearance, multiple data security level environment. This paper describes the software security design alternatives that were considered and what was ultimately implemented.

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Effect of oxide thickness on interface-trap buildup rates

Shaneyfelt, Marty R.

The time dependence of radiation-induced interface-trap charge buildup for MOS transistors of varying gate-oxide thickness was investigated in order to clarify how the location of hydrogen in the SiO{sub 2} contributes to N{sub it} buildup. Radiation-induced interface-trap buildup in wet and dry gate oxides is compared for irradiations and anneals at constant positive bias and for negative-bias irradiations followed by positive-bias anneals. Implications of these results for different models of interface-trap buildup are discussed. 2 figs, 9 refs. (DLC)

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Simulation of liquid drop breakup behavior in a flow field using discrete element techniques

Harper, Frederick T.

In this study, a discrete element technique was used to simulate drop breakup in two dimensions. A series of simulations in which the drop breakup occurred in the presence of a flow field was performed. The density ratio of the flow field to the drop in the simulations was comparable to many of the isothermal liquid/liquid drop breakup experiments performed to investigate hydrodynamic breakup during Fuel Coolant Interactions (FCIs). The randomly directed internal kinetic energy of the drop increased rapidly at the beginning of the interaction between the drop and the flow field due to momentum transfer from the flow field to the drop. After the initial increase in internal energy of the drop, the momentum transferred from the flow field to the drop in the form of translational kinetic energy of the center of mass of the drop. It was also observed that the drops simulated in the presence of a flow field required higher internal kinetic energies to fragment than did the drops observed in the simulations performed in the absence of a flow field.

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High speed imaging for flash radiography using PIN diodes

Selph, M.M.

A high speed readout imaging system utilizing a commercial flash X-ray machine and miniature X-ray detectors has been developed. This system was designed to operate in the environment near a nuclear detonation where film or camera imaging cannot be used. The temporal resolution of the system is set by the 20 nanosecond FWHM of the X-ray pulse. The spatial resolution of the system was determined by the size and close packing of the PIN diodes used as the X-ray detectors. In the array used here, the PIN diodes have an active area of 2mm in diameter and were placed 3.8mm center to center. Computer-generated images using algorithms developed for this system are presented and compared with an image captured on film in the laboratory.

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Application of the square root diffusivity analysis to measuring the diffusivity of multicomponent alloys

Romig Jr., Alton D.

The well known ``Boltzmann-Matano analysis`` can be used in general to measure the diffusivity of binary and ternary alloys. However for alloys containing four or more components, the analysis requires making assumptions, for example that the diffusivity is constant. Conversely, it can be shown that the ``square root diffusivity analysis`` applies to measuring diffusivities that vary with concentration, as long as the variation is linear with concentration. Methods of designing samples and evaluating data for the square root diffusivity analysis are discussed.

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Eddy current power dissipation at sharp corners

Warne, Larry K.

This paper develops corrections to the impedance per unit length when the conductor cross section includes sharp corners. The case of a right internal angle is treated in detail. Corrections are given for all values of the ratio of internal to external magnetic permeabilities. Both the real and imaginary parts of the corrections are determined. Application of the results to a conductor of square cross section is given. Higher order terms are developed and compared to a numerical solution.

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Summary on comparison of radiative heat transfer solutions for a specified problem

Skocypec, Russell D.

To assess the current capability for solving non-gray, anisotropically scattering multidimensional radiation problems, a specific problem was formulated for several participating authors to solve. They each applied their own methods to solve the problem, which was relevant to the modeling of heat transfer in coal-fired furnaces. This paper is a summary of the comparison of the results. Areas where future modeling efforts should address are identified.

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Bonding in simple phosphate glass

Brow, R.K.

The bonding configurations for simple phosphate glasses are quantitatively described by both the relative concentrations of different polyhedral phosphate sites (i.e., the Q{sup n} description) determined by {sup 31}p magic angle spinning nuclear magnetic resonance (MAS NMR) spectroscopy and by the relative concentrations of bridging and nonbridging oxygen as measured by x-ray photoelectron spectroscopy (XPS). Both spectroscopies illustrate the depolymerizing effects of modifier additions in two series of Na{sub 2}O and ZnO-P{sub 2}0{sub 5} glasses.

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RATLER: Robotic All-Terrain Lunar Exploration Rover

Purvis, James W.

A robotic rover vehicle designed for use in the exploration of the Lunar surface is described. The Robotic All-Terrain Lunar Exploration Rover (R.A.T.L.E.R.) is a four wheeled all-wheel-drive dual-body vehicle. A uniquely simple method of chassis articulation is employed which allows all four wheels to remain in contact with the ground, even while climbing over step-like obstacles as large as 1.3 wheel diameters. Skid steering and modular construction are used to produce a simple, rugged, highly agile mobility chassis with a reduction in the number of parts required when compared to current designs being considered for planetary exploration missions. The design configuration, mobility parameters, and performance of several existing R.A.T.L.E.R. prototypes are discussed.

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Heat-affected zone cracking of nitronic 60 stainless steel

Mcguire, Michael T.

Nitronic 60 is a nitrogen-strengthened austenitic stainless steel used for applications where metal-to-metal wear and galling resistance are required. In addition, it does not transfer to martensite with strain or upon cooling to cryogenic temperatures. In comparison to type 304 stainless steel, the nickel content is similar, chromium content is slightly reduced and manganese, silicon, and nitrogen are all increased in Nitronic 60. Although studies have shown that it can be joined with arc welding, it fabrication weldability is limited by heat-affected zone (HAZ) cracking. This study examined the HAZ cracking behavior of this alloy during autogenous gas tungsten arc welding and pulsed autogenous Nd:YAG welding.

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SE3158 development report

Siddiqui, M.A.

This report describes the SE3158 design and development tester that was designed by Digital Subsystem III Division 2314 at Sandia to support the development of the MC4073 SRAM II Programmer. The primary purpose of the SE3158 is to test the MC4073 SRAM II Programmer during its development phase.

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Nonideal thermoequilibrium calculations using a large product species data base

Shock Waves

Hobbs, Michael L.

Thermochemical data fits for approximately 900 gaseous and 600 condensed species found in the JANAF tables (Chase et al. 1985) have been completed for use with the TIGER non-ideal thermoequilibrium code (Cowperthwaite and Zwisler 1973). The TIGER code has been modified to allow systems containing up to 400 gaseous and 100 condensed constituents composed of up to 50 elements. Gaseous covolumes have been estimated following the procedure outlined by Mader (1979) using estimates of van der Waals radii for 48 elements and three-dimensional molecular mechanics. Molecular structures for all gaseous components were explicitly defined in terms of atomic coordinates in Å (Hobbs and Baer 1992a). The Becker-Kistiakowsky-Wilson equation of state (BKW-EOS) has been calibrated near C-J states using detonation temperatures measured in liquid and solid explosives and a large product species data base. Detonation temperatures for liquid and solid explosives were predicted adequately with a single set of BKW parameters. Values for the empirical BKW constants α, β, κ, and θ were 0.5, 0.174, 11.85, and 5160, respectively. Values for the covolume factors, κi, were assumed to be invariant. The liquid explosives included mixtures of hydrazine nitrate with hydrazine, hydrazine hydrate, and water; mixtures of tetranitromethane with nitromethane; liquid isomers ethylnitrate and 2-nitroethanol; and nitroglycerine. The solid explosives included HMX, RDX, PETN, Tetryl, and TNT. Color contour plots of HMX equilibrium products as well as thermodynamic variables are shown in pressure and temperature space. Similar plots for a pyrotechnic reaction composed of TiH2 and KClO4 are also reported. Calculations for a typical HMX-based propellant are also discussed. © 1992 Springer-Verlag.

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A Sandia weapon review bulletin : defense programs, Autumn 1992

Topics in this issue: (1) Focal Point and STEP. Sandia National Laboratories has always focused its advanced weapon development not only on future weapon needs, but also on the engineering and manufacturing sciences needed to meet them. Both areas are changing dramatically. As the nation dismantles many of its warheads, it becomes essential that those that remain are increasingly reliable, secure, capable, and safe. And as development resources diminish, it becomes vital that they are applied to the most critical technologies in a disciplined manner. The mission of the Focal Point program and the Stockpile Transition Enabling Program (STEP) is to develop processes for meeting these challenges. Focal Point offers a decision-making process for allocating Sandia's resources to meets its defense programs strategic goals. (2) Defense Programs news in brief. (3) Dismantling the nuclear stockpile. (4) W88/MK5: Arming, Fuzing, and Firing system meets all requirements and goals. (5) The Common Radar Fuze. (6) Insertable-explosive arming of firing sets. (7) Preparing for fewer underground tests.

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Natural fracture systems studies

Warpinski, Norman R.

The objectives of this program are (1) to develop a basinal-analysis methodology for natural fracture exploration and exploitation, and (2) to determine the important characteristics of natural fracture systems for use in completion, stimulation, and production operations. Natural-fracture basinal analysis begins with studies of fractures in outcrop, core and logs in order to determine the type of fracturing and the relationship of the fractures to the lithologic environment. Of particular interest are the regional fracture systems that are pervasive in western US tight sand basins. A Methodology for applying this analysis is being developed, with the goal of providing a structure for rationally characterizing natural fracture systems basin-wide. Such basin-wide characterizations can then be expanded and supplemented locally, at sites where production may be favorable. Initial application of this analysis is to the Piceance basin where there is a wealth of data from the Multiwell Experiment (MWX), DOE cooperative wells, and other basin studies conducted by Sandia, CER Corporation, and the USGS (Lorenz and Finley, 1989, Lorenz et aI., 1989, and Spencer and Keighin, 1984). Such a basinal approach has been capable of explaining the fracture characteristics found throughout the southern part of the Piceance basin and along the Grand Hogback.

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SMART: A modular architecture for robotics and teleoperation

Anderson, Richard E.

This paper introduces SMART: Sandia National Laboratory`s Modular Architecture for Robotics and Teleoperation. SMART is designed to integrate the different slave devices (e.g., large hydraulic arms, mobile manipulators, gantry robots), sensors (e.g., ultra-sonic sensors,force sensors), and input devices, (e.g., track ball,force-reflecting master, autonomous trajectory generators) required for waste management and environmental restoration tasks. The modular architecture allows for rapid synthesis of complex telerobotic systems. This paper introduces some sample modules and illustrates how the modules can be connected to achieve telerobotic behaviors. Examples include autonomous control, impedance control, and enhanced bilateral teleoperation.

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Results of an experiment in a Zion-like geometry to investigate the effect of water on the containment basement floor on direct containment heating (DCH) in the Surtsey Test Facility: The IET-4 test

Allen, Mark S.

This document discusses the fourth experiment of the Integral Effects Test (IET-4) series which was conducted to investigate the effects of high pressure melt ejection on direct containment heating. Scale models (1:10) of the Zion reactor pressure vessel (RPV), cavity, instrument tunnel, and subcompartment structures were constructed in the Surtsey Test Facility at Sandia National Laboratories. The RPV was modeled with a melt generator that consisted of a steel pressure barrier, a cast MgO crucible, and a thin steel inner liner. The melt generator/crucible had a hemispherical bottom head containing a graphite limitor plate with a 3.5-cm exit hole to simulate the ablated hole in the RPV bottom head that would be tonned by tube ejection in a severe nuclear power plant accident. The reactor cavity model contained 3.48 kg of water with a depth of 0.9 cm that corresponded to condensate levels in the Zion plant. A 43-kg initial charge of iron oxide/aluminum/chromium thermite was used to simulate corium debris on the bottom head of the RPV. Molten thermite was ejected into the scaled reactor cavity by 6.7 MPa steam. IET-4 replicated the third experiment in the IET series (IET-3), except the Surtsey vessel contained slightly more preexisting oxygen (9.6 mol.% vs. 9.0 mol.%), and water was placed on the basement floor inside the crane wall. The cavity pressure measurements showed that a small steam explosion occurred in the cavity at about the same time as the steam explosion in IET-1. The oxygen in the Surtsey vessel in IET-4 resulted in a vigorous hydrogen bum, which caused a significant increase in the peak pressure, 262 kPa compared to 98 kPa in the IET-1 test. EET-3, with similar pre-existing oxygen concentrations, also had a large peak pressure of 246 kPa.

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Efficient wiring of reconfigurable parallel processors

Greenberg, D.S.

The advent of chips which include one or more CPUS, some local memory, and rudimentary communications and routing hardware has opened a new area in computer architecture design. What is the best way to connect these chips to solve particular problems? This paper defines the efficiency of a wiring scheme for a set of communication patterns. It then gives upper and lower bounds on the best efficiency achievable. It also presents simple wiring schemes for some stencil patterns used in mesh-based discrete simulations.

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Thermal diffusion processes in aqueous sodium chloride solutions

Cygan, Randall T.

The experimental results for the Soret coefficients are variable, but suggest a trend with NaCl concentration that is consistent with electrolyte solution behavior. The temperature dependence of the Soret coefficients is in approximate agreement with previous measurements obtained using other techniques. In general, the Soret coefficient values are best interpreted based on the expansion of the fluid inclusion migration fields. The high temperature values for {sigma} at 1.0 N NaCl concentration suggest an expansion of the migration field to smaller inclusion sizes, which for a single halite crystal at these conditions, approach a dimension of one micron. The corresponding fluid inclusion size for the polycrystalline material, where grain boundaries retard the migration, is approximately 10 microns. Although the Soret results obtained in the present study provide additional data for high temperature applications in nuclear waste isolation, more experimentation and new equipment design are required in order to obtain data at temperatures above 80{degree}C. The experimental approach utilized in this study is limited in that respect. The almost immeasurable nature of the thermal diffusion process for the brines as examined in the laboratory, suggests that this effect will be insignificant (outside of fluid inclusion migration) in most rock-water interactions associated with a rocksalt nuclear waste repository. Other effects, such as convective fluid transport, pressure solution, and groundwater flow, will be orders-of-magnitude more important in evaluating the critical nature of brine migration, waste canister corrosion, and the potential for leaching radioisotopes from waste repositories.

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Boiler efficiency methodology for solar heat applications

Pacheco, James E.

This report contains a summary of boiler efficiency measurements which can be applied to evaluate the performance of steam-generating boilers via both the direct and indirect methods. This methodology was written to assist industries in calculating the boiler efficiency for determining the applicability and value of thermal industrial heat, as part of the efforts of the Solar Thermal Design Assistance Center (STDAC) funded by Sandia National Laboratories. Tables of combustion efficiencies are enclosed as functions of stack temperatures and the amount of carbon dioxide and carbon monoxide in the gas stream.

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An analysis of radionuclide behavior in water pools during accidents at the Annular Core Research Reactor

Powers, Dana A.

Physical and chemical phenomena that will affect the behavior of radionuclides released from fuel in the Annular Core Research Reactor during a hypothetical, core disruptive accident are described. The phenomena include boiling of water on heated clad, metal-water reactions, vapor nucleation to form aerosol particles, coagulation of aerosol particles, aerosol deposition within bubbles rising through the shield pool, vapor dissolution in the shield pool, and revaporization of radionuclides from the shield pool. A model of these phenomena is developed and applied to predict the release of radionuclides to the confinement building of the Annular Core Research Reactor. It is found that the shield pool provides overall decontamination factors for particulate of about 2.8 {times} 10{sup 5} and decontamination factors for noble gases of about 2.5--3.7. These results are found to be sensitive to the predicted clad temperature and bubble behavior in the shield pool. Slow revalorization of krypton, xenon and iodine from the shield pool is shown to create a prolonged, low-intensity source term of radioactive material to the confinement atmosphere.

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Robust solder joint attachment of coaxial cable leads to piezoelectric ceramic electrodes

Vianco, Paul T.

A technique was developed for the solder attachment of coaxial cable leads to the silver-bearing thick film electrodes on piezoelectric ceramics. Soldering the cable leads directly to the thick film caused bonds with low mechanical strength due to poor solder joint geometry. A barrier coating of 1.5 {mu}m Cu/1.5 {mu}m Ni/1.0{mu}m Sn deposited on the thick film layer improved the strength of the solder joints by eliminating the absorption of Ag from the thick film which was responsible for the improper solder joint geometry. The procedure does not require special preparation of the electrode surface and is cost effective due to the use of non-precious metal films and the batch processing capabilities of the electron beam deposition technique.

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A grid refinement study of two-dimensional transient flow over a backward-facing step using a spectral-element method

Torczynski, John R.

The two-dimensional transient flow over a backward-facing step is numerically simulated using the spectral-element computational fluid dynamics code NEKTON. The simulated geometry corresponds to that of Kaiktsis et al. (1991) and Armaly et al. (1983), and flow is examined at Reynolds numbers of 500 and 800. A systematic grid refinement study is performed by varying both the element size and the order of the polynomial representation within the elements. For both values of the Reynolds number, it is observed that low-resolution cases exhibit sustained chaotic temporal behavior but that high-resolution cases evolve toward asymptotically steady flow by a monotonic decay of the transient. The resolution required to obtain asymptotically steady behavior is seen to increase with Reynolds number. These results suggest that the recently reported transition to chaotic flow at Reynolds numbers around 700 is an artifact of inadequate spatial resolution. The cause of resolution-dependent temporal behavior of spectral-element methods is explored.

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Photothermal deflection spectroscopy of conjugated polymers

Synthetic Metals

Seager, Carleton H.

Along with the third-order nonlinear susceptibility, χ(3), the magnitude of the optical absorption in the transparent window below the principal absorption edge is an important parameter for conjugated polymers used in active integrated optical devices. Photothermal deflection spectroscopy (PDS) is an ideal technique for determining the absorption coefficients of thin films of 'transparent' materials. We have used PDS to measure the optical absorption spectra of the conjugated polymers, poly(1,4-phenylene-vinylene) (and derivatives) and polydiacetylene-4BCMU, in the spectral region from 0.55 to 3 eV. We find that the shape of the absorption edge varies considerably from polymer to polymer, with polydiacetylene-4BCMU having the steepest absorption edge. The minimum absorption coefficients measured varied somewhat with sample age and quality, but were typically in the range 1-10 cm-1. In the region below 1 eV, overtones of C-H stretching modes dominate the absorption behavior. We also observe that irradiation of all of these polymers with light above ∼ 2.5 eV produces enhanced absorption below the fundamental edge. In the absence of light, these excitations decay with characteristic times of 10-1000 s and in some cases they may determine the effective IR transparency in the energy range 1.0-1.8 eV. © 1992.

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Core-concrete interactions using molten UO sub 2 with zirconium on a basaltic basemat: The SURC-2 experiment

Copus, E.R.

An inductively heated experiment, SURC-2, using prototypic U0{sub 2}-ZrO{sub 2} materials was executed as part of the Integral Core-Concrete Interactions Experiments Program. The purpose of this experimental program was to measure and assess the variety of source terms produced during core debris/concrete interactions. These source terms include thermal energy released to both the reactor basemat and the containment environment, as well as flammable gas, condensable vapor and toxic or radioactive aerosols generated during the course of a severe reactor accident. The SURC-2 experiment eroded a total of 35 cm of basaltic concrete during 160 minutes of sustained interaction using 203.9 kg of prototypic U0{sub 2}-ZrO{sub 2} core debris material that included 18 kg of Zr metal and 3.4 kg of fission product simulants. The meltpool temperature ranged from 2400--1900{degrees}C during the first 50 minutes of the test followed by steady temperatures of 1750--1800{degrees}C during the middle portion of the test and increased temperatures of 1800--1900{degrees}C during the final 50 minutes of testing. The total erosion during the first 50 minutes was 15 cm with an additional 7 cm during the middle part of the test and 13 cm of ablation during the final 50 minutes. Comprehensive gas flowrates, gas compositions, and aerosol release rates were also measured during the SURC-2 test. When combined with the SURC-1 results, SURC-2 forms a complete data base for prototypic U0{sub 2}-ZrO{sub 2} core debris interactions with concrete.

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5AH10 Nickel-Cadmium (NiCad) Battery Maintenance Tester: User`s manual

Justice, L.B.; Wakefield-Reyes, C.

This manual is a user`s guide to the SE3253 and SE3254 versions of the 5AH10 Battery Maintenance Tester, a charger/discharger and test system for the 24-Cell 5-Ah Nickel-Cadmium Battery Pack. The manual provides information on rack equipment, power, communications, theory of operations, user interface, and operating procedures. Copies of users manuals for all equipment comprising the Battery Maintenance Tester are included as appendices.

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A philosophy for space nuclear systems safety

Marshall, Albert C.

The unique requirements and contraints of space nuclear systems require careful consideration in the development of a safety policy. The Nuclear Safety Policy Working Group (NSPWG) for the Space Exploration Initiative has proposed a hierarchical approach with safety policy at the top of the hierarchy. This policy allows safety requirements to be tailored to specific applications while still providing reassurance to regulators and the general public that the necessary measures have been taken to assure safe application of space nuclear systems. The safety policy used by the NSPWG is recommended for all space nuclear programs and missions.

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Reliability analysis of a utility-scale solar power plant

Kolb, Gregory J.

This paper presents the results of a reliability analysis for a solar central receiver power plant that employs a salt-in-tube receiver. Because reliability data for a number of critical plant components have only recently been collected, this is the first time a credible analysis can be performed. This type of power plant will be built by a consortium of western US utilities led by the Southern California Edison Company. The 10 MW plant is known as Solar Two and is scheduled to be on-line in 1994. It is a prototype which should lead to the construction of 100 MW commercial-scale plants by the year 2000. The availability calculation was performed with the UNIRAM computer code. The analysis predicted a forced outage rate of 5.4% and an overall plant availability, including scheduled outages, of 91%. The code also identified the most important contributors to plant unavailability. Control system failures were identified as the most important cause of forced outages. Receiver problems were rated second with turbine outages third. The overall plant availability of 91% exceeds the goal identified by the US utility study. This paper discuses the availability calculation and presents evidence why the 91% availability is a credible estimate. 16 refs.

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Ground test facilities for evaluating nuclear thermal propulsion engines and fuel elements

Allen, G.C.; Beck, D.F.; Harmon, C.D.; Shipers, L.R.

Interagency panels evaluating nuclear thermal propulsion development options have consistently recognized the need for constructing a major new ground test facility to support fuel element and engine testing. This paper summarizes the requirements, configuration, and design issues of a proposed ground test complex for evaluating nuclear thermal propulsion engines and fuel elements being developed for the Space Nuclear Thermal Propulsion (SNTP) program. 2 refs.

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Emergency diesel starting system monitor: Applications

Bundy, H.R.

The US Department of Energy`s Nuclear Plant Lifetime Improvement Program is investigating the use of prognostic monitoring to extend the operational lifetime of specific equipment. Benefits of these achievements will include safer and more reliable nuclear Plants, reduced maintenance costs, and increased lifetime of equipment. This report describes the development and application of a monitoring system designed to predict starting system performance of Emergency Diesel Generators. The monitor system is evaluated on two different engines, each using a different method of starting.

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Portable acoustic wave sensors for volatile organic compounds

Frye, G.C.; Cernosek, R.W.; Martin, S.J.

Portable acoustic wave sensor (PAWS) systems are being developed for real-time, on-line monitoring of volatile organic compounds (VOC`s). These systems are built around acoustic wave (SAW) devices coated with viscoelastic polymers. Two independent responses of the SAW sensor, wave velocity and wave attenuation, are measured to provide information about the chemical species sorbed by the coating. Rapid, reversible detection of gas phase volatile organics has been demonstrated for process monitoring and waste minimization in environmentally conscious manufacturing (ECM) applications and for documenting contaminant concentrations in remediation efforts.

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Overview: Hard Rock Penetration

Dunn, J.C.

The Hard Rock Penetration program is developing technology to reduce the costs of drilling and completing geothermal wells. Current projects include: lost circulation control, rock penetration mechanics, instrumentation, and industry/DOE cost shared projects of the Geothermal Drilling organization. Last year, a number of accomplishments were achieved in each of these areas. A new flow meter being developed to accurately measure drilling fluid outflow was tested extensively during Long Valley drilling. Results show that this meter is rugged, reliable, and can provide useful measurements of small differences in fluid inflow and outflow rates. By providing early indications of fluid gain or loss, improved control of blow-out and lost circulation problems during geothermal drilling can be expected. In the area of downhole tools for lost circulation control, the concept of a downhole injector for injecting a two-component, fast-setting cementitious mud was developed. DOE filed a patent application for this concept during FY 91. The design criteria for a high-temperature potassium, uranium, thorium logging tool featuring a downhole data storage computer were established, and a request for proposals was submitted to tool development companies. The fundamental theory of acoustic telemetry in drill strings was significantly advanced through field experimentation and analysis. A new understanding of energy loss mechanisms was developed.

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Universal Authenticated Item Monitoring System (AIMS) second generation equipment

Schoeneman, J.L.

Sandia National Laboratories (SNL) is in the final stages of developing a Universal Authenticated Item Monitoring System (AIMS). When completed, AIMS will provide applicable agencies in the US government, and those in the International arena, with a secure and convenient method of monitoring the physical status of selected items. The benefit derived from this development activity will be the commercial availability of an item monitoring system with the capability for ``quick set-up`` monitoring, as well as long-term unattended monitoring. The AIMS includes a variety of sensors, a robust and authenticated radio frequency (RF) communication link, a Receiver Processing Unit (RPU), and an inspector-friendly personal computer (PC) interface for collecting, sorting, viewing and archiving pertinent event histories. The system will provide the capability to monitor selected items in a real-time mode, a remotely interrogated mode, and a stand-alone, unattended data collection mode. The sensor suite under development includes advanced motion sensors, interior volumetric intrusion sensors, Re-usable, In-situ Verifiable Authenticated (RIVA) fiber-optic seal sensors, generic utility sensors (to accommodate contact closure inputs), and radiation and environmental sensors. A new generation authentication algorithm recently has been developed that provides a high degree of system security 121. The AIMS has potential safeguards applications in the areas of arms control and treaty verification military asset control, International Atomic Energy Agency (IAEA) and Euratom safeguards verification activities, as well as domestic nuclear safeguard activities. Commercial applications could include high-value inventory control and security systems. This paper describes the second-generation AIMS along with its recently expanded sensor suite and enhanced data collection capabilities.

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Authentication system for the JAERI Fast Critical Facility Advanced Containment and Surveillance System

Ystesund, Kenneth J.

In a joint effort conducted by Sandia National Laboratories, the International Atomic Energy Agency (IAEA), and the Japan Atomic Energy Research Institute (JAERI), an authentication system has been installed at the Fast Critical Assembly (FCA) facility in Tokai-mura, Japan. The purpose of this authentication system is to provide the IAEA with an independent means of authenticating the operator-provided Advanced Containment and Survellance (AC/S) system already in place at the facility. Authentication Controllers were installed at the AC/S Portal Monkor and Penetration Monitor to collect data and to randomly test sensor functions between IAEA inspections. During each inspection the authentication data is collected with an Inspector`s portable computer and printed for comparison to the data recorded by the AC/S system. Installation of the authentication equipment took place in November 1991 and a three-month field test began in December 1991. This paper will describe the authentication system, the operator interface, and the preliminary results of the field tests.

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Public-key data authentication for treaty verification

Draelos, Timothy J.

A public-key Treaty Data Authentication Module (TDAM) based on the National Institute of Standards and Technology (NIST) Digital Signature Standard (DSS) has been developed to support treaty verification systems. The TDAM utilizes the Motorola DSP56001 Digital Signal Processor as a coprocessor and supports both the STD Bus and PC-AT Bus platforms. The TDAM is embedded within an Authenticated Data Communication Subsystem (ADCS) which provides transparent data authentication and communications, thereby concealing the details of securely authenticating and communicating compliance data and commands. The TDAM has been designed according to the NIST security guidelines for cryptographic modules. Public-key data authentication is important for support of both bilateral and multi-lateral treaties. 8 refs.

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The effect of temperature dependent thermal properties on parametric weld size predictions

Knorovsky, Gerald A.

Parametric weld size predictions, in which weld size and shape are predicted given a knowledge of material and process parameters, offer a great deal of benefit to the welding engineer. This is so because the technique promises to replace expensive and time-consuming lab or shop activity followed by destructive examination with simple numeric or nomographic calculations. The work to be presented here uses a simple two-dimensional axisymmetric spot-on-plate computer simulation in which thermal diffusivity vs temperature is varied.

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Flexible data communications: The primary challenge in rapidly deployable integrated security systems

Christiansen, M.L.

The change in the world military posture and the reduction in military personnel require the flexible and rapid deployment of priority defense assets. Air Force security personnel and operators must maintain the ability to secure these deployed assets and receive advanced warning of threats. The Air Force will meet this need through the Dispersed Integrated Security System (DISS). The system will be rapidly deployable, relocatable, support mission flexibility, and be capable of intrusion detection, area and alarm display, night assessment, and wireless data communications. Wireless links, as obtained through radio, are quickly deployed and cost less than their hardwire counterpart when labor cost and equipment reuse are considered. DISS communications systems will be flexible and have broad application. By integrating commercial components and using menu-driven setup procedures, low cost, versatile, easy-to-use communication systems will be implemented to meet Air Force user requirements and provide desired capabilities.

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Technology Development for the US/DOE CRWMS

Case Jr., R.S.

It has long been United States Government (USG) policy to actively support nuclear nonproliferation efforts, as evinced in the 1970 US ratification of the Nuclear I Nonproliferation Treaty (NPT) and the 1978 US Voluntary Treaty with the IAEA (INFCIRC/288). Under INFCIRC 288, US facilities without direct national security involvement are eligible for International Atomic Energy Agency (IAEA) safeguards. Throughout the past decade, the IAEA has selected one or two US facilities for implementation of IAEA safeguards at a given time. The facilities selected have generally been those which allowed the IAEA to test new or advanced safeguards techniques, facilities which were prototypical or similar to other nuclear facilities which they will have to safeguard in other countries, or facilities which have been engaged in international commerce in nuclear materials. The US is now actively addressing issues of the interim and permanent disposal of nuclear waste and spent nuclear fuel -- the back end of the open US nuclear fuel cycle. The Nuclear Waste Policy Act (NWPA) of 1982 designated the US Department of Energy (DOE) to be responsible for the long term storage and isolation from the biosphere of spent nuclear fuel (SNF) and high-level waste (HLW) and created the DOE Office of Civilian Radioactive Waste Management (OCRWM) to develop, construct, and manage the Civilian Radioactive Waste Management System (CRWMS). Refinements to the NWPA occurred in 1987 in the Nuclear Waste Policy Amendments Act of 1987. CRWMS facilities will be eligible for IAEA safeguards. They are likely to be selected because they will be among the first SNF and HLW disposal operations worldwide.

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Robotics applications for the staging of weapon components

Martin, F.; Caskey, B.

As the US nuclear stockpile is reduced, large numbers of nuclear components must be placed in storage. The necessity for periodic inventories of these components as well as the act of placement of the components in storage areas could result in increased radiation exposure to operations personnel. The use of robotics can significantly reduce or even eliminate such exposure. An automated system is being designed in a project at Sandia Laboratories to allow an operator to remotely stack and retrieve component containers in storage areas using a robotic loader and a portable control console. The operator need not enter the storage area. Operator commands for the loader would be implemented through a supervisory architecture that would insure that the loader did not violate safety constraints. Individual aspects of the loader`s activities would be automated to reduce possible operator errors for many repetitive tasks. The loader will be outfitted with appropriate sensors so that the supervisory controller can enforce safe operations. The system will be configured so that monitoring of components for accountability can be accomplished.

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DOE International Technology Exchange Program (ITEP): Technical integration of sensor technology development

Ducharme, A.R.; Silva, R.J.; Bickford, D.F.

To achieve the goal of remediating waste sites throughout its complex and of bringing its facilities into full compliance by the year 2019, the DOE has established the Office of Environmental Restoration and Waste Management (E). Within E, the Office of Technology Development (OTD) has been created to develop technologies that will support DOE`s cleanup goal. The OTD is accelerating remediation technology application by leveraging the expenditure of available funds through international technology development and demonstration projects. These projects will address EM`s environmental restoration and waste management needs. For this reason, the OTD has created the International Technology Exchange Program (ITEP) whose primary objective is to effect collaboration among governments, industries, and educational institutions to identify worldwide technologies suitable for this purpose. These technologies should also meet US commercial needs. The ITEP will also serve as a mechanism for transferring technologies developed under DOE sponsorship to US industry for ultimate application in the international arena.

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EnviroTRADE: An information system for providing data on environmental technologies and needs worldwide

Harrington, M.W.

The US Department of Energy (DOE) has committed to the remediation of waste sites throughout its complex, and has recognized that it can accelerate its technology development efforts and leverage the expenditure of available funds through an international cooperation among government entities, private industry, and educational institutions. To support the technology transfer of environmental information, the DOE has sponsored the development of EnviroTRADE - an international information system that will facilitate the exchange of environmental restoration and waste management technologies worldwide. During DOE`s fiscal year 1992, a beta prototype is being developed by Sandia National Laboratories (SNL). During fiscal year 1993 and beyond, the full system will be developed and networked among international users. The system will contain profiles on both environmental restoration/waste management needs and foreign/domestic technologies. Users will be able to identify matches between worldwide needs and available or emerging technologies. Where matches between needs and existing technologies are not found, the system will identify the potential for development of new and innovative technologies to address environmental problems. EnviroTRADE will also provide general information on international environmental restoration and waste management organizations, sites, activities, and contacts.

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The Annular Core Research Reactor (ACRR) postulated limiting event initial and building source terms

Restrepo, L.F.

As part of the update of the Safety analysis Report (SAR) for the Annular Core Research Reactor (ACRR), operational limiting events under the category of inadvertent withdrawal of an experiment while at power or during a power pulse were determined to be the most limiting event(s) for this reactor. This report provides a summary of the assumptions, modeling, and results in evaluation of: Reactivity and thermal hydraulics analysis to determine the amount of fuel melt or fuel damage ratios; The reactor inventories following the limiting event; A literature review of post NUREG-0772 release fraction experiment results on severe fuel damages; Decontamination factors due to in-pool transport; and In-building transport modeling and building source term analysis.

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Preliminary lightning tests: Optical fiber penetration of an exclusion region barrier

Fisher, R.J.

As part of the Direct Optical Initiation (DOI) program, an assessment of the possibility of introducing lightning energy into an exclusion region via an Optical Barrier Feedthrough (OBF) is being carried out. One postulated penetration mechanism is the tracking of current past the OBF on the surface of the dielectric optical fiber itself. During September and October of 1991, a series of tests was conducted on a closed metallic cylindrical test object representing the electrical exclusion region of a weapon. Median-level (30-kA) and severe (200-kA) simulated lightning return strokes, singly, doubly, and in combination with a moderate continuing current, were attached directly to the exterior portion of a fiber optic cable, which penetrated through a hole of controlled size into the interior of the exclusion region. The thickness of the barrier surrounding the hole was 0.06 in. Attempts were made to measure any conducted current flowing on the fiber at distances of 1 and 4 inches from the interior surface of the stainless steel top of the cylinder. Test parameter variations included diameter of the penetration hole (475 and 500 microns), length of the exterior portion of the cable and whether or not its jacket was present, and the applied test currents. It is concluded that no signal above measurement noise was recorded on any of the data shots that made up the test series. Measurement resolution was of the order of several amperes. Based on the highest recorded response of 8.5 A, corresponding to a 200-kA input, the OBF can be characterized by a direct-strike lightning attenuation factor of approximately 5 {times} lO{sup {minus}5} or better. Based on the more typically observed noise level of a few amps, the attenuation is commensurately greater.

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Results 99001–99200 of 101,000
Results 99001–99200 of 101,000
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