Publications

Goal was to obtain dynamic mechanical property data on a quartz phenolic (abbreviated QP) composite. Shock loading and shock release measurements have been conducted using impact techniques utilizing both a light-gas gun and a powder gun at impact pressures up to 20 GPa. The primary diagnostic tool used was a velocity interferometer. The data analysis includes Hugoniot measurements to give both pressure-particle velocity and shock velocity-particle velocity relationships; spall measurements to determine the fracture stress at which the material spells; and attenuation measurements to determine the shock attenuation with material thickness. The QP Hugoniot relationship was found to be significantly different than that of a phenolic without a filler material indicating that the impedance of the QP used in this investigation was higher. The spall strength was measured to be {approximately}0.075 GPa, similar to nonfilled phenolic, which indicated that the presence of quartz fibers was not contributing to the fracture strength. The material was found to attenuate an imposed shock of approximately 6.3 GPa pressure and 0.18 {mu}s to 50% of the initial impact value after a propagation distance of 7mm.

Sandia National Laboratories is currently involved in the optimization of a Plane Shock Generator Explosive Lens (PSGEL). The PSGEL component consists of a detonator, explosive, brass cone and tamper housing. The purpose of the PSGEL component is to transmit a plane shock wave through the 4340 steel bulkhead (wave separator) which has a ferro-electric (PZT)ceramic disk attached to the opposite surface of the steel bulkhead. The planar shock wave depolarizes the PZT 65/35 ferro-electric ceramic to produce an electrical output. One aspect of the optimization program involves the possible replacement of 4340 steel with PH13-8Mo steel for the bulkhead. These materials, as well as the PZT 65/35 ferro-electric ceramic and the brass for the cone, required the stock characterization with respect to Hugoniot parameters. The work presented here gives the shock Hugoniot values for these four materials and documents their measurements.

This study involved the shock characterization of Diallyl Phthalate (DAP), in particular, the equation of state as measured by the shock Hugoniot. Tests were done between 1 and 11 GPa impact shock pressure. The Hugoniot parameters were determined to be: [rho][sub 0]= 1.743, C[sub 0] = 2.20, and S = 2.33.

A series of shock-loading experiments on a nitrocellulose-based (NC-based) gun propellant was conducted using a light-gas gun. The intent of this work was to characterize the shock sensitivity of the gun propellant. The initial objectives were to obtained Hugoniot data and to investigate the pressure threshold at which a reaction initiates. For the Hugoniot/reaction threshold experiments, 1/4-length grains of propellant were mounted on the front of projectiles and were impacted onto either polymethylmethacrylate (PMMA), fused silica or sapphire targets at velocities as high as 1.4 mm/{mu}s, the upper limit of the gun. The particle velocity data obtained from the VISAR (Velocity Interferometer System for Any Reflector) records for the propellant fit a Hugoniot curve found in the Russian literature for a double-base, NC-nitroglycerine propellant. The density initial bulk sound velocity, and empirical parameter S values for the gun propellant were 1.63 g/cm{sup 3}, 1.70 mm/{mu}s and 1.85, respectively. VISAR data were also used to obtained the ignition threshold pressures of the gun propellant. Reactions were observed at impact pressures of 2.6 GPa and above. 5 refs., 6 figs., 1 tab.

A series of impact experiments on a composite propellant, an energetic propellant, and their simulants was recently completed using a light-gas gun. Previous experiments were done to obtain Hugoniot data, to investigate the pressure threshold at which a reaction occurs, and to measure spall damage at various impact velocities. The present studies measured the attenuation of shock waves in these materials, completing the shock characterization needed for material modeling. An initial impulse of 2.0 GPa magnitude and {approximately}0.6 {mu}s duration was imposed upon samples of various thicknesses. VISAR was used to measure the free-surface velocity at the back of the samples; these data were used to generate a curve of shock-wave attenuation versus sample thickness for each material. Results showed that all four materials attenuated the shock wave very similarly. Material thicknesses of 3.0, 7.62, 12.7, and 19.0 mm attenuated the shock wave {approximately}16%, 33%, 50%, and 66% respectively. 14 refs., 12 figs., 4 tabs.

A series of shock-loading experiments on an energetic propellant and its simulant was conducted on a light-gas gun. The purpose of this work was to characterize the shock sensitivity of WAK-2, which is a composite-modified, double-based, booster-rocket propellant and its simulant UGS. The initial objectives were to obtain Hugoniot data, to investigate the pressure threshold at which a reaction occurs, and to measure spall threshold at various impact velocities. The Hugoniot data obtained for the propellant fits the Hugoniot curve provided by the manufacturer of the propellant. A Hugoniot curve developed for the simulant was found to match that of the propellant. The initial density, {rho}{sub 0}, initial bulk sound velocity, C{sub 0}, and constant S values for the energetic propellant WAK-2 and its simulant UGS were 1.85 g/cm{sup 3}, 2.2 mm/{mu}s and 2.66, respectively. The ignition threshold pressure of the WAK-2 was found to be in the range of 3 kbar. A violent reaction was observed for a sample impacted at a pressure of 22 kbar. In spall tests, impact pressures in the range of 1.1 to 3.1 kbar were applied to the propellant/simulant. The propellant exhibited spall strengths {approximately}0.33 kbar, with its simulant being somewhat weaker, {approximately}0.22 kbar. Scanning electron microscopy and electron microprobe analysis were used to characterize the microstructures of the materials and to determine the details of the spall events. 20 refs., 19 figs., 9 tabs.