The Sandia National Laboratories, in California (Sandia/CA) is a research and development facility, owned by the U.S. Department of Energy’s National Nuclear Security Administration agency (DOE/NNSA). The laboratory is located in the City of Livermore (the City) and is comprised of approximately 410 acres. The Sandia/CA facility is operated by National Technology and Engineering Solutions of Sandia, LLC (NTESS) under a contract with the DOE/NNSA. The DOE/ NNSA’s Sandia Field Office (SFO) oversees the operations of the site. North of the Sandia/CA facility is the Lawrence Livermore National Laboratory (LLNL), in which Sandia/CA’s sewer system combines with before discharging to the City’s Publicly Owned Treatment Works (POTW) for final treatment and processing. The City’s POTW authorizes the wastewater discharge from Sandia/CA via the assigned Wastewater Discharge Permit #1251 (the Permit), which is issued to the DOE/NNSA’s main office for Sandia National Laboratories, located in New Mexico (Sandia/NM). The Permit requires the submittal of this Monthly Sewer Monitoring Report to the City by the twenty-fifth day of each month.
TBSmerged integrates data from instruments flown on ARM’s Tethered Balloon System missions that collect in situ measurements of temperature, humidity, wind speed, wind direction, and aerosol properties with estimates of cloud base and boundary layer height from a surface-based ceilometer to improve the ease of use of TBS datasets. TBSmergedincloud includes supercooled liquid water content (tbsslwc) measurements collected within the cloud.
The overarching goal of the combined computational and experimental R&D activities proposed in this project is to enhance understanding of the mechanisms and thermal-mechanical-chemical (TMC) parameters controlling the instant release fraction (IRF) and matrix dissolution of high-burnup (HB; burnup) spent nuclear fuels (SNFs) and the subsequent formation, stability, and phase transformations of SNF alteration products under long-term storage and geological disposal conditions. Uranium dioxide may undergo oxidative corrosion/alteration, and the IRF may be increased for HB SNF, both of which may affect environmental systems associated with SNF long-term storage and disposal. The oxidative matrix dissolution may form various complex uranyl-based phases, including a rich variety of oxides, silicates, carbonates and other secondary minerals in varied geological environments (e.g., studtite, metastudtite, amorphous uranyl peroxide, uranium trioxide, triuranium octoxide, schoepite, dehydrated schoepite, metaschoepite, becquerelite, soddyite, rutherfordine,...). These uranyl phases generally have higher mobility UO2+2 species than less soluble U4+ phases. However, limited information on the thermodynamic properties and formation kinetics of these uranyl-bearing phases is available to predict explicitly paragenesis under the conditions relevant to long-term storage or disposal. The proposed project draws on complementary expertise and research backgrounds from the team members: (i) to apply a combined ab initio modeling (UNLV/UTEP and SNL) and experimental (UNLV) strategy investigating the high-temperature TMC mechanisms of alteration of SNF under α-radiolysis conditions; (ii) to investigate the mechanistic of phase transformations in UNF degradation products under various conditions expected in long-term storage systems (e.g. (UO2)O2(H2O)4 → (UO2)O2(H2O)2 → U2O7 → UO3 → U3O8); (iii) to determine high-accuracy TMC parameters for complex uranyl-based phases formed in storage or geological disposal environments (e.g. UO3(H2O)2, Ca[(UO2)6O4(OH)8]8H2O, (UO2)2(SiO4)32H2O,…). The unforeseen COVID-19 pandemic led to the laboratory/campus closure since March 2020, that resulted in a significant delay in reaching milestones in a satisfactory manner, due to (i) the statewide recommendation from stop-working to later limited work in the lab and work-from-home (WFH), (ii) no in-person interactions, and (iii) a hiring freeze at UNLV. Therefore, a no cost extension (10/01/2021- 9/30/2022) was requested to help make up the time we lost during the global pandemic in 2020-2021, leading to paradigm shifts in the focus of the project in the following three main tasks: Task 1 (Computational), Task 2 (Experimental), and Task 3 (Final report, due on 12/29/2022).
This SAND report provides system effectiveness analysis results for notional chemical facilities. Two facilities were analyzed in total, evaluating the effectiveness of the unique security systems in place at each location. Each analysis looked at a range of threat and response capabilities, specific target configurations, and task times to acquire target material in both theft and release scenarios. This report details results for both facilities.
