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Functionally graded magnetic materials: a perspective to advance charged particle optics through compositional engineering

Materials Research Letters

Lang, Eric; Milne, Zac; Adamczyk, Jesse A.; Barrick, Erin J.; Firdosy, Samad; Ury, Nicholas; Dillon, R.P.; Monson, Todd M.; Kustas, Andrew K.; Jungjohann, Katherine; Hattar, Khalid

Additive manufacturing has ushered in a new paradigm of bottom-up materials-by-design of spatially non-uniform materials. Functionally graded materials have locally tailored compositions to provide optimized global properties and performance. In this letter, we propose an opportunity for the application of graded magnetic materials as lens elements for charged particle optics. A Hiperco50/Hymu80 (FeCo-2 V/Fe-80Ni-5Mo) graded magnetic alloy was successfully additively manufactured via Laser Directed Energy Deposition with spatially varying magnetic properties. The compositional gradient is then applied using computational simulations to demonstrate how a tailored material can enhance the magnetic performance of a critical, image-forming component of a transmission electron microscope.

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Analyzing barium titanate TiO2 surface interactions with tert-butylphosphonic acid using density functional theory

MRS communications

Marvin, Jessica; Nicholson, James; Turek, Cedar; Iwasa, Erina; Pangrekar, Nilay; Fowler, Whitney C.; Van Ginhoven, Renee M.; Monson, Todd M.

Barium titanate (BTO) is a widely researched ferroelectric useful for energy storage. While BTO’s surface chemistry is commonly studied using density functional theory, little has been published on the TiO2 surface. Here, we determined that BTO’s surface response can be decoupled from the ferroelectric response by using a pre-optimized ferroelectric slab and allowing only the top three atomic z-layers to respond to ligand binding. Multiple favorable binding modes were identified for hydrogen, hydroxyl, water, and tert-butyl phosphonic acid on BTO’s TiO2 surface. Of these ligands, tBuPA dominates surface binding with binding energies as low as -2.61 eV for its nine configurations.

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Negligible magnetic losses at low temperatures in liquid phase epitaxy grown Y3Fe5O12 films

Physical Review Materials

Will-Cole, A.R.; Hart, James L.; Lauter, Valeria; Grutter, Alexander; Dubs, Carsten; Lindner, Morris; Reimann, Timmy; Pearce, Charles J.; Monson, Todd M.; Cha, Judy J.; Heiman, Don; Sun, Nian X.

Yttrium iron garnet (Y3Fe5O12; YIG) has a unique combination of low magnetic damping, high spin-wave conductivity, and insulating properties that make it a highly attractive material for a variety of applications in the fields of magnetics and spintronics. While the room-temperature magnetization dynamics of YIG have been extensively studied, there are limited reports correlating the low-temperature magnetization dynamics to the material structure or growth method. Here, in this study, we investigate liquid phase epitaxy grown YIG films and their magnetization dynamics at temperatures down to 10 K. We show there is a negligible increase in the ferromagnetic resonance linewidth down to 10 K, which is unique when compared with YIG films grown by other deposition methods. From the broadband ferromagnetic resonance measurements, polarized neutron reflectivity, and scanning transmission electron microscopy, we conclude that these liquid phase epitaxy grown films have negligible rare-earth impurities present, specifically the suppression of Gd diffusion from the Gd3Ga5O12 (GGG) substrate into the Y3Fe5O12 film, and therefore negligible magnetic losses attributed to the slow-relaxation mechanism. Overall, liquid phase epitaxy YIG films have a YIG/GGG interface that is five times sharper and have ten times lower ferromagnetic resonance linewidths below 50 K than comparable YIG films by other deposition methods. Thus, liquid phase epitaxy grown YIG films are ideal for low-temperature experiments/applications that require low magnetic losses, such as quantum transduction and manipulation via magnon coupling.

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Metrics and Strategies for Design of DC Bias Resilient Transformers

IEEE Open Access Journal of Power and Energy

Prasad, Akhil; Sudhoff, Scott D.; Monson, Todd M.; Subramania, Ganapathi S.

Geomagnetic disturbances (GMDs) give rise to geomagnetically induced currents (GICs) on the earth's surface which find their way into power systems via grounded transformer neutrals. The quasi-dc nature of the GICs results in half-cycle saturation of the power grid transformers which in turn results in transformer failure, life reduction, and other adverse effects. Therefore, transformers need to be more resilient to dc excitation. This paper sets forth dc immunity metrics for transformers. Furthermore, this paper sets forth a novel transformer architecture and a design methodology which employs the dc immunity metrics to make it more resilient to dc excitation. This is demonstrated using a time-stepping 2D finite element analysis (FEA) simulation. It was found that a relatively small change in the core geometry significantly increases transformer resiliency with respect to dc excitation.

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Electric Drive Technologies Research: Bottom-Up Soft Magnetic Composites (FY2022 Annual Progress Report)

Monson, Todd M.

In order to meet 2025 goals for enhanced peak power (100 kW), specific power (50 kW/L), and reduced cost (3.3 $\$$/kW) in a motor that can operate at ≥ 20,000 rpm, improved soft magnetic materials must be developed. Better performing soft magnetic materials will also enable rare earth free electric motors. In fact, replacement of permanent magnets with soft magnetic materials was highlighted in the Electrical and Electronics Technical Team (EETT) Roadmap as a R&D pathway for meeting 2025 targets. Eddy current losses in conventional soft magnetic materials, such as silicon steel, begin to significantly impact motor efficiency as rotational speed increases. Soft magnetic composites (SMCs), which combine magnetic particles with an insulating matrix to boost electrical resistivity (ρ) and decrease eddy current losses, even at higher operating frequencies (or rotational speeds), are an attractive solution. Today, SMCs are being fabricated with values of ρ ranging between 10-3 to 10-1 μohm∙m, which is significantly higher than 3% silicon steel (~0.05 μohm∙m). The isotropic nature of SMCs is ideally suited for motors with 3D flux paths, such as axial flux motors. Additionally, the manufacturing cost of SMCs is low and they are highly amenable to advanced manufacturing and net-shaping into complex geometries, which further reduces manufacturing costs. There is still significant room for advancement in SMCs, and therefore additional improvements in electrical machine performance. For example, despite the inclusion of a non-magnetic insulating material, the electrical resistivities of SMCs are still far below that of soft ferrites (10 – 108 μohm∙m).

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Phase stability and magnetic and electronic properties of a spark plasma sintered CoFe – P soft magnetic alloy

Journal of Alloys and Compounds

Belcher, Calvin H.; Zheng, Baolong; Dickens, Sara D.; Domrzalski, Jessica N.; Langlois, Eric D.; Lehman, Benjamin; Pearce, Charles J.; Delany, Robert E.; Macdonald, Benjamin E.; Apelian, Diran; Lavernia, Enrique J.; Monson, Todd M.

More efficient power conversion devices are able to transmit greater electrical power across larger distances to satisfy growing global electrical needs. A critical requirement to achieve more efficient power conversion are the soft magnetic materials used as core materials in transformers, inductors, and motors. To that effect it is well known that the use of non-equilibrium microstructures, which are, for example, nanocrystalline or consist of single phase solid solutions, can yield high saturation magnetic polarization and high electrical resistivity necessary for more efficient soft magnetic materials. In this work, we synthesized CoFe – P soft magnetic alloys containing nanocrystalline, single phase solid solution microstructures and studied the effect of a secondary intermetallic phase on the saturation magnetic polarization and electrical resistivity of the consolidated alloy. Single phase solid solution CoFe – P alloys were prepared through mechanically alloying metal powders and phase decomposition was observed after subsequent consolidation via spark plasma sintering (SPS) at various temperatures. The secondary intermetallic phase was identified as the orthorhombic (CoxFe1−x)2P phase and the magnetic properties of the (CoxFe1−x)2P intermetallic phase were found to be detrimental to the soft magnetic properties of the targeted CoFe – P alloy.

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Investigating the dielectric constant of barium titanate in a polymer-matrix nanocomposite

MRS Advances

Cooper, Emma C.; De Anda, Eduardo; Flitz, Evan; Kim, Halie; Casanas, Nicholas; Johnson, Lillian; Kedzierski, Zoe; Domrzalski, Jessica N.; Dato, Albert; Monson, Todd M.

Barium titanate (BTO) is a ferroelectric material used in capacitors because of its high bulk dielectric constant. However, the impact of the size of BTO on its dielectric constant is not yet fully understood and is highly contested. Here, we present an investigation into the dielectric constant of BTO nanoparticles with diameters ranging between 50 and 500 nm. BTO nanoparticles were incorporated into acrylonitrile butadiene styrene and injection molded into parallel plate capacitors, which were used to determine nanocomposite dielectric constants. The dielectric constants of BTO nanoparticles were obtained by combining experimental measurements with computational results from COMSOL simulations of ABS-matrix nanocomposites containing BTO. The dielectric constant of BTO was observed to be relatively constant at nanoparticle diameters as small as 200 nm but sharply declined at smaller nanoparticle sizes. These results will be useful in the development of improved energy storage and power conditioning systems utilizing BTO nanoparticles.

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Surface Functionalized Barium Titanate Nanoparticles: A Combined Experimental and Computational Study

ECS Journal of Solid State Science and Technology

Domrzalski, Jessica N.; Stevens, Tyler E.; Van Ginhoven, Renee M.; Fritzsching, Keith F.; Walder, Brennan W.; Johnson, Emily M.; Lewis, Riley E.; Vreeland, Erika C.; Pearce, Charles J.; Vargas, David A.; Coker, Eric N.; Laros, James H.; Grey, John K.; Monson, Todd M.

Barium titanate (BTO) nanoparticles show great potential for use in electrostatic capacitors with high energy density. This includes both polymer composite and sintered capacitors. However, questions about the nanoparticles’ size distribution, amount of agglomeration, and surface ligand effect on performance properties remain. Reducing particle agglomeration is a crucial step to understanding the properties of nanoscale particles, as agglomeration has significant effects on the composite dielectric constant. BTO surface functionalization using phosphonic acids is known reduce BTO nanoparticle agglomeration. We explore solution synthesized 10 nm BTO particles with tert-butylphosphonic acid ligands. Recent methods to quantifying agglomeration using an epoxy matrix before imaging shows that tert-butylphosphonic acid ligands reduce BTO agglomeration by 33%. Thermometric, spectroscopic, and computational methods provide confirmation of ligand binding and provide evidence of multiple ligand binding modes on the BTO particle surface.

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Adrian Portales Coop Internship Report

Portales, Adrian P.; Monson, Todd M.

Using the thesis of W.R. Nolan (cite) as a guide, Cobalt Iron (CoFe) powders were reacted with 0.1 wt.% and 0.2 wt.% phosphoric acid in a 20:1 ratio of acetone to phosphoric acid. The powders were then dried at room temperature. The resulting phosphate coated CoFe was then mixed with 0.75 wt.% of the lubricant N,N' ethylene bis-stearamide (trade name: Acrawax C) and hot pressed to form a consolidated soft magnetic material referred to as CoFeP. With an avenue of synthesis for CoFeP determined, a proper amount of stock was synthesized for continuous “brick” production. While under current optimization, these 1x1 mm magnetic bricks will ultimately be placed and secured along the inside wall of each MK Magnetics transformer core by an appropriate CoFeP dispersed epoxy. As of now each brick has been produced though a pressing and annealing process via square 2x2 cm die. Before a brick is made a pressure calculation is run to ensure the dies maximum operating pressure is not exceeded. Figure 1. ensures the user’s safety by showing that the tons-on-ram required for a 2x2 cm square die to reach 760 MPa is below the point of die failure.

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The role of microstructural evolution during spark plasma sintering on the soft magnetic and electronic properties of a CoFe–Al2O3 soft magnetic composite

Journal of Materials Science

Belcher, Calvin H.; Zheng, Baolong; Macdonald, Benjamin E.; Langlois, Eric D.; Lehman, Benjamin; Pearce, Charles J.; Delany, Robert E.; Apelian, Diran; Lavernia, Enrique J.; Monson, Todd M.

For transformers and inductors to meet the world’s growing demand for electrical power, more efficient soft magnetic materials with high saturation magnetic polarization and high electrical resistivity are needed. This work aimed at the development of a soft magnetic composite synthesized via spark plasma sintering with both high saturation magnetic polarization and high electrical resistivity for efficient soft magnetic cores. CoFe powder particles coated with an insulating layer of Al2O3 were used as feedstock material to improve the electrical resistivity while retaining high saturation magnetic polarization. By maintaining a continuous non-magnetic Al2O3 phase throughout the material, both a high saturation magnetic polarization, above 1.5 T, and high electrical resistivity, above 100 μΩ·m, were achieved. Through microstructural characterization of samples consolidated at various temperatures, the role of microstructural evolution on the magnetic and electronic properties of the composite was elucidated. Upon consolidation at relatively high temperature, the CoFe was to found plastically deform and flow into the Al2O3 phase at the particle boundaries and this phenomenon was attributed to low resistivity in the composite. In contrast, at lower consolidation temperatures, perforation of the Al2O3 phase was not observed and a high electrical resistivity was achieved, while maintaining a high magnetic polarization, ideal for more efficient soft magnetic materials for transformers and inductors.

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Synthesis and behavior of bulk iron nitride soft magnets via high-pressure spark plasma sintering

Journal of Materials Research

Monson, Todd M.; Zheng, Baolong; Delany, Robert E.; Pearce, Charles J.; Zhou, Yizhang; Atcitty, Stanley A.; Lavernia, Enrique

Abstract: In this study, dense bulk iron nitrides (FexN) were synthesized for the first time ever using spark plasma sintering (SPS) of FexN powders. The Fe4N phase of iron nitride in particular has significant potential to serve as a new soft magnetic material in both transformer and inductor cores and electrical machines. The density of SPSed FexN increased with SPS temperature and pressure. The microstructure of the consolidated bulk FexN was characterized with X-ray diffraction (XRD), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and superconducting quantum interference device (SQUID) magnetometry. XRD revealed a primary phase of Fe4N with secondary phases of Fe3N and metallic iron. Finite element analysis (FEA) was also applied to investigate and explain localized heating and temperature distribution during SPS. The effects of processing on interface bonding formation and phase evolution were investigated and discussed in detail to provide insight into fundamental phenomena and microstructural evolution in SPSed FexN. Graphic abstract: [Figure not available: see fulltext.]

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Emerging Opportunities in Manufacturing Bulk Soft-Magnetic Alloys for Energy Applications: A Review

JOM

Kustas, Andrew K.; Susan, D.F.; Monson, Todd M.

Soft-magnetic alloys exhibit exceptional functional properties that are beneficial for a variety of electromagnetic applications. These alloys are conventionally manufactured into sheet or bar forms using well-established insgot metallurgy practices that involve hot- and cold-working steps. However, recent developments in process metallurgy have unlocked opportunities to directly produce bulk soft-magnetic alloys with improved, and often tailorable, structure–property relationships that are unachievable conventionally. The emergence of unconventional manufacturing routes for soft-magnetic alloys is largely motivated by the need to improve the energy efficiency of electromagnetic devices. In this review, literature that details emerging manufacturing approaches for soft-magnetic alloys is overviewed. This review covers (1) severe plastic deformation, (2) recent advances in melt spinning, (3) powder-based methods, and (4) additive manufacturing. These methods are discussed in comparison with conventional rolling and bar processing. Perspectives and recommended future research directions are also discussed.

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Bottom-Up Soft Magnetic Composites

Monson, Todd M.

In order to meet 2025 goals for enhanced peak power (100 kW), specific power (50 kW/L), and reduced cost (3.3 $/kW) in a motor that can operate at ≥ 20,000 rpm, improved soft magnetic materials must be developed. Better performing soft magnetic materials will also enable electric motors without rare earth elements. In fact, replacement of permanent magnets with soft magnetic materials was highlighted in the Electrical and Electronics Technical Team (EETT) Roadmap as a R&D pathway for meeting 2025 targets. Eddy current losses in conventional soft magnetic materials, such as silicon steel, begin to significantly impact motor efficiency as rotational speed is increased. Soft magnetic composites (SMCs), which combine magnetic particles with an insulating matrix to boost electrical resistivity (ρ) and decrease eddy current losses, even at higher operating frequencies (or rotational speeds), are an attractive solution. Today, SMCs are being fabricated with values of ρ ranging between 10-3 to 10-1 μohm∙m, which is significantly higher than 3% silicon steel (~0.5 μohm∙m). The isotropic nature of SMCs is ideally suited for motors with 3D flux paths, such as axial flux motors. Additionally, the manufacturing cost of SMCs is low and they are highly amenable to advanced manufacturing and net-shaping into complex geometries, which further reduces manufacturing costs. There is still significant room for advancement in SMCs, and therefore additional improvements in electrical machine performance. For example, despite the inclusion of a non-magnetic insulating material, the electrical resistivities of SMCs are still far below that of soft ferrites (10 – 108 μohm∙m).

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Development of Vertical GaN Power Devices for Use in Electric Vehicle Drivetrains (invited)

Kaplar, Robert K.; Binder, Andrew B.; Yates, Luke Y.; Allerman, A.A.; Crawford, Mary H.; Dickerson, Jeramy R.; Armstrong, Andrew A.; Glaser, Caleb E.; Steinfeldt, Bradley A.; Abate, Vincent M.; Laros, James H.; Pickrell, Gregory P.; Sharps, Paul; Flicker, Jack D.; Neely, Jason C.; Rashkin, Lee; Gill, Lee G.; Goodrick, Kyle J.; Monson, Todd M.; Bock, Jonathan A.; Subramania, Ganapathi S.; Scott, Ethan A.; Cooper, James

Abstract not provided.

Investigating the dielectric properties of barium titanate nanocomposites using transmission electron microscopy image processing

MRS Advances

Ferro, Gio; Ganjam, Dithi; Gibson, Maia; Partington, Katie; Trikha, Akshay; Wu, Mandy; Domrzalski, Jessica N.; Dato, Albert; Monson, Todd M.

Barium titanate (BTO) is a ferroelectric perovskite material used in energy storage applications because of its high dielectric constant. A previous study showed that the dielectric constant for BTO nanoparticles drastically increases to over 15,000 at a particle size of 70 nm. This result is highly contested, but its implications to energy storage motivated our investigation into the dielectric constants of BTO nanoparticles that are incorporated into a polymer matrix. We developed a novel method of using image processing techniques on transmission electron microscope images of BTO-polymer nanocomposites. Data on the positions, shapes, sizes, and orientations of BTO nanoparticles were used to build more realistic computational models that simulate the dielectric behavior of the nanocomposites. Here, we investigate the relationship between regions of enhanced electric field and the composite dielectric constant.

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Design and Evaluation of Nano-Composite Core Inductors for Efficiency Improvement in High- Frequency Power Converters

Conference Proceedings - IEEE Applied Power Electronics Conference and Exposition - APEC

Langlois, Eric L.; Huber, Dale L.; McDonough, Matthew; Monson, Todd M.; Neely, Jason C.; Watt, John

This paper evaluates the performance of a novel nano-composite core inductor. In this digest, a brief explanation of the superparamagnetic magnetite nanoparticle core is given along with magnetic characterization results and simulated design parameters and dimensions. A nearly flat relative permeability (μr) of around 5 is measured for the magnetic material to 1 MHz. A synchronous buck converter with nano-composite inductor was constructed and evaluated; the converter demonstrates a 1% improvement in conversion efficiency at higher currents (4% reduction in electrical losses), compared to an identical circuit with a benchmark commercial ferrite inductor.

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Soft Magnetic Multilayered FeSiCrB-Fe x N Metallic Glass Composites Fabricated by Spark Plasma Sintering

IEEE Magnetics Letters

Monson, Todd M.; Zheng, Baolong; Delany, Robert E.; Pearce, Charles J.; Langlois, Eric L.; Lepkowski, Stefan M.; Stevens, Tyler E.; Zhou, Yizhang; Atcitty, Christopher B.; Lavernia, Enrique J.

Novel multilayered FeSiCrB-Fe x N (x = 2-4) metallic glass composites were fabricated using spark plasma sintering of FeSiCrB amorphous ribbons (Metglas 2605SA3 alloy) and Fe x N (x = 2-4) powder. Crystalline Fe x N can serve as a high magnetic moment, high electrical resistance binder, and lamination material in the consolidation of amorphous and nanocrystalline ribbons, mitigating eddy currents while boosting magnetic performance and stacking factor in both wound and stacked soft magnetic cores. Stacking factors of nearly 100% can be achieved in an amorphous ribbon/iron nitride composite. FeSiCrB-Fe x N multilayered metallic glass composites prepared by spark plasma sintering have the potential to serve as a next-generation soft magnetic material in power electronics and electrical machines.

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Permittivity effects of particle agglomeration in ferroelectric ceramic-epoxy composites using finite element modeling

AIP Advances

Kaufman, Jonas L.; Tan, Scott H.; Lau, Kirklann; Shah, Ashka; Gambee, Robert G.; Gage, Chris; Macintosh, Lupe; Dato, Albert; Saeta, Peter N.; Haskell, Richard C.; Monson, Todd M.

The size dependence of the dielectric constants of barium titanate or other ferroelectric particles can be explored by embedding particles into an epoxy matrix whose dielectric constant can be measured directly. However, to extract the particle dielectric constant requires a model of the composite medium. We compare a finite element model for various volume fractions and particle arrangements to several effective medium approximations, which do not consider particle arrangement explicitly. For a fixed number of particles, the composite dielectric constant increases with the degree of agglomeration, and we relate this increase to the number of regions of enhanced electric field along the applied field between particles in an agglomerate. Additionally, even for dispersed particles, we find that the composite method of assessing the particle dielectric constant may not be effective if the particle dielectric constant is too high compared to the background medium dielectric constant.

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Soft magnetic materials for a sustainable and electrified world

Science

Silveyra, Josefina M.; Ferrara, Enzo; Huber, Dale L.; Monson, Todd M.

Soft magnetic materials are key to the efficient operation of the next generation of power electronics and electrical machines (motors and generators). Many new materials have been introduced since Michael Faraday's discovery of magnetic induction, when iron was the only option. However, as wide bandgap semiconductor devices become more common in both power electronics and motor controllers, there is an urgent need to further improve soft magnetic materials.These improvements will be necessary to realize the full potential in efficiency, size, weight, and power of high-frequency power electronics and high-rotational speed electrical machines. Here we provide an introduction to the field of soft magnetic materials and their implementation in power electronics and electrical machines. Additionally, we review the most promising choices available today and describe emerging approaches to create even better soft magnetic materials.

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Electric Drive Technologies (FY19 Annual Progress Report)

Pickrell, Gregory P.; Flicker, Jack D.; Neely, Jason C.; Monson, Todd M.

This project is part of a multi-lab consortium that leverages U.S. research expertise and facilities at national labs and universities to significantly advance electric drive power density and reliability, while simultaneously reducing cost. The final objective of the consortium is to develop a 100 kW traction drive system that achieves 33 kW/L, has an operational life of 300,000 miles, and a cost of less than $\$6$/kW. One element of the system is a 100 kW inverter with a power density of 100 kW/L and a cost of $\$2.7$/kW. New materials such as widebandgap semiconductors, soft magnetic materials, and ceramic dielectrics, integrated using multi-objective cooptimization design techniques, will be utilized to achieve these program goals. This project focuses on a subset of the power electronics work within the consortium, specifically the design, fabrication, and evaluation of vertical GaN power devices suitable for automotive applications.

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Barium titanate nanoparticles: Short-range lattice distortions with long-range cubic order

Physical Review B

Shi, Chenyang; Billinge, Simon J.L.; Puma, Eric; Bang, Sun H.; Bean, Nathaniel J.H.; De Sugny, Jean C.; Gambee, Robert G.; Haskell, Richard C.; Hightower, Adrian; Monson, Todd M.

Barium titanate (BTO) nanoparticles (sizes 10-500 nm) exhibit a displacement of the Ti atom from the center of the perovskite unit cell as inferred from synchrotron x-ray diffraction patterns (XRD) analyzed using atomic pair distribution functions (PDFs). Fits to PDFs acquired at temperatures of 20 °C-220 °C indicate that these Ti displacements (∼0.1 Å) are comparable to or even greater than those in the bulk material. Moreover, these displacements persist at temperatures well above 120 °C, where the tetragonal-to-pseudocubic phase transition occurs in the bulk. Tetragonal Raman spectral lines were observed for all sizes of these BTO nanoparticles and confirm a distorted unit cell up to 120 °C. Above 120 °C, the small BTO nanoparticles (10, 50, 100 nm) continue to display tetragonal Raman lines, though with slowly decreasing amplitudes as the temperature rises. In contrast, the tetragonal Raman lines of large BTO nanoparticles (300, 400, 500 nm) disappear abruptly above 120 °C, suggestive of bulk material. Indeed, fits to large-particle x-ray PDFs over the range 20-60 Å reveal a sharp, long-range structural change toward a cubic lattice at 120 °C, again consistent with bulk material. This sharp, long-range structural change is absent in the small particles. In fact, laboratory XRD Bragg peak profiles for the small BTO particles appear to be singlets at 20 °C, indicating that significant long-range cubic order already exists at room temperature. As temperature rises, this long-range cubic order is gradually reinforced, as inferred from long-range fits of the small particle PDFs. By combining information from x-ray PDFs, Raman spectra, and Bragg peak profiles, we conclude that small BTO nanoparticles exhibit both short-range (unit-cell) distortion and long-range (mesoscale) cubic order from 20 °C to 220 °C, while the large nanoparticles behave as bulk material, differing from small particles only by exhibiting long-range tetragonal order below 120 °C and a mesoscale structural phase change at 120 °C.

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Finite element modeling of nanoscale-enabled microinductors for power electronics

Journal of Materials Research

Langlois, Eric L.; Monson, Todd M.; Huber, Dale L.; Watt, John D.

This article focuses on the finite element modeling of toroidal microinductors, employing first-of-its-kind nanocomposite magnetic core material and superparamagnetic iron nanoparticles covalently cross-linked in an epoxy network. Energy loss mechanisms in existing inductor core materials are covered as well as discussions on how this novel core material eliminates them providing a path toward realizing these low form factor devices. Designs for both a 2 μH output and a 500 nH input microinductor are created via the model for a high-performance buck converter. Both modeled inductors have 50 wire turns, less than 1 cm3 form factors, less than 1 Ω AC resistance, and quality factors, Q's, of 27 at 1 MHz. In addition, the output microinductor is calculated to have an average output power of 7 W and a power density of 3.9 kW/in3 by modeling with the 1st generation iron nanocomposite core material.

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Gram scale synthesis of Fe/FexOy core-shell nanoparticles and their incorporation into matrix-free superparamagnetic nanocomposites

Journal of Materials Research

Watt, John D.; Bleier, Grant C.; Romero, Zachary W.; Hance, Bradley G.; Bierner, Jessica A.; Monson, Todd M.; Huber, Dale L.

Significant reductions recently seen in the size of wide-bandgap power electronics have not been accompanied by a relative decrease in the size of the corresponding magnetic components. To achieve this, a new generation of materials with high magnetic saturation and permeability are needed. Here, we develop gram-scale syntheses of superparamagnetic Fe/FexOy core-shell nanoparticles and incorporate them as the magnetic component in a strongly magnetic nanocomposite. Nanocomposites are typically formed by the organization of nanoparticles within a polymeric matrix. However, this approach can lead to high organic fractions and phase separation; reducing the performance of the resulting material. Here, we form aminated nanoparticles that are then cross-linked using epoxy chemistry. The result is a magnetic nanoparticle component that is covalently linked and well separated. By using this 'matrix-free' approach, we can substantially increase the magnetic nanoparticle fraction, while still maintaining good separation, leading to a superparamagnetic nanocomposite with strong magnetic properties.

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Degradation of Superconducting Nb/NbN Films by Atmospheric Oxidation

IEEE Transactions on Applied Superconductivity

Henry, Michael D.; Wolfley, Steven L.; Young, Travis R.; Monson, Todd M.; Pearce, Charles J.; Lewis, Rupert; Clark, Blythe C.; Brunke, Lyle B.; Missert, Nancy A.

Niobium and niobium nitride thin films are transitioning from fundamental research toward wafer scale manufacturing with technology drivers that include superconducting circuits and electronics, optical single photon detectors, logic, and memory. Successful microfabrication requires precise control over the properties of sputtered superconducting films, including oxidation. Previous work has demonstrated the mechanism in oxidation of Nb and how film structure could have deleterious effects upon the superconducting properties. This study provides an examination of atmospheric oxidation of NbN films. By examination of the room temperature sheet resistance of NbN bulk oxidation was identified and confirmed by secondary ion mass spectrometry. Meissner magnetic measurements confirmed the bulk oxidation not observed with simple cryogenic resistivity measurements.

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Self-Assembled Array of Tethered Manganese Oxide Nanoparticles for the Next Generation of Energy Storage

Scientific Reports

Monson, Todd M.; Stevens, Tyler E.; Pearce, Charles J.; Whitten, Caleah N.; Grant, Richard P.

Many challenges must be overcome in order to create reliable electrochemical energy storage devices with not only high energy but also high power densities. Gaps exist in both battery and supercapacitor technologies, with neither one satisfying the need for both large power and energy densities in a single device. To begin addressing these challenges (and others), we report a process to create a self-assembled array of electrochemically active nanoparticles bound directly to a current collector using extremely short (2 nm or less) conductive tethers. The tethered array of nanoparticles, MnO in this case, bound directly to a gold current collector via short conducting linkages eliminates the need for fillers, resulting in a material which achieves 99.9% active material by mass (excluding the current collector). This strategy is expected to be both scalable as well as effective for alternative tethers and metal oxide nanoparticles.

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Unprecedented magnetic behaviour in lanthanide-based ionic liquids

Chemical Communications

Monson, Todd M.; Stevens, Tyler E.; Leger, Jean L.; Manson, Jamie L.; Lovejoy, Katherine S.; Newsham, Aimee L.; Del Sesto, Rico E.

Ionic liquids containing lanthanide halide anions give the opportunity to investigate magnetic behaviour in non-ordered systems. Reported herein is the synthesis and characterization of ionic liquids containing a series of lanthanide halide anions, with the resulting materials displaying unusual behaviour below 50 K. Specifically, the ionic liquid structural glass formation appears to drive magnetic behaviour due to cluster formation of the anions during rapid cooling. This system presents a possible probe to study the dynamics of glass forming materials.

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High pressure FAST of nanocrystalline barium titanate

Ceramics International

Monson, Todd M.; Fraga, Martin B.; Delplanque, Jean P.; Yang, Nancy Y.; Lavernia, Enrique J.

This work studies the microstructural evolution of nanocrystalline (<1 µm) barium titanate (BaTiO3), and presents high pressure in field-assisted sintering (FAST) as a robust methodology to obtain >100 nm BaTiO3 compacts. Using FAST, two commercial ~50 nm powders were consolidated into compacts of varying densities and grain sizes. Microstructural inhomogeneities were investigated for each case, and an interpretation is developed using a modified Monte Carlo Potts (MCP) simulation. Two recurrent microstructural inhomogeneities are highlighted, heterogeneous grain growth and low-density regions, both ubiqutously present in all samples to varying degrees. In the worst cases, HGG presents an area coverage of 52%. Because HGG is sporadic but homogenous throughout a sample, the catalyst (e.g., the local segregation of species) must be, correspondingly, distributed in a homogenous manner. MCP demonstrates that in such a case, a large distance between nucleating abnormal grains is required—otherwise abnormal grains prematurely impinge on each other, and their size is not distinguishable from that of normal grains. Compacts sintered with a pressure of 300 MPa and temperatures of 900 °C, were 99.5% dense and had a grain size of 90±24 nm. These are unprecedented results for commercial BaTiO3 powders or any starting powder of 50 nm particle size—other authors have used 16 nm lab-produced powder to obtain similar results.

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Magnetic Smart Tags (MaST) for Arms Control and Treaty Verification

Langlois, Eric L.; Pillars, Jamin R.; Monson, Todd M.; Arrington, Christian L.; Finnegan, Patrick S.; St John, Christopher S.; Smartt, Heidi A.

The ability to track nuclear material is a challenge for resiliency of complex systems, e.g., harsh environments. RF tags, frequently used in national security applications, cannot be used for technological, operational, or safety reasons. Magnetic Smart Tags (MaST) is a novel tag technology based on magnetoelastic sensing that circumvents these issues. This technology is enabled by a new, cost-effective, batch manufacturing electrochemical deposition (ECD) process. This new advancement in fabrication enables multi-frequency tags capable of providing millions of possible codes for tag identification unlike existing theft deterrent tags that can convey only a single bit of information. Magnetostrictive 70% Co: 30% Fe was developed as the base alloy comprising the magnetoelastic resonator transduction element. Saturation magnetostriction, λS, has been externally measured by the Naval Research Laboratory to be as high as 78 ppm. Description of a novel MEMS variable capacitive test structure is described for future measurements of this parameter.

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Results 1–100 of 194
Results 1–100 of 194