Publications

A semiconductor laser coupled to an external cavity is investigated using a composite-cavity mode approach. Strong frequency hopping for small cavity length changes is obtained, indicating instability of the laser operation against cavity lengths fluctuations.

Results have been obtained on hydrogen dose, dose rate and substrate temperature dependence for hydrogen-assisted thermal donor formation in Czochralski Si. The study combined ion implantation and hydrogen plasma exposure to inject hydrogen, and infrared absorption and spreading resistance probe measurements to detect the donors. Near surface donor concentrations increase with dose and temperature between 350 and 400°C. The penetration depth for thermal donor formation exhibits a $\sqrt{t}$ dependence, and a thermal activation energy of 1.5 ± 0.2 eV.

Adhesion between diamond films synthesized by a CVD method and tungsten has been investigated by a scratch and pull testing methods. Diamond films have been deposited at temperatures from 1173 to 1323 K with a growth rate ranging from 0.2 to 0.45 μm/hour. The films are highly crystalline and are dominated by (100) faces at low temperatures, changing to (111) at higher temperatures. Grain size and residual stress in the films increases with increasing deposition temperature. X-ray diffraction shows the expected diamond diffraction peaks plus peaks attributed to WC and W₂C. Raman spectroscopy shows a sharp diamond band for all of the films, with a small broad peak, attributed to amorphous carbon. There is no distinct correlation between diamond/amorphous carbon intensity with deposition temperature. Scratch adhesion testing shows the expected failure mode for brittle coatings, but can not be quantified because of severe degradation of the diamond stylus tip. Sebastion pull testing shows that the failure mode of the films correlates with deposition temperature, but specific adhesion strength values do not. Efforts are continuing to correlate adhesion strength with deposition and structural parameters of the diamond films.

Rational interpolation is frequently useful for generating functions which have an extended range over an abbreviated domain of definition. A simple technique for continued fraction interpolating function evaluation can easily be modified to obtain the function's derivative. This is a useful technique for developing numerical solutions for certain stiff partial differential equations. 9 refs., 2 figs.

Accomodation of lattice mismatch is investigated for the case of large (ε{lunate}>0.02) mismatch. In particular, the regime where the separation D between misfit dislocations is much less than the strained layer thickness h is considered here. The conventional Matthews-Blakeslee mechanism for creation of misfit dislocations is found to be inadequate for the case of large lattice relaxation owing to interactions amongst the misfit dislocations at the interface. According to St. Venant's principle, the stress fields of the dislocation network are screened beyond a distance D from the dislocation cores. This observation has several consequences, including large densities of threading dislocations and the "melting" of moderately relaxed heterointerfaces at conventional semiconductor growth temperatures. A number of experimental observations may be explained via these models. © 1991.

This 1990 report contains monitoring data from routine radiological and nonradiological environmental surveillance activities. Summaries of significant environmental compliance programs in progress such as National Environmental Policy Act (NEPA) documentation, environmental permits, environmental restoration, and various waste management programs for Sandia National Laboratories in Albuquerque (SNL, Albuquerque) are included. The maximum offsite dose impact was calculated to be 2.0 {times} 10{sup {minus}3} mrem. The total 50-mile population received a collective dose of 0.82 person-rem during 1990 from SNL, Albuquerque, operations. As in the previous year, the 1990 SNL operations had no adverse impact on the general public or on the environment. This report is prepared for the US Department of Energy in compliance with DOE Order 5400.1. 97 refs., 30 figs., 137 tabs.

There is no routine radioactive emission from Sandia National Laboratories, Tonopah Test Range (SNL, TTR). However, based on the types of test activities such as air drops, gun firings, ground- launched rockets, air-launched rockets, and other explosive tests, possibilities exist that small amounts of depleted uranium (DU) (as part of weapon components) may be released to the air or to the ground because of unusual circumstances (failures) during testing. Four major monitoring programs were used in 1990 to assess radiological impact on the public. The EPA Air Surveillance Network (ASN) found that the only gamma ({gamma}) emitting radionuclide on the prefilters was beryllium-7 ({sup 7}Be), a naturally-occurring spallation product formed by the interaction of cosmic radiation with atmospheric oxygen and nitrogen. The weighted average results were consistent with the area background concentrations. The EPA Thermoluminescent Dosimetry (TLD) Network and Pressurized Ion Chamber (PIC) reported normal results. In the EPA Long-Term Hydrological Monitoring Program (LTHMP), analytical results for tritium ({sup 3}H) in well water were reported and were well below DOE-derived concentration guides (DCGs). In the Reynolds Electrical and Engineering Company (REECo) Drinking Water Sampling Program, analytical results for {sup 3}H, gross alpha ({alpha}), beta ({beta}), and {gamma} scan, strontium-90 ({sup 90}Sr) and plutonium-239 ({sup 239}Pu) were within the EPA's primary drinking water standards. 29 refs., 5 figs., 15 tabs.

PC-1D is a software package for personal computers that uses finite-element analysis to solve the fully-coupled two-carrier semiconductor transport equations in one dimension. This program is particularly useful for analyzing the performance of optoelectronic devices such as solar cells, but can be applied to any bipolar device whose carrier flows are primarily one-dimensional. This User's Guide provides the information necessary to install PC-1D, define a problem for solution, solve the problem, and examine the results. Example problems are presented which illustrate these steps. The physical models and numerical methods utilized are presented in detail. This document supports version 3.1 of PC-1D, which incorporates faster numerical algorithms with better convergence properties than previous versions of the program. 51 refs., 17 figs., 5 tabs.

The disappearance of isocyanate groups in 20 lb/ft{sup 3} rigid polyurethane encapsulating foam (44402-20) was monitored by FTIR spectroscopy leading to an activation energy of 4 kcal/mole. The disappearance of isocyanates can be due to either crosslinking reactions or gas production. Attempting to separate these two reaction paths, we measured the gel time and volume change during cure leading to activation energies of 5 and 6 kcal/mole for the crosslinking and foaming mechanisms respectively. 3 refs., 16 figs.

This study examined the feasibility of the Safety Engineering Reactor for Accident Phenomenology (SERAPH), a research reactor with the capability to perform a wide array of safety experiments important in the design of commercial nuclear reactors. The study proceeded in two phases. In Phase 1, the experimental needs were examined and a wide-ranging survey of many fuel/coolant options for the SERAPH driver reactor was done. In Phase 2, the most promising candidates identified in Phase 1 were studied in more detail. A reactor with heavy-water coolant, BeO-PuO{sub 2} fuel matrix, and a standard pin geometry was found to have the required experiment capabilities while using relatively current technology. A reactor with helium coolant, BeO-PuO{sub 2} fuel matrix, and a unique geometrical configuration was found to have significantly higher capabilities but with greater technical risk. 5 refs., 34 figs., 36 tabs.

This report describes the results of high temperature steam testing and submergence testing of 12 different cable products that are representative of typical cables used inside containments of US light water reactors. Both tests were performed after the cables were exposed to simultaneous thermal and radiation aging, followed by exposure to loss-of-coolant accident simulations. The results of the high temperature steam test indicate the approximate thermal failure thresholds for each cable type. The results of submergence test indicate that a number of cable types can withstand submergence at elevated temperature, even after exposure to a loss-of-coolant accident simulation. 4 refs., 6 figs., 9 tabs.

This work documents a comparison of sensitivity and uncertainty analysis techniques that are likely to be used in support of repository performance assessments to determine compliance with the Nuclear Regulatory Commission (NRC) and the Environmental Protection Agency (EPA) regulations for high-level radioactive waste (HLW) repositories. A variety of parameter estimation and sensitivity analysis techniques were applied to a model of the Avra Valley aquifer, Arizona. Two approaches to sensitivity analyses were used, statistical and deterministic; these were applied to evaluate the sensitivity of the ground water travel time to changes in transmissivity. The effect of different boundary conditions on the calculated sensitivity derivatives was also evaluated. Parameter estimates and estimation errors were obtained via geostatistical and inverse techniques. The throughput'' of the kriging techniques suggests that the mean estimates derived from these techniques are frequently off the mark'' or inconsistent with the conceptual model. With no screening of the input parameter estimates for realism, non- conservative travel time estimates were obtained. The differential analysis sensitivity technique is shown to be dependent on the choice of design point, providing only a local measure of the sensitivity. The statistical approach to sensitivity identifies parameters which are both sensitive and uncertain, i.e., it shows when the uncertainty in a model parameter is important. Sensitivity estimates are also shown to be dependent on the choice of boundary conditions used. 92 refs., 55 figs., 13 tabs.

This report describes an architecture for compiling and representing electronic documents in a framework which accommodates knowledge about how the documents are composed, organized, and correlated. A general concept of referenceability is employed. While the concept is relevant to a wide range of application areas, it is described in familiar terms of an electronic document comprised of related textual information and graphics. The concept is applicable to all classes of objects which, together with their references, constitute the electronic document. The documents may themselves contain references to other documents, as well as to constituent object classes such as textual components, figures, footnotes, subject indexes, and the like. The objects and references can be dynamically combined according to a total logical structure representable within a window environment. The framework supports automatic resolution of references and display of related document objects through intercommunicating windows which constitute a relevant user view of a document. 6 refs., 9 figs.

This document describes the NEFTRAN-S computer code and is intended to provide the reader with enough information to use the code. NEFTRAN-S was developed for the United States Environmental Protection Agency for the assessment of ground-water flow and radionuclide transport from radioactive waste disposal in geologic formations. NEFTRAN-S is a successor to the NEFTRAN code. The code was developed in conjunction with NEFTRAN-2, which was developed recently for the United States Nuclear Regulatory Commission. As a result, some of the features contained in NEFTRAN-2 have been included in NEFTRAN-S. In particular, NEFTRAN-S includes an exponential-leach-rate source, decoupled time steps for source and transport, and an option for inputting pore-water velocities. Features unique to NEFTRAN-S include a user-friendly format for use on personal computers and coupling with statistical sampling and analysis using the SUNS software shell. This document was written to provide a comprehensive discussion of the NEFTRAN-S code including its history, the theory, its use and examples of possible applications. Minimal reference to previous documents is intended. 25 refs., 132 figs., 30 tabs.

The default format for the storage of x,y data for use with the UFO code is described. The format assumes that the data stored in a file is a matrix of values; two columns of this matrix are selected to define a function of the form y = f(x). This format is specifically designed to allow for easy importation of data obtained from other sources, or easy entry of data using a text editor, with a minimum of reformatting. This format is flexible and extensible through the use of inline directives stored in the optional header of the file. A special extension of the format implements encoded data which significantly reduces the storage required as compared wth the unencoded form. UFO supports several extensions to the file specification that implement execute-time operations, such as, transformation of the x and/or y values, selection of specific columns of the matrix for association with the x and y values, input of data directly from other formats (e.g., DAMP and PFF), and a simple type of library-structured file format. Several examples of the use of the format are given.

This report documents the findings of an experimental investigation of the effects of thermal aging on the fire damageability of electric cables. Two popular types of nuclear qualified cables were evaluated. For each cable type, both unaged (i.e., new off the reel) and thermally aged samples were exposed to steady-state elevated temperature environments until conductor-to-conductor electrical shorting was observed. Plots of the time to electrical failure versus the exposure temperature were developed and thermal damage thresholds were determined. For one cable type, the thermally aged cables were less vulnerable to thermal damage than were the unaged samples as demonstrated by an increase in the thermal damage threshold for the aged samples, and an extended survival time at exposure temperatures above the damage threshold for aged samples compared to unaged samples. For the second cable, the threshold of thermal damage was lowered somewhat by the aging process, an indication of an increased vulnerability to thermal damage due to aging. However, for the higher temperature exposures, no statistical difference between the damage times for aged and unaged cable samples was noted. For both cable types, the changes in the thermal damage threshold observed were not considered significant in terms of fire risk. 4 refs., 9 figs., 8 tabs.

The thrust of this progress report deals with the significant advances we have made in the past few months toward optimal radiating efficiency and optimal directionality from antenna arrays that fit inside a 5.5 in.-OD tool. The reasons spawning this development effort on antennas are the many uses for underground radar systems that can be built around such high-performance antennas. Targets of interest include large man-made voids, natural voids in strata, fractures zones in hard rock, edges and internal faults in salts domes and glaciers, etc. Recent progress includes observation of the radiation patterns of several dipole arrays which we designed to fit within a 5.5-inch OD borehole tool and to radiate efficiently at wavelengths in the band from 0.4 meter to 2 meters with optimal directionality. Front-to-back ratios of 15 dB are consistently observed in the horizontal plane of these arrays. These antennas are observed to radiate with high efficiencies, less than 1 dB loss, into air at 1.3 meter wavelength. 18 figs.

This report describes the finite difference computer code ZEPHYR3D, which is designed to solve three-dimensional, transient incompressible flow problems. ZEPHYR3D includes an energy equation that allows coupled thermal/fluid problems to be solved with the limits of the Boussinesq approximation. It also includes an implementation of the Smagorinsky subgrid scale turbulence model, which allows ZEPHYR3D to perform large eddy simulation of turbulent flows. This report includes the mathematical and numerical basis for ZEPHYR3D, a user's guide, and several example/benchmark problems. These problems include flow over a backward-facing step, free convection in an enclosure, and the collapse of a mixed region in a stratified environment. 22 refs., 32 figs., 2 tabs.

Early in 1990, J. A. Wilder, Supervisor of Sandia National Laboratories (SNLA), Division 2565 requested that a meeting of the scientists and engineers responsible for developing and producing switch tubes be set up to discuss in a semi-formal way the science and technology of switch tubes. Programmatic and administrative issues were specifically exempted from the discussions. L. Beavis, Division 7471, SNL and A. Shuman, EG G, Salem were made responsible for organizing a program including the materials and processes of switch tubes. The purpose of the Switch Tube Advanced Technology meeting was to allow personnel from Allied Signal Kansas City Division (AS/KCD); EG G, Salem and Sandia National Laboratories (SNL) to discuss a variety of issues involved in the development and production of switch tubes. It was intended that the formal and informal discussions would allow a better understanding of the production problems by material and process engineers and of the materials and processes by production engineers. This program consisted of formal presentations on May 23 and informal discussions on May 24. The topics chosen for formal presentation were suggested by the people of AS/KCD, EG G, Salem, and SNL involved with the design, development and production of switch tubes. The topics selected were generic. They were not directed to any specific switch tube but rather to all switch tubes in production and development. This document includes summaries of the material presented at the formal presentation on May 23.

The diffraction patterns produced by passing a laser beam through two different types of flowing gases are calculated. The first type of flow consists of periodic lines of gas flowing transverse to the beam's propagation. The second flow is turbulent. The measurable parameters in the diffraction patterns are derived and related to the gas temperature, pressure, velocity, and (in the case of the turbulent flow) to the flow's structure constant. A discussion on using the photorefractive effect to study turbulent flows is also given. In the latter case a method that relates the flow's structure constant to the decay time of the photorefractive crystal is given. 24 refs., 11 figs.

NEFTRAN-S was developed by Sandia National Laboratories for the United States Environmental Protection Agency as part of a program providing technical support for re-promulgation of the standard 40 CFR 191. The code is intended to provide realistic estimates of releases to the environment that could result from disposal of radioactive waste in geologic subsurfaces. One of the geologic environments that will be considered by the EPA in their analyses is unsaturated tuff. The information given in this report is intended to provide a conceptual model for the NEFTRAN-S code for calculations involving a generic site in unsaturated tuff. Information about the phenomena expected to dominate transport and methods for modeling transport in an unsaturated medium are presented. NEFTRAN-S calculations using this conceptual model are compared to TOSPAC calculations for three possible infiltration rates. TOSPAC is the code currently used in performance assessment for an unsaturated tuff site at Yucca Mountain in Nevada. 14 refs., 21 figs., 22 tabs.

The prediction of the chemical alteration of cementitious sealing materials and other cementitious components such as liners in the tuffaceous environment of Yucca Mountain is an essential element in understanding the longevity of these materials. This study uses a chemical equilibrium model to obtain information about the chemical reaction of ground water with concretes. Because concretes, cements, and grouts are metastable assemblages, it is expected that these materials will dissolve, cause secondary precipitations and react with the environment. These reactions will alter the porosity and hydraulic conductivity of the concretes. While the importance of these chemical and conductivity changes has not been completely assessed, this study provides insight into the importance of this chemical alteration.

Large-scale numerical simulations of turbulent flow past bare and appended submarine hulls have been completed with FIDAP versions 4.5 and 5.0. A standard k-ε turbulence model was employed to resolve the near-body flow field for all numerical calculations. Results from these simulations (profile plots and wake surveys of velocity, pressure and turbulent kinetic energy -- hull pressures and shear stresses -- total drag) are compared with data from dynamically similar experiments. The Reynolds number, based upon model length, for both simulation and experiment was 1.2 x 10⁷. Agreement between untuned numerical predictions and experimental data is remarkably close for several model geometries. In other cases, quantitative differences are attributed to the choice of turbulence model and the numerical implementation of boundary conditions.

Radiation measurement have been used for many years to aid in the characterization, handling, and processing of spent nuclear fuel. Applications have included radiation protection, international safeguards, fissile content estimation for reprocessing, and verification of records and calculations. The application of radiation measurements to support the identification of spent fuel assemblies for loading into burnup credit'' transport casks is of interest in the cask development program. A possible alternative to measurements is to use the administrative controls and operational procedures that have been used at reactor sites that make use of burnup credit for spent fuel storage. Experience at such sites needs to be carefully analyzed for its applicability to the misloading and misidentification probabilities. Since there are over 40,000 spent fuel assemblies stored at more than one hundred locations in the US, it is important to determine carefully the necessity for and applicability of any measurement requirement. It is imperative that any measurement system selected be as simple, inexpensive, quick, and non-intrusive as possible. In this report we will consider the information available from measurements of spent fuel that has cooled for more than ten years and examine the possible application of existing instrumentation to verifying the loading of burnup credit casks.

Sandia National Laboratories is conducting long-term aging research on representative samples of nuclear power plant Class 1E cables to determine the suitability of these cables for extended life (beyond the 40-year design basis) and to assess various cable condition monitoring techniques for predicting remaining cable life. This paper provides some results of mechanical measurements that were performed on cross-linked polyolefin (XLPO) cables and cable materials aged at relatively mild, simultaneous thermal and radiation exposure conditions for period of up to nine months. The mechanical measurements discussed in this paper include tensile strength, ultimate elongation, hardness, and compressive modulus. The modulus measurements were performed using an indenter developed at Franklin Research Center under EPRI sponsorship.

Reflux solar receivers for dish-Stirling electric power generation systems are currently being investigated by several companies and laboratories. In support of these efforts, the AEETES thermal performance numerical model has been developed to predict thermal performance of pool-boiler and heat-pipe reflux receivers. The formulation of the AEETES numerical model, which is applicable to axisymmetric geometries with asymmetric incident fluxes, is presented in detail. Thermal efficiency predictions agree to within 4.1% with test data from on-sun tests of a pool-boiler reflux receiver. Predicted absorber and sidewall temperatures agree with thermocouple data to within 3.3.% and 7.3%, respectively. The importance of accounting for the asymmetric incident fluxes is demonstrated in comparisons with predictions using azimuthally averaged variables. The predicted receiver heat losses are characterized in terms of convective, solar and infrared radiative, and conductive heat transfer mechanisms. 27 refs., 9 figs., 4 tabs.

Sandia National Laboratories, Albuquerque, manages the Utility Battery Exploratory Technology Development Program, which is sponsored by the US Department of Energy's Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses and development of advanced rechargeable batteries for stationary energy storage applications. This report details the technical achievements realized during fiscal year 1990. 82 figs., 40 tabs.

This document presents the quality assurance (QA) philosophy and procedures for software used by the Performance Assessment Division of the Nuclear Waste Technology Department (NWTD) of Sandia National Laboratories, which directly supports the Waste Isolation Pilot Plant (WIPP). Software procedures described herein will be incorporated into the general Performance Assessment Quality Assurance Procedures (QAP 2-2) and will apply to all Sandia and Sandia contractor activities related to Performance Assessment (except where the contractor has its own NWTD-approved QA procedures). This report presented the philosophy behind the QA procedures, provides the standards adopted for Performance Assessment software, discusses the implementation of these standards, and summarizes the software executive package, CAMCON, which aids in implementing the standards. 24 refs., 6 figs., 5 tabs.

Our charged particle simulation models a relativistic electron beam for which the field solution is local and thus requires no grid. We have implemented the simulation on a CRAY and on two parallel machines, a nCUBE 2 and Connection Machine. We present implementation details and contrast the approaches necessary for the three architectures. On the parallel machines a dynamic load-balancing problem arises because the beam grows uniformly in one dimension from a few hundred to hundreds of thousands of particles as the simulation progresses. We discuss a folded Gray-code mapping of the processors to the length scale of the simulation that expands (or shrinks) as the beam changes length so as to minimize inter-processor communication. This improves the efficiency of the nCUBE version of the simulation which runs at 10x the speed of the vectorized CRAY version.

Surry was used as a representative dry containment plant for the evaluation of possible ways that containment performance could be improved. Sensitivity studies using the NUREG-1150 models and methodologies were used to estimate the reduction of risk potentials resulting from bypass scrubbing and DCH partial depressurization. These studies showed that the greatest reduction of risk occurs when bypass releases are mitigated by scrubbing or prevented. High-pressure DCH are also important. The CONTAIN code was used to estimate reduction in peak containment pressure resulting from mitigation actions including venting, partial depressurization and ~3 bar with igniters. Limited studies of the benefits of venting and inerting were made, but additional investigations are needed to complete this area of investigation. A brief discussion regarding concepts to mitigate the consequences of bypass is presented. CONTAIN-code calculations were performed to investigate the possible overpressurization of the containment for the station blackout scenario.

Difficulties in the accurate heat transfer computation of high speed, blunt body flows have been encountered by numerous researchers. The primary reason for these difficulties has been shown to be the grid dependency of the wall flux quantities. Obviously, the accuracy of the computed heat fluxes will, to a certain extent, depend on the particular numerical scheme employed. This article will be limited to the investigation of the flux vector splitting technique. An attempt has been made to develop procedures which will provide guidelines for selecting appropriate grid systems and, in particular, the grid line distribution near the surface for accurate heat transfer computations. The results have clearly shown the dependency of the heat flux quantities on the grid system. In addition, it is shown that changes in flow Mach number and/or Reynolds number may require further refinement of the grid system.

Analytical equations for explosively accelerated flyer plates are used to generate graphical solutions to flyer problems. Given the problem geometrical configuration, explosive weight, flyer weight, tamping weight and Gurney velocity, the graphical representation of the calculated data allows for a fast approximation of the final or maximum flyer velocity. The graphical solution for flyer velocity is particularly useful when a computer is not available. The graphical analysis scheme can be used with any explosive, tamper and flyer materials. Analytical data are presented for grazing, spherical, cylindrical, open, symmetric and asymmetric sandwich explosive configurations. 13 refs., 7 figs., 4 tabs.

Al with additions of Cu is commonly used as the conductor metallizations for integrated circuits (ICs). As the packing density of ICs increases, interconnect lines are required to carry ever higher current densities. Consequently, reliability due to electromigration failure becomes an increasing concern. Cu has been found to increase the lifetimes of these conductors, but the mechanism by which electromigration is improved is not yet fully understood. In order to evaluate certain theories of electromigration it is necessary to have a detailed description of the Cu distribution in the Al microstructure, with emphasis on the distribution of Cu at the grain boundaries. In this study analytical electron microscopy (AEM) has been used to characterize grain boundary regions in an Al-2 wt.% Cu thin film metallization on Si after a variety of thermal treatments. The results of this study indicate that the Cu distribution is dependent on the thermal annealing conditions. At temperatures near the θ phase (CuAl₂) solvus, the Cu distribution may be modelled by the collector plate mechanism, in which the grain boundary is depleted in Cu relative to the matrix. At lower temperatures, Cu enrichment of the boundaries occurs, perhaps as a precursor to second phase formation. Natural cooling from the single phase field produces only grain boundary depletion of Cu consistent with the collector-plate mechanism. The kinetic details of the elemental segregation behavior derived from this study can be used to describe microstructural evolution in actual interconnect alloys.

A 70/30 wt% salt/bentonite mixture is shown to be preferable to pure crushed salt as backfill for disposal rooms in the Waste Isolation Pilot Plant (WIPP). This report discusses several selection criteria used to arrive at this conclusion: the need for low permeability and porosity after closure, chemical stability with the surroundings, adequate strength to avoid shear erosion from human intrusion, ease of emplacement, and sorption potential for brine and radionuclides. Both salt and salt/bentonite are expected to consolidate to a final state of impermeability (i.e., {le} 10{sup {minus}18}m{sup 2}) adequate for satisfying federal nuclear regulations. Any advantage of the salt/bentonite mixture is dependent upon bentonite's potential for sorbing brine and radionuclides. Estimates suggest that bentonite's sorption potential for water in brine is much less than for pure water. While no credit is presently taken for brine sorption in salt/bentonite backfill, the possibility that some amount of inflowing brine would be chemically bound is considered likely. Bentonite may also sorb much of the plutonium, americium, and neptunium within the disposal room inventory. Sorption would be effective only if a major portion of the backfill is in contact with radioactive brine. Brine flow from the waste out through highly localized channels in the backfill would negate sorption effectiveness. Although the sorption potentials of bentonite for both brine and radionuclides are not ideal, they are distinctly beneficial. Furthermore, no detrimental aspects of adding bentonite to the salt as a backfill have been identified. These two observations are the major reasons for selecting salt/bentonite as a backfill within the WIPP. 39 refs., 16 figs., 6 tabs.

We present an algorithm for the QR factorization of a dense matrix without column pivoting on a hypercube multiprocessor. The algorithm combines the optimal numerical efficiency of Householder reflections with the excellent communication properties of the torus wrap mapping. Analytical results indicate that the communication cost for this algorithm is less than that for other common approaches. Numerical results on an nCUBE 2 confirm the efficiency of our technique. 23 refs., 5 figs., 1 tab.

This memorandum is a synopsis of the description and operation of the equipment used, and the events occurring during the calibration of an accelerometer on the 1000 G centrifuge. 2 refs., 1 tab.

The objective of this study was to perform a systematic sampling of the intergranular brines that slowly weep'' from four of the main stratigraphic units exposed in the WIPP. This information was added to the data base on brine compositions used in performance assessment and also employed in characterizing Salado Formation hydrology at the repository horizon. Concentrations of Na, K, Mg, Ca, Cl, SO₄, and Br were all highly variable. It was also established that this variability reflects neither post-excavation evaporation nor imprecision in the analytical techniques. Compositional variability on the length scale of a few tens of centimeters is as large as that found over several hundreds of meters. Stratigraphy did not appear to exert any control over weep brine compositions. Programmatically relevant applications of these results are: (1) a valid performance assessment must consider the possibility of a wide range of brines, rather than carry out evaluations using a single best'' average brine, and (2) the Salado appears not to function as a continuous aquifer since brines originating millions of years ago have failed to homogenize though separated by only short distances.

In September 1990, the President's Office of Science and Technology released a document that bears on the future of our nation's technological vigor and economic performance. Entitled, US Technology Policy, it is a statement of a set of broad principles that will constitute the federal government's technology policy for the 1990s. One of the leading principles of this policy is the imperative for cooperation and teamwork among government, industry, and academia, including an active, partnership role for the national laboratories in the mainstream US technology community. Until now, the nation's technology policy has never been explicit, although a tacit technology policy of one sort or another has at all times been in effect. The federal government has consistently been willing to create and fund institutions and programs to promote important national technology goals. Historical examples of such sponsorship include atomic energy, agriculture, aeronautics and space, energy, and medicine. The recognition in US Technology Policy that government has an active role to play in fostering technology development is a particularly significant admission. The vision of a partnership between the federal government and the private sector, as the policy outlines, provides a foundation upon which the national laboratories of the Department of Energy (DOE) can build to play a stronger role in enhancing US economic competitiveness. 6 refs.

A number of metal oxides were evaluated for their ability to immobilize molten LiCl-KCl eutectic in electrolyte-binder (EB) mixes used in thermally activated batteries. These metal oxides included fumed silicas, alumina, and a titania (all prepared by steam hydrolysis of the halides), floated silicas, MgO, and an alumina molecular sieve. The characteristics of the EB powders that were used as metrics were flow properties, homogeneity, BET surface area, particle-size distribution, and moisture content. The characteristics of EB pellets used as metrics were deformation at 530{degrees}C under an applied pressure and tendency for electrolyte leakage at 400{degrees}C. Many of the same characterization techniques used for EB powders were applied to the LiCl-KCl eutectic, its component halides, and the metal oxides as well. The reproducibility of the properties of several of the standard Sandia EB mixes was evaluated for materials prepared at a number of thermal-battery manufacturing facilities following the same processing procedures. 13 refs., 14 figs., 18 tabs.

A new technique for tunnel detection and location has recently been theoretically modeled and experimentally demonstrated. The objective of this research is to develop a general method for remotely detecting the presence of unauthorized tunneling activities using one or more boreholes and a surface source. A line current or dipole-dipole array, positioned on or near the surface of the earth, is used as the TE current source. Subsurface electric and magnetic field measurements are made in a borehole that is situated near a suspected tunnel location. The presence of a tunnel causes subsurface scattering of the field components created by the source. Both the electric and magnetic field strength and phase data is perturbed by the presence of a nearby tunnel. The scattered fields are observed on both sides of the tunnel relative to the source position. This paper will describe the development electromagnetic scattering models using a buried cylinder to represent a tunnel. A homogeneous whole-space model will be used.

Eight samples of 4.5 in. steel oil well drill pipe which had perforated or fractured in use were analyzed to determine the reasons for failure. These pipe sections were used for drilling in the Permian Basin fields of southeastern New Mexico and western Texas. Six of the eight samples failed by a common mechanism: stress corrosion cracks initiated at the insides of the pipes at the bottoms of large corrosion blisters which formed under a plastic protective layer. Stress corrosion cracking (SCC) was driven by a differential oxygen concentration cell between the drilling fluid (high oxygen) and the bottom of the blisters (low oxygen). The stress corrosion process occurs by a film rupture-plastic slip-electrochemical dissolution mechanism. Thus crack propagation rates may be altered by chemical modification of drilling fluids. Additional crack extension occurred by fatigue in some samples; the extent of fatigue cracking apparently was determined by the later cyclic history of the pipe. Treatment of the drilling fluids to lower the oxygen concentration and thus the driving force for SCC has been shown to decrease drill pipe loss by perforation in limited drilling to date. 16 refs., 8 figs.

The purpose of this report is to provide general approaches and concepts that can be applied in validation of models used in performance assessment of high-level waste (HLW) repositories. The approaches are based on a validation strategy that Sandia National Laboratories has implemented as participants in the International Transport Validation Study (INTRAVAL). This strategy focuses on the demonstration that performance assessment models are adequate representations of the real systems they are intended to represent, given the pertinent regulatory requirements rather than proving absolute correctness from the purely scientific point of view. Positions that are taken consist of the following: due to the relevant time and space scales, models that are used to assess the performance of a HLW repository can never be validated; therefore, validation is a process that consists of building confidence in these models and not providing "validated" models; in this context, model validation includes comparisons to "reality," however, adequacy for the given purpose is the overall goal; comparisons to "reality" consist of comparing model predictions against laboratory and field experiments, natural analogues, and site-specific information; when comparing experimental data to model predictions, a model can be either "invalid" or "not invalid," based on the null hypothesis concept, however, confidence in the model arises in finding a model to be "not invalid" over a wide range of conditions; an attempt should be made to consider in the validation process all plausible conceptual models; and when comparing experimental data to model predictions, a logical systematic approach should be followed. This report discusses the definition of validation in the context of performance assessment for HLW repositories, the need for validation, an approach to validation, and an approach to comparing model predictions with experimental data proposed by the authors.

During 1990, the Sandia Transportable Triggered Lightning Instrumentation Facility (SATTLIF) was designed, fabricated, and fielded at the Kentucky Space Center (KSC) rocket-triggered lighting test range in Florida. In preparation for lighting tests of a specially fitted munitions storage bunker during 1991, instrumentation for directly measuring lightning channel currents and response currents in structures was evaluated and demonstrated to function well. A set of 77-mil-thick 2024-T3 aluminum and 35-mil-thick 4130 steel metallic samples was exposed to measured triggered lighting flash currents. The resultant damage spots on these specimens represent the first such data points produced by known lighting currents. They are intended for use as benchmarks against which to improve and quantify the fidelity of laboratory simulations of lightning penetration. Two particularly significant results were obtained. In the first, a damage spot of approximately 0.3-inch diameter and >0.01-inch depth was produced by a continuing current of well less than median-level severity that transferred less than 13.6 coulombs of charge. In the second case, one of the steel samples was virtually burned through under a return-stroke/continuing current combination transferring an eightieth percentile charge of approximately 49 coulombs. Photographic evidence of upward-going streamers preceding return strokes initiated by dart leaders was also obtained and is presented.

An investigation of the impact of thermal aging on the flammability of two common types of nuclear grade electrical cables has been performed. Four large-scale flammability tests were performed with each of the two cable types tested in both an unaged (i.e., new off the reel) and a thermally aged (artificially aged) condition. In all cases, the fire was observed to consume virtually all of the combustible cable jacket and insulation material present. However, for both cable types tested, the thermal aging process caused a decrease in the cable flammability as demonstrated by decreases in the rate of fire growth, peak fire intensity, total heat released and near fire temperatures. This result is consistent with past cable aging studies because it has been observed that the thermal aging process will drive off certain of the more volatile constituents of a polymeric material. Presumably, when these aged materials are subjected to a fire, the evolution of volatile combustible gases is reduced as compared to the unaged materials, and hence, flammability is reduced. The results of these tests indicate that, at least for the two cable types tested, the evaluation of cable flammability using unaged cable samples will remain a conservative indicator of cable flammability in a thermally aged condition.

This investigation involves the development of a general two- dimensional continuum model to describe jointed rock mass. Chen recently developed a model for the analysis of rock mass containing two orthogonal joint sets. Development of the orthogonal joint set model followed the general formulation of Morland and the special single joint set implementation of Morland`s model by Thomas. Although the orthogonal joint set model has proven useful for analyzing field-scale problems, it remains restrictive in terms of the general field conditions. In this paper, the orthogonal joint set model has been extended to a more general model where the orthogonality restriction has been relaxed. Fundamental approaches remain the same for both models. However, as the general model becomes capable of treating physically more complicated problems, it becomes mathematically more complex. This complexity provides the potential to study more completely the interaction of various parameters representing the characteristics of jointed rock mass behavior. The equation governing the solution of the problem has been given, and example problems have been solved. The behavior of the rock mass predicted by the orthogonal joint set model has been compared to the general model. This model has been developed to aid in characterizing the site of the repository at Yucca Mountain, Nevada, for the potential geologic disposal of radioactive waste. Disposal of high-level nuclear waste is currently being considered by the Yucca Mountain Project, administered by the Nevada Operations Office of the US Department of Energy.

The distribution of moisture beneath a two-dimensional strip source is analyzed by applying the quasi-linear approximation. The source is described by specifying either the moisture content or the infiltration rate. A water table is specified at some depth, D, below the surface, the depth varying from shallow to semi-infinite. Numerical solutions are determined, via the boundary integral equation method, as a function of material sorptivity, α, the width of the strip source, 2L, and the depth to the water table. The moisture introduced at the source is broadly spread below the surface when αL $\ll$ 1, for which absorption by capillary forces is dominant over gravity-induced flow. Conversely, the distribution becomes finger-like along the vertical when αL $\gg$ 1, where gravity is dominant over absorption. For a source described by specifying the moisture content, the presence of a water table at finite depth influences the infiltration through the source when αD is less than about 4; infiltration rates obtained when the water table depth is semi-infinite are of sufficient accuracy for greater values of αD. When the source is described by a specified infiltration flux, the maximum allowable value of this flux for which the material beneath the source remains unsaturated is determined as a function of nondimensional sorptivity and depth to the water table.

This report presents a summary of the conduct and findings of the Exploratory Shaft Alternatives Study. The study basis and findings are presented in sufficient detail to allow the Department of Energy to make an informed decision as to the Exploratory Shaft Facility (ESP)/Repository design option to be used as the basis for resumption of ESF Title 2 design. As a result of the desire for a rigorous, logically defensible analysis and the complexity of the required evaluation, a multi-attribute utility analysis was used as the primary decision-aiding tool. Over 2500 regulations, requirements and concerns were considered under four broad objectives. The analysis resulted in the ranking of 34 options, in accordance with the extent to which each option could achieve the objectives. Additional findings regarding design features that were identified as key elements in an options ability to provide good overall performance are also discussed. 4 figs., 9 tabs.

The objective of this work was to investigate whether a subsurface plume may be detected and followed using crosshole and surface-to-borehole electromagnetic geophysical techniques. both of these techniques were experimentally demonstrated to be feasible. The presence of the injected plume was easily detected with these methods but additional work must be done to refine the techniques. 5 refs., 15 figs., 1 tab.

The USDOE initiated the Production Risk Evaluation Program (PREP) at Sandia National Laboratories (SNL) to assess quantitatively the potential for serious production disruption as the result of random failures, accidents, natural disasters, or sabotage at its facilities. SNL developed a procedure incorporating both network and fault tree models that identifies production vulnerabilities. For each production step, a steady-state flow model computers the "critical time,'' which is the maximum period a step can be shut down without preventing the system from achieving production goals. The critical time is then used in fault tree analysis to determine the failure modes that can stop the process for longer than this period. Modular logic modeling is used for constructing the fault trees. Equipment restorable within its critical time need not be considered critical even though it may perform significant work. This paper focuses on sabotage, but the methodology is applicable to analyzing the other production system vulnerabilities mentioned above. The PREP models can be used to identify those plant areas to which a saboteur would need to gain access. A security strategy using graded protection based on a PREP analysis potentially could reduce security costs. PREP methods also provide quantitative insights to develop protection measures that do not infringe upon the liberties of personnel or complicate work practices.

Environmentally Conscious Manufacturing (ECM) refers to those processes that reduce the harmful environmental impacts of manufacturing, including minimization of hazardous waste, reduction of energy consumption, improvement of materials utilization efficiency, and improvement of operational safety. Approaches involve substitution of non-hazardous for hazardous materials, replacement of existing processes with new, waste-free processes, and increased use of recycle. Reducing waste at the source, through ECM, saves energy and money -- and provides value-added for the production and process. End-of-the-pipe treatment is much more expensive than waste minimization and ECM. Protecting the environment by reducing or eliminating waste is industrially efficient. Industry must create cleaner processes and products that contribute to profitability, rather than just focusing on pollution control. By expanding the return-on-investment equation, it can be shown that manufacturing products without producing hazardous wastes will result in an increase in industrial competitiveness. The optimum time to consider waste minimization is when a manufacturing process is first conceived. A significant and economically beneficial goal would be the development of zero effluent or closed loop manufacturing processes. Several programs at Sandia National Laboratories (SNL) are addressing the issues of waste minimization and pollution prevention through the application of ECM. Many of these programs involve collaboration with other national laboratories, industry, universities, and the production agencies. The following sections will provide a synopsis of Sandia's activities in ECM. 14 refs.

Polyurethane foams are dispensed into firesets to protect their electrical integrity under extreme environmental conditions. Although the production process has generally high precision, reliability problems have been identified. Preliminary results from a research program involving the use of rapid infrared sensors combined with multivariate analysis to monitor the blend of raw materials in near real time are presented. Two distinct regions of the infrared spectrum are considered. The mid infrared region is shown to make sufficiently precise concentration predictions while the near infrared region will require more experimentation. Both infrared regions will be considered for pilot and/or plant scale studies in order to completely specify the infrared sensor. The concentration predictions from the infrared sensor will be used in a closed loop control system in order to improve the reliability of the process.

This report discusses the cycloaliphatic epoxide that is UV cured to create protective coatings. Mechanical and electrical properties are briefly discussed.

Sandia National Laboratories is currently assessing whether the Waste Isolation Pilot Plant (WIPP) complies with the Environmental Protection Agency's Environmental Standards for the Management and Disposal of Spent Nuclear Fuel, High-Level, and Transuranic Radioactive Wastes. Assessing compliance of a geologic repository requires the use of many different types of computer modeling programs. For this task, Sandia is developing a controller, CAMCON (Compliance Assessment Methodology CONtroller), which is a software package consisting of a suite of procedural files that control the flow of data between a computational data base and various modeling programs. CAMCON prompts the analyst for specifics about modeling needs, such as code name(s) and number of runs, thus providing a flexible, yet semi-automated framework in which analysts can select the code(s) best suited for a particular problem. CAMCON also incorporates quality assurance features.

Melt-grown crystals in the Tl-Ca-Ba-Cu-O system with the same structure type can have substantial differences in the superconducting transition, both in width and onset temperature. These differences are attributed to stoichiometry variations arising from cation site substitution. Magnetization and electrical resistivity data are presented which emphasize the extreme sensitivity of the superconductivity to the exact stoichiometry in this system. High quality single crystals exhibit large flux creep due to a weak pinning potential for magnetic flux lines. Flux pinning and thus the critical current density are shown to be significantly enhanced by irradiation with high-energy protons or neutrons. © 1991.

A dynamic finite element analysis was performed to study the penetration mechanics of a commercial fastener called Metal-Tack{reg sign}. This study evaluated the fastener and identified parametric changes required for attachment to AISI 1070 steel (R{sub c} = 26), a material harder than the fastener was designed for. A set of baseline calculations was performed to evaluate the fastener's performance in yellow brass, a much softer material. The analysis indicated that a driving energy of 3.03 ft{center dot}lbs was required to drive the tack into yellow brass. Excellent correlation of this model with experimental data provided confidence for applying the model to AISI 1070 steel. Tack performance was investigated with respect to variations in driving energy and tack strength. The results demonstrated that increasing driving energy was not sufficient for a successful attachment in the steel. An increase in tack strength was also required. Higher tack strength was obtained by increasing the heat treat specification of the tack material, Carpenter R.D.S. steel, to obtain a hardness of R{sub c} = 60. With this increase in strength and a driving energy of 20.8 ft{center dot}lb, the results indicated that the tack would attach but develop high plastic strain (21.5%) during attachment. The calculations were confirmed with tests using a high energy pyrotechnic driver developed to attach the tack. Finally, a geometry modification intended to reduce stress concentrations in the tack was evaluated experimentally but not computationally. The experimental results indicated an improvement in the tack strength and attachment quality. 4 refs., 19 figs., 4 tabs.

This report describes an automatic calibration system used in the calibration of all precision AC calibrators. The system includes an AC-DC Transfer Standard, a DC Voltage Standard, and a high-resolution digital multimeter, with an IBM-XT Personal Computer for data acquisition and analysis. Specialized instrumentation and measurement techniques make it possible to achieve high accuracy measurements with repeatability. 5 refs., 3 figs.

The Formerly Utilized Sites Remedial Action Program has updated an extensive objective concentration factor and biological half-life data base from the international marine radioecological literature. A microcomputer-based data management system has been implemented to provide statistical and graphic summaries of these data. The data base is constructed in a manner which allows subsets to be sorted using a number of interstudy variables such as organism category, tissue/organ category, geographic location (for in situ studies), and several laboratory-related conditions (e.g., exposure time and exposure concentrator). This report updates earlier reviews, and provides summaries of the tabulated data. In addition to the concentration factor/biological half-life data base, we provide an outline of other published marine radioecological works. Our goal is to present these data in a form that enables those concerned with predictive assessment of radiation dose in the marine environment to make a more judicious selection of data for a given application. 588 refs., 18 figs., 3 tabs.

This document describes the NEFTRAN II (NEtwork Flow and TRANsport in Time-Dependent Velocity Fields) computer code and is intended to provide the reader with sufficient information to use the code. NEFTRAN II was developed as part of a performance assessment methodology for storage of high-level nuclear waste in unsaturated, welded tuff. NEFTRAN II is a successor to the NEFTRAN and NWFT/DVM computer codes and contains several new capabilities. These capabilities include: (1) the ability to input pore velocities directly to the transport model and bypass the network fluid flow model, (2) the ability to transport radionuclides in time-dependent velocity fields, (3) the ability to account for the effect of time-dependent saturation changes on the retardation factor, and (4) the ability to account for time-dependent flow rates through the source regime. In addition to these changes, the input to NEFTRAN II has been modified to be more convenient for the user. This document is divided into four main sections consisting of (1) a description of all the models contained in the code, (2) a description of the program and subprograms in the code, (3) a data input guide and (4) verification and sample problems. Although NEFTRAN II is the fourth generation code, this document is a complete description of the code and reference to past user`s manuals should not be necessary. 19 refs., 33 figs., 25 tabs.

The spatial correlation structure of volcanic tuffs at and near the site of the proposed high-level nuclear waste repository at Yucca Mountain, Nevada, is estimated using samples obtained from surface outcrops and drill holes. Data are examined for four rock properties: porosity, air permeability, saturated hydraulic conductivity, and dry bulk density. Spatial continuity patterns are identified in both lateral and vertical (stratigraphic) dimensions. The data are examined for the Calico Hills tuff stratigraphic unit and also without regard for stratigraphy. Variogram models fitted to the sample data from the tuffs of Calico Hills indicate that porosity is correlated laterally over distances of up to 3000 feet. If air permeability and saturated conductivity values are viewed as semi-interchangeable for purposes of identifying spatial structure, the data suggest a maximum range of correlation of 300 to 500 feet without any obvious horizontal to vertical anisotropy. Continuity exists over vertical distances of roughly 200 feet. Similar variogram models fitted to sample data taken from vertical drill holes without regard for stratigraphy suggest that correlation exists over distances of 500 to 800 feet for each rock property examined. Spatial correlation of rock properties violates the sample-independence assumptions of classical statistics to a degree not usually acknowledged. In effect, the existence of spatial structure reduces the ``equivalent`` number of samples below the number of physical samples. This reduction in the effective sampling density has important implications for site characterization for the Yucca Mountain Project.

The US Department of Energy (DOE) is responsible for designing, obtaining a license for, and constructing a geologic repository for the disposal of commercial high-level radioactive waste. The candidate repository site is currently at Yucca Mountain in Nevada. Part of DOE`s responsibility is to assess compliance with the appropriate environmental regulations, including the Environmental Protection Agency`s containment requirements in 40 CFR Part 191. Sandia National Laboratories (SNL) and Pacific Northwest Laboratories (PNL) have been contracted to aid DOE in the assessment of total systems performance. SNL has been tasked with evaluating and comparing the performance assessment methodologies developed by PNL and SNL, as applied to one conceptual model. In this report, SNL has attempted to reproduce, by way of a benchmark exercise, the results of PNL`s preliminary risk assessment of the proposed repository at Yucca Mountain. In general, the results of the PNL analysis and the SNL benchmark of that analysis agreed quite well, in terms of both ground-water flow and transport of unretarded radionuclides. The largest discrepancy between the analyses was noted for transport of retarded radionuclides, and was the result of different techniques for calculating retardation factors. 27 refs., 28 figs., 17 tabs.

The objective of this work is to develop a general method for remotely sensing the presence of tunneling activities using one or more boreholes and a combination of surface sources. New techniques for tunnel detection and location of tunnels containing no metal and of tunnels containing only a small diameter wire have been experimentally demonstrated. A downhole magnetic dipole and surface loop sources were used as the current sources. The presence of a tunnel causes a subsurface scattering of the field components created by the source. Ratioing of the measured responses enhanced the detection and location capability over that produced by each of the sources individually. 4 refs., 18 figs., 2 tabs.

The gas-generation characteristics of contact-handled transuranic waste from Rocky Flats Plant (RFP) and Idaho National Engineering Laboratory (INEL) will be tested at the Waste Isolation Pilot Plant (WIPP) in a series of bin-scale experiments. Bin-scale experiments are necessary because the extreme heterogeneity of CH TRU waste precludes adequate simulation of the waste in the laboratory. A stratified random sample of waste drums will be selected from the collection of drums at RFP and INEL that can be certified for shipment to the WIPP by August 1991. Before the waste is emplaced in the bins, 11 physical characteristics expected to control gas- generation behavior will be measured. These 11 controlling variables'' are expected to apply to all existing and future transuranic waste throughout the Department of Energy complex. Experiments will examine gas generation by radiolysis, microbial degradation, corrosion, and any synergistic mechanisms under many of the environmental conditions that will or may occur in the WIPP repository during the next 10,000 years. Because gas-generation behavior will be interpreted in terms of the controlling variables, gas generation by existing RFP/INEL waste that is not currently shippable, existing waste at other sites, and future waste can be predicted from the results of the WIPP bin-scale experiments. The results of the bin-scale experiments will support the WIPP Project's evaluation of compliance with 40 CFR 191, 40 CFR 268, and the National Environmental Policy Act.

A series of impact experiments on polymethyl methacrylate (PMMA) manufactured by Polycast Technology Corporation has recently been completed using a light gas gun. The intent of this work was to compare these Hugoniot data with those data from a previous study on PMMA manufactured by Rohm and Haas. The results show that there are no significant differences in Hugoniot parameters for the two materials in the pressure range of 1.9 to 6.9 GPa. 8 refs., 10 figs., 3 tabs.

This report describes the current status and recent progress in the Advanced Handling Technology Project (AHTP) initiated to explore the use of advanced robotic systems and handling technologies to perform automated cask handling operations at radioactive waste handling facilities, and to provide guidance to cask designers on the impact of robotic handling on cask design. Current AHTP tasks have developed system mock-ups to investigate robotic manipulation of impact limiters and cask tiedowns. In addition, cask uprighting and transport, using computer control of a bridge crane and robot, were performed to demonstrate the high speed cask transport operation possible under computer control. All of the current AHTP tasks involving manipulation of impact limiters and tiedowns require robotic operations using a torque wrench. To perform these operations, a pneumatic torque wrench and control system were integrated into the tool suite and control architecture of the gantry robot. The use of captured fasteners is briefly discussed as an area where alternative cask design preferences have resulted from the influence of guidance for robotic handling vs traditional operations experience. Specific robotic handling experiences with these system mock-ups highlight a number of continually recurring design principles: (1) robotic handling feasibility is improved by mechanical designs which emphasize operation with limited dexterity in constrained workspaces; (2) clearances, tolerances, and chamfers must allow for operations under actual conditions with consideration for misalignment and imprecise fixturing; (3) successful robotic handling is enhanced by including design detail in representations for model-based control; (4) robotic handling and overall quality assurance are improved by designs which eliminate the use of loose, disassembled parts. 8 refs., 15 figs.

The Pre-Tiger Team Self-Assessment (PTTSA) Report identified findings with respect to the way Sandia National Laboratories (SNL), Albuquerque, (including Tonopah Test Range (TTR) and Kauai Test Facility (KTF)) conducts its environment, safety, and health (ES H) activities. It presented Action Plan Requirements (APR) addressing these findings. The purpose of this PTTSA Action Plan Report is to assist in managing these action plan requirements by collecting, prioritizing, and estimating required resources. The specific objectives addressed by this report include: collection of requirements for the resolution of the findings presented in the PTTSA Report; consolidation of proposed Action Plan Requirements into logical Action Plan groupings for efficiency of resolution; categorization of Action Plans according to severity of the hazards represented by the findings; provision of a basis for long-range planning and issues management; documentation of the status of the proposed corrective actions; establishment of traceability of the corrective action to the original problem or issue; and integration of these plans into the existing ES H structure. The Action Plans in this report are an intermediate step between the identification of a problem or a finding in the PTTSA Report and the execution of the solution. They consist of requirements for solution, proposed actions, and an estimate of the time and (where applicable) resources required to develop the solution. This report is an input to the process of planning, resource commitment, development, testing, implementation, and maintenance of problem resolution. 2 figs.

This handbook outlines the basic job of guest editors for the HEART Conference proceedings, published by the DoD Nuclear Information and Analysis Center in the Journal of Radiation Effects, Research and Engineering. Suggestions are offered for procedures to aid the editors, authors, reviewers, and the publisher in assuring that the journal communicates clearly, concisely, and honestly.

The output intensity of a laser can be expressed in the form I{sub out} = Ag{sub 0}I{sub s} + BI{sub s}. The constants A and B are independent of the pump rate for laser systems with nonsaturable losses, but both g{sub 0}I{sub s} and I{sub s} can depend upon the pump rate. Methods for determining the pump rate dependence of g{sub 0}I{sub s} and I{sub s} are given for experiments in which the pump rate varies continuously. 6 refs., 1 fig.

A towed linear hydrophone array is subject to snakelike bending. If the array were processed as if it were truly linear, poor array gain coupled with a degraded source bearing estimate would result. The signal phase errors produced by sensor position uncertainty in passive sonar arrays are similar to those observed in Synthetic Aperture Radar (SAR) imagery. The Phase Gradient Autofocus (PGA) Algorithm has been shown to be a robust and effective method used to extract degrading phase errors prevalent in SAR imagery. This report shows that with slight modifications, the PGA algorithm can be applied to correct phase errors resulting from sensor position uncertainty introduced into linear-passive arrays. The results of the technique applied to simulated linear array data is also presented. 9 refs., 8 figs.

As part of Sandia National Laboratories` (SNL) pollution prevention program a system is under development to track the movement of hazardous and radioactive materials from procurement, through use, to final disposition. The information provided by this system will improve the flow and enhance the quality of data, avoid duplication of effort, facilitate timely and accurate reporting, better support the information needs of various Environmental, Safety, and Health (ES&H) programs, and allow waste to be minimized more effectively. Such a comprehensive system will incorporate information from other sources and build upon existing databases. The component include the Chemical Information System/Material Safety Data Sheet (CIS/MSDS) system installed by AT&T Bell Laboratories (AT&T-BL) at SNL in Livermore, along with a barcode chemical waste tracking system already in operation at SNL in Albuquerque. Also being developed in Albuquerque are Process Waste Assessments, a radioactive material tracking system, and a radioactive/mixed waste tracking system. A SNL and AT&T-BL joint project is addressing how PWAs will link raw materials to waste streams. With a ``cradle-to-grave`` tracking system, it is possible to assess both financial and environmental life cycle costs. Once in place, this information will improve long-run efficiency and environmental protection, and provide benefits exceeding the initial demands placed upon personnel.

Tests have been conducted on bench-scale heat-pipe solar receivers to explore methods of constructing wicks. The primary objective was to develop a wick structure that was easy to fabricate and was capable of transporting liquid sodium over long distances against hydrostatic and frictional pressure drops. One of the wicks tested in this program was able to lift sodium 45 cm by capillary pumping alone to cool a 3-cm×10-cm area subjected to an average flux of 50 W/cm².

Knowledge of the solubility of gases in pure water and sodium chloride brine is required for the evaluation of gas-liquid behavior associated with numerous processes in the chemical, biological, and geological sciences and in chemical engineering. Modelling of multiphase flow and transport processes used to simulate fluid behavior in geological media requires suitable and accurate gas solubility data, especially when applied to potential nuclear waste repositories such as WIPP. This report contains a critical evaluation of data available in the literature and provides compiled data sets for the solubility of hydrogen, nitrogen, methane, and carbon dioxide gases in pure water and in sodium chloride brine. Mole fraction gas solubilities are presented as functions of temperature and pressure. To evaluate the influence of electrolyte content of the aqueous solution upon the gas solubility, Sechenov coefficients are provided for several concentrated sodium chloride solution. An estimate of the solubility of hydrogen in 5 N sodium chloride brine as a function of pressure exhibits a solubility at 40 MPa that is one fifth the value observed for pure water at the same pressure.

In this paper, a design methodology is presented for assessing drift stability for a potential high-level radioactive waste repository. Excavation stability is required during construction, emplacement, retrieval (if required) and closure phases to ensure worker health and safety, and to prevent development of potential pathways for radionuclide migration in the post-closure period. Requirements for the design, site conditions and stresses are considered in the methodology. Methods for evaluating empirical and analytical results in order to estimate ground support requirements are outlined.

There are three aspects to an environmentally safe battery. The first deals with the manufacturing process, the second with the use of environmentally friendly materials, and the third with the disposal and/or recycling of spent units. In this paper, several ongoing programs at Sandia National Laboratories that relate to the environmentally conscious manufacturing of batteries, are discussed. The solvent substitution/elimination program is a two-pronged effort, aimed at identifying new solvents which are compatible with the environment, while at the same time developing dry process cleaning technology. The joining program is evaluating new solvents for flux removal as well as the development of fluxless soldering processes. In the area of welding, new cleaning processes are under study. Chemical microsensors are under development that are capable of identifying and quantifying single chemical species. These sensors have been used to monitor and improve processes using toxic/hazardous solvents. 1 ref., 1 fig.

Phased-array antenna systems are well known for rapid beam steering and their ability to bring high power to the target. Such systems are also quite complex and heavy, which have limited their usefulness. The issues of weight, size, power use, and complexity have been addressed through a system named COMPASS (Coherent Optical Monolithic Phased Array Steering System). All phased-array antenna systems need: (1) small size; (2) low power use; (3) high-speed beam steering; and (4) digitally-controlled phase shifting. COMPASS meets these basic requirements, and provides some very desirable additional features. These are: (1) phase control separate from the transmit/receive module; (2) simple expansion to large arrays; (3) fiber optic interconnect for reduced sensitivity to EMI; (4) an intrinsically radiation-hard GaAs chip; and (5) optical power provided by a commercially available continuous wave (CW) laser. 4 refs., 8 figs.

Titanium alloys offer desirable properties that make them attractive candidates for tribological applications. Their surface-related properties, however, such as coefficient of friction and wear rate, are less than optimum and must be improved by surface modification. To increase the tribological properties of Ti-6Al-4V, a high temperature ion implantation method, employing a high current density beam (e.g., 500 {mu}A/cm{sup 2}) of nitrogen (N) ions is being developed, where surface temperatures greater than 1000{degrees}C can be obtained. A systematic study was performed with N implantation at temperatures from 400{degrees} to >1000{degrees}C, and to a range of doses from 0.1--1.0{times}10{sup 18} N{sub 2}{sup +}--N{sup +}/cm{sup 2}. Microstructure characterization by Rutherford Backscattering Spectroscopy (RBS) and Glancing Incidence X-ray Diffraction (GID) was performed to determine N distribution and compound formation. RBS analysis showed enhanced N penetrations (i.e., greater than 0.3 {mu}m) for the 800{degrees} and 1000{degrees}C implantations, with the deepest penetration (about 3.5 atomic percent N remaining at 0.75 {mu}m) for the 1000{degrees}C treatment. GID indicated TiN and Ti{sub 2}N concentrations were the greatest for the 800{degrees}C implantation treatment. 11 refs., 4 figs.

The debonding rates of H-passivated P and As in silicon have been observed to be very sensitive to the concentration of majority and minority charge carriers. A theoretical study of the stable and metastable configurations of the {l brace}P,H{r brace} and {l brace}As,H{r brace} pairs in the 0 and +1 charge states has been carried out at the near-ab-initio Hartree-Fock level. These calculations show that the lowest-energy configuration in the 0 charge state is the highest-energy configuration in the +1 charge state and vice-versa. This bistability of donor-hydrogen pairs implies that H cannot remain in place upon change of charge state, whether 0 {r arrow} +1 or +1 {r arrow} 0. Quantitative differences between the P and the As cases are qualitatively consistent with the observed differences in the temperature dependence of the debonding rates of {l brace}P,H{r brace} and {l brace}As,H{r brace}. 14 refs., 1 fig.

The usefulness of neutron radiography as a nondestructive engineering tool is heavily dependent on how a neutron reaches the image plane. Neutron interactions such as scattering and absorption, within a neutron radiography facility or a test part, affect the contrast of the resulting image generated by the process. It is important that the radiographer has a general understanding of how neutrons interact with matter to produce a quality image utilizing a neutron beam. 4 refs.

Short communication.

Short communication.

The electron photo-excitation from the K- state and its subsequent trapping by K+ state is probably at the origin of the silicon dangling bonds (K0) formation during broad-band UV illumination of the N-rich amorphous silicon nitride films. Because the photo-excited electron will move towards the metal electrode the positive charge is expected to accumulate near the nitride-silicon interface with illumination time. Our data also suggest that the N-H group may be at the origin of the nitrogen dangling bonds creation in N-rich films. © 1991 Elsevier Science Publishers B.V. All rights reserved.

Engineers invest several years becoming skilled in the many disciplines necessary to effectively carry out analysis, design and development. This typically includes math, physics, computer science, and special study in their core area of expertise. However, once promoted into management, engineers use less and less of these hard-earned technical skills and find themselves operating in nontechnical arenas in which they have little or no formal training. (The formal training that they do get is often through company-sponsored courses, lacking both the rigor and cohesiveness that they have grown accustomed to in their engineering curriculum.) Often, what they are exposed to are continually varying management doctrines that resemble the flavor of the month, each laying claim to the true secrets of motivation, productivity, and organizational competitiveness. Under such circumstances, it is difficult for the neophyte manager to sort out fact from fancy, and help from hype. It therefore would be helpful to put such theories in perspective and present them in a form most easily digested by technical managers, i.e., from an analytical point of view. This paper attempts to do just that. There are many factors that influence a manager's career progression. One of the most rational factors is how the manager's actions affect the productivity of his or her group. This paper focuses on principles and techniques that a manager can, and should, employ to improve group productivity and enhance his or her opportunities for further advancement.

A hydraulic fracture stimulation conducted during 1983-1984 in non-marine, deltaic, Mesaverde strata at a depth of 7100 ft (2164 m) was cored in a deviated well in 1990. The observed fracture consists of two fracture intervals, both containing multiple fracture strands (30 and 8, respectively). While the core had separated across many of the fracture strands during coring, the rock remained intact across 20 of the strands, preserving materials within the fractures. Nine of the remaining intact strands were split open, revealing abundant gel residue on the surfaces of every fracture examined. Of 7 strands associated with major bedding planes, 4 displayed offsets of 1-3 mm at the planes and 3 strands had their growth terminated at the planes, showing the importance of bedding (petrophysical heterogeneities) on fracture propagation. Implications of all these findings for hydraulic fracture design and analysis are also addressed.

The Space Exploration Initiative (SEI) seeks to reestablish a U. S. program of manned and unmanned space exploration. The President has called for a program which includes a space station element, a manned habitation of the moon, and a human exploration of Mars. The NASA Synthesis Group has developed four significantly different architectures for the SEI program. One key element of a space exploration effort is the power required to support the missions. The Power Specialty Team of the Synthesis Group was tasked with assessing and evaluating the power requirements and candidate power technologies for such missions. Inputs to the effort came from existing NASA studies as well as other government agency inputs such as those from DOD and DOE. In addition, there were industry and university briefings and results of solicitations from the AIAA and the general public as a part of the NASA outreach effort. Because of the variety of power needs in the SEI program, there will be a need for multiple power system technologies including solar, nuclear and electrochemical. Due to the high rocket masses required to propel payloads to the moon and beyond to Mars, there is great emphasis placed on the need for high power density and high energy density systems. Power system technology development work is needed and results will determine the ultimate technology selections.

Shockwave techniques have been used for decades to study the dynamic states of matter in temperature and pressure regimes inaccessible by other methods. These techniques have been employed in a wide variety of scientific, military, and commercial applications. A principal scientific objective has been to determine high-pressure equations of state (EOS) to ultra-high pressures; pressures of tens of Mbar have been reported for several materials. Most recently, these methods have been used for studies of thermophysical properties under shock compression, including phase transition kinetics, and mechanical properties, such as the high-pressure yield strength. In this paper, a brief discussion of recent developments in high velocity launchers is given. Advances in techniques for subjecting materials to a wide range of loading conditions is presented, including selected illustrations of shockwave measurements to Mbar pressures. 54 refs.

The modern investigation of the thermochemical behavior of salt started in the mid-1930's and, for what appears to be a very narrow discipline, salt mechanics'' has acquired considerable technical depth and sophistication. The last three decades have been especially productive in constitutive model development and laboratory investigations of time-dependent creep behavior. This has been largely due to anticipated use of domal or bedded salt deposits as sites for radioactive waste repositories and to expanded need for hydrocarbon and feedstock storage caverns. Salt is an interesting material, in that it is metal like''; and, therefore, constitutive modeling can draw upon a large body of metal deformation information to arrive at appropriate models of behavior. Testing apparatus and methods have centered on either uniaxial or triaxial compression to obtain steady state and transient creep responses. Flow and fracture potentials have been defined. Validation attempts of the models against field data, although limited, have proved promising. 27 refs.

Typical aerospace joints lead to apertures which are very narrow and thick. We develop a systematic analytical treatment of this type of aperture (precise conditions of validity given in the text), although the results are also applicable to apertures on a thin conducting body. An antenna integral equation with an equivalent antenna radius is used to describe the voltage across a narrow and thick aperture in a perfectly conducting plane. The result shows the voltage across the aperture has very high Q (quality-factor) resonances, because the equivalent radius is exponentially small. Transmitted power also exhibits similar behavior. When metallic and gasket losses are included, a nonlocal antenna model together with a local transmission line model is used to describe the voltage across the aperture. Good metallic walls, such as aluminum, are found to significantly reduce the penetration of an aperture of typical dimensions. Gaskets with relatively small loss tangents also result in significant penetration reductions. A simple transmission line with uniform loading is used to approximate the governing equation described in. In the lossless limit and for moderate fatness parameter this simple transmission line model is comparable in accuracy to King's three-term theory. The loading of the bolts or hinges is demonstrated to act in many cases as a short. Finally, the low frequency penetration for a narrow slot aperture of arbitrary depth is characterized by the equivalent polarizabilities (dominating longitudinal component) as a function of the ratio of the depth to the width and ratio of the length to the width. A general relationship is shown to exist between the equivalent radius and the transverse line dipole moments of a slot aperture with depth. The longitudinal equivalent polarizabilities of antennas and slot apertures are used to derive a coupling energy bound for a step function EMP. 9 refs., 8 figs.

Recent reevaluation of the neutron displacement damage function for silicon qualifies it as a sensor for spectra determinations. This development is especially useful in the critical energy region from 0.2 to 2.0 MeV where, in the absence of fission foils, there is a shortage of response functions needed to define spectra satisfactorily. This paper describes how silicon bipolar devices can be used to improve neutron spectra determinations and therefore to better predict the displacement damage induced in devices. © 1991 IEEE

Gas conductivities of narrow natural fractures in sandstone and chalk were measured under varying stress and pore pressure conditions and showed a decrease in conductivity with increasing net stress. Natural fractures in mudstones exhibited continuously decreasing conductivity upon application of stress, so that correlatable conductivity data could not be obtained. Effective-stress-law behavior for the sandstone and chalk fractures were examined, giving α values in the range of 0.8-1.06, where α is the parameter in the effective-stress law, σ - αP. The value of α for the fracture in chalk was nearly constant, but the values for the fracture in sandstone tended to decrease with increasing stress. Transition Reynold's numbers and turbulence factors for flow through the chalk and sandstone fractures were determined, yielding turbulence factors ranging from 6.0-20×106 ft-1 (2.0-6.6×10-5 cm-1) for differently stressed fractures. The entire flow behavior of these natural fractures, including conductivity, effective-stress law, and turbulence, is controlled by stress and pore pressure. As a result, pressure depletion during production will significantly change the productivity of a reservoir with similar natural fractures.

This report is an overview of advanced nonvolatile memory technologies. The memory technologies discussed are: floating gate nonvolatile memory technologies; SNOS nonvolatile technology; ferroelectric technology; and thin film magnetic memories.

We present a method to conservatively estimate MOS hardness in space that shares the same technical basis as MIL-STD 883C, Test Method 1019.4, but permits greater latitude in part selection for low-dose space systems. Cobalt-60 irradiation at 50–300 rad(Si)/s followed by 25°C anneal is shown to provide an effective test of oxide-charge related failures at low dose rates that is considerably less conservative than Method 1019.4. For MOS devices with gate oxides thinner than 100 nm, we show that an elevated temperature “rebound test” generally is not required for systems with total dose requirements less than 5 krad(Si). For thicker gate oxides and/or higher-dose system requirements, rebound testing per Method 1019.4 generally is required to ensure that devices do not fail in space due to interface-trap effects. © 1991 IEEE

Changes in brine and gas permeability of rock salt as a result of nearby excavation (mine-by) have been measured from the underground workings of the WIPP facility. Prior to the mine-by, the formation responds as a porous medium with a very low brine permeability, a significant pore (brine) pressure and no measurable gas permeability. The mine-by excavation creates a dilated, partially saturated zone in the immediate vicinity of the excavation with an increased permeability to brine and a measurable permeability to gas. The changes in hydrologic properties are discussed in the context of pore structure changes.

For several years Phillips Petroleum Company has been waterflooding portions of the Ekofisk Field reservoir for purposes of enhanced oil recovery. Boreholes drilled in waterflooded portions of the reservoir have encountered poor core recoveries and highly fractured rock (poor core recoveries and highly fractured zones were not uncommon in the Ekofisk reservoir before waterflooding, however). Results of laboratory compression tests designed to simulate production-related compaction and subsequent waterflooding indicate that injection pressures currently used to inject seawater into the reservoir are high enough to induce shear failure in high porosity reservoir chalks. A model of chalk deformation explains brittle failure of chalk that has been subjected to stresses well in excess of yield stress.

The Sandia National Laboratories Pre-Tiger Team Self-Assessment Report contains an introduction that describes the three sites in Albuquerque, New Mexico, Kauai, Hawaii, and Tonopah, Nevada, and the activities associated therewith. The self-assessment was performed October 1990 through December 1990. The paper discusses key findings and root causes associated with problem areas; environmental protection assessment with respect to the Clean Air Act, Clean Water Act, Comprehensive Environmental Response, Compensation, and Liability Act and the Superfund amendments, Resource Conservation and Recovery Act; and other regulatory documents; safety and health assessment with respect to organization administration, quality assurance, maintenance, training, emergency preparedness, nuclear criticality safety, security/safety interface, transportation, radiation protection, occupational safety, and associated regulations; and management practices assessment. 5 figs. (MHB)

Large two- and three-dimensional simulations of shock wave physics problems constitute a major expense in ongoing research efforts at Sandia National Laboratories. Massively parallel computing may provide a solution. A simplified version of the production hydrocode CTH, in current use at Sandia National Laboratories, has been successfully developed for the Connection Machine. The parallel version, named PCTH, solves problems in multi-fluid shock wave physics. The development of the Connection Machine code is described and initial performance statistics are presented. These are compared with similar results for the CRAY Y-MP and nCUBE2. 7 refs., 3 figs., 1 tab.

A Low Altitude High Speed Cargo (LAHSC) parachute is being developed for deployment at velocities up to 250 knots at 300 ft altitude. The LAHSC parachute will decelerate and turnover a load to a 40 to 60 ft/sec vertical velocity at first vertical at approximately 30 ft AGL. The acceleration limit is 5 g's. Main chute cargo extraction will be necessary. A single parachute will be utilized for a 7500 lb load, and clusters will be used for larger loads. The 64-gore, 70-ft-dia parachute has a ring-slot/solid construction with a flare at the skirt to aid the inflation. This paper describes the parachute, the design process and testing to date. Model parachutes have been tested in wind tunnels and in free flight. A single full-scale parachute has been tested at low speeds with conventional load extraction, and with a vertical trajectory at deployment. 5 refs., 18 figs., 3 tabs.

High-speed water-entry is a very complex, dynamic process. As a first attempt at modeling the process, a numerical solution was developed at Sandia National Laboratories for predicting the forces and moments acting on a body with a steady supercavity, that is, a cavity which extends beyond the base of the body. The solution is limited to supercavities on slender, axisymmetric bodies at small angles of attack. Limited data were available with which to benchmark the axial force predictions at zero angle of attack. Even less data were available with which to benchmark the pitching moment and normal force predictions at nonzero angles of attack. A water tunnel test was conducted to obtain force and moment data on a slender shape. This test produced limited data because of waterproofing problems with the balance. A new balance was designed and a second water tunnel test was conducted at Tracor Hydronautics, Inc. This paper describes the numerical solution, the experimental equipment and test procedures, and the results of the second test. 8 refs., 11 figs.

Path planning among movable obstacles is a practical problem that is in need of a solution. An efficient heuristic algorithm is presented that uses a generate-and-test paradigm: a good candidate path is hypothesized by a global planner and subsequently verified by a local planner. In the process of formalizing the problem, a technique for modeling object interactions through contact is presented. The algorithm has been tested on a variety of examples, and was able to generate solutions within 10 s on a 17-MIPS Sun Sparc workstation.

A high-resolution capacitive image sensing technique for measuring edge and surface profiles during manufacturing processes has been invented. A prototype device utilizing this technique consists of two 500-μm-diameter electrodes fabricated on a printed circuit board with a 250-μm gap between them. As the device is mechanically scanned over the workpiece, the spatial variations in the edge or surface to be measured interfere with an electric field imposed between the electrodes, altering the mutual capacitance. The sensor functions as a near-field proximity sensor producing range images of surface imperfections. This sensor has been used in applications requiring a preview image of burns on the edge of a machined part and other processes requiring an inspection image after automated deburring operations.

A series of haptic exploratory procedures (EPs) implemented for a multifingered, articulated, sensate robot hand is discussed. These EPs are designed to extract specific tactile and kinesthetic information from an object via their purposive invocation by an intelligent robotic system. Taken together, they form an active robotic touch perception system. This system utilizes a PUMA 560 robot arm, a JPL/Stanford robot hand with joint torque sensing in the fingers, a wrist force/torque sensor, and a 256-element spatially resolved fingertip tactile array. The EPs are described, and experimental results are given.

An analysis is made of the experimental results of a minimum-time trajectory control scheme for a two-link flexible robot. An offline optimization routine determines a minimum-time, straight-line tip trajectory which stays within the torque constraints of the motors and ends with no vibrational transients. An efficient finite-element model is used in the optimization to approximate the flexible arm dynamics. The control strategy described is used to determine the feedback gains for the position, velocity, and strain gage signals from a quadratic cost criterion based on the finite-element model linearized about the straight-line tip trajectory. These feedback signals are added to the modeled torque values obtained from the optimization routine and used to control the robot arm actuators. The results indicate that this combination of model-based and error-driven control strategies achieves a closer tracking of the desired trajectory and a better handling of modeling errors than either strategy alone.

This paper describes the impact of paving, a new automatic mesh generation algorithm, on the analysis portion of the design process. Paving generates an all-quadrilateral mesh in arbitrary 2D geometries. The paving technique significantly impacts the analysis process by drastically reducing the time and expertise requirements of traditional mesh generation. Paving produces a high quality mesh based on geometric boundary definitions and user specified element sizing constraints. In this paper we describe the paving algorithm, discuss varying aspects of the impact of the technique on design automation, and elaborate on current research into 3D all-hexahedral mesh generation. © 1991.

A panel research experiment (PRE) was designed, built, and tested as a scaled-down model of a direct absorption receiver (DAR). The PRE is a 3-MWt DAR experiment that will allow flow testing with molten nitrate salt and provide a test bed for DAR testing with actual solar heating. In a solar central receiver system DAR, the heat absorbing fluid (a blackened molten nitrate salt) flows in a thin film down a vertical panel (rather than through tubes as in conventional receiver designs) and absorbs the concentrated solar flux directly. The ability of the flowing salt film to absorb the incident solar flux depends on the panel design, hydraulic and thermal fluid flow characteristics, and fluid blackener properties. Testing of the PRE is being conducted to demonstrate the engineering feasibility of the DAR concept. The DAR concept is being investigated because it offers numerous potential performance and economic advantages for production of electricity when compared to other solar receiver designs. The PRE utilized a 1-m wide by 6-m long absorber panel. The salt flow tests are being used to investigate component performance, panel deformations, and fluid stability. Salt flow testing has demonstrated that all the DAR components work as designed and that there are fluid stability issues that need to be addressed. Future solar testing will include steady-state and transient experiments, thermal loss measurements, responses to severe flux and temperature gradients and determination of peak flux capability, and optimized operation. In this paper, we describe the design, construction, and some preliminary flow test results of the Panel Research Experiment.

An obvious group of applications for HTS materials is microwave and millimeter wave circuitry. Besides low loss, the unique features of these materials, such as flux flow, can be exploited. We have been concentrating on the Tl-Ca-Ba-Cu-O family of materials. The film growth techniques, lithographic processing methods and the characteristics of several devices we have developed will be presented. These devices include a flux flow-based transistor with demonstrated operation at over 35 GHz, real gain in a 50 ω system and potentially useful non-linearities and impedance levels. A number of passive microwave components are under investigation to form a more complete HTS microwave technology group.

Gas contained in a rectangular laser cell of large length and small width is subjected to large, transient, spatially nonuniform, volumetric heating when pumped. The heating time scale is much longer than the time required for an acoustic wave to traverse the width but can be comparable to the time required for an acoustic wave to traverse the length. Approximate equations describing the motion are derived by applying partial acoustic filtering to the equations of motion: pressure waves traversing the width are removed while pressure waves traversing the length are retained. For a simplified one-dimensional example, a significant density variation is found across the width of the laser cell; moreover, this density variation is in good agreement with a numerical solution of the unap-proximated gas dynamic equations although the latter requires two orders of magnitude more computational time. © 1991 by ASME.

The lifetimes of zinc/bromine flow batteries may be limited by the durability of components which are fabricated from thermoplastic materials and exposed to bromine-containing electrolytes. Examples of such components are flowframes and carbon-filled plastic electrodes. In early versions of the zinc/bromine battery, flowframes and electrodes were made from copolymers of propylene and ethylene. In later versions of the zinc/bromine battery, these materials were replaced by poly(vinyl chloride) (PVC) and polyethyle (flowframes) and polyethylene as the plastic component in electrodes. We found that carbon-plastic electrodes made from polypropylene rich copolymers were swelled and chemically attacked by the bromine-containing electrolytes. As a result, warpage occurred and the battery failed. On the basis of accelerated aging studies we estimated the lifetimes of the electrode and its polypropylene based component to be 96 and 10 months, respectively. The enhanced stability of the electrode was attributed to the presence of carbon which is known to be an antioxidant for thermoxidation. In accelerated exposure tests, bromine-containing electrolytes were also found to attack and leach out the additives used in PVC flowframes. PVC itself was only slightly degraded by the electrolyte. A commercial fluorocarbon, TefzelR, which contains no additives, was determined to be stable in bromine-containing electrolytes and is recommended as a replacement for PVC. Currently, aging studies on carbonfilled polyethylene electrodes are in progress.

The state-of-the-art of parabolic dish solar concentrators is the faceted, glass-metal dish. The mass-production costs of glass-metal dishes may be high because they do not incorporate the innovations of design and materials developed over the last eight years. Therefore, Sandia National Laboratories has undertaken to develop two stretched-membrane parabolic dish concentrators for the Department of Energy's Solar Thermal Program. These solar concentrators are being designed for integration with an advanced solar receiver and a Stirling engine/generator in a 25-kWe power production unit. The first dish, which builds on the successful design of the stretched-membrane heliostats, is to be a low-risk, near-term commercial solar concentrator. This solar concentrator comprises twelve large, 3.6-meter diameter, stretched-membrane facets that are formed into parabolic shapes either with a large vacuum or by preforming the thin membranes plastically. The focal length-to-diameter ratios (f/D) for the facets are about 3.0, relatively large for a dish but much lower than heliostats where they typically range from 50 to 100. Two contractors are currently fabricating facets for this dish, and a third contractor is designing the facet support structure and pedestal for the dish. The second stretched-membrane concentrator is a single-element monolithic dish with an f/D of 0.6. The dish is shaped into a parabola by plastically yielding the membrane using a combination of uniform and nonuniform loading. Initial measurements of the of the dish indicate that it has a slope error of 3.6 milliradian (one standard deviation) relative to a perfect parabola. In this paper, the designs of the two stretched-membrane dishes are analyzed using the computer code CIRCE to model the optical performance of the concentrators and a thermal model, which includes conduction, convection, and radiation heat transfer, to calculate the thermal losses from the cavity solar receivers. The solar collector efficiency, defined as the product of the optical efficiency of the collector and the thermal efficiency of the receiver, is optimized for comparing the performance of several solar concentrator configurations. Ten facet arrangements for the faceted stretched-membrane dish and the single-element stretched-membrane dish are modeled and their performances compared with that of a state-of-the art glass-metal dish. Last, the initial designs of these two stretched-membrane dishes are described along with the results of preliminary performance measurements on their respective optical elements.

A three-dimensional finite element structural analysis of the Intermediate Scale Borehole Test at the WIPP has been performed. The analysis provides insight into how a relatively new excavation in a creeping medium responds when introduced into an existing pillar which has been undergoing stress redistribution for 5.7 years. The stress field of the volume of material in the immediate vicinity of the borehole changes significantly when the hole is drilled. Closure of the hole is predicted to be larger in the vertical direction than in the horizontal direction, leading to an ovaling of the hole. The relatively high stresses near the hole persist even at the end of the simulation, 2 years after the hole is drilled.

As part of the Yucca Mountain Project, our research program to develop and validate conceptual models for flow and transport through unsaturated fractured rock integrates fundamental physical experimentation with conceptual model formulation and mathematical modeling. Our research is directed toward developing and validating macroscopic, continuum-based models and supporting effective property models because of their widespread utility within the context of this project. Success relative to the development and validation of effective property models is predicted on a firm understanding of the basic physics governing flow through fractured media, specifically in the areas of unsaturated flow and transport in a single fracture and fracture-matrix interaction.

Construction of well-posed scenarios for the range of conditions possible at any proposed repository site is a critical first step to assessing total system performance. Event tree construction is the method that is being used to develop potential failure scenarios for the proposed nuclear waste repository at Yucca Mountain. An event tree begins with an initial event or condition. Subsequent events are listed in a sequence, leading eventually to release of radionuclides to the accessible environment. Ensuring the validity of the scenarios requires iteration between problems constructed using scenarios contained in the event tree sequence, experimental results, and numerical analyses. Details not adequately captured within the tree initially may become more apparent as a result of analyses. To illustrate this process, we discuss the iterations used to develop numerical analyses for PACE-90 using basaltic igneous activity and human-intrusion event trees.

Three series of measurements were performed on oriented cores of several Yucca Mountain tuffs to determine the importance of mechanical anisotropy in the intact rock. Outcrop and drillhole samples were tested for acoustic velocities, linear compressibilities, and strengths in different orientations. The present data sets are preliminary, but suggest the tuffs are transversely anisotropic for these mechanical properties. The planar fabric that produces the anisotropy is believed to be predominantly the result of the preferred orientation of shards and pumice fragments. The potential of significant anisotropy has direct relevance to the formulation of constitutive formulation and the analyses of an underground opening within Yucca Mountain.

Yucca Mountain, located in southwestern Nevada, is the site for a proposed high-level nuclear waste repository. The hydrologic units at Yucca Mountain appear to have quite different material characteristics. Additionally, measurements show that the material properties within each hydrologic unit vary significantly. Rock core samples taken from this site indicate that the volcanic tuff is highly fractured and nonhomogeneous. Modeling studies were conducted to determine the effects of material heterogeneities on the flow of water through rock. Multiple numerical calculations were made using random variations in spatial distributions of material properties. The results of these material variations on flow resistance, mechanical dispersion, and channeling were determined. Computed results were compared with a linear analytical model. Good agreement was obtained in the majority of the flow cases investigated.

Under the sponsorship of the US Nuclear Regulatory Commission (NRC), Sandia National Laboratories (SNL) is developing a performance assessment methodology for the analysis of long-term disposal and isolation of high-level nuclear wastes (HLW) in alternative geologic media. As part of this exercise, SNL created a conceptualization of ground-water flow and radionuclide transport in the far field of a hypothetical HLW repository site located in unsaturated, fractured tuff formations. This study provides a foundation for the development of conceptual mathematical, and numerical models to be used in this performance assessment methodology. This conceptualization is site specific in terms of geometry, the regional ground-water flow system, stratigraphy, and structure in that these are based on information from Yucca Mountain located on the Nevada Test Site. However, in terms of processes in unsaturated, fractured, porous media, the model is generic. This report also provides a review and evaluation of previously proposed conceptual models of unsaturated and saturated flow and solute transport. This report provides a qualitative description of a hypothetical HLW repository site in fractured tuff. However, evaluation of the current knowledge of flow and transport at Yucca Mountain does not yield a single conceptual model. Instead, multiple conceptual models are possible given the existing information.

Sandia National Laboratories, as a participant in the Yucca Mountain Project, administered by the Nevada Operations Office of the US Department of Energy, is in the process of evaluating a proposed site for geologic disposal of high-level nuclear wastes in the volcanic tuffs at Yucca Mountain, Nevada. In a repository, loads will be imposed on the rock mass as a result of excavation of the openings and heating of the rock by the nuclear waste. In an attempt to gain a better understanding of the thermal, mechanical, and thermomechanical response of fractured tuff, a series of experiments have been performed, and measurements have been taken in the welded and nonwelded tuffs at the G-Tunnel underground test facility at Rainier Mesa, Nevada. Comparisons between measured and calculated data of the G-Tunnel High-Pressure Flatjack Development Experiment are presented in this investigation. Calculated results were obtained from two dimensional finite element analysis using a recently developed compliant-joint rock-mass model. The purpose of this work was to assess the predictive capability of the model based on limited material property data for the G-Tunnel welded tuff. The results of this evaluation are discussed.

A new facility is being constructed for the Primary Standards Laboratory (PSL) at Sandia National Laboratories in Albuquerque, New Mexico. Features of the final design are at the state of the art and were developed over a number of years of study and design effort. Based on experience and evaluation of anticipated needs, a philosophy was established for the design and followed through the effort. A temperature control limit of {plus minus}0.01{degrees}C is required for some of the dimensional measuring spaces; isolation from vibration and electromagnetic interference (EMI) are required for all measurement spaces. The requirements for the facility and the principal design features are presented. 4 refs.

Two devices or tools are described which can be used to evaluate the ability of chip passivation or postbond coatings to protect a Si device from moisture penetration and resultant Al corrosion. The first device is a test chip with a number of Al triple track and other corrosion measurement structures. The authors present HAST data to illustrate the use of this chip in measuring failure rates and determining failure modes. The second device is a rugged, moisture sensitive, porous Si capacitor, which is compatible with high temperature passivation and postbond IC processing. Data are presented showing the stability of the device relative to that of an anodized Al moisture sensor and showing the variation of capacitance with moisture. Data are also presented showing that the capacitor can respond to a point source of water located over the porous region but remotely from the top electrode.

While the backscattered field as a function of angular incidence of a plane wave for dihedral corner reflectors having right, acute, and obtuse angles has been studied extensively, it has generally been stated that the RCS of a 90{degree} dihedral corner reflector oriented for maximum backscattered return to a radar is given by the expression {sigma} = 8{pi}a{sup 2}b{sup 2}/{lambda}{sup 2}. The intent of this paper is to present experimental results which demonstrate that not only does the RCS of a dihedral corner reflector oriented for maximum backscattered return differ significantly from this value, but that high range resolution measurements of the dihedral can serve to identify the dominant contributors to the backscattered field. Further, inclusion of these backscattered components in an analytical calculation will allow an accurate calibration model to be generated. 6 refs., 8 figs.

Computer-aided molecular design (CAMD) has been used to define the structural conformations and intramolecular interactions of bituminous coal models. Molecular dynamics studies have produced representative minimum energy conformations for several published molecular models. These studies show the importance of van der Waals (vdW) and hydrogen-bonding interactions as cohesive forces responsible for the three-dimensional (folded) structures of the coal methods. Calculations on pairs of small ring compounds representative of those found in coal clusters demonstrate that aromatics exhibit stronger vdW interactions compared with saturated ring compounds. Correlations of the vdW interactions compared with saturated ring compounds. Correlations of vdW interactions with boiling points also show differences between aromatics and saturated rings. 23 refs., 2 figs., 1 tab.

Large computational physics codes are increasing in complexity as customers demand improved physics packages and more flexible algorithms and problem specifications. It is not uncommon for a code to exceed one hundred thousand lines of FORTRAN, and some codes are much larger. This poses a considerable challenge for program management. The Computational Physics Research and Development Division at Sandia National Laboratories is aggressively pursuing C++ as the language of choice for new coding efforts. We feel that we cannot meet the stringent customer requirements and delivery schedules we now face with either FORTRAN77 or Fortran-90. 8 refs., 3 tabs.

Cleaning, plating, and painting are chemically intensive processes that involve toxic and potentially carcinogenic materials that pose a significant threat to the environment. EPA/OSHA, the Clean Air Act, and the Montreal Protocol are forcing development of environmentally sound materials and processes. A review is given of the materials and processes that are under investigation that will minimize the environmental impact of these operations. 7 refs.

The Recirculating Linear Accelerator (RLA) is returning to operation with a new relativistic electron beam (REB) injector and a modified accelerating cavity. Upon completion of our pulsed-power test program, we will capture the injected beam on an Ion Focussed Regime (IFR) guiding channel in either a spiral or a closed racetrack drift tube. The relativistic beam will recirculate for four passes through two accelerating cavities, in phase with the ringing cavity voltage, and increase to 8--12 MeV before being extracted. We designed the METGLAS ribbon-wound core, inductively isolated, four-stage injector to produce beam parameters of 4 MeV. 10--20 kA, and 40--55 ns FWHM. The three-line radial cavity is being modified to improve the 1-MV accelerating pulse shape while an advanced cavity design study is in progress. This is a continuation of the Sandia National Laboratory program to develop compact, high-voltage gradient, linear induction accelerators. The RLA concept is based on guiding an injected REB with an IFR channel. This channel is formed from a plasma created with a low energy electron beam inside a beam line containing about 2 {times} 10{sup {minus}4} Torr of argon. The REB is injected onto the IFR channel and is transported down the beamline through a water dielectric accelerating cavity based on the ET-2 design. If the round-tip path of the beam matches the period of the cavity, the REB can be further accelerated by the ringing waveform on every subsequent pass. We have installed the new REB injector because we need a higher amplitude, longer duration., flat-topped pulse shape with a colder beam than that produced by the previous injector. We made extensive use of computer simulations in the form of network solver and electrostatic field stress analysis codes to aid in the design and modifications for the new RLA. The pulsed-power performance of the RLA injector and cavity and the associated driving hardware are discussed.

A major center with emphasis on validation of nondestructive inspection techniques for aging aircraft, the Aging Aircraft NDI Development and Demonstration Center (AANC), has been funded by the FAA at Sandia National Laboratories. The Center has been assigned specific tasks in developing techniques for the nondestructive inspection of static engine parts, assessing inspection reliability (POD experiments), developing test beds for nondestructive inspection validation, maintaining a FAA library of characterized aircraft structural test specimens, and leasing a hangar to house a high flight cycle transport aircraft for use as a full scale test bed. 3 refs.

This paper describes procedure used to produce a test-validated finite element model of a three-stage solid propellant booster system. A series of system-level modal tests were performed for several inert and live propellant configurations. Test-analysis models (TAMs) were used to provide pretest support of the live propellant system tests. Confidence in the model was established by a test-analysis correlation procedure. Optimization techniques were used to determine appropriate model updates. 11 refs., 8 figs., 3 tabs.

Soldering is often referred to as a mature technology whose fundamentals were established long ago. Yet a multitude of soldering problems persist, not the least of which are related to the wetting and spreading of solder. The Buff-Goodrich approach to thermodynamics of capillarity is utilized in a review of basic wetting principles. These thermodynamics allow a very compact formulation of capillary phenomena which is used to calculate various meniscus shapes and wetting forces. These shapes and forces lend themselves to experimental techniques, such as the sessile drop and the Wilhelmy plate, for measuring useful surface and interfacial energies. The familiar equations of Young, Wilhelmy, and Neumann are all derived with this approach. The force-energy duality of surface energy is discussed and the force method is developed and used to derive the Herring relations for anisotropic surfaces. The importance of contact angle hysteresis which results from surface roughness and chemical inhomogeneity is presented and Young's equation is modified to reflect these ever present effects. Finally, an analysis of wetting with simultaneous metallurigical reaction is given and used to discuss solder wetting phenomena. 60 refs., 13 figs.

Titanium dioxide (TiO{sub 2}) is a known photocatalyst for solar detoxification of water containing organic contaminants including PCB's and dioxins. Unfortunately, the UV light used by the photocatalyst only comprises about 4% of the strong spectrum. Metalloporphyrins strongly absorb in the visible and near infrared region. Using visible light, we have investigated Ni(II) uroporphyrin (NiUroP), Sn(IV)Cl{sub 2} uroporphyrin (SnUroP) and Sn(IV)Cl{sub 2} tetrakis(p-carboxyphenyl) porphyrin (SnTCPP) as possible enhancers of destruction of a model organic compound, salicylic acid (SA), by means of photosensitization of colloidal TiO{sub 2} particles. All three porphyrins are found to adsorb reversibly onto the colloidal TiO{sub 2} upon variation of pH. Adsorption of porphyrins results in the increased colloidal stability of fine TiO{sub 2} particles in the pH range 5--8. While NiUroP on TiO{sub 2} does not show any enhancement of photodestruction, the adsorption of SnUroP increases the destruction rate compared to that of the bare TiO{sub 2} surface. The effect of ambient oxygen on the observed photolability of the Sn porphyrins and enhancement of photodestruction of SA was also investigated. SnTCPP does not photodecompose upon illumination either in the presence or absence of TiO{sub 2}, but neither does it bind to the photocatalyst at pH 6. At pH 4.5 it adsorbs onto TiO{sub 2} but it also photodecompose at this pH. We are attempting to stabilize the adsorbed porphyrins by adding suitable peripheral substituents onto the porphyrin macrocycle. 27 refs., 6 figs.

The frequency response of the Faraday rotation in fiber current sensors is computed and measured for sensor coils of noncircular cross section and with displaced coil and conductor axes. Resonances are observed at higher frequencies with magnitudes approaching that of the low frequency response. Narrowband current sensors at frequencies above 100 MHz are reported. 7 refs., 4 figs.

We have designed and tested a system for applying a ramped vertical magnetic field for turning the electron beam in the IFR Recirculating Linear Accelerator. The field is highly uniform over two Gaussian beam radii, and can be adjusted for a large radial gradient for increased energy bandwidth. The system includes shielding of the current-carrying rods to protect the pulser from REB induced fields and to reduce the effect of REB images on the beam transport to negligible levels. The system has been tested on the IBEX accelerator with > 95% peak current transport and > 90% charge transport through a 90{degree} turn. 2 refs., 6 figs.

The cleaning efficiency of five alternative solvents for chlorofluorocarbons (CFCs) and chlorohydrocarbons (CHCs) used in the manufacture of certain electronic components was studied. These solvents were evaluated in the first phase of a two-phase program to remove various manufacturing contaminants such as oils, greases, mold release, and body oils. Results have shown that EXXATE 1000 and EC-7 were able to effectively remove these contaminants from copper board substrates. 4 refs., 5 figs., 1 tab.

Eight Gulf Coast salt domes have emerged as candidate sites for possible expansion of the Strategic Petroleum Reserve (SPR) to one billion barrels. Two existing SPR sites, Big Hill, TX, and Weeks Island, LA, are among the eight that are being considered. To achieve the billion barrel capacity, some 25 new leached caverns would be constructed, and would probably be established in two separate sites in Louisiana and Texas because of distribution requirements. Geotechnical factors involved in siting studies have centered first and foremost on cavern integrity and environmental acceptability, once logistical suitability is realized. Other factors have involved subsidence and flooding potential, loss of coastal marshlands, seismicity, brine injection well utility, and co-use by multiple operators. 5 refs., 11 figs., 2 tabs.

A series of numerical simulations has been performed using the multi-dimensional hydrodynamics code CTH to computationally determine a ballistic limit for a Whipple bumper shield. The ballistic limit is generally characterized as a critical diameter such that particle diameters greater than the ballistic limit will generate debris clouds that will penetrate the rear wall and particle diameters less than the ballistic limit will not. The particular shield design used for these analyses is defined as a 1.27 mm bumper, a 102 mm void space, and a 3.18 mm rear wall. Since debris shape is expected to be a contributing factor in the impact phenomena, two different shapes are considered for the numerical simulations. The particle shapes considered were flat plates of constant 1 mm thickness and varying diameters and spheres of varying diameters. The critical diameter (ballistic limit) was determined over the velocity range 4 km/s to 15 km/s for both geometries. 13 refs., 2 figs.

In response to a request from the US Government, Sandia National Laboratories has developed an instrumentation system to monitor the conditions along an underwater, rotating drive shaft. It was desired to study the structural integrity and signal acquisition capabilities of the Shaft Instrumentation System (SIS) in an environment which closely simulates the actual deployment conditions. In this manner, the SIS response to ill-defined conditions, such as flow field turbulence or temperature fluctuations, could be determined. An Underwater Spin Facility was developed in order to verify the operation of the instrumentation and telemetric data acquisition system in a combined environment of external pressure, transient axial loads and centrifugal force. The main components of the Underwater Spin Facility are a large, five foot diameter pressure vessel, a dynamically sealed shaft, a drive train assembly and a shaker table interface which is used to apply the axial loads. This paper presents a detailed description of the design of the Underwater Spin Facility. It also discusses the SIS certification test program in order to demonstrate the successful performance of the Underwater Spin Facility. 8 refs., 10 figs.

The Magma Energy Program is a speculative endeavor regarding practical utility of electrical power production from the thermal energy which reside in magma. The systematic investigation has identified an number of research areas which have application to the utilization of magma energy and to the field of geothermal energy. Eight topics were identified which involve thermal processes and which are areas for the application of the techniques of numerical simulation. These areas are: (1) two-phase flow of the working fluid in the wellbore, (2) thermodynamic cycles for the production of electrical power, (3) optimization of the entire system, (4) solidification and fracturing of the magma caused by the energy extraction process, (5) heat transfer and fluid flow within an open, direct-contact, heat-exchanger, (6) thermal convection in the overlying geothermal region, (7) thermal convection within the magma body, and (8) induced natural convection near the thermal energy extraction device. Modeling issues have been identified which will require systematic investigation in order to develop the most appropriate strategies for numerical simulation. It appears that numerical simulations will be of ever increasing importance to the study of geothermal processes as the size and complexity of the systems of interest increase. It is anticipated that, in the future, greater emphasis will be placed on the numerical simulation of large-scale, three-dimensional, transient, mixed convection in viscous flows and porous media. Increased computational capabilities, e.g.; massively parallel computers, will allow for the detailed study of specific processes in fractured media, non-Darcy effects in porous media, and non-Newtonian effects. 23 refs., 13 figs., 1 tab.

Sensitivity studies have been conducted for the gas release from the Waste Isolation Pilot Plant (WIPP) using the TOUGH2 computer code with performance measures of peak repository pressure and gas migration distance at 1000 years. The effect of formation permeabilities including impermeable halite, two-phase characteristic curves including different models and residual saturations, and other variations was studied to determine their impact on the performance of the WIPP repository. 15 refs., 7 figs., 2 tabs.

The standard operating mode produces bremsstrahlung with an endpoint energy of about 18 MeV. This paper describes a new mode with a 8.5 MeV endpoint energy and the same standard mode pulse characteristics achieved by operating only half of the accelerator at full charge with the advantage of minimal setup time. An extension of the new half-voltage mode is to use the other half of the accelerator for delivering a second pulse at a later time with the same technique. The double pulse mode is ideal for beam generation which requires a long interpulse time in the millisecond regime. The beam characteristics of the two half-voltage pulses are nearly identical with the nominal radiation pulse full width at half maximum of 21 ns and 10--90 risetime of 11 ns recorded by the same Compton diode radiation monitors on instruments triggered 30 ms apart.

A series of shock-loading experiments on a nitrocellulose-based (NC-based) gun propellant was conducted using a light-gas gun. The intent of this work was to characterize the shock sensitivity of the gun propellant. The initial objectives were to obtained Hugoniot data and to investigate the pressure threshold at which a reaction initiates. For the Hugoniot/reaction threshold experiments, 1/4-length grains of propellant were mounted on the front of projectiles and were impacted onto either polymethylmethacrylate (PMMA), fused silica or sapphire targets at velocities as high as 1.4 mm/{mu}s, the upper limit of the gun. The particle velocity data obtained from the VISAR (Velocity Interferometer System for Any Reflector) records for the propellant fit a Hugoniot curve found in the Russian literature for a double-base, NC-nitroglycerine propellant. The density initial bulk sound velocity, and empirical parameter S values for the gun propellant were 1.63 g/cm{sup 3}, 1.70 mm/{mu}s and 1.85, respectively. VISAR data were also used to obtained the ignition threshold pressures of the gun propellant. Reactions were observed at impact pressures of 2.6 GPa and above. 5 refs., 6 figs., 1 tab.

We report on the use of a deposition/etch approach to the loss of selectivity problem, using high activity fluorine chemistries in the etch step. Proof-of-concept experiments were initially performed in a hot wall system, the excellent results obtained lead us to prove out the concept in a commercially available cold wall Genus reactor. We observed that WF{sub 6} is ineffective as an etchant of W. The technique has been able to produce perfectly selective depositions 1 micron thick in both hot wall, and cold wall, systems. Sheet resistivity values and film morphology are good. 9 refs., 4 figs., 1 tab.

This paper's main result is an O(({radical}{bar m}lgm)(n lg n) + mlg n)-time algorithm for computing the kth smallest entry in each row of an m {times} n totally monotone array. (A two-dimensional A = a(i,j) is totally monotone if for all i{sub 1} < i{sub 2} and j{sub 1} < j{sup 2}, < a(i{sub 1},j{sub 2}) implies a(i{sub 2},j{sub 1})). For large values of k (in particular, for k=(n/2)), this algorithm is significantly faster than the O(k(m+n))-time algorithm for the same problem due to Kravets and Park. An immediate consequence of this result is an O(n{sup 3/2} lg{sup 2}n)-time algorithm for computing the kth nearest neighbor of each vertex of a convex n-gon. In addition to the main result, we also give an O(n lg m)-time algorithm for computing an approximate median in each row of an m {times} n totally monotone array; this approximate median is an entry whose rank in its row lies between (n/4) and (3n/4) {minus} 1. 20 refs., 3 figs.

This paper presents a practical algorithm for partitioning a program into sequential threads. A thread is a sequence of instructions, possibly including branches, which can be scheduled as an indivisible unit on a von Neumann-like processor. The partitioning algorithm is designed for a non-strict (but not lazy) language with non-strict data structures and side-effects. The primary target of the proposed compilation strategy is large-scale parallel systems which rely on multithreading at the processor level to tolerate long communication latencies. As such, the algorithm incorporates a mechanism to balance the desire to maximize thread length with the desire to expose useful high-level parallelism. Although this paper focuses on non-strict semantics in conjunction with a parallel multithreaded architecture, the partitioning analysis is equally well suited (with appropriate simplifications) to a non-strict language on a sequential machine or a strict language on a parallel multithreaded machine. Our analysis is accomplished without compromising non-strict semantics and without creating dependencies which sacrifice useful high-level parallelism. It can also exploit known dependency information. The analysis starts with a traditional dataflow graph and partitions it into a set of interrelated threads. 16 refs., 9 figs.

The Silver Bullet Skunk Works, and experimental product realization team at AT T Consumer Products, designed and shipped a new telephone answering system to market in eight months, approximately one year faster than previous AT T products of similar complexity. This paper outlines the Design for X'' (DFX) philosophies and the team structure that enabled the group to accelerate the Product Realization Process. The Answering System 1300, developed in record time, was a successful product that met its schedule and cost objectives, and sold out its entire high-volume manufacturing run. Lessons learned from the Skunk Works experience have since been applied to other development activities in AT T Consumer Products. 3 figs.

Increasingly stringent air emission standards in various states has dictated the elimination of engineering finishes which are derived from high volatile organic compound (VOC) paint chemistries. In July 1989, Allied-Signal, Inc., Kansas City Division, Kansas City, Missouri, voluntarily closed its paint facility, due to non-compliance with local air emission standards. The following details the materials selection and evaluations which led to current processing using low VOC paints, which permitted the Allied Signal, Inc., paint facility to achieve compliance and resume operations. 1 tab.

We have developed a model which utilizes a probabilistic failure criterion to describe intergranular stress corrosion cracking (IGSCC). A two-dimensional array of elements representing a section of a pipe wall is analyzed, with each element in the array representing a segment of grain boundary. The failure criterion is applied repetitively to each element of the array that is exposed to the interior of the pipe (i.e. the corrosive fluid) until that element dissolves, thereby exposing the next element. A number of environmental, mechanical, and materials factors have been incorporated into the model, including: (1) the macroscopic applied stress profile, (2) the stress history, (3) the extent and grain-to- grain distribution of carbide sensitization levels, which can be applied to a subset of elements comprising a grain boundary, and (4) a data set containing IGSCC crack growth rates as function of applied stress intensity and sensitization level averaged over a large population of grains. The latter information was obtained from the literature for AISI 304 stainless steel under light water nuclear reactor primary coolant environmental conditions. The resulting crack growth simulations are presented and discussed. 14 refs., 10 figs.

Edge finishing and deburring of parts is a tedious operation that should be automated. This paper describes the use of direct-drive XY table in the automated edge finishing of machined parts. The table is faster and more accurate than an articulated robot, thus where planar motion in a small work area is sufficient it is preferable. Hybrid force/position control is used to guide the table (with mounted workpiece) past the tool and maintain the contact force at the desired level. A six-axis force sensor on the tool spindle is used to measure contact force. We identified a dynamic model for the table from experimental measurements and used this model to design a force/position controller for the table. An example application of the table in the deburring of an actual jet engine turbine hub is presented. 5 refs., 12 figs.

This paper justifies the need for and describes studies of brine chemistry under way for German and American high- and intermediate-level radioactive waste repositories in domal and bedded salt formation. In particular, it discusses the origin and composition of fluids that could enter these repositories and some sampling, modeling, and statistical techniques used to characterize them. 24 refs., 4 figs., 5 tabs.

Historically, characterization of fluid flow and transport of soluble elements in the unsaturated, or vadose, zone has been limited. Until recently, most of the interest in transport of water-soluble pollutants has been focused on aquifer contamination, i.e. saturated conditions. Vadose zone investigations are hampered by a lack of appropriate technology for the necessary measurements; little work has been done to relate laboratory measurements to field-scale effects; and development and validation of computational models has been limited, in part through lack of data. We describe here results of a small-scale field experiment in which existing technology is used to quantify fluid movement following controlled infiltration. 6 refs., 2 figs.

Sandia National Laboratories has considerable experience with video systems used for alarm assessment. Until recently the camera of choice for lighted security applications was the monochrome vacuum tube video camera. However, with recent advancements in the solid state imager technology, the integration of tube cameras in security systems may soon become obsolete. The sensitivity and resolution of solid state imagers is approaching that of vacuum tube imagers. In addition, solid state cameras have a relatively long lifetime and require little maintenance. Initial equipment costs are similar. Due to the increased performance of solid state imagers, Sandia has established an ongoing program to evaluate these cameras. The evaluations are performed mainly to verify manufacturers' specifications for resolution, sensitivity, and signal to noise ratio, which are the critical camera parameters that should be considered when designing video systems. This report defines these parameters, describes the test procedures, and provides test results. 1 figs., 2 tabs.

Zeolite-based tritium lamps are a possible alternative to traditional tritium gas tube light sources. Rare earth luminescing centers may be ion-exchanged into zeolite matrices. Close proximity of tritium atoms to the rare earths can be provided by highly tritiated water sorbed within the pore structure of the zeolite aluminosilicate matrix. Zeolites are optically clear and radiation stable. Light outputs from tritium-loaded zeolites are shown here to exceed 2{mu}W/cm{sup 2}, with good stability. Procedures for obtaining light sources are presented and results are discussed. The possible use of these luminescent materials as process monitors for zeolite absorption columns in tritium service is also discussed. 13 refs., 3 figs.

To provide a method for addressing the uncertainty associated with conceptual models developed for performance assessment of waste management sites, probabilistic networks have been applied to the conceptual model development process. The application of probabilistic networks provides a graphical representation of the reasoning process that goes into developing conceptual models. Probability tables associated with decision points in the process provide a quantification of the uncertainty that is associated with the resulting conceptual models. To support the development of this probabilistic network, a formal process is being designed and implemented to elicit expert information about the conceptual model development process. This paper discusses the approach to designing this expert judgment elicitation process. 10 refs.

The short-transverse (S-T) stress corrosion cracking (SCC) behavior of Al-Li-CU alloy 2090 was studied using a static load SCC test technique. Time to failure was measured as a function of applied potential in several different environments. Rapid SCC failures (< 10 hours) were observed only when the following criteria were satisfied: E{sub br, T1} < E{sub applied} < E{sub br, matrix} where potentials refer to the breakaway potentials of the subgrain boundary T{sub 1} (Al{sub 2}CuLi) phase and the {alpha}-Al matrix phase. E{sub br} values were measured using potentiodynamic polarization of bulk materials intended to simulate the individual phases found in the subgrain boundary region. Results strongly suggest an anodic dissolution based SCC mechanism for this alloy where selective dissolution of T{sub 1} on the subgrain boundary is a critical step. The unusual pre-exposure embrittlement phenomenon demonstrated by Al- Li alloys is also shown to be consistent with these simple SCC criteria. 21 refs., 9 figs., 6 tabs.

One of the possible consequences of disruptions is the generation of runaway electrons which can impact plasma facing components and cause damage due to high local energy deposition. This problem becomes more serious as the machine size and plasma current increases. Since large size and high currents are characteristics of proposed future machines, control of runaway generation is an important design consideration. A lumped circuit model for disruption runaway electron generation indicates that control circuitry on strongly influence runaway behavior. A comparison of disruption data from several shots on JET and D3-D with model results, demonstrate the effects of plasma motion on runaway number density and energy. 6 refs., 12 figs.

Benchmarking a network file server introduces some unique considerations over traditional benchmarking scenarios. Since the user is executing on a client system interconnected to the file server, the client and network must be provided for during benchmarking. During a recent procurement action, Sandia National Laboratories was challenged to develop a benchmark suite that would accurately test the network requirements. This paper describes the benchmark design and summarizes the experience gained from the benchmark executions. 8 refs., 2 figs.

The electromagnetic field in a mode-stirred chamber is a random process. Samples of this random process are random variables. Different realizations of this random variable can be obtained by changing the paddle-wheel angle, changing the frequency, or changing the location at which the sample is taken. Correlation widths can be defined for each of these three variables. For examples, the spatial correlation width is the distance a point sensor must be moved to realize an uncorrelated value of the field (paddle-wheel angle and frequency held constant). Likewise, the paddle-wheel correlation width is the angle through which the paddle wheel must turn to yield an uncorrelated value (location and frequency held constant). The frequency correlation width is the frequency change required to yield an uncorrelated value (location and paddle-wheel angle held constant). These values were determined experimentally for the sandia mode-stirred chamber by sampling the field at equal increments (for each variable) and calculating an autocorrelation function. The autocorrelation function is a random process (because it is calculated from a random process) and must be averaged to determine it width. The correlation widths were found to be less than 0.1{degree} for paddle-wheel angle, 50 kHz for frequency, and half a wavelength for spatial location. 4 refs., 3 figs., 2 tabs.

Although the feasibility of using PZT and PLZT films for optical data processing applications, such as optical storage disks, image comparators, and spatial light modulators, has clearly been established, most of the critical parameters related to the storage and readout processes still need to be evaluated. Optical readout techniques capable of nondestructively determining the value of polarization are based either on the quadratic electrooptic effect or on a photocurrent response. In reflection, large electrooptic retardations (>60{degrees}) have now been achieved with thin PZT films ({approx equal} 0.5 {mu}m) under conditions that optimize interference effects. These results are quite attractive for device applications. Model calculations, based on the equations of reflection ellipsometry, have been used to develop a framework for understanding those results. The magnitude of the photocurrent response has also been used to determine the polarization state. However, the photocurrent always has the same sign, regardless of the sign of the polarization, which suggests the presence of a strong bias field due to at least one of the interfaces. In addition, the accumulation of space charge after a succession of measurements suppresses the photocurrent transient, which severely limits the utility of a photocurrent based readout. 7 refs., 9 figs.

The contact of aluminum-based melts with liquid water has been shown to be explosive in many experiments performed by the aluminum industry and in several nuclear reactor experiments and accidents. In order to obtain quantitative information relating to the fuel-coolant interactions that might occur with aluminum-based fuel, a laboratory-scale experimental study is being performed at Sandia National Laboratories. The overall objective of this research program is to provide an understanding of the mechanism of steam explosions with the melt compositions expected in several hypothetical core meltdown accident scenarios in production reactors. In this program it has been demonstrated that rapid exothermic metal-water reactions can accompany the steam explosions under certain conditions resulting in enhanced energy release and in the concomitant generation of hydrogen. 4 refs., 2 figs.

The INTEROP Achievement Award will be given to those customer organizations that make the most effective use of internetworking technology to further their own specific business aims. This paper is an application for this award by Sandia National Laboratories. Given are the network application, topology, and the types of systems to which it is applied.(JEF)

One problem with electromagnetic time domain finite-difference simulations in cylindrical coordinates is the rapidly decreasing characteristic dimension of the cells as r approaches zero. In order to satisfy the Courant stability condition a small time step is needed to insure stability, which is undesirable because it increases the cost of the simulation. In our presentation, we will describe a method which uses a rectangular grid and an annular cylindrical grid which overlap to perform electromagnetic simulations of cylindrical geometries. The two grids are connected by interpolating the field at the grid points of one grid using field values from the second grid. 2 refs.

Short communication.

The strength of deuterium bonding to the walls of closed cavities within Si was determined in ion-beam experiments. These studies circumvented an inherent indeterminacy in the analysis of external-surface desorption and thereby allowed the Si-H surface bond energy to be quantified for the first time. The bond energy is 2.5 {plus minus} 0.2 eV for submonolayer coverages. 14 refs., 3 figs.

Scan path testing and debugging offers a structured, proven way to debug and test arbitrarily complex electronic systems. The interface and equipment requirements are far lower than traditional debug and test techniques. The system is also completely testable even when physically remote from the lab where it was originally developed. This report describes our experience using scan techniques to debug the EPSILON-2 processor board, a system with over 300 ICs and over 2500 independently controllable and observable test points. The debug time of the circuit was greatly reduced by the adoption of scan path methodology. The use of expensive test equipment was drastically reduced, and the level of control of the circuitry increased. We have run tests on the processor from physically remote sites. Our experiences are described, and the adoption of scan path techniques is shown to be simple enough that it should be useful in all electronic projects. 8 refs., 12 figs.

Sandia National Laboratories is a large multi-program DOE laboratory. The Recorded Information Management Division (RIM) has an expanding mission to meet Sandia's needs for cost-effective management in information from creation to final disposition in accordance with applicable regulations and requirements. An analysis based on the need to meet requirements and to improve business practice was successful in convincing management to allocate increased resources to the RIM Compliance Project.

Historically, the electronics industry has always attempted to increase the speed of electronic components and decrease the size of electronic assemblies by developing and manufacturing smaller and faster basic level components (e.g., integrated circuits). However, it is now becoming apparent that the next significant advancement in electronic assembly size and speed may come not as a result of smaller and faster devices, but rather as a consequence of smaller and more closely spaced packages. This increased packaging density will occur at early levels of assembly as industry moves towards multichip modules. It will also occur at later packaging steps as industry continues to expand the use of surface mount technology (SMT) and mixed mounting technology (through hole attachment as well as SMT on one circuit board). Furthermore, there will be an increased propensity to use higher packaging density on printed wiring boards (PWB) and to place more PWB's in a given volume at yet the next level of packaging. One class of materials on which this advanced packaging technology will place severe new demands will be the alloys used to join assemblies and subassemblies (e.g. solders and brazes). These materials will be taxed both from the perspective of enhanced manufacturability as well as greater in-service robustness. It is the objective of this paper, through the use of selected case studies, to illustrate how advanced microstructural characterization techniques can be used to improve packaging technology. The specific case studies discussed are: (1) Microstructural Characterization of Solders, (2) Microstructural Characterization of Solder Joint Embrittlement of Leaded, Surface Mount Transistors (3) Microstructural Characterization of Metal/Ceramic Brazes in Electronic Applications, and (4) Microstructural Characterization of Direct Brazing of Graphite to Copper. 25 refs., 16 figs.

A number of models that predict the impulse generated in solid targets by short high-intensity radiation loads are described. It is shown that the impulse is insensitive to the details of the energy deposition and interaction processes. Thus with the proper nondimensionalization and normalization, all the models are known to be very nearly equivalent. 5 refs., 5 figs., 1 tab.

The radiation produced by a 15.5-MeV monoenergetic electron beam incident on optimized and nonoptimized bremsstrahlung targets is characterized using the ITS Monte Carlo code and measurements with equilibrated and non-equilibrated TLD dosimetry. Comparisons between calculations and measurements verify the calculations and demonstrate that the code can be used to predict both bremsstrahlung production and TLD response for radiation fields that are characteristic of those produced by pulsed simulators of gamma rays. At optimum bremsstrahlung production, the predicted total forward radiation fluence detected in equilibrated TLD dosimetry agrees with that measured within the {plus minus}6% uncertainty of the measurement. The absolute comparisons made here provide independent confirmation of the validity of the TLD calibration for photon fields characteristic of gamma-ray simulators. The empirical Martin equation, which is often used to calculate radiation dose from optimized bremsstrahlung targets, is examined, and its range of validity is established from the data presented. 23 refs., 11 figs., 2 tabs.

Acoustic emissions and conventional strain measurements were used to follow the evolution of the damage surface and the plastic potential in a limestone under conditions of triaxial compressions. Confining pressures were chosen such that macroscopically, the limestone exhibited both brittle and ductile behavior. The parameters thus derived are useful for modeling the deformation of a pressure-dependent material and for computing when localization would occur. 10 refs., 8 figs.

The Gaseous Electronics Conference (GEC) RF Reference Cell was developed to enhance studies of radiofrequency (rf) discharge systems analogous to those used to fabricate microelectronic devices. The Reference Cell concept includes both a standard discharge-chamber design and a set of diagnostic tools that can be used to verify that different Cells behave similarly. Voltage and current measurements in Reference Cells in the United States show that, with proper care, plasmas that behave in a similar manner can be generated in different Cells. The versatility of the Reference Cell is illustrated by results on the use of planar laser-induced fluorescence imaging to obtain two-dimensional spatial profiles of SO{sub 2} in an SF{sub 6}/O{sub 2} rf discharge. 4 refs., 5 figs.

We have used the highly sensitive technique of Photothermal Deflection Spectroscopy (PDS) to measure changes in the infrared absorption spectra of MEHPPV, P3HT and Polydiacetylene-4BCMU induced by pumping these polymers with light above the {pi}--{pi}* transition energy. In contrast to previous chopped light transmission measurements of these effects, the PDS technique can directly measure the buildup or decay of the absorption coefficient, {alpha}, on the time scale of second to days. In the case of MEHPPV we observe that the time scale of seconds to days. In the case of MEHPPV we observe that above-gap light causes the appearance of a broad infrared peak in {alpha}, which continues to grow-in hours after the pump light is first applied. For this polymer the general shape of the absorption spectra in the unpumped state mimics the photo-induced changes, suggesting that remnant photo-induced states determine the maximum transparency observed under normal experimental conditions. For P3HT and to a lesser extent, MEHPPV, we also observe irreversible photo-induced absorption components which we tentatively identify with photo-induced oxidation of the polymer matrix. 10 refs., 8 figs.

Present practice in most computer codes intended for the solution of dynamic mechanics problems is to use the classical infinitesimal plasticity relations together with the Jaumann stress rate to account for finite rotations. Use of the Jaumann stress rate is known to lead to oscillating stress-strain response in simple shear at large deformations for elastic and some plastic relations, and is limited to isotropic material descriptions. Formulations of finite deformation plasticity based on the Lagrangian reference configuration and an unrotated configuration have been proposed which, in principle, should overcome these limitations. The latter has been implemented in a finite element computer code. In this paper, it is shown how a Lagrangian description based on the reference configuration may be implemented in computer codes, and how it may be translated into a corresponding Eulerian description based on the current configuration and a description based on the unrotated configuration for comparison with currently used descriptions. 11 refs.

This paper presents information on measures taken by Sandia National Laboratories to prepare for environmental, safety, and health compliance assessments conducted by Tiger Teams'' at Department of Energy facilities.

Woven Kevlar fabrics exhibit a number of beneficial mechanical properties which include strength, flexibility, and relatively low density. The desire to engineer or design Kevlar fabrics for specific applications has stimulated interest in the development of theoretical models which relate their effective mechanical properties to specific aspects of the fabric morphology and microstructure. In this work the author provides a theoretical investigation of the large deformation elastic response of a plane woven Kevlar fabric and compares these theoretical results with experimental data obtained from uniaxially loaded Kevlar fabrics. The theoretical analysis assumes the woven fabric to be a regular network of orthogonal interlaced yarns and the individual yarns are modeled as extensible elastica, thus coupling stretching and bending effects at the outset. This comparison of experiment with theory indicates that the deformation of woven fabric can be quite accurately predicted by modeling the individual yarns as extensible elastica. 2 refs., 1 fig.

The Modular Integrated Video System (MIVS) Image Processing System (MIPS) was developed to assist the International Atomic Energy Agency (IAEA) Inspectorate in the safeguards review of MIVS surveillance data. MIPS is designed to review MIVS surveillance data automatically; firstly detecting significantly changed images and secondly identifying if the changed images show IAEA defined objects of safeguards interest. To achieve this, MIPS uses both digital image processing and neural network techniques. A change detector uses image processing techniques to identify significantly changed images. The MIPS neural network classifier detects images which may show an important object(s). The neural network is trained , i.e., given example images showing the objects that it must recognize, for each different facility. The MIPS change detection algorithms reduce the original MIVS data by eliminating images without significant activity. The MIPS neural network algorithms further reduce this data by eliminating images which may not show a safeguards significant object. The images analyzed by both the change detector and the neural network are available for inspector review. The MIPS algorithms are implemented in commercially available hardware. A high-level menu-driven system interface allows inspectors to train the neural network and to operate both the change detection and neural network classification. An evaluation program was conducted jointly by Sandia National Laboratories (SNL) and the IAEA to determine the systems capabilities on a variety of MIVS data. The MIPS processing techniques and the user interface were evaluated by IAEA inspectors. Performance tests were also completed on a variety of MIVS data. This paper provides a description of the Class II MIPS and the evaluation program and reports on the results of this joint evaluation. 7 refs., 4 figs., 3 tabs.

Betavoltaic power sources operate by converting the nuclear decay energy of beta-emitting radioisotopes into electricity. Since they are not chemically driven, they could operate at temperatures which would either be to hot or too cold for typical chemical batteries. Further, for long lived isotopes, they offer the possibility of multi-decade active lifetimes. Two approaches are being investigated: direct and indirect conversion. Direct conversion cells consist of semiconductor diodes similar to photovoltaic cells. Beta particle directly bombard these cells, generating electron-hole pairs in the semiconductor which are converted to useful power. Many using low power flux beta emitters, wide bandgap semiconductors are required to achieve useful conversion efficiencies. The combination of tritium, as the beta emitter, and gallium phosphide (GaP), as the semiconductor converter, was evaluated. Indirect conversion betacells first convert the beta energy to light with a phosphor, and then to electricity with photovoltaic cells. An indirect conversion power source using a tritium radioluminescent (RL) light is being investigated. Our analysis indicates that this approach has the potential for significant volume and cost savings over the direct conversion method. 7 refs., 11 figs.

Over the past three years, several experiments have been conducted at the Brookhaven National Laboratory Radiation Effects Facility. These experiments have been investigations of proton induced radiation effects in individual electronic components, circuits, operational subsystems and full systems. Our investigations using 170--200 MeV protons have included total dose effects up to 12 Mrad, dose rate effects of the ionizing radiation in the 10{sup 5} to 10{sup 8} rad/s range, the displacement damage effects of the protons up to 10{sup 15} p/cm{sup 2}, and the proton induced thermal shift and thermal-rate effects. The target thickness of many test devices was an appreciable fraction of the range of 200 MeV protons. In our proton beam testing experiments at BNL, dosimetry placed downstream of the target consistently yielded higher dose in rad and in particle fluence than in dosimetry placed upstream of the target. We designed and performed an experiment to study this dose enhancement. The objective of the experiment was to determine the effect of sample thickness on our three methods of dosimetry. The data from the PIN diodes and tantalum calorimeters were consistent and followed the expected DE/DX curve. They show a dose enhancement effect. The proton beam interacts and loses energy as it travels through thick targets. The exiting lower energy beam deposits more energy into the dosimetry because the stopping power increases with decreasing proton energy.

In this paper we review three proposed mechanisms for GaAs ALE and review or present data support or contradiction of these mechanisms. Surface chemistry results clearly demonstrated that TMGa irreversibly chemisorbs on the Ga-rich GaAs(100) surface. The reactive sticking coefficient (RSC) of TMGa on the adsorbate-free Ga-rich GaAs(100) surface was measured to be {approximately}0.5, conclusively demonstrating that the selective adsorption'' mechanism of ALE is not valid. We describe kinetic evidence for methyl radical desorption in support of the adsorbate inhibition'' mechanism. The methyl radical desorption rates determined by temperature programmed desorption (TPD) demonstrate that desorption is at least a factor of {approximately}10 faster from the As-rich c(2 {times} 8)/(2 {times} 4) surface than from the Ga-rich surface. It is disparity in CH{sub 3} desorption rates between the As-rich and Ga-rich surfaces that is largely responsible for GaAs ALE behavior. A gallium alkyl radical (e.g. MMGa) is also observed during TPD and molecular beam experiments, in partial support of the flux balance'' mechanism. Stoichiometry issues of ALE are also discussed. We have discovered that arsine exposures typical of atmospheric pressure and reduced pressure ALE lead to As coverages {ge} 1 ML, which provides the likely solution to the stoichiometry question regarding the arsine cycle. 32 refs., 6 figs.

A procedure was developed to use solder technology in the assembly of a single-crystal quartz accelerometer. 87.5Au-12.5Ge (wt.%) solder films 0.5 {times} 10{sup {minus}6}, 1.0 {times} 10{sup {minus}6}, and 2.0 {times} 10{sup {minus}}6 m thick were formed by the electron beam deposition of individual layers of Au and Ge with thicknesses so that the bulk film composition equals the eutectic composition. Interdiffusion of the Au and Ge formed the solder; thermal-physical measurements showed the multilayer films to behave similarly to bulk 87.5Au-12.5Be solder in process thermal cycles. The 2.0 {times} 10{sup {minus}6}m thick quartz/Au-Ge/quartz bonds had an adhesive tensile strength of 17 {plus minus} 2 MPa. The strength increased to 29 {plus minus} 3 MPa and 27 {plus minus} 12 MPa after thermal shock and thermal cycle exposures respectively. The 1.0 {times} 10{sup {minus}6} m thick bonds exhibited strengths of 16 {plus minus} 3 MPa, 16 MPa and 15 {plus minus} 8 MPa in the as-fabricated, post-thermal shock, and post-thermal cycled samples, respectively. The 0.5 {times} 10{sup {minus}6} m joints produced a large degree of scatter in the strength values. Accelerometers assembled with the 2.0 {times} 10{sup {minus}6} m thick joints demonstrated a significant improvement in temperature performance as opposed to units fabricated with a polyimide adhesive. 8 refs., 12 figs., 8 tabs.

This paper is about the spatial resolution of x-ray microanalysis in thin foils. The theory of the scattering of an electron beam with a thin foil is discussed.

Upon becoming Secretary of the Department of Energy (DOE), Admiral Watkins first pledged to Congress that he would clean-up'' the nuclear weapons production complexes and then initiated many changes in the way DOE facilities are operated. He generated new orders regarding environments, safety, and health and created investigation units called Tiger Teams'' to check on how well his orders were being followed. During the spin-up of this massive undertaking, DOE decided to include all its facilities and not just the ones involved in nuclear production. This resulted in research and development labs, such as Lawrence Livermore, Los Alamos, and Sandia National Laboratories being subjected to more stringent regulations. This paper addresses the action Sandia National Laboratories has taken during the past year, particularly in regard to its pulsed-power accelerators, to come into compliance with the new DOE orders. 2 tabs.

The measurement and understanding of the fracture toughness of ductile cast irons, DCI, are critical to the analysis of nuclear transportation casks made from these alloys. Cask containment must be assured for all loading events from normal handling to accidents during which high loads can be delivered at elevated rates. Cask walls are commonly in the range of 20 to 50 cm thick (or greater) in order to provide requisite nuclear shielding, and this requires that associated mechanical constraint effects must be considered. At elevated temperatures (i.e., in the vicinity of ambient) DCI behaves in an elastic-plastic manner, even for large section sizes (B>20 cm) and moderately high loading rates. However, as the temperature is lowered or the loading rate is increased, ferritic DCI alloys exhibit a relatively sharp transition to linear elastic behavior, with a significant decrease in the fracture toughness. The fracture toughness of a DCI alloy has been measured using linear elastic and elastic-plastic experimental techniques. Measurements have been made as a function of temperature, loading rate and section size. The loading rates span the range which a cask could experience during normal transport and handling, as well as accident events. 15 refs., 7 figs., 4 tabs.

Sandia National Laboratories and the University of New Mexico's Anderson School of Management are developing a program which enables M.B.A. students to assist in commercializing Sandia developed technologies. Thus far, students have prepared detailed business plans (which include market analyses, design and development sections, and pro forma financials) for a wide range of technologies. Potential applications include waste management, cancer treatment, oil and gas transportation, coating of plastics, manufacturing and assembly, and parts inspections. By having graduate students conduct the research necessary to identify positive net-present-value projects, Sandia is able to interest private sector firms in its technologies.

Short communication.

Several countries propose to permanently dispose of spent reactor fuel as waste in geologic repositories. There is no basis for terminating safeguards on spent fuel, since it does not meet the criteria specified for termination, and conceivably it might be subsequently recovered and used for prohibited purposes. The paper proposed safeguards measures for spent fuel undergoing preparation, emplacement, recoverable storage, and after site closure which are consistent with other IAEA safeguards but which differ in detail, commensurate with the lesser risk of diversion relative to materials in other parts of the fuel cycle. The proposed measures rely on item accountability of discrete units, by means of containment and surveillance. The concept is consistent with the guidelines contained in Part I of the Safeguards Document, INFCIRC/153, but not entirely with Part II, which is based on verified material balances. After final site closure safeguards are limited to infrequent site observations, which would be sufficient to detect any attempts to recover the material. The paper points out the magnitude of effort required for recovery and the difficulty of concealing if from casual observation. 4 refs.

This paper addresses the issue of collision avoidance in unknown or partially modeled environments using a capacitive sensor. An eight channel capacitance-based sensor system which can detect obstacles up to 400 mm (16 inches) away has been developed. This sensor can detect both conductive and non-conductive obstacles of arbitrary color and shape. The sensor hardware is reliable and inexpensive, and it may be fabricated using flexible printed circuit boards to provide whole-arm and joint protection for any robot or manipulator. Simple collision avoidance control algorithms have been implemented on a two-link robot arm. The sensor and control system enable the robot arm to avoid a conductive post and a concrete block. 13 refs., 9 figs.

This paper presents two algorithms that construct a set of initial (x, y, {theta}) configurations from which a given action will reliably accomplish a planar manipulation task. The first algorithm applies energy arguments to construct a conservative set of successful initial configurations, while the second algorithm performs numerical integration to construct a set that is much less conservative. The algorithms may be applied to a variety of tasks, including pushing, placing-by-dropping, and force-controlled assembly tasks. Both algorithms consider the task geometry and mechanics, and allow uncertainty in every task parameter except for the object shapes. Experimental results are presented which demonstrate the validity of the algorithms' output for two example manipulation tasks. 16 refs., 8 figs.

Sandia National Laboratories developed an Authenticated Secure Container System (ASCS) for the International Atomic Energy Agency (IAEA). Agency standard weights and safeguards samples can be stored in the ASCS to provide continuity of knowledge. The ASCS consists of an optically clear cover, a base containing the Authenticated Item Monitoring System (AIMS) transmitter, and the AIMS receiver unit for data collection. The ASCS will provide the Inspector with information concerning the status of the system, during a surveillance period, such as state of health, tampering attempts, and movement of the container system. The secure container is located inside a Glove Box with the receiver located remotely from the Glove Box. AIMS technology uses rf transmission from the secure container to the receiver to provide a record of state of health and tampering. The data is stored in the receiver for analysis by the Inspector during a future inspection visit. 2 refs.

Short communication.

Short communication.

The advent of optical storage has made the digital storage of documents a viable option from both a practical and legal perspective. However, the availability of Optical Disk Storage raises questions regarding the destruction of the stored records and standards of longevity, and the admissibility in court of records produced from optical storage has not been tested. This paper will attempt to address these issues. 6 refs.

A 1K bit Shadow RAM has been developed for storage of critical data in a high transient radiation environment. The circuit includes a 1K bit (128 {times} 8) static RAM with two non-volatile (NV) shadows. The NV shadows are used to back-up the data in the static RAM allowing the circuit to be powered down during transient radiation without losing critical data. This paper will describe the circuit's operation and characterization results.

The use of carbon materials in catalytic system has been traditionally associated with their properties as supports. There are, however, some literature data describing their use as catalysts. Our results show that no simple relationship exists between the catalytic activity of some carbon materials for selective cleavage of carbon-carbon bonds adjacent to condensed polyaromatic rings an the elemental composition or surface area of these materials. The activity is dependent, however, upon the precursor used to generate the carbon material. Moreover, for a given precursor the activity is determined by the method of conversion to the carbon material. It remains to be established what elements of structure are responsible for the observed activity in carbon materials that are catalytically active. 12 refs., 7 tabs., 1 fig.

The strain rate in steady shock waves is proportional to the fourth power of shock amplitude for a wide variety of materials over a broad range of strain rates. A model based on this observation gives good agreement not only with steady-wave profiles but also with data on non-steady waves in aluminum. In apparent contrast, data on vanadium and uranium at low strain rates indicates a departure from the fourth power law if the wave profiles are assumed to be steady. However, when predicted profiles are produced by allowing the waves to propagate and evolve over the actual experimental sample thickness, the fourth power model gives excellent agreement with the wave profile data even though the wave profiles in the calculations have not yet reached steady state. The implication is that the experimental data do not represent steady waves, and the model is predicting the correct evolution of non-steady waves in vanadium and uranium. 7 refs., 2 figs.

The National Competitiveness Technology Transfer Act of 1989 has opened up the vast resources of our nation's national laboratories to the electronics industry. The electronics industry stands to gain advanced technology development, increased competitiveness, resource-sharing, and technology protection from this act. Sandia National Laboratories can help our nation's companies and universities in developing and applying advanced, commercially valuable technologies and in solving technological problems. These technological areas are discussed. A clear, non-bureaucratic process of tapping the microelectronics expertise and resources of Sandia National Laboratories is presented.

Highly reactive coal pyrites and unstable museum specimens are easily distinguished from the stable pyrites by the growth of white crystals that cover samples exposed to room atmosphere for short periods of time. Continued exposure to the atmosphere will eventually cause the specimens to fall apart. The term rotten pyrite has been applied to museum specimens that fall apart in this way. SEM studies show that reactive (rotten) pyrites contain between 100 and 10,000 times more dislocations than stable pyrites. Shock-loading of a stable pyrite to 7.5 GPa and 17 GPa increased its reactivity by a factor of two, probably caused by an increase in the number of imperfections. However, shock-loading at 22 GPa decreased the reactivity of pyrite because the imperfections produced at the higher pressure were removed during annealing the sample received at the higher temperature. Although there was a factor of six difference between the most and least reactive shocked MCB (commercial pyrite) samples, shock-loading did not increase the reactivity of the MCB pyrite to that of the Queensland coal pyrite. The results in hand show that while shock-loading produces sufficient imperfections to increase the reactivity of pyrites, there is insufficient data to show that imperfections are the main reason why some coal pyrites are highly reactive. 9 refs., 1 fig., 1 tab.

A wafer-level test system, capable of 50-MHz data rates, is shown to support (1) process improvement and control and (2) test-structure-to-IC correlation efforts for total-dose hardness assurance. 11 refs., 3 figs.

Transmitting digital voice via packetized mobile communications systems that employ relatively short packet lengths and narrow bandwidths often necessitates very low bit rate coding of the voice data. Sandia National Laboratories is currently developing an efficient voice coding system operating at 800 bits per second (bps). The coding scheme is a modified version of the 2400 bps NSA LPC-10e standard. The most significant modification to the LPC-10e scheme is the vector quantization of the line spectrum frequencies associated with the synthesis filters. An outline of a hardware implementation for the 800 bps coder is presented. The speech quality of the coder is generally good, although speaker recognition is not possible. Further research is being conducted to reduce the memory requirements and complexity of the vector quantizer, and to increase the quality of the reconstructed speech. 4 refs., 2 figs., 3 tabs.

BA85 is a routine for the quantitative reduction of x-ray data collected from oxide samples in an electron microprobe. BA85 is based on the correction procedures developed by Bence and Albee and is coded in Flextran for use with the TASK8 microprobe operating system. Features include stoichiometry and statistical calculations, the use of a 90 - oxide A-factor matrix which contains all of the common valence states for such elements as Fe and Cr, the ability to analyze up to 45 oxides, and the ability to create and use mineral codes which permit associating up to 15 oxides with three letter mnemonic codes. Entering a mineral code results in the analysis of the oxides associated with it and the performance of one of 21 endmember calculations. 13 refs., 2 figs., 3 tabs.

Application of conventional fracture mechanics concepts to treat crack growth and failure problems in geological media is discussed in this paper. Conventional fracture mechanics methods were developed mainly for metallic materials which exhibit nonlinearity associated mainly with plasticity type responses. Thus, these are not directly applicable to geological materials whose inelastic responses originate from inherent large-scale heterogenities, microcracking, strain softening, et. Proposed fracture mechanics methods for geological materials and their associated problems are discussed. To demonstrate the utility of fracture mechanics concepts in geological applications, examples involving multiple-fracture generation in tight gas formations and oil shale blasting design are presented.

This paper seeks to improve the synergism between computational aerodynamics and wind tunnel experimentation. In this paper, experimental and computational results are presented for a hypersonic vehicle configuration at Mach 8. Comparisons are made between experimental and computational results in order to improve the accuracy of both approaches. The basic vehicle configuration is a spherically blunted cone with a slice parallel with the axis of the vehicle. The half-angle of the cone is 10 deg. and the ratio of spherical nose radius to base radius in 10%. Onto the slice portion of the vehicle can be attached flaps with three different deflection angles; 10, 20, and 30 deg. All of the experimental results were obtained in the Sandia Mach 8 long duration, blow-down, hypersonic wind tunnel. Flow visualization results include surface oil flow, spark schlieren, and liquid crystal photographs and video. The liquid crystals were used as an aid in verifying that a laminar boundary layer existed over the entire body. An extensive uncertainty analysis was conducted to estimate quantitatively the accuracy of the measurement. Computational aerodynamic force and moment predictions are compared with the wind tunnel data. The Sandia Parabolized Navier-Stokes code is used to generate solutions for the sliced vehicle (no flap) and partial solutions for the flapped vehicle. For the geometry with the flap, an axially separated flow occurs and a time iterative Navier-Stokes code is used to provide comparisons with the data. This paper presents a portion of the results given in earlier works and also discusses new experimental results with this configuration.

Plotting and summary routines available for the TASK8 microprobe operating system are able to accept both spectral and quantitative data. All of the routines are able to be run as subroutines from within the TASK8 program or as stand alone programs. Additionally, the spectral plotting routine can be run from within a modified version of SQ. The quantitative routines currently in use with TASK8. Quantitative output can be sent by the summary program to a serial port that is connected to a VAX or PC in addition to printing it. The plotting codes have been written so that either a Tracor Northern TN2000 or a TN5xxx analyzer may be used with either a Hewlett Packard HP7221 series or a HP7470/HP7550 series plotter. The plotting routine for spectra incorporates a user definable usual was'' option to simplify most input procedures. The quantitative plotting routine offers numerous options including scale expansion, smoothing, auto-labeling, special symbols, and multiple pens. 5 refs., 5 figs.

A computational scheme is presented to solve the unsteady Navier-Stokes equations over a blunt body at high altitude, high Mach number atmospheric reentry flow conditions. This continuum approach is directed to low Reynolds/low density hypersonic flows by accounting for non-zero bulk viscosity effects in near frozen flow conditions. A significant difference from previous studies is the inclusion of the capability to model non-zero bulk viscosity effects. The grid definition for these low Reynolds number, viscous dominated flow fields is especially important in terms of numerical stability and accurate heat transfer solutions. 11 refs., 15 figs.

This paper describes a new technique for the detection of x-rays in electron column instruments used in microanalysis. In electron column instruments, the point source of x-rays is produced by the interaction of a focused electron beam with the sample. Neither of the conventional methods, wavelength dispersive (WDS) nor energy dispersive (EDS) based spectrometry, is optimized for low Z element quantitative analysis. In WDS applications, where the analyte elements are Be through P, chemical effects complicate the x-ray measurement process. Peak positions and shapes are altered, sometimes very strongly, by the electron configurations of the analyte atoms and neighboring atoms. In these cases, the ideal spectrometer would profile the peak and some small amount of continuum on either side of the peak such that an accurate peak area could be calculated. Present WDS spectrometers are serial in nature and cannot directly measure peak areas, often causing errors in the determination of light element concentrations. Bastin and co-workers have developed an elegant method to provide accurate area determinations, using the serial spectrometer, by a three point procedure. The parallel wavelength dispersive spectrometer (PWDS) we propose here is ideally suited for those applications.

A new facility is being constructed for the Primary Standards Laboratory at Sandia National Laboratories in Albuquerque, New Mexico. Salient features of the final design, described briefly in this paper, follow the conceptual design of 1984 to a fairly high degree. Because the facility is in process of construction, this paper is a progress report. 6 refs., 2 figs., 1 tab.

Curved and planar inversion domain boundaries (IDB) in aluminum nitride (AIN) form in sintered AIN ceramics containing oxygen, and oxygen is known to segregate to them. A number of interface models shown in Table 1, have been suggested based upon crystallographic constraints, chemical information and observed high resolution electron microscope (HREM) images. Until recently, problems with simulation of HREM images from AIN have made accurate determination of the structure of the IDB interface difficult. The aim of the present study was to use quantitative analytical electron microscopy (AEM) to determine the oxygen concentration at the IDBs, and then to compare the experimental results with calculated oxygen concentrations for each of the IDB models using a Monte Carlo electron trajectory simulation program. A match, if any, between the experimental and calculated oxygen concentrations would indicate the model which best described the IDB structure. The best match was obtained for Youngman's defect model. 14 refs., 5 figs., 3 tabs.

Plessite in iron meteorites is a two phase structure with an fcc precipitate phase in a bcc matrix. After Fe-Ni martensite forms during slow cooling, the martensite decomposition occurs at different temperatures. The morphology of the precipitates and the Ni content of both precipitate and matrix vary with the local average Ni composition of the plessite. In this study, the plessite structure of two octahedrites, Carlton and Grant, was characterized using the analytical electron microscope (AEM). The composition of the taenite precipitates in various regions of plessite which have 9 to 13 wt% and 15 to 20 wt% Ni composition were measured using an x-ray energy dispersive spectrometer (EDS) in the AEM. To understand the phase transformation processes which occurred during the plessite formation, an experimental set of Fe-Ni binary and Fe-Ni-P ternary alloys were made and analyzed also using the AEM. The alloys, which have 15 to 30 wt% Ni (0.2-0.3 wt% P for ternary alloys), were first homogenized at 1,200{degree}C and quenched to liquid nitrogen temperature to form martensite. They were then isothermally heat treated for 60 to 400 days in the temperature range from 450{degree}C to 300{degree}C. Two phase structures, which are similar to those of plessite, were formed in these alloys. The Fe-Ni phase equilibria measured in the decomposed martensite alloys can be used to explain the difference in Ni composition between precipitates in the high Ni and low Ni plessite regions. 3 refs., 2 figs.