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Reactive multilayers fabricated by vapor deposition: A critical review

Thin Solid Films

Adams, David P.

Reactive multilayer thin films are a class of energetic materials that continue to attract attention for use in joining applications and as igniters. Generally composed of two reactants, these heterogeneous solids can be stimulated by an external source to promptly release stored chemical energy in a sudden emission of light and heat. In this critical review article, results from recent investigations of these materials are discussed. Discussion begins with a brief description of the vapor deposition techniques that provide accurate control of layer thickness and film composition. More than 50 reactive film compositions have been reported to date, with most multilayers fabricated by magnetron sputter deposition or electron-beam evaporation. In subsequent sections, we review how multilayer ignition threshold, reaction rate, and total heat are tailored via thin film design. For example, planar multilayers with nanometer-scale periodicity exhibit rapid, self-sustained reactions with wavefront velocities up to 100 m/s. Numeric and analytical models have elucidated many of the fundamental processes that underlie propagating exothermic reactions while demonstrating how reaction rates vary with multilayer design. Recent, time-resolved diffraction and imaging studies have further revealed the phase transformations and the wavefront dynamics associated with propagating chemical reactions. Many reactive multilayers (e.g., Co/Al) form product phases that are consistent with published equilibrium phase diagrams, yet a few systems, such as Pt/Al, develop metastable products. The final section highlights current and emerging applications of reactive multilayers. Examples include reactive Ni(V)/Al and Pd/Al multilayers which have been developed for localized soldering of heat-sensitive components.

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TYPE Journal Article YEAR 2015
ScopusOSTIDOI

Laser Marking and Composition Analysis of 13-8 Steel and Nitronics 60 Surfaces

Murphy, Ryan D.; Saiz, David J.; Cruz-Cabrera, Alvaro A.; Aragon, Phil; Rodriguez, Mark A.; Adams, David P.

Pulsed laser irradiation is used to irradiate and mark 13-8 steel and Nitronics 60 parts in order to create observable markings on the surfaces. The best optical contrast ratio between marked regions and unmarked regions is desired for digital image correlation. The contrast is optimized by using pulsed-laser irradiation and varying the laser power, pulse length, and scan speed. X-ray diffraction was used to characterize the laser-irradiated surface, and it was found that oxide formation and surface roughness are responsible for the observed contrast.

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TYPE SAND Report YEAR 2014
DOIOSTI
Results 151–175 of 263
Results 151–175 of 263
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