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A predictive analytical model of electrical transport in multi-principal-element alloys

Scripta Materialia

Abere, Michael J.; Mcpherson, Shane L.; Jarzembski, Amun; Mcdonald, Anthony; Ton-That, Toai; Huang, Hailong; Argibay, Nicolas

A predictive analytical model is presented for the electrical conductivity of multi-principal-element alloys (MPEAs), including those containing aluminum, transition metals, and refractory metals. Given that the lattice parameter of the Wigner-Seitz cell of an MPEA is similarly variable to a bulk metallic glass, it is postulated that electron scattering can be approximated by a series of two-level systems. The resulting reduced-order model enabled an accurate determination of electrical resistivity and electron thermal conductivity based on the scattering of electrons in a two-level system across a Bloch-potential-based virtual crystal approximation. Model results are compared to experimental four-point probe electrical resistivity measurements between 300 K and 700 K for Al0.3CoCrCuFeNi, CoCrFeMnNi, (CoCrFeMnNi)0.98W0.02, (CoCrFeMnNi)0.95W0.05, and Nb4Ta4V3Ti, for model validation.

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LDRD 227829: Multifunctional Composite LDRD: Radiation Effect on CeO2 -HDPE Composites

Suman, Guddi K.; Reyes, Aspen N.; Jolowsky, Claire N.; Koss, Eun-Kyung C.; Wall, Sydnee R.; Piontkowski, Zachary T.; Ton-That, Toai; Mccoy, Chad A.; Hanson, Donald J.; Treadwell, Larico J.; Mcelhanon, James R.

Commercial high-density polyethylene (HDPE) is lightweight with excellent mechanical properties but has limited thermal stability. To enhance this, lanthanide-based nanomaterials like CeO2 were mixed with HDPE. Using a twin-screw extruder improved dispersion. This study examines the effects of neutron, X-rays and gamma radiation on the crystallinity of polymer of CeO2-HDPE composites.

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