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Finite-difference analysis of a buried munitions storage bunker subject to direct lightning and comparison with experiment

Merewether, Kimball O.

Recently, significant progress has been made in using finite-difference analysis cod es to simulate the responses of complex structures due to direct lightning. Advances have been made in interfacing a finite-difference code with commercial computer aided design tools, in suppressing a weak instability associated with the thin-wire algorithm for modeling conductors much smaller than a cell size, and in visualizing the results with color movies. Preliminary comparisons between the results of the finite-difference code and the results obtained during a recent rocket-triggered lightning test are also presented.

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A numerical study of bench blast row delay timing and its influence on percent cast

Preece, Dale S.

Sandia National Laboratories and ICI Explosives USA have worked together since 1987 to develop computer modeling techniques for Rock Blasting. A result of this effort is the computer program DMC (Distinct Motion Code) which was developed for two-dimensional simulation of rock motion following a blast (Taylor and Preece, 1989 1992). This program has been used to study blasting-induced rock motion resulting from oil shale mining and has been coupled with a gas flow computation capability for better treatment of the explosive behavior. This past year it has been customized for simulations of bench blasting in coat mines and rock quarries (Preece and Knudsen, 1992b). The explicit descretized nature of DMC gives it an advantage over previous blast modeling programs because subtle differences, such as row delay timing, have an influence on the results. This paper will present a DMC study of the influence on percent cast of row delay timing in a typical coal mine bench blast.

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Estimation of the limitations for surficial water addition above a potential high level radioactive waste repository at Yucca Mountain, Nevada; Yucca Mountain Site Characterization Project

Fewell, M.E.

The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level nuclear waste repository. Site characterization includes surface-based and underground testing. Analyses have been performed to design site characterization activities with minimal impact on the ability of the site to isolate waste, and on tests performed as part of the characterization process. One activity of site characterization is the construction of an Exploratory Studies Facility, consisting of underground shafts, drifts, and ramps, and the accompanying surface pad facility and roads. The information in this report addresses the following topics: (1) a discussion of the potential effects of surface construction water on repository-performance, and on surface and underground experiments; (2) one-dimensional numerical calculations predicting the maximum allowable amount of water that may infiltrate the surface of the mountain without affecting repository performance; and (3) two-dimensional numerical calculations of the movement of that amount of surface water and how the water may affect repository performance and experiments. The results contained herein should be used with other site data and scientific/engineering judgement in determining controls on water usage at Yucca Mountain. This document contains information that has been used in preparing Appendix I of the Exploratory Studies Facility Design Requirements document for the Yucca Mountain Site Characterization Project.

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Changes in risk perception over time

Gomez, L.S.; Jenkins-Smith, H.C.; Miller, K.W.

The focus of this paper is on changes in perceptions of the risks associated with nuclear waste management over time. In particular, we are interested in the kinds of change that take place when the management programs, and those who are charged with implementing them, are subject to intensive public debate over an extended period of time. We are undertaken an over-time study of perceived risks in Colorado and New Mexico by implementing sequential random household surveys in each state, timed at six month intervals. This study employs three of these surveys, spanning the period from summer, 1990 to summer, 1991. Using these data, we examine the dynamics that may underlie variations in perceived risks over time. In particular, our analysis is focused on changes in the roles played by (1) basic political orientations (i.e. political ideology) and (2) trust in those who advocate conflicting policy positions.

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Summary and evaluation of existing geological and geophysical data near prospective surface facilities in Midway Valley, Yucca Mountain Project, Nye County, Nevada; Yucca Mountain Site Characterization Project

Gibson, J.D.

Midway Valley, located at the eastern base of the Yucca Mountain in southwestern Nevada, is the preferred location of the surface facilities for the potential high-level nuclear waste repository at Yucca Mountain. One goal in siting these surface facilities is to avoid faults that could produce relative displacements in excess of 5 cm in the foundations of the waste-handling buildings. This study reviews existing geologic and geophysical data that can be used to assess the potential for surface fault rupture within Midway Valley. Dominant tectonic features in Midway Valley are north-trending, westward-dipping normal faults along the margins of the valley: the Bow Ridge fault to the west and the Paintbrush Canyon fault to the east. Published estimates of average Quaternary slip rates for these faults are very low but the age of most recent displacement and the amount of displacement per event are largely unknown. Surface mapping and interpretive cross sections, based on limited drillhole and geophysical data, suggest that additional normal faults, including the postulated Midway Valley fault, may exist beneath the Quaternary/Tertiary fill within the valley. Existing data, however, are inadequate to determine the location, recency, and geometry of this faulting. To confidently assess the potential for significant Quaternary faulting in Midway Valley, additional data are needed that define the stratigraphy and structure of the strata beneath the valley, characterize the Quaternary soils and surfaces, and establish the age of faulting. The use of new and improved geophysical techniques, combined with a drilling program, offers the greatest potential for resolving subsurface structure in the valley. Mapping of surficial geologic units and logging of soil pits and trenches within these units must be completed, using accepted state-of-the-art practices supported by multiple quantitative numerical and relative age-dating techniques.

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Instrumentation and Telemetry at Sandia National Laboratories

Fienning, William

Sandia National Laboratories (SNL) is a Department of Energy multiprogram engineering and scientific facility with unique design, development, and test capabilities arising from their work in nuclear weapons, energy resources, defense systems, nuclear safeguards, and specialized scientific endeavors. To support these programs, they have developed instrumentation and telemetry expertise not available elsewhere. This technology is applicable to projects in government and industry. Since the 1950s, they have applied our technical competence to meet difficult challenges with innovative solutions to data acquisition and telemetry problems. Sandia - with experience in fields as diverse as parachute design and plasma physics, geology and rocket guidance, human factors and high-speed aerodynamics, non-destructive testing and satellite communications - can use the power of synergism among our many disciplines to solve your complex problems of data and acquisition and analysis. SNL solves difficult data acquisition problems for extreme environments with expertise in advanced telemetry techniques, high data rate telemetry design, specialized electronics packaging, MIL-STD-1553 communications, instrumentation development, real-time data analysis, project management, specialized testers and data encryption.

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Analysis of slot cutting methods for the Yucca Mountain heated block test using a compliant-joint model

Chen, Er-Ping

Pretest analysis of a heated block test, proposed for the Exploratory Studies Facility at Yucca Mountain, Nevada, was conducted in this investigation. Specifically, the study focuses on the evaluation of the various designs to drill holes and cut slots for the block. The thermal/mechanical analysis was based on the finite element method and a compliant-joint rock-mass constitutive model. Based on the calculated results, relative merits of the various test designs are discussed.

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Photovoltaics as a worldwide energy source

Jones, G.J.

Photovoltaic energy systems have historically been treated as a bulk power generation source for the future. However, utilities and other agencies involved with electrification throughout the world are beginning to find photovoltaics a least-cost option to meet specific loads both for themselves and their customers, in both off-grid and grid-connected applications. These expanding markets offer the potential of hundreds of megawatts of sales in the coming decade, but a strategy addressing both industrial growth and user acceptance is necessary to capitalize on this opportunity. 11 refs.

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Phase mixing of transverse oscillations in the linear and nonlinear regimes for IFR relativistic electron beam propagation

Shokair, Isaac R.

Phase mixing of transverse oscillations changes the nature of the ion hose instability from an absolute to a convective instability. The stronger the phase mixing, the faster an electron beam reaches equilibrium with the guiding ion channel. This is important for long distance propagation of relativistic electron beams where it is desired that transverse oscillations phase mix within a few betatron wavelengths of injection and subsequently an equilibrium is reached with no further beam emittance growth. In the linear regime phase mixing is well understood and results in asymptotic decay of transverse oscillations as 1/Z{sup 2} for a Gaussian beam and channel system, Z being the axial distance measured in betatron wavelengths. In the nonlinear regime (which is likely mode of propagation for long pulse beams) results of the spread mass model indicate that phase mixing is considerably weaker than in the regime. In this paper we consider this problem of phase mixing in the nonlinear regime. Results of the spread mass model will be shown along with a simple analysis of phase mixing for multiple oscillator models. Particle simulations also indicate that phase mixing is weaker in nonlinear regime than in the linear regime. These results will also be shown. 3 refs., 4 figs.

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The Alaska Energy Authority PV-Diesel hybrid assessment and design program

Bower, Ward

Photovoltaic (PV) systems are increasing in popularity in the northern latitudes and in the arctic regions in the state of Alaska. This increased interest and the high cost of providing electric power in these remote areas have prompted the Alaska Energy Authority (AEA) to request assistance from the Photovoltaic Design Assistance Center at Sandia National Laboratories. A project to investigate the feasibility of using PV-Diesel hybrid power systems in small villages in Alaska was started in 1989. Data acquisition systems (DAS) were designed and installed in selected villages to obtain resource and load information. The DAS is described and village electrical and resource data are presented. Simulations were run using the collected village data and actual cost data provided by the AEA. Results of the simulations and the economic analysis are presented. 5 refs., 8 figs.

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Process development for high-efficiency silicon solar cells

Gee, James M.

Fabrication of high-efficiency silicon solar cells in an industrial environment requires a different optimization than in a laboratory environment. Strategies are presented for process development of high-efficiency silicon solar cells, with a goal of simplifying technology transfer into an industrial setting. The strategies emphasize the use of statistical experimental design for process optimization, and the use of baseline processes and cells for process monitoring and quality control. 8 refs.

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A comparison of Whipple shield hypervelocity impact tests to penetration predictors

Hertel, Eugene S.

The purpose of this paper is to develop an analytical model to convert ballistic limit curves obtained from flat projectile experiments to ballistic limit curves based on equivalent diameter spheres. Results from a test program involving flat plat projectiles conducted at Sandia National Laboratories are compared against the predicted performance of equivalent spherical projectiles as determined from the Wilkinson and Cour-Palais penetration equations. The developed method demonstrates good correlation of the ballistic limit of the shield concept for the flat plate projectiles to the theoretical ballistic limit for equivalent spheres as predicted by the penetration equations. 3 refs.

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Adiabatic equilibrium models for direct containment heating

Pilch, M.M.

PRA studies are being extended to include a wider spectrum of reactor plants than was considered in NUREG-1150. There is a need for computationally simple models for Direct Containment Heating (DCH) that could be used for screening studies aimed at identifying potentially significant contributors to risk. This paper discusses two adiabatic equilibrium models that are candidates for the task. The first, a 1-cell model, places a true upper bound on DCH loads. This upper bound, however, often far exceeds reasonable expectations of containment loads based on best estimate CONTAIN calculations or experiment observations. In this paper, a 2-cell model is developed that largely captures the major mitigating features of containment compartmentalization, thus providing more reasonable estimates of the containment load. Predictions of the equilibrium models are compared with experiment data from the Limited Flight Path (LFP) test series conducted at Sandia National Laboratories.

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Initial performance assessment of the Westinghouse AP600 containment design and related safety issues

Washington, Kenneth

The CONTAIN code is currently being used to predict containment thermal hydraulic conditions during design basis and severe accidents for advanced light water reactor (ALWR) designs such as the Westinghouse AP600. In the AP600 design, a passive containment cooling system (PCCS) is used for reducing long-term overpressure during accidents. CONTAIN models for heat and mass transfer within the AP600 containment and outer air cooling channel are verified by comparing recent CONTAIN calculations to integral test data obtained by Westinghouse in their PCCS Integral Test Facility. The comparison includes test in which the outer containment wall is both dry and wet, that is, the wet tests involve an evaporative water film that enhances heat transfer as will be the case for AP600. The appropriateness of the heat and mass transfer analogy methodology used in the CONTAIN code is demonstrated. Code model limitations are discussed along with model development plans and applications for AP600.

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Selective deposition of copper on poly(tetrafluoroethylene)

Rye, R.R.

An additive three step process has been developed for patterned deposition of Cu onto poly(tetrafluoroethylene) (PTFE). The first step involves patterned irradiation with X-rays or electrons which is thought to cross link the PTFE surface; step two involves chemical etching with the result that only the non-irradiated areas are etched; and step three involves selective chemical vapor deposition (CVD) of Cu onto the etched surface at 200 C using (hexafluoroacetylacetonato)Cu(I) trimethylphosphine ((hfac)Cu(PMe{sub 3})). The non-irradiated areas of the surface are covered by a continuous, dense Cu film with X-ray photoelectron spectra show to contain only surface impurities that are easily removed by a short Ar ion sputter. The irradiated areas show the presence of only C and F, characteristic of PTFE.

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The Integral Effects Test (IET-1) in the Surtsey Test Facility

Allen, Mark S.

The first experiment of the Integral Effects Test (IET-1) series was conducted to investigate the effects of high pressure melt ejection (HPME) on direct containment heating (DCH). A 1:10 linear scale model of the Zion reactor pressure vessel (RPV), cavity, instrument tunnel, and subcompartment structures were constructed in the Surtsey Test Facility at Sandia National Laboratories (SNL). The RPV was modelled with a melt generator that consisted of a steel pressure barrier, a cast MgO crucible, and a thin steel inner liner. The melt generator/crucible had a semi-hemispherical bottom head containing a graphite limitor plate with a 3.5 cm exit hole to simulate the ablated hole in the RPV bottom head that would be formed by tube ejection in a severe nuclear power plant (NPP) accident. The reactor cavity model contained 3.48 kg of water with a depth of 0.9 cm that corresponded to condensate levels in the Zion plant. A steam driven iron oxide/aluminum/chromium thermite was used to simulate HPME. A relatively small steam explosion occurred in the cavity during IET-1. Steam blowthrough entrained debris into the Surtsey vessel resulting in a peak pressure increase in Surtsey of 98 kPa. The Surtsey vessel had been previously inerted with N{sub 2}. The total debris mass ejected into the Surtsey vessel was 43 kg. The hydrogen concentration was 3.1 mol.% in the vessel at equilibrium. The concentration measured inside the subcompartment structures immediately following HPME transient was 20.7 mol.% H{sub 2}. 4 refs., 17 figs., 5 tabs.

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Optical measurements of the RADLAC II beam

Struve, K.W.; Welch, D.R.; Frost, C.A.; Crist, C.E.

During the RADLAC II open-air beam propagation experiments this last year three separate optical diagnostics were used. (1) Streak cameras were deployed to measure matched beam radius and centroid versus time. (2) Three gated, intensified TV cameras were used to image the beam from the end of the propagation range. They gave beam radius and centroid for three slices of the beam over a five meter propagation length. (3) Open shutter cameras were developed to give the time-averaged beam position over the entire propagation range. Data from all three diagnostics were digitized, stored in files on a computer, and post-processed to give temporally and spatially resolved beam size and position. These diagnostics used beam induced air-fluorescence as the mechanism to provide a prompt signal representative of the beam current density. Previous experiments and analysis have shown that the radiation is prompt with the intensity proportional to the beam current density for high energy, high current electron beams propagating in full density air.

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The relevancy of current environmental issues to solder joints in microelectronic applications

Yost, Frederick G.

The technical issues brought about by recent federal mandates are reviewed and discussed. Progress made in the elimination of CFCs is briefly reviewed. The problems, implications, and status of pending anti-lead legislation and taxation are discussed at length. Recommendations are made for the enactment of rational, fair, and orderly legislation and taxation.

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A miniaturized sensor laboratory for in situ characterization of hazardous waste by a robot

Feddema, John T.

This paper describes current research and development on a miniaturized sensing system for use during in situ characterization of nuclear waste storage tanks. Sandia is designing this sensing system as a tool for a large robotic arm that is deployed through an access port in the top of a storage tank. While the robot arm scans the sensing package over the waste, a distributed computing system acquires sensor data, correlates the data with the position of the robot, and produces maps of the chemical and radiological contents of the tanks in real time. We have built and demonstrated a first prototype system containing eight sensors. 53 refs.

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New containment modeling features of the contain code

Washington, Kenneth

Two revisions of the CONTAIN code, CONTAIN 1.11 and 1.12 , have recently been released. The purpose of this paper is to highlight the new features of these revisions and to discuss other new code features currently under development. The features of CONTAIN 1.11 discussed here include a quasi-mechanistic concrete outgassing model, the connected structure option for heat conduction between compartments, and a new approach for modeling forced convective heat transfer. The direct containment heating (DCH) models released as part of CONTAIN 1.12 are also discussed. New code features currently under development include a revised gas combustion model and a new multifield DCH model. New features of the revised combustion model include the treatment of spontaneous recombination and diffusion flames. CONTAIN plant calculations comparing the old and the revised combustion models are presented. The new features of the multifield DCH model are discussed, and demonstration calculations using this model to analyze a small scale experiment are presented.

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Technical issues resolution associated with spent fuel transport cask development

Sanders, Thomas L.

The Department of Energy`s (DOE`s) Office of Civilian Radioactive Waste Management (OCRWM) is in the process of developing a new generation of casks to transport spent fuel from commercial nuclear reactor facilities to federal waste facilities. In evaluating the needs of the cask development program a number of unresolved technical issues with potential impacts on the transportation system were identified. This paper provides three samples of issues being addressed by the Cask Systems Development Program for technical resolution: (1) burn-up credit, (2) containment source term evaluation, and (3) weeping.

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SMILE transmission line adder for RADLAC II

Mazarakis, M.G.; Poukey, J.W.; Shope, S.L.; Frost, C.A.; Turman, B.N.; Ramirez, J.J.; Prestwich, K.R.; Pankuch, P.J.

SMILE is a coaxial Self Magnetically Insulated Transmission Line voltage adder. It replaces the original beam line of the RADLAC II accelerator by a 12.5 m long cathode electrode. The anode electrode remains practically the same, consisting of the original eight insulating stacks or feeds which are connected with equal diameter stainless steel cylinders. The beam is produced at the end of the accelerator and is free of all the possible instabilities associated with accelerating gaps and magnetic vacuum transport. Annular beams with {beta}{perpendicular} {le} 0.1 and radius r{sub b} {le} 1 cm were routinely obtained and extracted from a small magnetically-immersed foilless electron diode. Results of the experimental evaluation are presented and compared with design parameters and numerical simulation predictions. 4 refs.

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Recent advances in shock and quasi-isentropic compression techniques for dynamic material property studies

Chhabildas, L.C.

In this paper, measurements on the quasi-isentropic compression of tungsten to stress levels of 250 GPa are reported. Results of these experiments have been compared to those obtained under shock loading conditions to comparable stresses. These experiments have allowed the determination of temperature, pressure, and loading rate effects on the dynamic yield strength of tungsten up to 250 GPa. These results show that the dynamic yield strength of tungsten is dependent on the loading rate with the strength being higher for the relatively slower rates of loading along the quasi-isentropic. The pressure dependence of the yield strength of tungsten is determined nearly independent of temperature effects from quasi-isentropic loading experiments to 250 GPa, because the temperature rise in an quasi-loading experiment is much lower than those associated with shock loading experiments.

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Eulerian computational methods

Mcglaun, M.

Continuum dynamics codes are categorized as Lagrangian or Eulerian according to the motion of the mesh. A Lagrangian code`s mesh moves with the material, so no mass flows between cells. An Eulerian code`s mesh is stationary, so mass flows between the cells. Eulerian codes have improved to the point where they are routinely used to solve a broad variety of large deformation solid and fluid dynamics problems ranging from air flow over an airplane wing to meteor impact on space structures. This presentation will concentrate on multi-fluid Eulerian codes capable of modeling transient were propagation in solids. These codes use a two-step process to integrate the physics across a time step. The first step, referred to as the Lagrangian step, integrates the physics on a Lagrangian mesh across the time step. The field values are then at the new time, but they are on the distorted Lagrangian mesh. The second step, referred to as the remap step, remaps the data on the distorted Lagrangian mesh back to the original Eulerian mesh thus completing one time step. The algorithms used in the first step are similar to those used in modern Lagrangian codes but they must be extended to handle multi-material cells. The algorithms used in the second step are complex and must be very carefully chosen to minimize errors. These algorithms include second-order, monotone advection equations to calculate the quantities flowing between cells. They also require algorithms that construct material interfaces inside multi-material cells. The strength and limitations of currently used numerical techniques will be discussed. New code development activities that combine the best features on both Lagrangian and Elueian codes will also be discussed. These new codes will employ the strengths of both technologies to address problems that cannot be adequately solved at this time.

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Modeling arbitrarily directed slots that are narrow both in width and depth with regard to the FDTD spatial cell

Riley, Douglas J.

The Hybrid Thin-Slot Algorithm (HTSA) integrates a transient integral-equation solution for an aperture in an infinite plane into a finite-difference time-domain (FDTD) code. The technique was introduced for linear apertures and was extended to include wall loss and lossy internal gaskets. A general implementation for arbitrary thin slots is briefly described here. The 3-D FDTD-code TSAR was selected for the implementation. The HTSA does not provide universal solutions to the narrow slot problem, but has merits appropriate for particular applications. The HTSA is restricted to planar slots, but can solve the important case that both the width and depth of the slot are narrow compared to the FDTD spatial cell. IN addition, the HTSA is not bound to the FDTD discrete spatial and time increments, and therefore, high-resolution solutions for the slot physics are possible. The implementation of the HTSA into TSAR is based upon a ``slot data file`` that includes the cell indices where the desired slots are exist within the FDTD mesh. For an HTSA-defined slot, the wall region local to the slot is shorted, and therefore, to change the slot`s topology simply requires altering the file to include the desired cells. 7 refs.

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The electronic structure of icosahedral boron clusters

Switendick, A.C.

The one-electron energy levels of icosahedral boron clusters have been calculated as a function of intericosahedral spacing maintaining the intraicosahedral spacing of {alpha}-boron. For crystalline lattice constants greater than 1.25 times the equilibrium one, band overlap occurs with concomitant metallic behavior. At smaller lattice constants, orbitals(bands) associated with bonds to adjacent icosahedra are lowered and orbitals(bands) associated with ``antibonds`` are raised. Four bands which were three quarters full become empty, while three bands which were empty become filled. This leads to an energy gap between the filled states and the empty states which accounts for the experimentally observed insulating behavior of this elemental material with three valence electrons per atom.

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Evaluating the velocity accuracy of an integrated GPS/INS system: Flight test results

Owen, Todd E.

Verifying the velocity accuracy of a GPS receiver or an integrated GPS/INS system in a dynamic environment is a difficult proposition when many of the commonly used reference systems have velocity uncertainities of the same order of magnitude or greater than the GPS system. The results of flight tests aboard an aircraft in which multiple reference systems simultaneously collected data to evaluate the accuracy of an integrated GPS/INS system are reported. Emphasis is placed on obtaining high accuracy estimates of the velocity error of the integrated system in order to verify that velocity accuracy is maintained during both linear and circular trajectories. Three different reference systems operating in parallel during flight tests are used to independently determine the position and velocity of an aircraft in flight. They are a transponder/interrogator ranging system, a laser tracker, and GPS carrier phase processing. Results obtained from these reference systems are compared against each other and against an integrated real time differential based GPS/INS system to arrive at a set of conclusions about the accuracy of the integrated system.

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Molecular design of substrate binding sites

Shelnutt, John A.

Computer-aided molecular design methods were used to tailor binding sites for small substrate molecules, including CO{sub 2} and methane. The goal is to design a cavity, adjacent to a catalytic metal center, into which the substrate will selectively bind through only non-bonding interactions with the groups lining the binding pocket. Porphyrins are used as a basic molecular structure, with various substituents added to construct the binding pocket. The conformations of these highly-substituted porphyrins are predicted using molecular mechanics calculations with a force field that gives accurate predictions for metalloporhyrins. Dynamics and energy-minimization calculations of substrate molecules bound to the cavity indicate high substrate binding affinity. The size, shape and charge-distribution of groups surrounding the cavity provide molecular selectivity. Specifically, calculated binding energies of methane, benzene, dichloromethane, CO{sub 2} and chloroform vary by about 10 kcal/mol for metal octaethyl-tetraphenylporphyrins (OETPPs) with chloroform, dichloromethane, and CO{sub 2} having the lowest. Significantly, a solvent molecule is found in the cavity in the X-ray structures of Co- and CuOETPP crystals obtained from dichloromethane. 5 refs., 3 figs., 3 tabs.

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Single event upset and charge collection imaging using ion microbeams

Horn, Kevin M.

Single Event Upset Imaging utilizes the scanning of a micro-focused MeV ion beams across an integrated circuit to test the upset response of the circuit to energetic heavy ions. Using this technique, the position dependence of logic state upsets, as well as the charge collection efficiency of an integrated circuit, can be directly measured with micron resolution. We present in this paper a review of a series of measurements carried out on the TA670 16K static random access memory chip which display this technique`s capabilities.

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Differential thermal analysis in the study of weld metal solidification and hot cracking

Cieslak, Michael J.

Hot cracking, or solidification cracking, is one of the most extensively studied phenomenon in welding metallurgy. The efforts made to identify the causes of this type of cracking have been driven by the negative commercial and engineering consequences resulting from the formation of these defects. Through judicious weld joint design, the mechanical restraint can be minimized, but it can never be entirely eliminated simply because metals expand and contract when heated and cooled, respectively. The localized nature of heat input in fusion welding insures a non-homogeneous thermal field being applied to the parts being welded, resulting in the development of strains in the as-solidifying weld metal. With the inherent limitations on the mechanical restraint factor, much research has gone into identifying those alloy compositions which minimize the microstructural factor required for hot cracking to occur. Examples from the author`s own research are presented as a tutorial to show how differential thermal analysis techniques have been used to study the chemical/microstructural factors associated with solidification and fusion zone hot cracking in nickel based engineering alloys. References to other uses of these techniques in related welding metallurgy studies are also given.

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Fermi level effects on dislocation formation in InAs{sub 1-x}Sb{sub x} grown by MOCVD

Biefeld, Robert M.

Dislocation formation in InAs{sub 1-x}Sb{sub x} buffer layers grown by metal-organic chemical vapor deposition is shown to be reproducibly enhanced by p-type doping at levels greater than or equal to the intrinsic carrier concentration at the growth temperature. To achieve a carrier concentration greater than 2 {times} 10{sup 18} cm{sup {minus}3}, the intrinsic carrier concentration of InSb at 475 C, p-type doping with diethylzinc was used. Carrier concentrations up to 6 {times} 10{sup 18} cm{sup {minus}3} were obtained. The zinc doped buffer layers have proven to be reproducibly crack free for InAs{sub 1-x}Sb{sub x} step graded buffer layers with a final composition of x = 0.12 and a strained layer superlattice with an average composition of x = 0.09. These buffer layers have been used to prepare SLS infrared photodiodes. The details of the buffer layer growth, an explanation for the observed Fermi level effect and the growth and characterization of an infrared photodiode are discussed.

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Arc-jet tests of coated carbon-carbon materials

Sheldahl, R.E.

The use of coatings on carbon-carbon materials to reduce the oxidation of carbon is of interest for the production of non-ablative aerospace structures. The arc-jet ground test facility can produce the high energy oxidizing environment necessary to simulate hypersonic flight in which to test candidate coatings. The test conditions usually required are characterized by material temperature and length of time the material remains at that temperature. Material specimens were exposed to high energy supersonic air exhausting from the NASA-Ames Research Center`s 20-MW arc-jet facility. The carbon-carbon materials were heated to required temperatures with arc-heated air for specified lengths of time. This report describes the test methodology and observations of those tests.

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Versatile bistable optical switches and latching optical logic using integrated photothyristors and surface-emitting lasers

Myers, David R.

We described a new family of versatile, cascadable, optical switches with different functional characteristics -- latching, non-latching, and bistable -- using a single epitaxial structure base don the monolithic integration of photothyristors and surface-emitting layers. High performance optical switching characteristics have been achieved for all three switch archetypes. We also demonstrate the AND, OR, NAND, NOR, and INVERT optical logic functions using monolithic switch structures. 7 refs.

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A boundary integral method for steady unsaturated flow in nonhomogeneous media

Martinez, Mario J.

A boundary integral equation method for steady unsaturated flow in nonhomogeneous porous media is presented. Steady unsaturated flow in porous media is described by the steady form of the so-called Richards equation, a highly nonlinear Fokker-Planck equation. By applying a Kirchhoff transformation and employing an exponential model for the relation between capillary pressure and hydraulic conductivity, the flow equation is rendered linear in each subdomain of a piece-wise homogeneous material. Unfortunately, the transformation results in nonlinear conditions along material interfaces, giving rise to a jump in the potential along these boundaries. An algorithm developed to solve the nonhomogeneous flow problem is described and verified by comparison to analytical and numerical solutions. The code is applied to examine the moisture distribution in a layered porous medium due to infiltration from a strip source, a model for infiltration from shallow ponds and washes in arid regions.

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Structural system identification of a composite shell

Red-Horse, J.R.; Carne, T.G.; James, G.H.; Witkowski, W.R.

Structural system identification is undergoing a period of renewed interest. Probabilistic approaches to physical parameter identification in analysis finite element models make uncertainty in test results an important issue. In this paper, we investigate this issue with a simple, though in many ways representative, structural system. The results of two modal parameter identification techniques are compared and uncertainty estimates, both through bias and random errors, are quantified. The importance of the interaction between test and analysis is also highlighted. 25 refs.

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Rapid anodic dissolution based SCC of an Al-Li-Cu alloy by isolated pit solutions

Buchheit Jr., R.G.; Moran, J.P.; Wall, F.D.; Stoner, G.E.

Pre-exposure induced stress corrosion cracking (SCC) of an Al-Li-Cu, AA 2090, was studied using a variety of test techniques. Results from SCC testing in a simulated isolated pit solution are correlated with electrochemical corrosion rate data obtained for individual phases in the subgrain boundary region. These experimental data, combined with existing data on the crevice chemistry of isolated pits in Al-Li alloys and X-ray diffraction studies of solid corrosion products formed in crevice environments are used to propose a model for pre-exposure induced cracking based on anodic dissolution along subgrain boundaries. Key features of the model are selective dissolution of the subgrain boundary T{sub 1} phase (Al{sub 2}CuLi) at the crack tip and passivation of crack walls by the formation of an Li{sub 2}[Al{sub 2}(OH){sub 6}]{sub 2}{center_dot}CO{sub 3}{center_dot}nH{sub 2}O barrier film.

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Applications of RADTRAN 4 to route-specific analysis

Neuhauser, S.; Weiner, R.F.

The transportation risk evaluation code RADTRAN 4 is designed to evaluate doses and risks associated with the transportation of radioactive materials (Ne92). RADTRAN 4 may be used to calculate dose consequences for incident-free transportation and dose risks for accidents. Consequences of normal (or incident-free) transportation include doses to crew members, persons at stops, and members of the public sharing a route segment (on-link) and residing near the segment (off-link) during normal transportation. These dose estimates are not multiplied by a probability factor and, hence, are referred to as dose consequences. Calculated doses that might be incurred during accidents are multiplied by the probabilities of those accidents, and hence are referred to as dose risks. RADTRAN 4 includes a LINK option that allows the user to characterize each link or segment of a transportation route in greater detail than that provided by average or default values for route-related parameters.

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A coilgun design primer

Marder, Barry M.

This paper explains how an induction coilgun works and presents the factors which go into its design. Our purpose is to obtain algebraic expressions which, although crude, provide useful predictors of behavior, illustrate the dependence on various parameters, and suggest ways to optimize the design. Detailed prediction of the gun`s behavior can be obtained from simulation codes, such as SLINGSHOT.

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A new HyperVelocity Launcher (HVL) for space science application

Chhabildas, L.C.

Very high driving pressures (tens or hundreds of GPa), are required to accelerate flier plats to hypervelocities. This loading pressure pulse on the fiber plates must be nearly shockless to prevent the plate from melting or vaporizing. This is accomplished by using graded-density impactors referred to as ``pillows.`` When this graded-density material is used to impact a flier-plate in a modified two-stage light gas gun, nearly shockless megabar pressures are introduced into the flier plate. The pressure pulses must also be tailored to prevent spallation of the flier-plate. This technique has been used to launch nominally 1-mm-thick aluminum, magnesium and titanium (gram-size) intact plates to 10.4 km/s, and 0.5-mm-thick aluminum and titanium (half-gram size) intact plates to 12.2 km/s. This is the highest mass-velocity capability attained with laboratory launchers to data, and should open up new regimes of impact physics and lethality studies related to space sciences for laboratory investigations. 14 refs.

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Propagation of relativistic high current electron beams across the geomagnetic field

Wagner, John S.

Relativistic high current electron beams can be transported long distances across the geomagnetic field using the IFR (Ion focused Regime) technique. IFR is a method of providing strong electrostatic focusing and guiding of the beam. The guiding is sufficiently strong to allow the beam to transport any angle with respect to geomagnetic field. In the IFR method, first an ionizing laser (or any ionizing method) is used to create a preionized cylindrical channel.

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An impact technique to accelerate flier plates to velocities over 12 km/s

Chhabildas, L.C.

Very high pressure and acceleration is necessary to launch flier plates to hypervelocities. In addition, the high pressure loading must be uniform, structured, and shockless, i.e., time-dependent to prevent the flier plate from either fracturing or melting. In this paper, a novel technique is described which allows the use of 100 GPa megabar loading pressures and 10{sup 9}-g acceleration to launch intact flier plates to velocities of 12.2 km/s. The technique has been used to launch nominally 1-mm thick aluminum, magnesium and titanium alloy plates to velocities over 10 km/s, and 0.5-mm thick aluminum and titanium alloy plates to velocities of 12.2 km/s.

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Improving path planning with learning

Chen, P.C.

We present a learning algorithm designed to improve robot path planning. The algorithm relies on an existing path planner to provide solutions to difficult tasks. From these solutions, it learns a sparse network of useful robot subgoals which guide and support fast planning. We analyze the algorithm theoretically by developing some general techniques useful in characterizing behaviors of probabilistic learning. We also demonstrate the effectiveness of the algorithm empirically with an existing path planner in practical environments. The learning algorithm not only reduces the time cost of existing planners, but also increases their capability in solving difficult tasks. 7 refs.

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Fault stress analysis for the Yucca Mountain Site Characterization Project

Bauer, Stephen J.

An understanding of the state of stress on faults is important for pre- and postclosure performance considerations for the potential high-level radioactive waste repository at Yucca Mountain. This paper presents the results of three-dimensional numerical analyses that provide estimates of the state of stress through time (10,000 years) along three major faults in the vicinity of the potential repository due to thermal stresses resulting from waste emplacement. It was found, that the safety factor for slip close to the potential repository increases with time after waste emplacement. Possible fault slip is predicted above and below the potential repository for certain loading conditions and times. In general, thermal loading reduces the potential for slip in the vicinity of the potential repository.

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Summary of the Exploratory Studies Facility Alternatives Study; Draft

Costin, Laurence S.

This paper presents a summary of the conduct and findings of the Exploratory Studies Facility Alternatives Study (ESF-AS). The Exploratory Studies Facility (ESF) is being planned for use in the characterization of a site for a potential high-level nuclear waste repository at Yucca Mountain, NV. The purpose of the ESF-AS were to identify and rank order ESF-repository options and to improve understanding of the favorable or unfavorable features of the ESF design. The analysis resulted in the ranking of 34 options, in accordance with the extent to which each option could achieve the objectives. Additional findings regarding design features that were identified as key elements in an option`s ability to provide good overall performance are also discussed.

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Alloy design options for improvement of the thermomechanical fatigue life of solder joints

American Society of Mechanical Engineers, Applied Mechanics Division, AMD

Frear, D.R.; Jones, W.B.; Morris Jr., J.W.; Mei, Z.

The eutectic Sn-Pb solder alloy is discussed with respect to alloy development options to improve the thermomechanical fatigue behavior of solder joints. Eutectic Sn-Pb solder joints fail through the development of a heterogeneous coarsened band of recrystallized and coarsened Pb- and Sn-rich phases. All imposed deformation concentrates solely into this thin region, accelerating fatigue failures. The development of solder alloys is currently being undertaken to improve the fatigue characteristics of eutectic Sn-Pb solder. New alloys must retain wetting and manufacturability characteristics similar to eutectic Sn-Pb. The options discussed to improve fatigue life include: creating a fine superplastic microstructure, small alloy additions to homogenize the microstructure, carbon reinforced composite solder, dispersed second phase precipitates that break up the solder microstructure, and using different solder alloys to replace eutectic Sn-Pb.

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The large deformation elastic response of woven kevlar fabric

Polymer Composites

Warren, William L.

The large deformation elastic response of a plane woven Kevlar fabric is investigated analytically and experimentally. The analysis assumes the undeformed geometry to be a sequence of interlaced arcs of circles that reverse at each yarn midpoint, and each yarn is modeled as an extensible elastica subject to certain compatibility conditions. Deflection-force relations for the fabric are determined in terms of the initial weave geometry and the elastic properties of the individual yarns. The theoretical results agree well with the results of experiments performed on a fabric woven from 400 denier Kevlar yarns under conditions of uniaxial loading in both warp and fill directions.

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Testing of the prototype facets for the stretched-membrane faceted dish

Grossman, James W.

The Faceted Stretched-Membrane Dish Program is part of a DOE-sponsored effort to develop a commercial 25 kWe dish/Stirling system employing a twelve-facet dish concentrator. The facets will utilize the stretched-membrane technology originated in the heliostat development program. Each facet is constructed with a thin metal membrane stretched over both sides of a steel ring. When a small vacuum is induced between the membranes they assume a parabolic contour capable of concentrating sunlight at a predetermined focal length. A reflective polymer film is attached to the face of the facet of the facet to enhance the optical performance. During Phase II of the Faceted Stretched-Membrane Dish Program, Science Applications International Corp. and Solar Kinetics, Inc., constructed prototype 3.5-meter facets utilizing different design approaches to demonstrate their manufacturability and optical performance. Sandia engaged in a program to determine the on-sun performance of the facets (for f/Ds of 2.7 to 3.0). A uniformly distributed slope error was used as the basis for comparison. Flux arrays based on slope error from a computer model were compared to a measured flux array for each facet. The slope error for the facet was determined by the value that would produce a modeled array with the minimum mean square difference to the measured array. The facet produced by SAIC demonstrated uniform slope errors of 2.2 to 3.0 milliradians with peak flux intesities of 334 to 416 kW/m{sup 2}. The SKI facet had slope errors of 1.6 to 1.9 milliradians with peak flux intesities of 543 to 1186 kW/m{sup 2}.

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Neutron damage equivalence in GaAs

IEEE Transactions on Nuclear Science

Griffin, Patrick J.

A 1-MeV neutron damage equivalence methodology and damage function have been developed for GaAs based on a recoil-energy dependent damage efficiency and the displacement kerma. This method, developed using life-time degradation in GaAs LEDs in a variety of neutron spectra, is also shown to be applicable to carrier removal. A validated methodology, such as this, is required to ensure and evaluate simulation fidelity in the neutron testing of GaAs semiconductors.

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PSD computations using Welch's method. [Power Spectral Density (PSD)]

This report describes Welch's method for computing Power Spectral Densities (PSDs). We first describe the bandpass filter method which uses filtering, squaring, and averaging operations to estimate a PSD. Second, we delineate the relationship of Welch's method to the bandpass filter method. Third, the frequency domain signal-to-noise ratio for a sine wave in white noise is derived. This derivation includes the computation of the noise floor due to quantization noise. The signal-to-noise ratio and noise flood depend on the FFT length and window. Fourth, the variance the Welch's PSD is discussed via chi-square random variables and degrees of freedom. This report contains many examples, figures and tables to illustrate the concepts. 26 refs.

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Expert judgement on inadvertent human intrusion into the Waste Isolation Pilot Plant

Trauth, K.M.

Four expert-judgment teams have developed analyses delineating possible future societies in the next 10,000 years in the vicinity of the Waste Isolation Pilot Plant (WIPP). Expert-judgment analysis was used to address the question of future societies because neither experimentation, observation, nor modeling can resolve such uncertainties. Each of the four, four-member teams, comprised of individuals with expertise in the physical, social, or political sciences, developed detailed qualitative assessments of possible future societies. These assessments include detailed discussions of the underlying physical and societal factors that would influence society and the likely modes of human-intrusion at the WIPP, as well as the probabilities of intrusion. Technological development, population growth, economic development, conservation of information, persistence of government control, and mitigation of danger from nuclear waste were the factors the teams believed to be most important. Likely modes of human-intrusion were categorized as excavation, disposal/storage, tunneling, drilling, and offsite activities. Each team also developed quantitative assessments by providing probabilities of various alternative futures, of inadvertent human intrusion, and in some cases, of particular modes of intrusion. The information created throughout this study will be used in conjunction with other types of information, including experimental data, calculations from physical principles and computer models, and perhaps other judgments, as input to performance assessment.'' The more qualitative results of this study will be used as input to another expert panel considering markers to deter inadvertent human intrusion at the WIPP.

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Aging, condition monitoring, and loss-of-coolant accident (LOCA) tests of Class 1E electrical cables: Summary of results

Jacobus, M.J.

This paper summarizes the results of aging, condition monitoring, and accident testing of Class 1E cables used in nuclear power generating stations. Three sets of cables were aged for up to 9 months under simultaneous thermal ({approx_equal} 100{degrees}C) and radiation ({approx_equal}0.10 kGy/hr) conditions. After the aging, the cables were exposed to a simulated accident consisting of high dose rate irradiation ({approx_equal}6 kGy/hr) followed by a high temperature steam exposure. A fourth set of cables, which were unaged, were also exposed to the accident conditions. The cables that were aged for 3 months and then accident tested were subsequently exposed to a high temperature steam fragility test (up to 400{degrees}C), while the cables that were aged for 6 months and then accident tested were subsequently exposed to a 1000-hour submergence test in a chemical solution. The results of the tests indicate that the feasibility of life extension of many popular nuclear power plant cable products is promising and that mechanical measurements (primarily elongation, modulus, and density) were more effective than electrical measurements for monitoring age-related degradation. In the high temperature steam test, ethylene propylene rubber (EPR) cable materials generally survived to higher temperatures than crosslinked polyolefin (XLPO) cable materials. In dielectric testing after the submergence testing, the XLPO materials performed better than the EPR materials. This paper presents some recent experimental data that are not yet available elsewhere and a summary of findings from the entire experimental program.

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High rate heating driven decomposition of energetic materials: Diagnostics evaluation

Renlund, Anita M.

Combustion of energetic materials involves processes in both gas and condensed phases and is governed by coupled thermal, physical, and chemical phenomena. Development of reliable models for design, performance, stability, and hazard analyses requires detailed understanding of three general chemical reaction regimes: (1) initial condensed-phase decomposition, (2) subsequent interaction of decomposition products with the remaining condensed phase, and (3) gas-phase reaction of decomposition products to form the ultimate combustion products. The first two regimes are the least understood and most difficult to study, particularly the initial condensed-phase decomposition. The basic difficulty in studying condensed phase phenomena has been the inability to probe directly chemistry in the condensed phase under isothermal condition and with the spatial and temporal resolution needed at higher temperatures and reaction rates. Thin-film samples provide a means to study condensed-phase chemistry at isothermal conditions and with microsecond temporal resolution. We are developing an experiment system that employs rapidly heated thin- film samples and multiple diagnostics to examine condensed-phase chemistry and monitor evolved gas species. Results from our initial work have been encouraging. Thin-film samples of several energetic materials have been prepared and appear to be representative of bulk materials. Furthermore, preliminary experiments indicate that all the use of these samples with two chemical diagnostic techniques, time-of- flight mass spectrometry (TOFMS) and time-resolved infrared spectral photography (TRISP), is viable. 5 refs., 8 figs.

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Polarimetric calibration of a coherent measurement radar

Brock, Billy C.

The polarimetry problem (the measurement of the radar-cross-section polarization scattering matrix) is described. Two methods of calibrating a polarimetric radar are outlined. The first is a general multiple-calibration-target (MCT) method applicable to almost any radar system. The second is a simple, single-calibration-target (SCT) method applicable to systems which use a single antenna for both transmit/receive and a reciprocal RF network. The performance of the MCT method is examined through the use of Monte Carlo simulations. Finally, the SCT method is applied to measurements from the SCATTER facility, demonstrating about 40 dB isolation between polarization components in the frequency domain and in excess of 50 dB in the range domain.

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Utility Battery Exploratory Technology Development Program report for FY91

Magnani, N.J.

Sandia National Laboratories, Albuquerque, manages the Utility Battery Exploratory Technology Development Program, which is sponsored by the US Department of Energy`s Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses and development of rechargeable batteries for utility-energy-storage applications. This report details the technical achievements realized during fiscal year 1991. Sodium/Sulfur, Zinc/Bromine, Nickel/Hydrogen, Aluminium/Air and Lead/Acid batteries are evaluated.

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Interpretations of single-well hydraulic tests of the Rustler Formation conducted in the vicinity of the Waste Isolation Pilot Plant site, 1988--1989

Beauheim, Richard L.

This report presents the results of single-well hydraulic tests performed in seven wells in the vicinity of the Waste Isolation Pilot Plant (WIPP) site in southeastern New Mexico in 1988 and 1989. The tests discussed in this report were performed in four of the five members of the Rustler Formation. The tests include: a slug-withdrawal test of the unnamed lower member of the Rustler ate well H-16; slug-withdrawal and slug-injection tests of the Culebra Dolomite Member at well AEC-7; slug-injection tests of the Culebra at well D-268; a pumping test of the Culebra at well H-18; pulse-injection, slug-injection, and slug-withdrawal tests of Magenta Dolomite Member at well H-2b1; pulse-withdrawal, slug-withdrawal, and slug-injection tests of the Magenta at well H-3b1; and pulse-withdrawal and slug-withdrawal tests of the Forty-niner Member at well H-3d. The tests were intended to provide data on the transmissivities of the Rustler members for use in regional-scale modeling of groundwater flow through the Rustler.

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Environment, safety and health training catalog. Investing in our future

Ehart, Linda L.

The ES&H Training Catalog is a tool to assist managers in determining which training courses they require their employees to complete. The narrative description under ``Who Shall Attend`` describes the characteristics of the employees and contractors under the direction of Sandia who are required by law, regulation, DOE Order, or SNL Directive to complete the training in order to be in compliance. The narrative is ``Who Should Attend`` describes the individuals for which the course is `highly recommended,`` although they are not mandated to attend.

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SANET 1.0 User`s Guide and Reference Manual

Camp, Allen L.

SANET is a computer program intended for use in constructing, evaluating, and printing event trees for safety and reliability studies. SANET allows the user to graphically construct event trees, assign probabilities to the branches on the tree and include a variety of labels. Fast, publication quality printed output can be obtained. SANET requires an IBM compatible PC with a 80286, 80386 or 80486 processor, VGA graphics, a mouse and an HP Laserjet printer.

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Innovation, the economy, and the federal laboratories: Principles and issues of the innovation process

Debriun, J.P.; Corey, J.D.

The technological innovation process comprises a range of stages, steps, and activities extending fro generation of new ideas through successful practical application of those ideas. This process constitutes the larger context within which technology transfer programs must necessarily operate if the goal is to transform new knowledge and technology into products which are competitive in the emerging global marketplace. A basic grasp of the principles and issues involved in the total innovation process is essential for developing and improving programs, prioritizing activities, and making strategic and operational decisions which will be appropriate and effective. This report attempts to provide a relatively brief overview of the total innovation process and related issues. This focus follows from the intent of the federal technology transfer initiative, which is essentially to facilitate the rapid advance of technological progress and to enhance national economic competitiveness. It is important to recognize that the transfer of technology between organizations or individuals is only one part of the complete process, although possibly a critical part in some situations. From an economic standpoint, technology transfer without resulting successful commercialization is meaningless. This report should be useful primer for people from any sector of the economy, even though it is intended to address the context for the transfer of federal laboratory technology in particular.

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Interaction of tin telluride and cesium hydroxide with reactor materials in steam

Elrick, R.M.; Ouellette, A.L.

Two laboratory tests were designed to study the behavior of SnTe and CsOH in steam at {approximately}1230 K with the reactor materials Inconel 600, 304 stainless steel, silver and nickel, a nonoxidizing constituent of Inconels and steels in reactor accident environments. Thermochemical calculations examined the sensitivity of species in the H-O-Cs-Te-Sn system to temperature, to hydrogen and SnTe concentrations and to total system pressure. Test results indicate that should SnTe be formed from fission product tellurium and the tin in zircaloy cladding, it may not remain stable in steam in the presence of unoxidized (or lightly oxidized) metals. Calculations show a small amount of SnTe, in equilibrium with steam, decomposes to primarily Te and SnO. It is felt that these decomposition producets react with the reactor materials since Sn and Te are seen to be deposited separately and not as SnTe. The deposition velocity for SnO vapor in the system was estimated to be 0.57 m/s. The response of CsOH in the system was similar to behavior observed previously: some cesium combined with silicon found in Inconel and stainless steel oxides. At lower temperatures ({le}940 K) CsOH corroded Inconel, stainless steel and nickel providing enhanced surface area for additional trapping of species. There was no experimental evidence for the formation of cesium telluride; vapor equilibrium calculations did not predict formation either. 33 refs., 29 figs, 7 tabs.

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Multiple scattering background in heavy ion backscattering spectrometry

Brice, D.K.

An analytical expression and an integral representation are presented for the contribution, Y{sup (n)} = {Sigma}{sup (n)}{delta}{Omega}{sub n}, of n-event multiple scattering chains to the observed backscattering spectrum in heavy-ion backscattering (HIBS) measurements. The approximations introduced in deriving the results are chosen such that an upper limit is placed on Y{sup (n)} by the expressions. The Rutherford elastic scattering cross section is used to describe individual collisions between incident projectiles and target atoms. Screening of the Rutherford scattering cross section is included in an approximate fashion which maintains the upper limit estimate. Inelastic energy loss between collision events is assumed proportional to the projectile velocity. Specific application of theses expressions is made to HIBS detection of trace amounts of heavy atom impurities on a Si by 200--400 keV C{sup +} beams. The predicted multiple scattering background for this applications is compared with the predicted single scattering signal for 10{sup 10} atoms/cm{sup 2} of Fe, Cu, Zr, Sn, or Au, as surface impurity. The comparison shows that the multiple scattering background poses no barrier to extending the sensitivity of HIBS detection of impurities in this mass range to levels as low as 10{sup 8} atoms/cm{sup 2} for the upper part of the energy range considered. Comparison of calculations with and without screening included show that the screening of the Rutherford cross section by atomic electrons is a significant factor in preventing multiple scattering effects from interfering with HIBS spectrometry at impurity levels in the 10{sup 10} atoms/cm{sup 2} range.

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MELCOR 1.8.1 assessment: FLECHT SEASET natural circulation experiments

Kmetyk, Lubomyra N.

The MELCOR code has been used to simulate the FLECHT SEASET natural circulation experiments done in a scale-model Westinghouse-PWR test facility, with code results compared to experimental data. Sensitivity studies have been done, for both single-phase and two-phase natural circulation conditions, on time step effects and machine dependencies; nodalization studies and studies on several code modelling options were also done. Good agreement is found between prediction and observation for steady-state, single-phase liquid natural circulation. The code could reproduce the major thermal/hydraulic response characteristics in two-phase natural circulation, but only through a number of nonstandard input modelling modifications; MELCOR cannot reproduce the requisite physical phenomena with ``normal`` input models. Because the same response is observed in similar tests at other facilities over a range of scales and is expected to occur in full-scale plants as well, the ability of the user to ``match`` the observed behavior through a small set of nonstandard input modelling changes allows MELCOR to be used in PRA studies in which such physics are expected to be encountered, while awaiting corrections to the code models involved. The time step control algorithm in MELCOR does not run this problem efficiently; a substantial reduction in time step results in significantly less oscillation predicted at only a small increase run time.

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Background information presented to the expert panel on inadvertent human intrusion into the Waste Isolation Pilot Plant

Weart, Wendell D.

The Waste Isolation Pilot Plant (WIPP) is planned as a mined geologic repository for the disposal of transuranic (TRU) radioactive wastes generated by defense programs of the United States Department of Energy. One of the criteria for evaluating the suitability of the WIPP for disposal of TRU wastes is compliance with the United States Environmental Protection Agency`s (EPA) standards for such facilities. The Containment Requirements of those standards require calculating cumulative releases of radionuclides to the accessible environment by all combinations of events and processes (scenarios) that may affect the escape and transport of radionuclides from the repository for 10, 000 years after decommissioning of the facility. Because the release limits established by the EPA are probabilistic, scenario probabilities are also required. A panel of experts was convened to estimate the probabilities of occurrence of the events used in scenario development and to identify additional human-intrusion events for inclusion in a safety assessment of the WIPP. This report documents the background presentations that were made to the panel about the WIPP program, regulatory guidelines, and performance-assessment program, and site-specific and regional geologic and hydrologic characteristics that may affect the WIPP disposal system.

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Strategic Petroleum Reserve (SPR) additional geologic site characterization studies, West Hackberry salt dome, Louisiana

Neal, J.T.

This report is a revision and update of the original geologic site characterization report that was published in 1980. Many of the topics addressed in the earlier report were predictive in nature and it is now possible to reexamine them some 12 years later, using the data from 17 new caverns and more than ten years of SPR storage experience. Revised maps of the salt configuration show on overhand and faults on the north side of the dome, defining more clearly the edge relationships with respect to the SPR caverns. Caprock faults may locally influence the pattern of subsidence, which is occurring primarily as a result of cavern creep closure. The greater subsidence rate occurring at West Hackberry will likely require mitigative action within a few years. Seismicity of low intensity recurs infrequently at West Hackberry, but a small earthquake in 1983 caused dish rattling in the immediate vicinity.

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Drift design methodology and preliminary application for the Yucca Mountain Site Characterization Project; Yucca Mountain Site Characterization Project

Bauer, Stephen J.

Excavation stability in an underground nuclear waste repository is required during construction, emplacement, retrieval (if required), and closure phases to ensure worker health and safety, and to prevent development of potential pathways for radionuclide migration in the post-closure period. Stable excavations are developed by appropriate excavation procedures, design of the room shape, design and installation of rock support reinforcement systems, and implementation of appropriate monitoring and maintenance programs. In addition to the loads imposed by the in situ stress field, the repository drifts will be impacted by thermal loads developed after waste emplacement and, periodically, by seismic loads from naturally occurring earthquakes and underground nuclear events. A priori evaluation of stability is required for design of the ground support system, to confirm that the thermal loads are reasonable, and to support the license application process. In this report, a design methodology for assessing drift stability is presented. This is based on site conditions, together with empirical and analytical methods. Analytical numerical methods are emphasized at this time because empirical data are unavailable for excavations in welded tuff either at elevated temperatures or under seismic loads. The analytical methodology incorporates analysis of rock masses that are systematically jointed, randomly jointed, and sparsely jointed. In situ thermal and seismic loads are considered. Methods of evaluating the analytical results and estimating ground support requirements for all the full range of expected ground conditions are outlines. The results of a preliminary application of the methodology using the limited available data are presented. 26 figs., 55 tabs.

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Movement of shaft and drift construction water in Yucca Mountain, Nevada: An extended study; Yucca Mountain Site Characterization Project

Fewell, M.E.

The Yucca Mountain Site Characterization Project is studying Yucca Mountain in southwestern Nevada as a potential site for a high-level nuclear waste repository. Site characterization includes surface-based and underground testing. Analyses have been performed to design site characterization activities with minimal impact on the ability of the site to isolate waste, and on tests performed as part of the characterization process. One activity of site characterization is the construction of an Exploratory Studies Facility, for which many design options are being considered, including shafts, drifts, and ramps. The information in this report pertains to: (1) engineering calculations of the potential distribution of residual water from constructing the shafts and drifts; (2) numerical calculations predicting the movement of residual construction water from the shaft and drift walls into the rock; and (3) numerical calculations of the movement of residual water and how the movement is affected by ventilation. This document contains information that has been used in preparing Appendix 1 of the Exploratory Studies Facility Design Requirements document for the Yucca Mountain Project.

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PACE-90 water and solute transport calculations for 0.01, 0.1, and 0. 5 mm/yr infiltration into Yucca Mountain; Yucca Mountain Site Characterization Project

Eaton, R.R.

Numerical results are presented for the Performance Assessment Calculational Exercise (PACE-90). One- and two-dimensional water and solute transport are presented for steady infiltration into Yucca Mountain. Evenly distributed infiltration rates of 0.01, 0.1, and 0.5 mm/yr were considered. The calculations of solute transport show that significant amounts of radionuclides can reach the water table over 100,000 yr at the 0.5 mm/yr rate. For time periods less than 10,000 yr or infiltrations less than 0.1 mm/yr very little solute reaches the water table. The numerical simulations clearly demonstrate that multi-dimensional effects can result in significant decreases in the travel time of solute through the modeled domain. Dual continuum effects are shown to be negligible for the low steady state fluxes considered. However, material heterogeneities may cause local amplification of the flux level in multi-dimensional flows. These higher flux levels may then require modeling of a dual continuum porous medium.

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Over-the-road tests of nuclear materials package response to normal environments

Gwinn, K.W.; Glass, R.E.; Edwards, K.R.

In support of the development of American National Standards Institute standards for the transport of radioactive materials, Sandia has a program to characterize the normal transport environment. This program includes both analytical modeling of package and trailer responses, and over-the-road tests to measure those responses. This paper presents the results of a series of over-the-road tests performed using Chem-Nuclear equipment in the Barnwell, SC, area. The test events included a variety of road types such as rough concrete, shock events such as railroad grade crossings, and driver responses such as sharp turns. The response of the package and trailer to these events was measured with accelerometers at various locations to determine the inertial loads. Either load cells or strain gages were used to measure tiedown response. These accelerations and loads were measured on systems with flexible and ``rigid`` tiedowns. The results indicated that while significant accelerations occur on the trailer bed, these do not translate into equivalent loads in either the package or the tiedown system. This indicates that trailer-bed response should not be used in determining the load factor for fatigue calculations of the package components or in determining design loads for tiedowns.

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Waste inventory and preliminary source term model for the Greater Confinement Disposal site at the Nevada Test Site

Chu, Sze-Tai Y.

Currently, there are several Greater Confinement Disposal (GCD) boreholes at the Radioactive Waste Management Site (RWMS) for the Nevada Test Site. These are intermediate-depth boreholes used for the disposal of special case wastes, that is, radioactive waste within the Department of Energy complex that do not meet the criteria established for disposal of high-level waste, transuranic waste, or low-level waste. A performance assessment is needed to evaluate the safety of the GCD site, and to examine the feasibility of the GCD disposal concept as a disposal solution for special case wastes in general. This report documents the effort in defining all the waste inventory presently disposed of at the GCD site, and the inventory and release model to be used in a performance assessment for compliance with the Environmental Protection Agency`s 40 CFR 191.

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The hydrothermal stability of cement sealing materials in the potential Yucca Mountain high level nuclear waste repository

Krumhansl, James L.

Cementitious materials, together with other materials, are being considered to seal a potential repository at Yucca Mountain. A concern with cementitious materials is the chemical and mineralogic changes that may occur as these materials age while in contact with local ground waters. A combined theoretical and experimental approach was taken to determine the ability to theoretically predict mineralogic changes. The cementitious material selected for study has a relatively low Ca:Si ratio approaching that of the mineral tobermorite. Samples were treated hydrothermally at 200{degrees}C with water similar to that obtained from the J-13 well on the Nevada Test Site. Post-test solutions were analyzed for pH as well as dissolved K, Na, Ca, Al, and Si. Solid phases formed during these experiments were characterized by scanning electron microscopy and X- ray diffraction. These findings were compared with predictions made by the geochemical modeling code EQ3NR/E06. It was generally found that there was good agreement between predicted and experimental results.

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Massively Parallel Computing at Sandia and its Application to National Defense

Dosanjh, Sudip S.

Two years ago, researchers at Sandia National Laboratories showed that a massively parallel computer with 1024 processors could solve scientific problems more than 1000 times faster than a single processor. Since then, interest in massively parallel processing has increased dramatically. This review paper discusses some of the applications of this emerging technology to important problems at Sandia. Particular attention is given here to the impact of massively parallel systems on applications related to national defense. New concepts in heterogenous programming and load balancing for MIMD computers are drastically increasing synthetic aperture radar (SAR) and SDI modeling capabilities. Also, researchers are showing that the current generation of massively parallel MIMD and SIMD computers are highly competitive with a CRAY on hydrodynamic and structural mechanics codes that are optimized for vector processors.

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Case History: Failure Analysis of a CMOS SRAM with an Intermittent Open Contact

Campbell, Ann N.

Analysis of an intermittent failure to write the "1" state to a particular memory location at low temperature (-55° C) in a 16K x 1 CMOS SRAM is presented. The failure was found to be due to an open metallization at a metal-to-silicon contact. The root cause of the failure was poor step coverage of the metallization over an oxide step. A variety of failure analysis techniques including dynamic electron beam analysis at low temperature using a Peltier cold stage were employed to study the intermittently failing SRAM. The failure site was located by using capacitive coupling voltage contrast analysis. PSPICE simulation, light emission microscopy, scanning electron microscopy, and focused-ion beam techniques were used to confirm the failure mechanism and location. The write cycle time of the failed IC was abnormally long, but within the allowable tester limit. The vulnerability of other ICs to failure by open metallization in metal-to silicon contacts is reviewed.

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Radial dependence of silicon KVV and L23VV Auger matrix elements

Journal of Vacuum Science and Technology A

Jennison, Dwight R.

We present calculations which show the radial dependence of the KVV and L23VV Auger matrix elements of silicon. We find greatly differing dependences, converging within ~1 a.u. of the nucleus in the case of the KVV, but not until ~4 a.u. in the case of the L23VV, well beyond the bond midpoint of ~2.2 a.u. We also find quite different dependences for the various elements within a particular CVV transition. Because the local density of states (LDOS) is dependent on the radius of the sphere of integration, our results suggest that different CVV Auger processes on the same atom in fact probe different LDOSs, as do even different contributions within the same transition. (This effect is separate from the well-known matrix element property which weights angular-momentum components differently.) These results call into question both the single-site LDOS approximation when used in the interpretation of low-energy (<100 eV) Auger spectra, and the application to high-energy spectra of local densities of states obtained by integration over muffin-tin or Wigner–Seitz spheres which have a large radius compared to the region probed by the Auger process.

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Design and testing of space-domain minimum average correlation energy (SMACE) filters for 2-D acousto-optic correlators

Proceedings of SPIE - The International Society for Optical Engineering

Stalker, K.T.

Two-dimensional Acousto-Optic (AO) correlators differ from the frequency plane correlators in that multiplying, shifting, and adding, rather than Fourier transforming are used to obtain the correlations. Thus, many of the available composite filter design techniques are not aimed at designing filters for use in AO correlators since they yield frequency-domain functions. In this paper, a method is introduced for designing filter impulse responses of arbitrary extent for implementation on AO correlators. These filters are designed to yield sharp correlation peaks. Simulation results are included to illustrate the viability of the proposed approach. Also included are some initial results from the first successful use of grey-scale composite filters on an AO correlator.

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Voltage delay in Li/SOCl2 cells for artillery applications at -35°C

Proceedings of the International Power Sources Symposium

Delnick, F.M.; Baldwin, A.R.

Two active Li/SOCl2 cells for use in artillery-fired atomic projectiles are being developed. Voltage delay is the primary mode of electrochemical failure in these cells at -35°C. To minimize this anode polarization, the anode passivation is inhibited by adding chloromethyl chlorosulfate (CMCS) to the sulfur dioxide complex of lithium tetrachloroaluminate (LiAlCl4-SO2) in the cell electrolyte. One battery powers the telemetry system (TM battery) and the other powers a projectile event timer circuit (PET battery). The authors utilize the PET battery and PET load profile to demonstrate the effect of electrolyte additives on anode passive film growth and associated voltage delay. Similar effects were also observed in the TM battery. A limited number of PET prototypes was available for this study. Therefore, several tests were performed in hermetically sealed prismatic laboratory test cells which were constructed using the same electrochemical components which are used in the PET cells.

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Combining scenarios in a calculation of the overall probability distribution of cumulative releases of radioactivity from the Waste Isolation Pilot Plant, southeastern New Mexico

Tierney, Martin S.

The Waste Isolation Pilot Plant (WIPP), in southeastern New Mexico, is a research and development facility to demonstrate safe disposal of defense-generated transuranic waste. The US Department of Energy will designate WIPP as a disposal facility if it meets the US Environmental Protection Agency's standard for disposal of such waste; the standard includes a requirement that estimates of cumulative releases of radioactivity to the accessible environment be incorporated in an overall probability distribution. The WIPP Project has chosen an approach to calculation of an overall probability distribution that employs the concept of scenarios for release and transport of radioactivity to the accessible environment. This report reviews the use of Monte Carlo methods in the calculation of an overall probability distribution and presents a logical and mathematical foundation for use of the scenario concept in such calculations. The report also draws preliminary conclusions regarding the shape of the probability distribution for the WIPP system; preliminary conclusions are based on the possible occurrence of three events and the presence of one feature: namely, the events attempted boreholes over rooms and drifts,'' mining alters ground-water regime,'' water-withdrawal wells provide alternate pathways,'' and the feature brine pocket below room or drift.'' Calculation of the WIPP systems's overall probability distributions for only five of sixteen possible scenario classes that can be obtained by combining the four postulated events or features.

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An experimental/analytical comparison of strains in encapsulated assemblies

Guess, Tommy R.

A combined experimental and analytical study of strains developed in encapsulated assemblies during casting, curing and thermal excursions is described. The experimental setup, designed to measure in situ strains, consisted of thin, closed-end, Kovar tubes that were instrumented with strain gages and thermocouples before being over-cast with a polymeric encapsulant. Four bisphenol A (three diethanolamine cured and one anhydride cured) epoxy-based materials and one urethane elastomeric material were studied. After cure of the encapsulant, tube strains were measured over the temperature range of {minus}55{degrees}C to 90{degrees}C. The thermal excursion experiments were then numerically modeled using finite element analyses and the computed strains were compared to the experimental strains. The predicted strains were over estimated (conservative) when a linear, elastic, temperature-dependent material model was assumed for the encapsulant and the stress free temperature T{sub i} was assumed to correspond to the cure temperature {Tc} of the encapsulant. Very good agreement was obtained with linear elastic calculations provided that the stress free temperature corresponded to the onset of the glassy-to-rubbery transition range of the encapsulant. Finally, excellent agreement was obtained in one of the materials (828/DEA) when a viscoelastic material model was utilized and a stress free temperature corresponding to the cure temperature was assumed. 13 refs., 20 figs., 3 tabs.

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An investigation of gouge initiation in high-velocity sliding contact

Tachau, R.D.M.

Surface damage has been observed on the rails of rocket sled tracks and on the barrels of high-velocity guns. The phenomenon is generally referred to as ``ongoing``. Damage to a stationary surface (guider) is created from the oblique impact of a high-velocity object (slider) moving over its surface. The surface damage (gouge) is typically a shallow crater in the shape of a teardrop with the leading edge characterized by the wider end and a slightly raised lip. For rocket sleds, rail gouging occurs when the sled velocity is greater than 1.5 km/sec; while in guns, barrel gouging occurs when the velocity exceeds 4 km/sec. A model is developed to describe the phenomenon of gouging. An unbalanced slider randomly causes a shallow-angle, oblique impact between the slider and the guider. At sufficiently high velocity, the impact produces a thin, but very hot, layer of soft material at the contact surface. Under the action of a moving load, the soft layer lends itself to an antisymmetric deformation and a gouge is formed when this soft material is over-run by the slider. The model is simulated numerically with a hydrodynamic (CTH) code. The results of the simulations are in good agreement with the observed phenomena. Based on the simulated temperature and pressure profiles at the contact surface, design criteria for gouge mitigation are developed in this study. 45 refs., 29 figs., 1 tab.

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Description of critical instrumentation systems Sandia National Laboratories/Defense Nuclear Agency Remote Area Monitoring System

Metcalf, J.H.

A description of the Remote Area Monitoring System utilized on nuclear tests conducted by Sandia National Laboratories and the Defense Nuclear Agency is presented. The configuration of the detectors as used on a test is described, as well as the system hardware. Calibration of the detectors before fielding is also discussed.

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Fission product release and fuel behavior of irradiated light water reactor fuel under severe accident conditions. The ACRR ST-1 Experiment

Allen, Mark S.

The annular Core Research Reactor (ACRR) Source Term (ST) Experiment program was designed to obtain time-resolved data on the release of fission products from irradiated fuels under well-controlled light water reactor severe accident conditions. The ST-1 Experiment was the first of two experiments designed to investigate fission product release. ST-1 was conducted in a highly reducing environment at a system pressure of approximately 0.19 MPa, and at maximum fuel temperatures of about 2490 K. The data will be used for the development and validation of mechanistic fission product release computer codes such as VICTORIA.

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Waste-Generated Gas at the Waste Isolation Pilot Plant: Papers Presented at the Nuclear Energy Agency Workshop on Gas Generation and Release from Radioactive Waste Repositories

Davies, Peter B.

There are four papers contained in this report which were presented at the Nuclear Energy Agency (NEA) Gas Workshop to provide information about studies of waste-generated gas being conducted for the Waste Isolation Pilot Plant (WIPP). The paper by Davies et al. provides a general overview of the physical conditions pertinent to waste-generated gas and of the coupling of chemical, hydrologic, and structural processes. The paper by Brush et al. describes specific gas-generation processes and the laboratory- and bin-scale experiments being carried out to characterize these processes. The paper by Mendenhall et al. describes coupled modeling of gas generation and room closure, and provides an analysis of the potential for fracture generation and growth. the paper by Webb describes a series of sensitivity calculations carried out to assess the importance of hydrologic parameters, such as formation permeability and two-phase characteristic curves. Together, these papers provide an overview of the present (September 1991) status of waste-generated gas studies for the WIPP.

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Pretest 3D finite element analysis of the WIPP Intermediate Scale Borehole Test

Arguello, J.G.

A three dimensional pretest finite element analysis of the Intermediate Scale Borehole Test has been performed. In the analysis, the 7.7 years simulation period includes the mining of Rooms C1 and C2, and the N1420 cross drift, at time zero; drilling of the borehole between the two rooms at 5.7 years; and 2 years of post-drilling response. An all salt configuration was used in the calculation. The 1984 Waste Isolation Pilot Plant (WIPP) reference elastic-secondary creep law, with reduced elastic moduli, was used to model the creeping response of the salt. Results show that after mining of the rooms and cross drift a relatively high von Mises stress state exists around the perimeter of the pillar. However, by 5.7 years, or immediately prior to drilling of the borehole, the pillar has relaxed to an almost uniform von Mises stress of about 7--8 MPa. After the borehole is drilled, a relatively high von Mises stress field is once again set up in the immediate vicinity of the hole. This drives the creep closure of the borehole. The hole closes more in the vertical direction than in the horizontal direction, resulting in ovalling of the hole. At the end of the simulation, the von Mises stress around the borehole is still higher than that in the remained of the pillar. Thus, the closure rates are relatively high at the end of the simulation time.

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A simplified radionuclide source term for total-system performance assessment; Yucca Mountain Site Characterization Project

Wilson, Michael L.

A parametric model for releases of radionuclides from spent-nuclear-fuel containers in a waste repository is presented. The model is appropriate for use in preliminary total-system performance assessments of the potential repository site at Yucca Mountain, Nevada; for this reason it is simpler than the models used for detailed studies of waste-package performance. Terms are included for releases from the spent fuel pellets, from the pellet/cladding gap and the grain boundaries within the fuel pellets, from the cladding of the fuel rods, and from the radioactive fuel-assembly parts. Multiple barriers are considered, including the waste container, the fuel-rod cladding, the thermal ``dry-out``, and the waste form itself. The basic formulas for release from a single fuel rod or container are extended to formulas for expected releases for the whole repository by using analytic expressions for probability distributions of some important parameters. 39 refs., 4 figs., 4 tabs.

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Areal power density: A preliminary examination of underground heat transfer in a potential Yucca Mountain repository and recommendations for thermal design approaches; Yucca Mountain Site Characterization Project

Hertel, Eugene S.

The design of the potential Yucca Mountain repository is subject to many thermal goals related to the compliance of the site with federal regulations. This report summarizes a series of sensitivity studies that determined the expected temperatures near the potential repository. These sensitivity studies were used to establish an efficient loading scheme for the spent fuel canisters and a maximum areal power density based strictly on thermal goals. Given the current knowledge of the site, a design-basis areal power density of 80 kW/acre can be justified based on thermal goals only. Further analyses to investigate the impacts of this design-basis APD on mechanical and operational aspects of the potential repository must be undertaken before a final decision is made.

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The Behavior and Testing Implications of CMOS IC Logic Gate Open [Book Chapter]

1991, Proceedings. International Test Conference

Henderson, Christopher L.

The electrical and test properties of several logic gate open circuit defect structures were measured. Results indicate that tunneling current across fine geometry discontinuities enables low frequency operation of Integrated Circuits (ICs). No significant capacitive coupling was observed for adjacent metal interconnect or for large metal opens on the gate interconnects. These results indicate the need for different methods of open circuit defect detection during test.

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Laser-induced damage studies on step-index multimode fibers

Proceedings, Laser-Induced Damage in Optical Materials: 1991

Setchell, Robert E.

A previous investigation of laser-induced damage mechanisms and corresponding thresholds in step-index, multimode fibers was motivated by an interest in optical systems for firing explosives. In the initial study, the output from a compact, multimode Nd/YAG laser was coupled into fiber cores of pure fused silica. End-face polishing steps were varied between successive fiber lots to produce improved finishes, and each fiber was subjected to a sequence of progressively increasing energy densities up to a value of more than 80 J/cm2. Essentially all of the tested fibers experienced a 'laser conditioning' process at the front fiber face, in which a visible plasma was generated for one or more laser shots. Rather than produce progressive damage at the front surface, however, this process would eventually cease and leave the surface with improved damage resistance. Once past this conditioning process, the majority of fibers damaged at the rear end face. Other modes of damage were observed either at locations of fixturing stresses or at a location of high static tensile stress resulting from bends introduced to the fiber. Although the previous results were encouraging in terms of achieving useful damage thresholds, a number of areas for further study were indicated. In the present study, a similar experimental procedure was used to address these areas. The relative permanence of front-surface laser conditioning was examined by re-testing fibers that had experienced this process at least a year previously. End-face mechanical polishing was again examined by testing fibers prepared using a refined polishing schedule. Attempts to use a single fixture to hold an entire lot of fibers throughout end-face polishing and damage testing met with mixed results, with fiber positions subjected to fixturing stresses likely sites for initial damage. In an effort to prepare fiber faces with the improved damage resistance observed with front faces following 'laser conditioning,' two schedules for CO2-laser polishing of end faces were developed and evaluated. Finally, to improve resistance to damage at sites with significant static stresses, fiber samples which passed a much higher tensile proof test during manufacturing were tested. The current experiments were conducted with a new laser having a shorter pulse width and a significantly different mode structure. The beam was injected into the fiber using a geometry that had been successful in the previous study in minimizing a damage mechanism which can occur at the core/cladding interface with the first few hundred fiber diameters. However, the different mode structure of the new laser apparently resulted in this mechanism dominating the current results.

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Fusion Welding of Refractory Metals

Robino, Charles V.

The refractory metals of Groups 5B and 6B and their alloys display a variety of unique physical and mechanical characteristics in addition to their high melting points. In turn, these characteristics make these materials strong candidates for severe service and specialized applications. However, these materials also present a variety of challenges with respect to both fabrication weldability and the in-service behavior of weldments, many of which are related to the dominant effects of interstitial impurities. This work reviews current understanding of the physical and joining metallurgy of these metals and their alloys with emphasis on fusion welding. Of specific interest are the role of impurities and alloy chemistry in fabrication and service weldability, the material processing route, eg. vacuum melting vs. powder metallurgy, the importance of welding process procedures and variables, weldment mechanical properties, and fracture behavior. Specific examples from the various alloy systems are used to illustrate general metallurgical and joining characteristics of this class of materials.

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Overlooked Fundamentals of Resistance Welding

Knorovsky, Gerald A.

Resistance Welding (RW) has been known for about a century and in common use for much of that time. Much knowledge has been accumulated concerning many aspects of the process. However, upon examining contemporary RW handbooks, a few subjects that have been "overlooked" were found. Usually, this oversight will not be important; however, when the RW process is being applied at its limits, these factors may become critical. In this paper we will discuss such overlooked'' factors as the Peltier and Thomson effects, and the dynamics of welding head motions and how they are affected by the current pulse. Examples taken from sheet metal and microwelding applications will be given as examples.

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Melting Efficiency in Fusion Welding

Fuerschbach, Phillip W.

Basic to our knowledge of the science of welding is an understanding of the melting efficiency, which indicates how much of the heat deposited by the welding process is used to produce melting. Recent calorimetric studies of GTAW, PAW, and LBW processes have measured the net heat input to the part thereby quantifying the energy transfer efficiency and in turn permitting an accurate determination of the melting efficiency. It is indicated that the weld process variables can dramatically affect the melting efficiency. This limiting value is shown to depend on the weld heat flow geometry as predicted by analytical solutions to the heat flow equation and as demonstrated by the recent empirical data. A new dimensionless parameter is used to predict the melting efficiency and is shown to correlate extremely well with recent empirical data. This simple prediction methodology is notable because it requires only a knowledge of the weld schedule and the material properties in order to estimate melting efficiency.

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A summary of high-temperature electronics research and development

Thome, F.V.; King, D.B.

Current and future needs in automative, aircraft, space, military, and well logging industries require operation of electronics at higher temperatures than today's accepted limit of 395 K. Without the availability of high-temperature electronics, many systems must operate under derated conditions or must accept severe mass penalties required by coolant systems to maintain electronic temperatures below critical levels. This paper presents ongoing research and development in the electronics community to bring high-temperature electronics to commercial realization. Much of this work was recently reviewed at the First International High-Temperature Electronics Conference held 16--20 June 1991 in Albuquerque, New Mexico. 4 refs., 1 tab.

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Improving Managers' Effectiveness

James, Mark R.

Upward Feedback is a program that gives employees and opportunity to anonymously provide their manager with feedback concerning the manager's job performance. It is an opportunity for managers to receive confidential feedback evaluating their implementation of corporate values and management behaviors as perceived by those who work for them. This feedback can come from employees who report directly to the manager, that is, one level below them (referred to as direct reports), or from those two reporting levels below them (referred to as skip-level reports). Managers then share information with their employees in feedback meetings and develop action plans to address areas of concern. Sandia National Laboratories has developed and implemented an Upward Feedback Pilot Program and follow up survey. This paper discussed the program and the lessons learned.

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PHYSLIB: A C++ tensor class library

Budge, Kent G.

C++ is the first object-oriented programming language which produces sufficiently efficient code for consideration in computation-intensive physics and engineering applications. In addition, the increasing availability of massively parallel architectures requires novel programming techniques which may prove to be relatively easy to implement in C++. For these reasons, Division 1541 at Sandia National Laboratories is devoting considerable resources to the development of C++ libraries. This document describes the first of these libraries to be released, PHYSLIB, which defines classes representing Cartesian vectors and (second-order) tensors. This library consists of the header file physlib.h, the inline code file physlib.inl, and the source file physlib.C. The library is applicable to both three-dimensional and two-dimensional problems; the user selects the 2-D version of the library by defining the symbol TWO D in the header file physlib.h and recompiling physlib.C and his own code. Alternately, system managers may wish to provide duplicate header and object modules of each dimensionality. This code was produced under the auspices of Sandia National Laboratories, a federally-funded research center administered for the United States Department of Energy on a non-profit basis by AT T. This code is available to US citizens, and institutions under research, government use and/or commercial license agreements.

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A user's guide to CEPXS/ONELD Version 1. 1

Lorence Jr., L.J.

This is the user's guide to CEPXS/ONELD Version 1.1, a code package for coupled electron-photon transport in one-dimensional slab geometry. The code package consists of the multigroup cross-section generating code, CEPXS; the preprocessor code, PRE1D; the discrete ordinates code, ONELD; and the postprocessor code, POST1D. In Version 1.1, new features have been implemented through several new keywords. Since Version 1.0 keywords are still applicable, this document should be considered as an addendum to the Version 1.0 User's Guide. 5 refs.

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Preliminary evaluation of hermetic JT/LJT/R P connector socket contact design

Baca, J.R.F.

This report presents a precursory examination of a number of issues pertaining to socket contacts in hermetic connectors. The principal issues addressed are high-contact resistance and contact chatter (circuit discontinuities). Efforts examining the characteristics of the existing socket contact design, the possibility of connector/contact rework, quick-fix solutions, and contact redesigns are summarized.

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A Simple Model for the Motion of Pulsed-Laser-Driven Thin Flyers

Journal de Physique. 4

Lawrence, R.J.

A model that predicts the final velocity of high-power, pulsed-laser-driven thin flyers is described. The required input parameters can either be obtained from standard handbooks or simply extracted from one set of data. The model yields a number of features and scaling laws that are well verified by experiment. Specific comparisons of model predictions with experimental results illustrate excellent agreement for variations of laser fluence and pulse width as well as flyer diameter and thickness.

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Experiments to investigate the effect of flight path on direct containment heating (DCH) in the Surtsey test facility

Allen, Mark S.

The goal of the Limited Flight Path (LFP) test series was to investigate the effect of reactor subcompartment flight path length on direct containment heating (DCH). The test series consisted of eight experiments with nominal flight paths of 1, 2, or 8 m. A thermitically generated mixture of iron, chromium, and alumina simulated the corium melt of a severe reactor accident. After thermite ignition, superheated steam forcibly ejected the molten debris into a 1:10 linear scale the model of a dry reactor cavity. The blowdown steam entrained the molten debris and dispersed it into the Surtsey vessel. The vessel pressure, gas temperature, debris temperature, hydrogen produced by steam/metal reactions, debris velocity, mass dispersed into the Surtsey vessel, and debris particle size were measured for each experiment. The measured peak pressure for each experiment was normalized by the total amount of energy introduced into the Surtsey vessel; the normalized pressures increased with lengthened flight path. The debris temperature at the cavity exit was about 2320 K. Gas grab samples indicated that steam in the cavity reacted rapidly to form hydrogen, so the driving gas was a mixture of steam and hydrogen. These experiments indicate that debris may be trapped in reactor subcompartments and thus will not efficiently transfer heat to gas in the upper dome of a containment building. The effect of deentrainment by reactor subcompartments may significantly reduce the peak containment load in a severe reactor accident. 8 refs., 49 figs., 6 tabs.

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Characteristics, finite element analysis, test description, and preliminary test results of the STM4-120 kinematic Stirling engine

Linker, Kevin L.

The Department of Energy's Solar Thermal Program has as one of its program elements the development and evaluation of conversion device technologies applicable to dish-electric systems. The primary research and development combines a conversion device (heat engine), solar receiver, and generator mounted at the focus of a parabolic dish concentrator. The Stirling-cycle heat engine was identified as the conversion device for dish-electric with the most potential for meeting the program's goals for efficiency, reliability, and installed cost. To advance the technology toward commercialization, Sandia National Laboratories has acquired a Stirling Thermal Motors, Inc., kinematic Stirling engine, STM4-120, for evaluation. The engine is being bench-tested at Sandia's Engine Test Facility and will be combined later with a solar receiver for on-sun evaluation. This report presents the engine characteristics, finite element analyses of critical engine components, test system layout, instrumentation, and preliminary performance results from the bench test.

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Interior intrusion detection systems

Rodriguez, Jose R.

The purpose of this NUREG is to present technical information that should be useful to NRC licensees in designing interior intrusion detection systems. Interior intrusion sensors are discussed according to their primary application: boundary-penetration detection, volumetric detection, and point protection. Information necessary for implementation of an effective interior intrusion detection system is presented, including principles of operation, performance characteristics and guidelines for design, procurement, installation, testing, and maintenance. A glossary of sensor data terms is included. 36 figs., 6 tabs.

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JT/LJT connector insert material evaluation

Baca, J.R.F.

Different insert (insulator) materials are undergoing evaluation to replace the Fiberite E-3938 BE96 material currently used. Also being evaluated is the reconfiguration of the insert and metal shell-edge geometries for the purpose of reducing the alleged interference principally responsible for insert damage.

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Radiation embrittlement of the neutron shield tank from the Shippingport reactor

Rosinski, S.T.

The irradiation embrittlement of neutron shield tank (NST) material (A212 Grade B steel) from the Shippingport reactor has been characterized. Irradiation increases the Charpy transition temperature (CTT) by 23--28{degrees}C (41--50{degrees}F) and decreases the upper-shelf energy. The shift in CTT is not as severe as that observed in high-flux isotope reactor (HFIR) surveillance specimens. However, the actual value of the CTT is higher than that for the HFIR data. The increase in yield stress is 51 MPa (7.4 ksi), which is comparable to HFIR data. The NST material is weaker in the transverse orientation than in the longitudinal orientation. Some effects of position across the thickness of the wall are also observed; the CTT shift is slightly greater for specimens from the inner region of the wall. Annealing studies indicate complete recovery from embrittlement after 1 h at 400{degrees}C (752{degrees}F). Although the weld metal is significantly tougher than the base metal, the shifts in CTT are comparable. The shifts in CTT for the Shippingport NST are consistent with the test and Army reactor data for irradiations at <232{degrees}C (<450{degrees}F) and show very good agreement with the results for HFIR A212-B steel irradiated in the Oak Ridge Research Reactor (ORR). The effects of irradiation temperature, fluence rate, and neutron flux spectrum are discussed. The results indicate that fluence rate has no effect on radiation embrittlement at rates as low as 2 {times} 10{sup 8} n/cm{sup 2}{center dot}s and at the low operating temperatures of the Shippingport NST, i.e., 55{degrees}C (130{degrees}F). This suggests that the accelerated embrittlement of HFIR surveillance samples is most likely due to the relatively higher proportion of thermal neutrons in the HFIR spectrum compared to that for the test reactors. 28 refs., 25 figs.

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Analysis of thermosyphoning in a steam generator model

Martinez, M.J.; Martinez, G.M.

An analysis of thermosyphoning in a stream generator model is presented. The model considers the transient development of buoyancy-driven steam flow in the steam generator tubing, secondary side heat transfer and an inlet plenum mixing model. Numerical solutions are obtained for conditions intended to simulate the natural circulation phenomena in a 3-Loop pressurized water reactor in a loss-of-coolant accident scenario. The relation between the circulation rate and the heating rate is determined. The sensitivity of the model to various key parameters is examined. 16 refs.

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Static load testing of a heliostat drive

Grossman, James W.

The drive designed and built by the Solar Power Engineering Company (SPECO) for its large area heliostat failed under high wind loads during a winter storm. This report details the testing and analysis done to verify the load capabilities of the rebuilt heliostat drive. Changes in design and improvements in fabrication resulted in a usable drive. 12 figs., 7 tabs.

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18 W/m{sup 2} Mockup for Defense High-Level Waste (Rooms A): In situ data report: Volume 1---Mechanical response gages (February 1985--June 1990). Waste Isolation Pilot Plant (WIPP) Thermal/Structural Interactions Program

Munson, Darrell E.

Data are presented from the 18 W/m{sup 2} Mockup for Defense High-Level Waste, a very large scale in situ test fielded underground at the Waste Isolation Pilot Plant (WIPP). These data include selected fielding information, test configuration, instrumentation activities, and comprehensive results from a large number of gages. The results in this report give measured data from the mechanical response gages, i.e., room closure gages, extensometers, and stress meters emplaced in the test. Construction of the test began in June 1984; gage data in this report cover the complete test duration, that is, to June 1990.

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Expanded coaxial transmission cells for electromagnetic testing

Cernosek, Richard W.

Coaxial transmission cells have been developed for testing optical fiber current sensors. Three of these cells are airlines that provide transverse electromagnetic mode operation to 1.0, 2.3, and 13.7 GHz. Standing wave ratios are <1.5 for the unloaded airlines over their given frequency ranges. Solid and liquid dielectric coaxial cells use materials with high relative permittivities, >9.1. A ceramic test cell has a useful frequency range to 2.5 GHz; the liquid cells, filled with propanol, methanol, or water, are good to {approximately}500 MHz. The properties of the liquid cells are described using a model of a multilayer coaxial dielectric system with complex relative permittivities. 15 refs.

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Structural analysis of the source term transportation cask

Hoffman, Edward L.

Structural calculations were performed to evaluate the source-term nuclear fuels transport cask (ST Cask) under various hypothetical accident scenarios. (1) Three-dimensional transient dynamic analyses were performed to evaluate the strength of the cask`s end-closure clamp mechanism. The calculations were performed for two impact orientations: a side impact and a 20{degrees} corner impact. The calculations identified three weaknesses in the clamp design: a gap designed between the clamp and the cask provides a deformation mode which loosens the clamp, two unconstrained swing bolts used to fasten the clamp can lose preload and come free; and insufficient stiffness of the clamp in torsion. (2) An axisymmetric finite element model was used to evaluate the dynamics of end-drops from 5 and 10 ft. The calculations show that loads generated in the end-drops could break the payload support cable and damage the payload winch. Lead slump resulted in both end-drop calculations. The stresses generated in the cask wall during the end-drops was insufficient to cause buckling. (3) To determine the factor of safety to yield, calculations in which the cask was treated as a beam loaded under its own weight were performed for two support configurations: simply supported at both ends and simply supported at the center (trunnion loading). (4) The survival of the cask from a 1-m drop onto a mild steel punch was evaluated based on equations derived from empirical data. The calculations showed that the ST Cask could survive such an event. (5) Finally, the bolt configuration for the upper-closure was analyzed and determined to be inadequate because it does not prevent the closure from sliding relative to the cask body. Specific recommendations for design changes are made in the report to eliminate identified problems.

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The North Slope of Alaska: ARM`s window on high latitude phenomena

Zak, Bernard D.

A major thrust of the Atmospheric Radiation Measurements (ARM) Program is the establishment of 5 primary and 4 supplementary Cloud and Radiation Testbed (CART) sites. The CART sites will provide the means to acquire the necessary data to test and further develop the components of GCMs (General Circulation Models) which describe the relationships between the characteristics of the atmosphere and the solar and thermal radiation which passes through it. The CART Locale Recommendation Team has presented a priority-ordered set of recommended locales for the primary and supplementary sites, along with alternatives for each. The selection was based primarily on the following criteria: geographical and climatological homogeneity; occurrence of climatologically important cloud types; seasonal change of surface properties; variability of radiatively-active atmospheric components; synergism with other programs; and manageable logistics. An additional criterion was that, taken together, the set of recommended locales must span a broad range of climate regimes. The recommended primary locales include two land and three ocean locales. The first CART Site will be established in the Southern Great Plains (SGP) of the US. The next CART site to be established on land is to be in the polar regions, on the North Slope of Alaska (NSA).

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Yucca Mountain Project thermal and mechanical codes first benchmark exercise: Part 3, Jointed rock mass analysis; Yucca Mountain Site Characterization Project

Costin, Laurence S.

Thermal and mechanical models for intact and jointed rock mass behavior are being developed, verified, and validated at Sandia National Laboratories for the Yucca Mountain Site Characterization Project. Benchmarking is an essential part of this effort and is one of the tools used to demonstrate verification of engineering software used to solve thermomechanical problems. This report presents the results of the third (and final) phase of the first thermomechanical benchmark exercise. In the first phase of this exercise, nonlinear heat conduction code were used to solve the thermal portion of the benchmark problem. The results from the thermal analysis were then used as input to the second and third phases of the exercise, which consisted of solving the structural portion of the benchmark problem. In the second phase of the exercise, a linear elastic rock mass model was used. In the third phase of the exercise, two different nonlinear jointed rock mass models were used to solve the thermostructural problem. Both models, the Sandia compliant joint model and the RE/SPEC joint empirical model, explicitly incorporate the effect of the joints on the response of the continuum. Three different structural codes, JAC, SANCHO, and SPECTROM-31, were used with the above models in the third phase of the study. Each model was implemented in two different codes so that direct comparisons of results from each model could be made. The results submitted by the participants showed that the finite element solutions using each model were in reasonable agreement. Some consistent differences between the solutions using the two different models were noted but are not considered important to verification of the codes. 9 refs., 18 figs., 8 tabs.

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Procedure development study: Low strain rate and creep experiments; Yucca Mountain Site Characterization Project

Price, Ronald H.

Licensing of the potential nuclear-waste repository at Yucca Mountain by the Nuclear Regulatory Commission would require, among other things, demonstrations of the long term usability of the underground facilities. Such a demonstration involves analysis of the mechanical response of the rock to the presence of underground openings and heat-producing waste, which in turn requires data on the mechanical properties of the rock. This document describes the experimental results from a scoping study which led to the development of procedures for performing quality-affecting rock-mechanics experiments on intact rock. The future experiments performed with these procedures will produce information on the time-dependent deformation of welded tuff and represent one aspect of the overall effort to characterize the rheology of the rock mass. 3 refs., 42 figs., 6 tabs.

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An analysis of a joint shear model for jointed media with orthogonal joint sets; Yucca Mountain Site Characterization Project

Koteras, J.R.

This report describes a joint shear model used in conjunction with a computational model for jointed media with orthogonal joint sets. The joint shear model allows nonlinear behavior for both joint sets. Because nonlinear behavior is allowed for both joint sets, a great many cases must be considered to fully describe the joint shear behavior of the jointed medium. An extensive set of equations is required to describe the joint shear stress and slip displacements that can occur for all the various cases. This report examines possible methods for simplifying this set of equations so that the model can be implemented efficiently form a computational standpoint. The shear model must be examined carefully to obtain a computationally efficient implementation that does not lead to numerical problems. The application to fractures in rock is discussed. 5 refs., 4 figs.

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NFS, Kerberos, and UNICOS

Haynes, R.A.

The Network File System (NFS) is used in UNIX-based networks to provide transparent file sharing between heterogeneous systems. Although NFS is well-known for being weak in security, it is widely used and has become a de facto standard. This paper examines the user authentication shortcomings of NFS and the approach Sandia National Laboratories has taken to strengthen it with Kerberos. The implementation on a Cray Y-MP8/864 running UNICOS is described and resource/performance issues are discussed. 4 refs., 4 figs.

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Impact of Fracture Coatings on the Transfer of Water Across Fracture Faces in Unsaturated Media

Gallegos, David P.

Ground water flow in unsaturated, fractured rock is often assumed to be dominated by the porous matrix component. This is frequently based on the argument that water flowing in the fractures is rapidly imbibed into the rock matrix by capillary suction forces with negligible resistance to uptake at the matrix-fracture interface. However, the existence of a low-permeability mineralized layer or coating at this interface may substantially reduce matrix imbibition and consequently result in fracture-dominated flow. To test this concept, four tuff samples containing natural fractures were obtained from tuff formations in southern Nevada. By performing imbibition experiments into the matrix rock, across a mineralized fracture face and then across a fresh uncoated fracture face, water uptake as a function of time and coating was measured. A relatively simple model has been developed to describe the imbibition behavior. 6 refs.

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Effective Waste Minimization in an R&D Setting: The Program at Sandia National Laboratories

Reilly, Hugh E.

An important aspect of environmentally-conscious operations is adoption of an aggressive waste minimization program. This paper describes the waste minimization and pollution prevention program at Sandia National Laboratories. Although Sandia's approach is patterned after the generic waste minimization models proposed by the Environmental Protection Agency and the Department of Energy, the specifics of implementation, and the potential for payoff, are influenced by the R&D nature of Sandia's work. Key aspects of the program are discussed, including why Sandia is developing and conducting the program; objectives; elements of the program; our approach to implementation; the magnitude of the undertaking; and the expected payoff.

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Effect of Cu at Al grain boundaries on electromigration behavior in Al thin films

Proceedings of SPIE - The International Society for Optical Engineering

Frear, Darrel R.

The distribution of copper in aluminum thin films is examined with respect to how the copper can influence electromigration behavior. Al-Cu thin films annealed in the single-phase region, to just below the solvus temperature, have θ-phase Al2Cu precipitates at the aluminum grain boundaries. The grain boundaries between precipitates are depleted in copper. Al-Cu thin films heat treated at lower temperatures, within the two-phase region, also have θ-phase precipitates at the grain boundaries but the aluminum grain boundaries continuously become enriched in copper, perhaps due to the formation of a thin coating of θ-phase at the grain boundary. Here, it is proposed that electromigration behavior of aluminum is improved by adding copper because the θ-phase precipitates may hinder aluminum diffusion along the grain boundaries. It was also found that resistivity of Al-Cu thin films decrease during accelerated electromigration testing prior to failure. Pure Al films did not exhibit this behavior. The decrease in resistivity is attributed to there distribution of copper from the aluminum grain matrix to the θ-phase precipitates growing at the grain boundaries thereby reducing the number of defects in the microstructure.

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A test vehicle to assess stress voiding models and acceleration methods

AIP Conference Proceedings

Filter, William F.

We have designed and manufactured a test chip devoted to the study of interconnect voiding. The test chip is suitable for evaluating theoretical models, acceleration recipes, and the effects of process variations. We describe the chip and a simple, stress-free packaging technique that eliminates any stress to the chip from die bonding or packaging thermal cycles. With this test chip, we can perform many necessary and desirable experiments: determining stress, observing or stimulating void growth, profiling hydrogen concentrations, and measuring excess current noise. We report here preliminary measurements of residual stress, observations of voids, and determinations of hydrogen concentrations of hydrogen concentration under variations in aluminum annealing and passivation. In agreement with observations elsewhere, we find that passivations which differ greatly in intrinsic stress do not differ much in the stress they impart to patterned metal; some workers have suggested instead that excess hydrogen in the aluminum contributes to voiding. Following this lead, we have used nuclear reaction analysis to profile the hydrogen concentration in passivation, metallization, barrier metal, and interlevel dielectric and present some preliminary measurements here. We conclude that passivated metallization may contain as much as 0.1 atomic % hydrogen.

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Fatigue life prediction of solder joints

Jones, Wendell B.

The current status of lifetime prediction under conditions of thermomechanical creep/fatigue is reviewed. Each method is summarized and the results of the application to solder joints is shown. While each method has been applied with some success, a predictive, phenomenological approach has not been developed and validated. A method which captures the response of a crack to steady-state and cycling environments appears to hold most the most promise to provide a useful design tool.

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Effective path planning through task restriction

Chen, P.C.

We present a simple and effective path planning algorithm, an essential component in facilitating robot programming, based on a series of plausible task restriction. It is designed to solve realistic'' problems very quickly, at the expense of not being able to solve every problem. First, the notion of realistic'' problems is motivated with heuristic arguments and formalized through task restrictions. Next, an algorithm solving the resulting tasks of interest is provided. We prove its corrections and theoretical efficiency, and demonstrate empirically its effectiveness and speed. We expect our algorithm to be of practical significance based on its simplicity and predicted performance. 9 refs., 7 figs.

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SANDROS: A motion planner with performance proportional to task difficulty

Hwang, Yong K.

To address the need of a practical motion planner for manipulators, we present an efficient and resolution-complete algorithm that has performance commensurate with task difficulty. The algorithm uses SANDROS, a new search strategy that combines hierarchical, nonuniform-multi-resolution, and best-fit search to find a near-optimal solution in the configuration space. This algorithm can be applied to any manipulator, and has been tested with 5 and 6-degree-of-freedom robots, with execution time ranging from 20 seconds to 10 minutes on a 16 MIPS workstation. 14 refs., 3 figs., 1 tab.

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An Auger Electron Spectroscopy Study of the Activation of Iron Fischer-Tropsch Catalysts

Journal of Catalysis

Sault, Allen G.

Activation procedures can have a dramatic effect on the activity of iron-based catalysts for Fischer-Tropsch (F-T) synthesis. CO conversion over a 100 Fe/3 Cu/0.2 K catalyst (parts by weight) can vary by nearly a factor of 3, depending on activation treatment. In contrast, a 100 Fe/5 Cu/4.2 K/25 SiO2 catalyst displays little dependence of F-T activity on activation treatment. An ultra-high vacuum surface analysis chamber coupled to an atmospheric reactor has been used to measure the surface composition of these catalysts following activation in carbon monoxide at 280°C, while transmission electron microscopy (TEM) and BET surface area measurements have been used to investigate catalyst morphology. CO activation of the 100 Fe/5 Cu/4.2 K/25 SiO2 catalyst at 280°C results in partial reduction of iron to a mixture of FexO and Fe3O4, and an overall surface composition very similar to that obtained following hydrogen activation at 220 or 280°C, consistent with the invariance of F-T activity with activation treatment for this catalyst. Activation of the 100 Fe/3 Cu/0.2 K catalyst in CO at 280°C results in the formation of iron carbide particles, growth of graphitic carbon (Cg) filaments, and formation of a thick, porous, Cg layer covering the carbide particles. Differences in F-T activity between the hydrogen- and CO-activated 100 Fe/3 Cu/O.2 K catalyst are discussed in terms of surface composition and catalyst morphology. The difference in sensitivity of the two catalysts to activation conditions is related to differences in the extent of reduction of the catalysts.

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HISPLT: A history graphics postprocessor

Thompson, S.L.; Kmetyk, L.N.

HISPLT is a graphics postprocessor designed to plot time histories for wave propagation codes. HISPLT is available for CRAY UNICOS, CRAY CTSS, VAX VMS computer systems, and a variety of UNIX workstations. The original HISPLT code employs a database structure that allows the program to be used without modification to process data generated by many wave propagation codes. HISPLT has recently been modified to process time histories for the reactor safety analysis code, MELCOR. This report provides a complete set of input instructions for HISPLT and provides examples of the types of plotted output that can be generated using HISPLT. 6 refs., 8 figs., 5 tabs.

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Video systems for alarm assessment

Greenwoll, D.A.

The purpose of this NUREG is to present technical information that should be useful to NRC licensees in designing closed-circuit television systems for video alarm assessment. There is a section on each of the major components in a video system: camera, lens, lighting, transmission, synchronization, switcher, monitor, and recorder. Each section includes information on component selection, procurement, installation, test, and maintenance. Considerations for system integration of the components are contained in each section. System emphasis is focused on perimeter intrusion detection and assessment systems. A glossary of video terms is included. 13 figs., 9 tabs.

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Numerical simulation of VAWT stochastic aerodynamic loads produced by atmospheric turbauence: VAWT-SAL code

Homicz, Gregory F.

Blade fatigue life is an important element in determining the economic viability of the Vertical-Axis Wind Turbine (VAWT). A principal source of blade fatigue is thought to be the stochastic (i.e., random) aerodynamic loads created by atmospheric turbulence. This report describes the theoretical background of the VAWT Stochastic Aerodynamic Loads (VAWT-SAL) computer code, whose purpose is to numerically simulate these random loads, given the rotor geometry, operating conditions, and assumed turbulence properties. A Double-Multiple-Stream Tube (DMST) analysis is employed to model the rotor's aerodynamic response. The analysis includes the effects of Reynolds number variations, different airfoil sections and chord lengths along the blade span, and an empirical model for dynamic stall effects. The mean ambient wind is assumed to have a shear profile which is described by either a power law or a logarithmic variation with height above ground. Superimposed on this is a full 3-D field of turbulence: i.e., in addition to random fluctuations in time, the turbulence is allowed to vary randomly in planes perpendicular to the mean wind. The influence of flow retardation on the convection of turbulence through the turbine is also modeled. Calculations are presented for the VAWT 34-m Test Bed currently in operation at Bushland, Texas. Predicted time histories of the loads, as well as their Fourier spectra, are presented and discussed. Particular emphasis is placed on the differences between so-called steady-state'' (mean wind only) predictions, and those produced with turbulence present. Somewhat surprisingly, turbulence is found to be capable of either increasing or decreasing the average output power, depending on the turbine's tip-speed ratio. A heuristic explanation for such behavior is postulated, and a simple formula is derived for predicting the magnitude of this effect without the need for a full stochastic simulation. 41 refs., 32 figs., 1 tab.

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Battery test facility hardware, software, and system operation

Rodriguez, G.P.

Division 2525 Battery Test Laboratory is a fully automated battery testing facility used in evaluating various battery technologies. The results of these tests are used to verify developers' claims, characterize prototypes, and assist in identifying the strengths and weaknesses of each technology. The Test Facility consists of a central computer and nine remote computer controlled battery test systems. Data acquired during the battery testing process is sent to the central computer system. The test data is then stored in a large database for future analysis. The central computer system is also used in configuring battery tests. These test configurations are then sent to their appropriate remote battery test sites. The Battery Test Facility can perform a variety of battery tests, which include the following: Life Cycle Testing; Parametric Testing at various temperature levels, cutoff parameters, charge rates, and discharge rates; Constant Power Testing at various power levels; Peak Power Testing at various State-of-Charge levels; Simplified Federal Urban Driving Schedule Tests (SFUDS79). The Battery Test Facility is capable of charging a battery either by constant current, constant voltage, step current levels, or any combination of them. Discharge cycles can be by constant current, constant resistance, constant power, step current levels, or also any combination of them. The Battery Test Facility has been configured to provide the flexibility to evaluate a large variety of battery technologies. These technologies include Lead-Acid, Sodium/Sulfur, Zinc/Bromine, Nickel/Hydrogen, Aluminum/Air, and Nickel/Cadmium batteries.

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Transient dynamic analysis of plates and shells with PRONTO 3D

Bergmann, V.L.

PRONTO 3D is a three-dimensional transient solid dynamics code for analyzing large deformations of highly nonlinear materials subjected to high strain rates. It is a Lagrangian finite element program with explicit integration of the equations of motion through time. This report documents the implementation of a four-scale quadrilateral shell element into Version 6.0 of PRONTO 3D. This report describes the theory, implementation and use of a four-node shell element. Also described are the required architectural changes made to PRONTO 3D to allow multiple element types. Several test problems are documented for verification of the PRONTO 3D implementation and for demonstration of computational savings using shell elements for thin structures. These problems also serve as examples for the user. A complete, updated list of the PRONTO 3D input commands is also included.

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Security system signal supervision

Matter, John C.

This purpose of this NUREG is to present technical information that should be useful to NRC licensees for understanding and applying line supervision techniques to security communication links. A review of security communication links is followed by detailed discussions of link physical protection and DC/AC static supervision and dynamic supervision techniques. Material is also presented on security for atmospheric transmission and video line supervision. A glossary of security communication line supervision terms is appended. 16 figs.

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A methodology for estimating the residual contamination contribution to the source term in a spent-fuel transport cask

Sanders, Thomas L.

This report describes the ranges of the residual contamination that may build up in spent-fuel transport casks. These contamination ranges are calculated based on data taken from published reports and from previously unpublished data supplied by cask transporters. The data involve dose rate measurements, interior smear surveys, and analyses of water flushed out of cask cavities during decontamination operations. A methodology has been developed to estimate the effect of residual contamination on spent-fuel cask containment requirements. Factors in estimating the maximum permissible leak rates include the form of the residual contamination; possible release modes; internal gas-borne depletion; and the temperature, pressure, and vibration characteristics of the cask during transport under normal and accident conditions. 12 refs., 9 figs., 4 tabs.

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Substitute conversion coatings on aluminum for waste minimization

Buchheit, R.G.; Bode, M.D.; Stoner, G.E.

Chromate conversion coatings such as Parker Company`s Alodine coatings are widely used to increase the corrosion resistance of aluminum and aluminum alloys. The primary disadvantage of chromate-based processes is that they use and produce as waste hexavalent chromium (Cr{sup 6+}). We have discovered that the corrosion resistance of Al can be increased by forming an inorganic barrier coating using chemicals that pose a relatively small environmental hazard. These new coatings are formed using a process that is procedurally identical to the basic chromate conversion process. We have prepared new and conventional coatings on 1100 (99.0 Al minimum), 2024-T3 (Al-Cu-Mg) and 7075-T6 (Al-Zn-Mg) commercial sheet stock for accelerated electrochemical testing and coating conductivity testing. Results show that the new coatings offer increased corrosion resistance compared to uncoated Al, but do not yet match the performance of the chromate conversion coatings. The conductivity of these new films on 1100 Al is comparable to that of Alodine coatings; however, the new coatings are more resistive than Alodine coatings on 2024-T3 and 7075-T6.

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In situ monitoring of thin film deposition using optical fibers

Pfeifer, Kent B.

A novel technique to monitor thin film deposition has been developed using optical fibers. The system measures the optical thickness of a film and not the physical thickness which results in accurate film deposition for optical applications regardless of deposition conditions. A discussion of the mathematics necessary to understand the operation of the system is presented. The details of the circuitry and software are presented. The performance of the system is then demonstrated for the deposition of SnO{sub 2} on an optical fiber. An analysis of the inherent errors present in the monitor electronics and measurement system and their effects on the accuracy of the deposition is presented. The system is then applied to several practical situations. First, the system is used to monitor the deposition of SnO{sub 2} films on microscope slides. The films on the slides are then shown to have optical thicknesses which are within 1% of the expected values. The system is next used to deposit SiO anti-reflective coatings on Si. The system is then used to monitor the aging effects seen in SiO and SnO{sub 2}. Finally, a seven layer dielectric mirror made from SnO{sub 2} and MgF{sub 2} films is deposited using the monitor. 25 figs., 1 tabs.

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Certification testing of the Los Alamos National Laboratory Heat Source/Radioisotopic Thermoelectric Generator shipping container

Bronowski, David R.

The Heat Source/Radioisotopic Thermoelectric Generator shipping counter is a Type B packaging currently under development by Los Alamos National Laboratory. Type B packaging for transporting radioactive material is required to maintain containment and shielding after being exposed to normal and hypothetical accident environments defined in Title 10 of the Code of Federal Regulations Part 71. A combination of testing and analysis is used to verify the adequacy of this packaging design. This report documents the testing portion of the design verification. Six tests were conducted on a prototype package: a water spray test, a 4-foot normal conditions drop test, a 30-foot drop test, a 40-inch puncture test, a 30-minute thermal test, and an 8-hour immersion test.

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MELCOR 1. 8. 1 assessment: LACE aerosol experiment LA4

Kmetyk, L.N.

The MELCOR code has been used to simulate LACE aerosol experiment LA4. In this test, the behavior of single- and double-component, hygroscopic and nonhygroscopic, aerosols in a condensing environment was monitored. Results are compared to experimental data, and to CONTAIN calculations. Sensitivity studies have been done on time step effects and machine dependencies; thermal/hydraulic parameters such as condensation on heat structures and on pool surface, and radiation heat transfer; and aerosol parameters such as number of MAEROS components and sections assumed, the degree to which plated aerosols are washed off heat structures by condensate film draining, and the effect of non-default values for shape factors and diameter limits. 9 refs., 50 figs., 13 tabs.

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Application of a damage model for rock fragmentation to the Straight Creek Mine blast experiments

Thorne, Billy J.

Early attempts at estimation of stress wave damage due to blasting by use of finite element calculations met with limited success due to numerical instabilities that prevented calculations from being carried past the fragmentation limit. More recently, the improved damage model PRONTO has allowed finite element calculations which remain stable and yield good agreement between calculated fragmented regions and excavated crater profiles for blasting experiments in granite. Application of this damage model to blast experiments at the Straight Creek Mine in Bell County, Kentucky were complicated by anisotropic conditions and uncertainties in material properties. It appears that significant modifications to the damage model and extensive material testing may be necessary in order to estimate damage in these anisotropic materials. 18 refs., 18 figs.

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Experiments in robotic sensori-motor control during grasp

Stansfield, S.A.

This paper presents a series of experiments in robotic sensori-motor control during grasping. The work utilizes a multifingered, dextrous robot hand equipped with a fingertip force sensor to explore dynamic grasp force adjustment during manipulation. The work is primarily concerned with the relationship between the weight of an object and the grasp force required to lift it. Too weak a grasp is unstable and the object will slip from the hand. Too strong a grasp may damage the object and/or the manipulator. An algorithm is presented which uses tactile information from the sensor to dynamically adjust the grasp force during lift. It is assumed that there is no a priori knowledge about the object to be manipulated. The effects of different arm/hand postures and object surfaces is explored. Finally, the use of sensory data to detect unexpected object motion and to signal transitions between manipulation phases -- with the coincident triggering of new motor programs -- is investigated. 15 refs., 12 figs.

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Lead-free solders for electronics applications: Wetting analysis

Vianco, Paul T.

The fabrication of electronic systems has relied upon eutectic tin-lead solder for the attachment of components to printed wiring boards. Higher service temperatures are approaching the durability limits of the eutectic solder. The tin-rich, lead-free solders are being actively studied as alternate alloys. Experiments that examined the wettability of 95Sn-5Sb (wt. %), 95.5Sn-4.0Cu0.5Ag, 96.5Sn-3.5Ag, and the control solder, 60Sn-40Pb, on oxygen-free, high conductivity copper were performed. A rosin based, mildly activated (RMA) flux and three water soluble, organic acid fluxes were used in the wetting balance/meniscometer measurements. The 95.5Sn-4.0Cu-0.5Ag and 95Sn-5Sb alloys exhibited good wetting, with contact angles of 35° < θc < 55° as compared to the excellent performance of the 60Sn-40Pb material (20°< θc <35°). The fair wettability observed with the 96.5Sn 3.5Ag solder (60° < θc <75°) was due in large part to the inability of the fluxes to significantly lower the solder-flux interfacial tension. The wetting rates of the 95.5Sn-4.0Cu-0.5Ag and 95Sn 5Sb solders were comparable to those of the control; the 96.5Sn 3.5Ag alloy wetting rate was slower than the other candidates. The solder film formed on the substrate surface by the 95.5Sn-4.0Cu0.5Ag alloy was very grainy. The water soluble fluxes exhibited a larger degree of residue formation than did the RMA flux.

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A parabolized Navier-Stokes analysis of wake/boundary-layer flow along a cable in tow

22nd Fluid Dynamics, Plasma Dynamics and Lasers Conference

Barnette, Daniel

A parabolized Navier-Stokes analysis of a turbulent, compressible, wake/boundary-layer flow field for a cable in tow is discussed. It is assumed that the cable is being towed by a missile-like configuration whose total drag coefficient is known. The cable is assumed to be perfectly aligned with the missile axis and is subjected to its wake. Modeled in the analysis is the far wake behind the missile, coupled with the turbulent boundary layer growth along the cable. An analytical starting solution for a parabolized Navier-Stokes code is presented. The starting solution is applicable downstream of the towing body's near wake and, therefore, circumvents the complex task of computing the towing body's flow field. An algebraic wake/boundary-layer turbulence model is used to simulate turbulent flow in both the decaying wake and growing boundary layer along the cable. Results are presented for a towing-body freestream Mach number of 5 and a Reynolds number of 36.0 x 106 per ft at select distances along a thin cable.

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A vortex panel method for calculating aircraft downwash on parachutetrajectories

11th Aerodynamic Decelerator Systems Technology Conference

Fullerton, T.L.

Parachute system performance issues such as turnover and wake recontact may be influenced by velocities induced by the wake of the delivering aircraft. The magnitude and direction of these aircraft-induced velocities is dependent on the specific delivering aircraft (as characterized by its size, shape, and weight), the aircraft’s speed and flight path (including any maneuvers which it is performing), and the location on the aircraft from which the system is released. In addition, the parachute deployment sequence is of major importance. The most significant effects will tend to occur after parachute deployment since induced velocities from the aircraft may become significant when compared to the velocity of the parachute system. For example, any downwash behind an aircraft will tend to cause a parachute system, which is horizontally deployed, to fly at a more positive angle of attack. As the forward speed of the parachute system decreases after deployment, this induced angle of attack will tend to increase. This effect tends to retard the rate at which the parachute system “turns over” from a horizontal trajectory into a vertical one. On the other hand, a maneuvering aircraft might produce upwash in its wake which would produce an opposite effect. In this case, the turnover rate would be enhanced. Aircraft-induced velocities may also affect the process known as “wake recontact” in which the momentum of the parachute wake causes the wake itself to overtake the parachute. This sometimes causes severe collapse of the canopy such as reported by Spahr and Wolf. Wake recontact may be either hastened or delayed, depending upon the aircraft flight path and the parachute deployment sequence

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An introduction to testing parachutes in wind tunnels

AIAA Journal

Macha, John M.

This paper reviews some of the technical considerations and current practices for testing parachutes in conventional wind tunnels. Special challenges to the experimentalist caused by the fabric construction, flexible geometry, and bluff shape of parachutes are discussed. In particular, the topics of measurement technique, similarity considerations, and wall interference are addressed in a summary manner. Many references are cited which provide detailed coverage of the state of the art in testing methods.

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The Fire Performance of Aged Electrical Cables

Nowlen, Steven P.

Sandia National Laboratories has performed a series of experiments under the sponsorship of the US Nuclear Regulatory Commission (USNRC) to assess the fire performance of thermally aged electrical cables. Two measures of fire performance were evaluated, namely, (1) the vulnerability of cables to thermal damage and (2) the flammability of cables. In each case, direct comparisons were made between experiments involving unaged (i.e., new off the reel) cables and cables subjected to accelerated thermal aging. The results were evaluated from the perspective of fire risk. It was found that thermal aging did cause changes in the thermal damageability of the cables tested; however, the changes observed are not considered risk significant. Large-scale fire tests demonstrated a clear decrease in material flammability due to thermal aging. Thus, it was concluded that the use of cable thermal damage and flammability information based on the testing of unaged cable samples is an acceptable risk assessment practice. Indeed, in the case of flammability, this is a conservative practice.

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The implementation of a standards based heterogeneous network

Tolendino, Lawrence F.

Computer networks, supporting an organization's activities, are prevalent and very important to the organization's mission. Implementing a heterogenous organizational network allows the staff to select the computing environment that best supports their job requirements. This paper outlines the lessons learned implementing a heterogenous computer network based on networking standards such as TCP/IP and Ethernet. Such a network is a viable alternative to a proprietary, vendor supported network and can provide all the functionality customers expect in a computer network. 2 figs.

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Experimental results of direct containment heating by high-pressure melt ejection into the Surtsey vessel: The DCH-3 and DCH-4 tests

Allen, Mark S.

Two experiments, DCH-3 and DCH-4, were performed at the Surtsey test facility to investigate phenomena associated with a high-pressure melt ejection (HPME) reactor accident sequence resulting in direct containment heating (DCH). These experiments were performed using the same experimental apparatus with identical initial conditions, except that the Surtsey test vessel contained air in DCH-3 and argon in DCH-4. Inerting the vessel with argon eliminated chemical reactions between metallic debris and oxygen. Thus, a comparison of the pressure response in DCH-3 and DCH-4 gave an indication of the DCH contribution due to metal/oxygen reactions. 44 refs., 110 figs., 43 tabs.

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Manual of analytical methods for the Industrial Hygiene Chemistry Laboratory

Greulich, K.A.

This Manual is compiled from techniques used in the Industrial Hygiene Chemistry Laboratory of Sandia National Laboratories in Albuquerque, New Mexico. The procedures are similar to those used in other laboratories devoted to industrial hygiene practices. Some of the methods are standard; some, modified to suit our needs; and still others, developed at Sandia. The authors have attempted to present all methods in a simple and concise manner but in sufficient detail to make them readily usable. It is not to be inferred that these methods are universal for any type of sample, but they have been found very reliable for the types of samples mentioned.

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Technology transfer in the national laboratories

Yonas, Gerold

The title of this paper might unfairly provoke readers if it conjures up visions of vast stores of high-tech gadgets in several hundred technology warehouses'' (also known as federal laboratories) around the country, open for browsing by those in search of a bargain. That vision, unfortunately, is a mirage. The term technology transfer'' is not really as accurate as is the term technology team-work,'' a process of sharing ideas and knowledge rather than widgets. In addition, instead of discussing the efforts of more than 700 federal labs in the US, I mean to address only those nine government-owned, contractor-operated multiprogram labs run by the Department of Energy. Nevertheless, the topic of technology team-work opportunities with DOE multiprogram national lab is of significance to those concerned with increasing economic competitiveness and finding technological solutions to a host of national problems. A significant fraction of US R D capabilities rests in the nine DOE multiprogram national laboratories -- and these labs have only just begun to join the other federal laboratories in these efforts due to the passage and recent implementation of the National Competitiveness Technology Transfer Act of 1989.

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Thermal analysis report of the SANDAC V processor module

Nelson, N.M.

The case and junction temperatures of selected integrated circuits (ICs) on the processor module of the SANDAC V computer were calculated using BETAsoft-R,'' a personal computer, thermal analysis software program. The predicted data was then compared to corresponding IC case temperature measurements from laboratory tests of a functional SANDAC V computer. Although the difference between the actual and calculated values was somewhat higher than expected, the results of the analysis indicate that BETAsoft-R'' identified the critical ICs on the processor module and that it is capable of analyzing printed circuit boards for potential thermal problems before the design layout is finalized. 8 figs., 12 tabs.

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A Sandia telephone database system

Tolendino, Lawrence F.

Sandia National Laboratories, Albuquerque, may soon have more responsibility for the operation of its own telephone system. The processes that constitute providing telephone service can all be improved through the use of a central data information system. We studied these processes, determined the requirements for a database system, then designed the first stages of a system that meets our needs for work order handling, trouble reporting, and ISDN hardware assignments. The design was based on an extensive set of applications that have been used for five years to manage the Sandia secure data network. The system utilizes an Ingres database management system and is programmed using the Application-By-Forms tools.

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Electrical characterization of rf plasmas

Miller, Paul A.

Radio-frequency (rf) electrical sources are commonly used to generate plasmas for processing of industrial materials and for related experimental work. Published descriptions of such plasmas usually include generator-power measurements, and occasionally include plasma dc-bias measurements. One or both of these quantitites are also used in industrial feedback ccontrol systems for setpoint regulation. Recent work at Sandia an elsewhere with an experimental rf discharge device (the GEC RF Reference Cell'') has shown that power and dc-bias levels are often insufficient information for specifying the state of the plasma. The plasma can have nonlinear electrical characteristics that cause harmonic generation, and the harmonic levels can depend sensitively on the impedance of the external circuitry at harmonic frequencies. Even though the harmonics may be low in amplitude, they can be directly related to large changes in plasma power and to changes in optical emission from the plasma. Consequently, in order for a worker to truly master the plasma-generation process, it is necessary to understand, measure, and control electrical characteristics of the plamsa. In this paper we describe technique that have been developed from work with the Reference Cell for making electrical measurements on rf plasmas, and we describe surprising observations of harmonic behavior. 10 refs., 4 figs.

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Interim report on conversion of coal to liquids via catalytic hydropyrolysis

Klavetter, E.A.; Salgado, L.V.

The catalytic hydropyrolysis tests performed on coals of varying rank clearly show that high conversions and tar yields can be achieved in a fixed-bed laboratory reactor system. Each of the three types of catalysts utilized, MoS{sub 2} derived from dioxydithiomolybdate, the metal HTO catalysts, and the Pd colloidal catalysts, were shown to be effective for the bituminous coals tested. For the lower rank coals, no significant increase in conversions or tar yields preliminary tests utilizing oil agglomeration as a pretreatment provided encouraging results, with conversions and tar yields achieved similar to using the metal HTO and colloid catalysts. This pretreatment process might be effective for use in catalyst dispersal and coal cleaning, and facilitating coal introduction into a high-pressure reactor. In summary, the data obtained show that catalytic hydropyrolysis on a laboratory scale can achieve the necessary conversions and tar yields to be considered as a potentially viable process for converting coal into liquid products. Through proper dispersal of selected catalysts onto bituminous coals, conversions greater than 80% and tar yields greater than 70% can be achieved at low active metal concentrations. 12 refs., 9 figs., 7 tabs.

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A review of the South Texas Project probabilistic safety analysis for accident frequency estimates and containment binning

Wheeler, Timothy A.

The objective of this review is to evaluate the South Texas Project (STP) Probabilistic Safety Analysis (PSA) for the USNRC. The PSA was reviewed for thoroughness of analysis, accuracy in plant modeling, legitimacy of assumptions, and overall quality of the work. The review is limited to the internal event analysis and the fire sequence analysis. This review is not a quantitative evaluation of the adequacy of the PSA. The adequacy of the PSA depends on the intended uses and must be addressed on a case-by-case basis by the licensee and the NRC. This review identifies strengths, weakness, and areas where additional clarification would assist the NRC in evaluating the PSA for specific regulatory purposes. The licensee, Houston Lighting and Power (HL P), reviewed a draft version of this report prior to its final release to the USNRC. The responses provided by HL P are provided in detail in appendices to this report, and they are summarized in the main body of the report. All issues raised during the review were adequately addressed by HL P in the responses. 27 refs., 4 tabs.

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Interpretation of brine-permeability tests of the Salado Formation at the Waste Isolation Pilot Plant site: First interim report

Beauheim, Richard L.

Pressure-pulse tests have been performed in bedded evaporites of the Salado Formation at the Waste Isolation Pilot Plant (WIPP) site to evaluate the hydraulic properties controlling brine flow through the Salado. Hydraulic conductivities ranging from about 10{sup {minus}14} to 10{sup {minus}11} m/s (permeabilities of about 10{sup {minus}21} to 10{sup {minus}18} m{sup 2}) have been interpreted from nine tests conducted on five stratigraphic intervals within eleven meters of the WIPP underground excavations. Tests of a pure halite layer showed no measurable permeability. Pore pressures in the stratigraphic intervals range from about 0.5 to 9.3 MPa. An anhydrite interbed (Marker Bed 139) appears to be one or more orders of magnitude more permeable than the surrounding halite. Hydraulic conductivities appear to increase, and pore pressures decrease, with increasing proximity to the excavations. These effects are particularly evident within two to three meters of the excavations. Two tests indicated the presence of apparent zero-flow boundaries about two to three meters from the boreholes. The other tests revealed no apparent boundaries within the radii of influence of the tests, which were calculated to range from about four to thirty-five meters from the test holes. The data are insufficient to determine if brine flow through evaporites results from Darcy-like flow driven by pressure gradients within naturally interconnected porosity or from shear deformation around excavations connecting previously isolated pores, thereby providing pathways for fluids at or near lithostatic pressure to be driven towards the low-pressure excavations. Future testing will be performed at greater distances from the excavations to evaluate hydraulic properties and processes beyond the range of excavation effects.

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Direct optical phase shifter for phased-array systems

Proceedings of SPIE - The International Society for Optical Engineering

Vawter, G.A.; Hietala, Vincent M.; Kravitz, Stanley H.; Meyer, W.J.

An all optical circuit in GaAs/AlGaAs for control of phased-array systems using a single photonic integrated circuit chip has the potential for high performance control of phasedarray systems from a small, lightweight, package. Such a circuit based exclusively on combinations of reverse-biased optical phase modulators, waveguide interconnects, corner reflectors, and power splitter combiners with optical-fiber output to the antenna elements has been designed at Sandia National Laboratories. This paper presents some basic features of optical phase modulators for photonic circuit applications and provide relevant performance data as achieved to date. Current structures have been shown to operate with a 76.5°/V-mm figure of merit at 1.06μm and losses as low as 2 cm-1. A novel digital phase shifter to allow direct digital control of phased arrays is also proposed and demonstrated.

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Phased-array antenna control by a monolithic photonic integrated circuit

Proceedings of SPIE - The International Society for Optical Engineering

Hietala, Vincent M.

A novel optical based RF beam steering system is proposed for phased-array antenna systems. The system, COMPASS (Coherent Optical Monolithic Phased Array Steering System), is based on optical heterodyning employed to produce microwave phase shifting. At the heart of the system is a monolithic Photonic Integrated Circuit (PIC) constructed entirely of passive components. Microwave power and control signal distribution to the antenna is accomplished by optical fiber, thus separating the PIC and its control functions from the antenna. This approach promises to reduce size, weight, and complexity of future phased-array antenna systems.

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Modifications of the PRONTO 3D finite element program tailored to fast burst nuclear reactor design

Oscar, Debby S.

This update discusses modifications of PRONTO 3D tailored to the design of fast burst nuclear reactors. A thermoelastic constitutive model and spatially variant thermal history load were added for this special application. Included are descriptions of the thermoelastic constitutive model and the thermal loading algorithm, two example problems used to benchmark the new capability, a user's guide, and PRONTO 3D input files for the example problems. The results from PRONTO 3D thermoelastic finite element analysis are benchmarked against measured data and finite difference calculations. PRONTO 3D is a three-dimensional transient solid dynamics code for analyzing large deformations of highly non-linear materials subjected to high strain rates. The code modifications are implemented in PRONTO 3D Version 5.3.3. 12 refs., 30 figs., 9 tabs.

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Ceramic coatings on package lids for radiation protection

Garino, T.J.; Reber, C.A.; Fleetwood, D.M.

A study was conducted to determine the feasibility of coating gold plated kovar lids with colloidally bonded aluminum oxide. Radiation that is incident on a gold plated lid generates a large number of photoelectrons. These electrons can enhance the damage to microelectronic devices and circuits (ICs). The primary purpose of the coating is to stop the electrons emitted from the lid that would otherwise increase the damage to the IC. A coating system consisting of {approximately}95 wt % alumina (0.5 {mu}m particles) and {approximately}5 wt % colloidal silica (10 nm particles) was developed. The coating was applied to the lids as an aqueous suspension which was then dried to form a porous coating. Coating processing conditions were optimized so that crack-free, uniform coatings with the required thickness ({approximately}80 {mu}m) could be consistently produced. Preliminary data have indicated that the coated lid can be attached to the IC package using current belt furnace sealing procedures. The adhesion and mechanical integrity of the coatings were evaluated by submitting coated lids to centrifuge and shock testing. Selected coatings successfully withstood the shock test and 85% were undamaged after being subjected to an acceleration of 30,000 g's. Several types of radiation tests were performed to determine the effectiveness of the coating to stop electron penetration. Evaluation testing included gamma dose enhancement and X- ray induced photocurrent enhancement. The results for lids with coatings 80 or 150 {mu}m thick were compared with results for uncoated kovar and ceramic lids. 6 refs., 6 figs.

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Sandia severe electrostatic discharge tester: Version 3 (SSET), Serial Number: 1

Barnum, John R.

This report documents the as-built operational performance of Sandia's Severe Electrostatic Discharge Tester Version-3 (SSET-3) SN:2 and lists the hardware and additional documentation delivered to Division 2174 on July 31, 1991. (The supplied items are listed.) The primary emphasis of this report is to provide a qualitative and quantitative evaluation of the SSET against requirements derived from the Severe Human Body ESD model (SHBESD) (1), which is defined in terms of an equivalent circuit (Figure 1.1) and a short-circuit current waveform (Figure 1.2). This report also presents supporting information on the calibration and verification of ancillary equipment used to assess the operation of the SSET. While the documentation of the verification and calibration of ancillary equipment is somewhat lengthy, it is considered necessary because the SSET may be used in situations where its output characteristics will be critically scrutinized. Thus, the supporting documentation is necessary to lend credibility to the performance/verification measurements made on the SSET. 5 refs., 36 figs.

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1991 DOE/Sandia Crystalline Photovoltaic Technology Project Review Meeting

Whipple, M.L.

This document serves as the proceedings for the manual project review meeting held by Sandia's Photovoltaic Technology Research Division. It contains information supplied by each organization making a presentation at the meeting, which was held July 30 through 31, 1991 at the Sheraton Hotel in Albuquerque, New Mexico. Sessions were held to discuss national photovoltaic programs, one-sun crystalline silicon cell research, concentrator silicon cell research, and concentrating collector development.

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Proof-of-Concept Advanced Nonpyrotechnic Smoke Generator Component Test Report

Greenholt, Charles J.

One decade ago, Sandia National Laboratories designed and developed a nonpyrotechnic smoke generator capable of producing large quantities of low corrosivity, low toxicity chemical smoke to be used as a visual obscurant in access delay applications. Utilizing the same chemistry, a proof-of-concept advanced smoke generator is presently being tested. The testing is being conducted to evaluate two new concepts providing unique capabilities. Hemispherical stainless steel bladders are installed in spherically shaped chemical storage reservoirs. This provides positive displacement of the chemicals and permits orientation insensitive operation. Also, a specially designed nozzle/valve is being evaluated as a means of providing a multiple initiation capability. Cyclic operation could be accomplished via time delay circuitry, sensor input, or on demand from the control console. These new capabilities provide distinct advantages. Some advantages may be longer obscuration times, optimal volume obscuration, easier facility sizing, no organic seals in contact with the stored chemicals, and elimination of the requirement to use ultrahigh purity nitrogen as a propellant.

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Design and testing of three-level optimal correlation filters

Proceedings of SPIE - The International Society for Optical Engineering

Stalker, K.T.

Previously, we have designed 3-level filters (suitable for implementation on magneto-optic spatial light modulators) to maximize the output signal-to-noise ratio (SNR) and to separately maximize Peak-to-Correlation Energy (PCE) that measures the correlation peak sharpness. In practice, we want the correlation peaks to be sharp (i.e., large PCE) as well as noise-tolerant (i.e., large SNR). In this paper, we will present a new method to optimally combine these two desirable properties into a single optimization procedure. Similar methods to trade off SRN versus Peak Efficiency and PCE versus Peak Efficiency will be presented. Both simulation and experimental results will be included.

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Steam Explosions of Single Drops of Core-Melt Simulants: Triggering, Work Output and Hydrogen Generation

Nelson, L.S.; Hyndman, D.A.; Duda, P.M.

We have studied triggering of fuel-coolant interactions, the work performed against the surrounding coolant during the interaction, and the generation of hydrogen produced by melt water chemical reactions with laboratory-scale experiments. We used single drops of three core-melt simulants: (a) molten stoichiometric thermite-generated iron-aluminum oxide melts to simulate the core-melt material that might be produced in the severe accident of an oxide fueled reactor; (b) molten aluminum to simulate melt that might be produced in the severe accident of a nonpower reactor; and (c) an intermediate material, aluminum-enriched iron aluminum oxide thermite, that might simulate severe meltdown of an oxide-metal dispersion fuel (cermet). As a result of these experiments, we have concluded that the peak pressure (or impulse) of the transient is not a governing parameter for the triggering of steam explosions of single drops of melt. We have observed maximum pressure-volume work outputs produced by the aluminum-rich and stoichiometric thermite melts of about 70 and 25 J/g of melt; the corresponding values for molten aluminum at 1273 and 1473 K are about 14 and 21 J/g of melt. The extent of metal-water reaction for the stoichiometric and aluminized melts were 13 and 19%. The aluminum melts at 1273 and 1473 K produced approximately 1 and 3% metal-water reaction.

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Shock wave codes at Sandia National Laboratories [Book Chapter]

Shock Waves

Mcglaun, M.

Sandia National Laboratories is very active in developing multi-dimensional, multi-material shock wave physics codes. One example is the state-of-the-art, three-dimensional Eulerian code CTH which is used at numerous government and university sites. CTH is being ported to both Single Instruction Multiple Data (SIMD) and Multiple Instruction Multiple Data (MIMD) massively parallel computers. The next-generation arbitrary-Lagrangian-Eulerian code RHALE is under development. This paper will discuss these codes. CTH is an Eulerian code for modelling multi-dimensional, multi-material, large deformation, strong shock physics. Finite-volume numerical schemes are used with one-dimensional, two-dimensional and three-dimensional meshes. CTH has models for elastic-plastic materials, porous materials, high explosive detonation, fracture, and energy deposition. Several analytic equations of state are available including ideal gasses, Jones-Wilkins-Lee high explosive reaction products, Mie-Griineisen solids, and sophisticated multi-phase models that are valid for a very broad range of densities and temperatures. Tabular equations of state are also available. Second-order accurate advection schemes are used to minimize the dispersion found in Eulerian codes. Very large three-dimensional calculations may be run efficiently on a CRAY supercomputer because the code is highly vectorized and the data bases reside on the Solid State Disk (SSD). Data bases larger than one hundred million words are commonly used. Sophisticated color post-processing software was developed to aid in interpreting the results. Much of CTH has been ported to both SIMD and MIMD massively parallel computers. The two-dimensional version is running three times faster than a single CPU CRAY/YMP on the 16k node SIMD Connection Machine and five times faster on the 1024 node nCUBE2 MIMD computer. Both of the massively parallel computers can be expanded by a factor of four to eight yielding a system an order of magnitude faster than a CRAY. The next-generation, three-dimensional arbitrary-Lagrangian-Eulerian code RHALE is under development. Finite element techniques are used to integrate the physics through time. The mesh will move with the material (Lagrangian mesh) until the distortion becomes excessive and then the nodes are automatically repositioned to smooth the mesh and improve the accuracy (Eulerian mesh). Node motion occurs only where the distortion is excessive. This results in a code with the best features of both Lagrangian and Eulerian codes. Arbitrary-connectivity meshes are used to generate very complicated and sophisticated meshes. However, this dramatically increases the complexity of the Eulerian algorithms.

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Hypervelocity Impact Jet Formation [Book Chapter]

Shock Compression of Condensed Matter–1991

Ang, James A.

The hypervelocity impact of a particle on a surface generates a jet of shocked material which is thrown from the impact site. A simple analytic model has been developed to obtain expressions for the evolution of this jet of ejecta. The analysis is based on applying the conservation equations of mass and momentum to the problem of a normal impact of a sphere against a semi-infinite flat target. Expressions are developed for the evolution of the jet velocity, jet release point and the locus of points which describe the ejecta envelope. These analytical ejecta profiles are compared with high speed photographs of impact jet formation.

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Converting a commercial electric direct-drive robot to operate from joint torque commands

Muir, P.F.

Many robot control algorithms for high performance in-contact operations including hybrid force/position, stiffness control and impedance control approaches require the command the joint torques. However, most commercially available robots do not provide joint torque command capabilities. The joint command at the user level is typically position or velocity and at the control developer level is voltage, current, or pulse-width, and the torque generated is a nonlinear function of the command and joint position. To enable the application of high performance in-contact control algorithms to commercially available robots, and thereby facilitate technology transfer from the robot control research community to commercial applications, an methodology has been developed to linearize the torque characteristics of electric motor-amplifier combinations. A four degree of freedom Adept 2 robot, having pulse-width modulation amplifiers and both variable reluctance and brushless DC motors, is converted to operate from joint torque commands to demonstrate the methodology. The commercial robot controller is replaced by a VME-based system incorporating special purpose hardware and firmware programmed from experimental data. The performance improvement is experimentally measured and graphically displayed using three-dimensional plots of torque vs command vs position. The average percentage torque deviation over the command and position ranges is reduced from as much as 76% to below 5% for the direct-drive joints 1, 2 and 4 and is cut by one half in the remaining ball-screw driven joint 3. Further, the torque deviation of the direct-drive joints drops below 2.5% if only the upper 90% of the torque range is considered. 23 refs., 20 figs., 2 tabs.

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Interim report on the effects of brine-saturation and shear stress on consolidation of crushed, natural rock salt from the Waste Isolation Pilot Plant (WIPP)

Zeuch, David H.

The mechanical behavior of crushed natural rock salt is of concern to the Waste Isolation Pilot Plant (WIPP) Project because excavated salt is a candidate material for use as backfill around the waste packages and in storage rooms, shafts and other underground openings. To complement existing studies on the compaction behavior of dry and damp (i.e., unsaturated) crushed rock salt under hydrostatic compression, we initiated an extensive experimental program to evaluate (1) the effect of brine-saturation on the consolidation rates and terminal densities of crushed salt subjected to hydrostatic compression, and (2) the influence of small deviatoric stresses on the consolidation rate damp crushed rock salt. This investigation is incomplete, and laboratory facilities are limited, therefore, in this report we review available results, in order to make available preliminary estimates of the effects of brine-saturation and shear stress on consolidation. Experiments with brine were carried out under nominally drained conditions. Experiments completed to data include five hydrostatic compaction tests on brine-saturated samples, run at pressures ranging from 1.72 to 10.34 MPa, and two prototype shear consolidation experiments run at a mean stress of 3.45 MPa and a stress difference of 0.69 MPa. Both sets of experiments were run at 20{plus minus}0.5 {degrees}C. Although the experiments on brine-saturated crushed rock salt exhibit several discrepancies, we can draw the following conclusions. (1) Though effects associated with brine-saturated apparently have a retarding effect on consolidation, rates are reduced by less than an order of magnitude when compared with unsaturated specimens. Despite saturation, high fractional densities (>0.95) are attainable even on laboratory time scales using pressures well below lithostatic at the WIPP ({approx} 15 MPa). 23 refs., 26 figs., 5 tabs.

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Merlin 2 - A computer program to transfer solution data betwwen finite element meshes

Gartling, David K.

The MERLIN 2 program is designed to transfer data between finite element meshes of arbitrary geometry. The program is structured to accurately interpolate previously computed solutions onto a given mesh and format the resulting data for immediate use in another analysis program. Data from either two-dimensional or three-dimensional meshes may be considered. The theoretical basis and computational algorithms used in the program are described and complete user instructions are presented. Several example problems are included to demonstrate program usage. 13 refs. 15 figs.

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Reference manual for the CONTAIN 1. 1 code for containment severe accident analysis

Washington, Kenneth

This report describes the phenomenological equations and the numerical procedures used by the CONTAIN 1.1 code to determine the conditions within nuclear power plant containment during a severe accident. The CONTAIN detailed models provide the capability to mechanistically calculate the containment internal thermalhydraulic conditions and the amount of radioactive matter that would be released to the environment if there were a leak from the containment. Note that the CONTAIN models can be verified by comparing the code calculations to experimental results. The models described include those to account for the flows of mass and energy between containment compartments, the exchange of energy between the atmosphere and heat structures, the thermodynamic conditions, the distributions of aerosols, the decay and transport of fission products, the deflagration of hydrogen and carbon monoxide, boiling water reactor suppression pool behavior, and engineering safety features, including a spray, fan coolers, and an ice condenser. These models are solved with implicit coupling, where appropriate, to obtain a stable and computationally efficient solution. 52 refs., 36 figs., 9 tabs.

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Primary standards laboratory report 2nd half 1990

Braudaway, D.W.

The Primary Standards Laboratory (PSL) operates a system-wide primary standards and calibration program for the US Department of Energy, Albuquerque Operations Office (DOE/AL). The PSL mission is as follows: to develop and maintain primary standards; to calibrate electrical, physical, and radiation reference standards for customer laboratories (DOE/Al integrated contractors); to conduct technical surveys and audits of these laboratories; and to recommend and implement system-wide improvements. This report summarizes activities of the PSL for the second half of 1990 and provides information pertinent to the operation of the DOE/AL Standards and Calibration Program. Specific areas covered include development projects, improvement projects, calibration and special measurements, surveys and audits, and significant events. Activities in these areas have been at a lower than normal level because of response to increased Environment, Safety, and Health (ES H) concerns and preparation for a Tiger Team visit. Appendices include certifications and reports, commercial calibration laboratories, PSL memoranda, and National Institute of Standards and Technology ((NIST)--formerly the National Bureau of Standards (NBS)) test numbers.

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The SolarTrak solar array tracking controller

Maish, Alexander B.

Sandia National Laboratories has developed an advanced self-contained tracking control system for use with one- or two-axis tracking solar arrays. The SolarTrak system computes the sun's position based on the time and stored position data, and then controls two motors to point the tracker at the sun without using sun sensors. When used with a photovoltaic concentrator array, the system initially performs a self-alignment routine using array-generated current to locate the sun. The routine computes six numbers that are used during the normal operation to correct the array pointing for the tracker's installation misalignment. This enables the tracker to point accurately even with installation misalignments of up to several degrees. The SolarTrak system consists of a control board, which contains a Motorola 68HC11 microcontroller, a power supply board, motor-interface boards, and a hand-held user interface board, which contains a liquid-crystal display and an input keypad. This report contains a thorough discussion of the controller software and hardware, including control algorithms, parts lists and estimated costs (about $300 per system). The performance measured on two trackers is reviewed. Tracking accuracy was better than {plus minus}0.1{degrees} over a full day on one system. A thorough user's manual is included. Companies interested in licensing the technology should contact the Technology Transfer Division of Sandia National Laboratories. 20 refs., 53 figs., 5 tabs.

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Summary of WIPP Room B heater test brine and backfill material data

Krumhansl, James L.

Simulated DHLW (Defense High Level Waste) package performance tests were carried out at the WIPP (Waste Isolation Pilot Plant) by emplacing a number of waste canisters containing electrical heaters into the floor of the mine. Peak temperatures were about 130{degrees}C, and the tests ran for three years. During this time, an unanticipated large amount of water was collected from heater hole BO42. A study was, therefore, undertaken to determine if this fluid was derived from normal weep brines. This was accomplished by comparing the amount of salt deposited by the dried weep brines with the volume of condensed steam collected during the test. Documenting the post-test condition of the various backfills was the other objective of this report. In spite of being exposed to acidic vapors, the bentonite-sand backfill retained its mineralogic integrity. However, the bentonite-sand backfill compacted between the canister and the wall only achieved a density that was about three quarters that of a pore-free material. The bentonite backfill also showed evidence of hair-line cracks through which steam had left the vicinity of the canister. In contrast, compacted crushed salt backfill exhibited no evidence of through-going cracks and was compacted to better than 99% of that of pure nonporous sodium chloride. Thus, the seal provided by a crushed salt backfill appears to be superior to that provided by bentonite. 13 refs., 6 tabs.

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Human factors engineering design guidelines for the software user interface

Allen, H.W.

This report provides system designers with basic human factors information and guidelines for designing and developing the software user interface. A brief discussion of the user interface design philosophy is presented, followed by an overview of the user interface options available (such as color and highlighting), candidate approaches, and discussion of general display concepts and user interface features. We have presented information to facilitate discussions of user interface options, to aid in making final user interface design decisions, and to further the refinement of the user interface. We provide a candidate questionnaire for evaluating your software user interface. 41 refs., 3 tabs.

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Numerical simulation of a split cavity oscillator and rf conversion

Lemke, Raymond W.

We have conducted an extensive investigation of the split cavity oscillator (SCO) using particle-in-cell simulation. The goal of this work is to test and optimize an inverse diode rf convertor for use with a cylindrical SCO, while simultaneously determining factors that control rf extraction efficiency. We present results from simulations of several configurations including the SCO with inverse diode extractor, the SCO in conjunction with post-acceleration and inverse diode extraction, and the SCO, using electron beams with a variety of currents, voltages, and radii. 7 refs., 8 figs.

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Technology assessment of ambient temperature rechargeable lithium batteries for electric vehicle applications

Doddapaneni, N.

This report presents an assessment of ambient temperature rechargeable lithium batteries for electric vehicle applications. It was prepared for the Department of Energy, Office of Propulsion Systems. The status of development programs in industry and research laboratories was determined for several positive and negative electrode materials and for organic liquid and solid polymer electrolytes. Recommendations are suggested for future research and development activities. 217 refs.

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Approximate treatment of a strong explosion and expansion in a near vacuum

Thornton, A.L.

The hydrodynamic blast created by the initiation of a 1 kev X-ray source from an arc-induced ionized gas column, involves density and temperature ratios of such magnitude that the strong shock theory of propagation from continuum fluid mechanics does not apply. Because these simulations occurs in a near vacuum, the continuum equations of motion break down and become invalid during the expansion process as the wavefront density decreases. This report summarizes an approximate treatment of the hydrodynamics of a strong explosion followed by an expanding wavefront in a near vacuum. The analysis was performed in support of the Saturn program to assist the test engineers in the design of a shroud which is optimized to receive the maximum cold X-ray radiation through its aperture while minimizing the hydrodynamic damage to the rest specimens. The analytical treatment uses mass conversion and the assumption of a liner velocity profile to assess the dynamic behavior of the developing wavefront. This technique provides a first estimate of the gas motion and pressure pulse and indicates some general trends of the hydrodynamic phenomenon. 9 refs., 16 figs., 1 tab.

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The feasibility of testing NASA's SCAD concentrator on earth

Mancini, Thomas R.

NASA has proposed that the solar concentrator for the manned space station, referred to as the Solar Concentrator Advanced Development (SCAD) dish, undergo terrestrial testing prior to being deployed in space. Because reliable flight concentrator performance is so important, independent tests of the SCAD concentrator are needed to demonstrate the offset parabolic concept and validate the computer codes needed for predicting concentrator flux profile and power generating capability. This report documents the first phase of a three-phase project to test the SCAD concentrator on sun. The three phases of the project are (1) Feasibility of On-Sun Testing; (2) Detailed Design and Fabrication of Test Fixtures; and (3) Testing and Analysis of Results. The objectives of Phase 1 are to evaluate the feasibility of testing the concentrator on sun in a terrestrial environment and to determine the potential for accurately predicting its performance in space. The feasibility study includes: an evaluation of terrestrial structures to support and track the concentrator; an assessment of methods for protecting the concentrator from the environment when it is not on test; the selection of the most feasible support structure and protection system; an evaluation of the effects of terrestrial solar power levels and sunshapes on the verification of computer codes for predicting the on-orbit performance of the concentrator; the development of a preliminary test plan complete with procedures and instrumentation; and the development of schedule and cost estimates for Phases 2 and 3 of the project.

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Analyzing photographically recorded atomic emission spectra using an automated densitometer

Hareland, W.A.

This report describes a computer-controlled densitometer and software designed for qualitative and semiquantitative analyses of photographically recorded atomic emission spectra. The instrument provides a number of operational features and unique capabilities for spectrochemical analyses. The purpose of this research was the evaluation of the automated densitometer system and computer algorithms for identifying and measuring atomic emission spectra from photographs. 11 refs., 10 figs., 5 tabs.

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Structure of icosahedral borides by Raman spectroscopy

AIP Conference Proceedings

Tallant, David R.

We have obtained Raman spectra of icosahedral boron-rich solids. The spectra of α-rhombohedral boron, boron arsenide, and boron phosphide are consistent with highly-ordered materials. Polarization studies have resulted in symmetry assignments for most of the Raman bands of α-rhombohedral boron. In contrast, the Raman spectra of the boron carbides reveal local substitutional disorder. They also change progressively as a function of carbon content. A structural model for the boron carbides has been developed to explain the Raman and infrared absorption spectra, x-ray data, and electrical and thermal transport properties. Raman spectra of boron carbide samples enriched in 10B, 11B, and 13C reveal details of the atomic motions. The vibrational frequencies and exceptionally narrow linewidths of certain Raman modes are discussed in terms of a ‘‘strong’’ bond model. In this model certain vibrational modes involving relatively stiff bonds between chain atoms, chain and icosahedral atoms, and atoms on different icosahedra are decoupled from the boride lattice by weak, intraicosahedral bonds.

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In situ measurements of rock salt permeability changes due to nearby excavation

Stormont, John C.

The Small-Scale Mine-By was an in situ experiment to measure changes in brine and gas permeability of rock salt as a result of nearby excavation. A series of small-volume pressurized brine- and gas-filled test intervals were established 8 m beneath the floor of Room L1 in the WIPP underground. The test intervals were isolated in the bottom of the 4.8-cm diameter monitoring boreholes with inflatable rubber packers, and are initially pressurized to about 2 MPa. Both brine- and gas-filled test intervals were located 1.25, 1.5, 2, 3, and 4 r from the center of a planned large-diameter hole, where r is the radius of the large-diameter hole. Prior to the drilling of the large-diameter borehole, the responses of both the brine- and gas-filled test intervals were consistent with the formation modeled as a very low permeability, low porosity porous medium with a significant pore (brine) pressure and no measurable gas permeability. The drilling of the mine-by borehole created a zone of dilated, partially saturated rock out to about 1.5 r. The formation pressure increases from near zero at 1.5 r to the pre-excavation value at 4 r. Injection tests reveal a gradient of brine permeabilities from 5 {times} 10{sup {minus}18} m{sup 2} at 1.25 r to about the pre-excavation value (10{sup {minus}21} m{sup 2}) by 3 r. Gas-injection tests reveal measurable gas permeability is limited to within 1.5 r. 17 refs., 24 figs., 6 tabs.

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Dual porosity models for solute transport at Yucca Mountain

Dykhuizen, Ronald C.

A fractured porous medium is often modeled as a dual porosity system. The subsystems of fractures and matrix pores are assumed to provide two flow continuums. This is especially true when considering solute transport through such a system. Coupling terms are then required to enable the calculation of the exchange of solute between the two subsystems. The coupling terms for solute transport through a fractured medium are derived in this report. This report then investigates the need for the dual porosity models for solute transport. It is shown that the complexity of a dual porosity model is required in some cases to accurately represent the solute motion. However, it is also shown that some situations can be well represented by approximate single porosity models if certain criteria are met. A single porosity model allows the use of analytical solutions. Sample calculations are presented using parameter values representative of Yucca Mountain tuffs. These calculations show that a dual porosity model is not required to model solute transport at Yucca Mountain if the water fluxes are as low as currently believed. 39 refs., 10 figs., 2 tabs.

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A performance assessment methodology for high-level radioactive waste disposal in unsaturated, fractured tuff

Gallegos, David P.

Sandia National Laboratories, has developed a methodology for performance assessment of deep geologic disposal of high-level nuclear waste. The applicability of this performance assessment methodology has been demonstrated for disposal in bedded salt and basalt; it has since been modified for assessment of repositories in unsaturated, fractured tuff. Changes to the methodology are primarily in the form of new or modified ground water flow and radionuclide transport codes. A new computer code, DCM3D, has been developed to model three-dimensional ground-water flow in unsaturated, fractured rock using a dual-continuum approach. The NEFTRAN 2 code has been developed to efficiently model radionuclide transport in time-dependent velocity fields, has the ability to use externally calculated pore velocities and saturations, and includes the effect of saturation dependent retardation factors. In order to use these codes together in performance-assessment-type analyses, code-coupler programs were developed to translate DCM3D output into NEFTRAN 2 input. Other portions of the performance assessment methodology were evaluated as part of modifying the methodology for tuff. The scenario methodology developed under the bedded salt program has been applied to tuff. An investigation of the applicability of uncertainty and sensitivity analysis techniques to non-linear models indicate that Monte Carlo simulation remains the most robust technique for these analyses. No changes have been recommended for the dose and health effects models, nor the biosphere transport models. 52 refs., 1 fig.

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A boundary integral equation method for steady two-dimensional flow in partially saturated media; Yucca Mountain Site Characterization Project

Martinez, Mario J.

The governing equation for steady flow in a partially saturated, porous medium can be written in a linear form if one adopts a hydraulic conductivity function that is exponential in the capillary-pressure head. The resulting linear field equation is well suited to numerical solution by the boundary integral equation method (BIEM). The exponential conductivity function is compared to a more complex form often assumed for tuffs, and is found to be a reasonable approximation over limited ranges of pressure head. A computer code based on the BIEM is described and tested. The BIEM is found to exhibit quadratic convergence with element size reduction on smooth solutions and on singular problems, if mesh grading is used. Agreement between results from the BIEM code an a finite-element code that solves the fully nonlinear problem is excellent, and is achieved at a substantial advantage in computer processing time. 26 refs., 23 figs., 8 tabs.

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Proposed extensions of United States fundamental and derived standards for high-level and transuranic radioactive waste disposal

Klett, R.D.

The development of the present United States standards for transuranic and high-level waste fundamental criteria, derived release limits, and risk limits for probabilistic releases is traced through supporting documentation. The development procedures and the resulting regulations are compared to requirements for the standards, traditional methods of regulating chemical and radiological carcinogens, and recommendations made by the International Commission on Radiological Protection, the Science Advisory Board, the Nuclear Waste Technical Review Board, and individual investigators. The development methodology, logic, assumptions, and models are reviewed relative to the two proposed repositories. Individual difficulties are defined, and their probable causes and potential effects are examined. Several options are suggested for modifying and extending the standards for each of the four major areas; these options make the standards more appropriate for the sites now under consideration, relate them more directly to the actual safety of the repositories, and make them more defensible. Many of the extensions are compatible with the present standards and would not require any significant changes in philosophy, methodology, or format. The benefits of an enhanced quality assurance program are discussed and several other changes in development procedures for waste disposal regulations are suggested. 49 refs., 17 figs., 4 tabs.

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Accelerometer and strain gage evaluation

Madsen, M.M.

This document describes the method developed by Sandia National Laboratories (SNL) to evaluate transducer used in the design certification testing of nuclear material shipping packages. This testing project was performed by SNL for the Office of Civilian Radioactive Waste Management (OCRWM). This evaluation is based on the results of tests conducted to measure ruggedness, failure frequency, repeatability, and manufacturers' calibration data under both field and laboratory conditions. The results of these tests are provided and discussed. The transducer were selected for testing by surveying cask contractors and testing facilities. Important insights relating to operational characteristics of accelerometer types were gained during field testing. 11 refs., 105 figs., 16 tabs.

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System Requirements for Low-Earth-Orbit Launch Using Laser Propulsion

Fusion Technology

Lawrence, R.J.

The use of ground-based lasers to launch small payloads but large total masses into low-Earth orbit may prove to be the most innovative and potentially economical approach for accomplishing this important mission. Of the several possible schemes for laser propulsion, two are examined: (1) ablative momentum transfer using pulsed lasers; and (2) heat exchanger thrusters in conjunction with CW lasers. For an entry-level payload of ~50 kg it is found that the former yields payload-to-power ratios of < 0.5 kg/MW with a requirement for an average laser power of at least 100 MW, whereas the latter might yield 1 to 3 kg/MW with a laser power of several 10s of MW. One of the promising approaches that could yield a driver for such a system is the reactor-pumped laser FALCON, which scales to these power levels with the potential for long run times.

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Department of Energy Interest and Involvement In Nuclear Plant License Renewal Activities

Bustard, Larry D.

Recognizing the importance of nuclear license renewal to the nation's energy strategy, the Department of Energy (DOE) initiated a plant lifetime improvement program during 1985 to determine the feasibility of the license renewal option for US nuclear plants. Initial activities of the DOE program focused on determining whether there were technical and economic obstacles that might preclude or limit the successful implementation of the license renewal option. To make this determination, DOE cosponsored with the Electric Power Research Institute (EPRI) pilot-plant efforts by Virginia Electric Power and Northern States Power. Both pilot-plant efforts concluded that life extension is technically and economically feasible. In parallel with the pilot-plant activities, DOE performed national economic studies that demonstrated the economic desirability of life extension. Having demonstrated the feasibility of life extension, DOE, in conjunction with EPRI, selected two lead plants to demonstrate the license renewal process. These lead plants are Yankee Atomic's Yankee Rowe facility and Northern States Power's Monticello facility. DOE also initiated activities to develop the technical and regulatory bases to support the license renewal process in the United States. DOE has recently identified nuclear plant license renewal to be an important element of its National Energy Strategy. This paper summarizes the significant results, conclusions, and ongoing activities of the DOE effort.

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The new quality philosophy and management's role

Narath, A.

This talk is about leadership. Leaders are people at every level in an organization who believe in change and are energized by it. They understand the difficult realities of competitive existence. They motivate and challenge. They provide positive reinforcement -- but are never satisfied with their achievements because opportunities for further improvement are never exhausted. Today, leadership is more important than ever because operating environments are changing at an unprecedented rate. The causes are geopolitical, economic, technological, etc. In fact, everything we know about nature tells us that change is inevitable. History shows quite clearly that human progress is not possible without change. Yet, humans crave stability and permanence. As a consequence, success often leads to complacency. But, demise is inevitable for those who protect the status quo. There exists a growing national awareness that global competitive pressures are forcing on American industry the need for ever higher levels of performance. And, similar forces are necessitating improved performance in DOE's nuclear weapons complex. Today, quality takes on a much larger meaning than it has traditionally. It is attention to cost, schedule and product performance that characterize the modern Quality ethic. This paper discusses the manager's role and the new Quality philosophy. 11 figs.

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Structural analysis of a reflux pool-boiler solar receiver

Hoffman, Edward L.

Coupled thermal-structural finite element calculations of a reflux pool-boiler solar receiver were performed to characterize the operating stresses and to address issues affecting the service life of the receiver. Analyses performed using shell elements provided information for receiver material selection and design optimization. Calculations based on linear elastic fracture mechanics principles were performed using continuum elements to assess the vulnerability of a seam-weld to fatigue crack growth. All calculations were performed using ABAQUS, a general purpose finite element code, and elements specifically formulated for coupled thermal-structural analysis. Two materials were evaluated: 316L SS and Haynes 230 alloys. The receiver response was simulated for a combination of structural and thermal loads that represent the startup and operating conditions of the receiver. For both materials, maximum stresses in the receiver developed shortly after startup due to uneven temperature distribution across the receiver surface. The largest effective stress was near yield in the 316L SS receiver and below 39 percent of yield in the Haynes 230 receiver. The calculations demonstrated that stress reductions of over 25 percent could be obtained by reducing the aft dome thickness to one closer to the absorber. The fatigue calculations demonstrated that the stress distribution near the seam-weld notch depends primarily on the structural load created by internal pressurization of the receiver rather than the thermal, indicating that the thermal loads can be neglected when assessing the stress intensity near the seam-weld notch. The stress intensity factor, computed using the J-integral method and crack opening-displacement field equations, was significantly below the fatigue threshold for most steels. The calculations indicated that the weld notch was always loaded in compression, a condition which is not conducive to fatigue crack growth. 15 refs., 30 figs., 3 tabs.

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Authentication of byte sequences

Stearns, S.D.

Algorithms for the authentication of byte sequences are described. The algorithms are designed to authenticate data in the Storage, Retrieval, Analysis, and Display (SRAD) Test Data Archive of the Radiation Effects and Testing Directorate (9100) at Sandia National Laboratories, and may be used in similar situations where authentication of stored data is required. The algorithms use a well-known error detection method called the Cyclic Redundancy Check (CRC). When a byte sequence is authenticated and stored, CRC bytes are generated and attached to the end of the sequence. When the authenticated data is retrieved, the authentication check consists of processing the entire sequence, including the CRC bytes, and checking for a remainder of zero. The error detection properties of the CRC are extensive and result in a reliable authentication of SRAD data.

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The depth of the oil/brine interface and crude oil leaks in SPR caverns

Heffelfinger, Grant S.

Monitoring wellhead pressure evolution is the best method of detecting crude oil leaks in SPR caverns while oil/brine interface depth measurements provide additional insight. However, to fully utilize the information provided by these interface depth measurements, a thorough understanding of how the interface movement corresponds to cavern phenomena, such as salt creep, crude oil leakage, and temperature equilibration, as well as to wellhead pressure, is required. The time evolution of the oil/brine interface depth is a function of several opposing factors. Cavern closure due to salt creep and crude oil leakage, if present, move the interface upward. Brine removal and temperature equilibration of the oil/brine system move the interface downward. Therefore, the relative magnitudes of these factors determine the net direction of interface movement. Using a mass balance on the cavern fluids, coupled with a simplified salt creep model for closure in SPR caverns, the movement of the oil/brine interface has been predicted for varying cavern configurations, including both right-cylindrical and carrot-shaped caverns. Three different cavern depths and operating pressures have been investigated. In addition, the caverns were investigated at four different points in time, allowing for varying extents of temperature equilibration. Time dependent interface depth changes of a few inches to a few feet were found to be characteristic of the range of cases studied. 5 refs, 19 figs., 1 tab.

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Aging predictions in nuclear power plants: Crosslinked polyolefin and EPR cable insulation materials

Gillen, Kenneth T.

In two earlier reports, we derived a time-temperature-dose rate superposition methodology, which, when applicable, can be used to predict cable degradation versus dose rate, temperature and exposure time. This methodology results in long-term predictive capabilities at the low dose rates appropriate to ambient nuclear power plant aging environments. The methodology was successfully applied to numerous important cable materials used in nuclear applications and the extrapolated predictions were verified by comparisons with long-term (7 to 12 year) results for similar or identical materials aged in nuclear environments. In this report, we test the methodology on three crosslinked polyolefin (CLPO) and two ethylene propylene rubber (EPR) cable insulation materials. The methodology applies to one of the CLPO materials and one of the EPR materials, allowing predictions to be made for these materials under low dose-rate, low temperature conditions. For the other materials, it is determined that, at low temperatures, a decrease in temperature at a constant radiation dose rate leads to an increase in the degradation rate for the mechanical properties. Since these results contradict the fundamental assumption underlying time-temperature-dose rate superposition, this methodology cannot be applied to such data. As indicated in the earlier reports, such anomalous results might be expected when attempting to model data taken across the crystalline melting region of semicrystalline materials. Nonetheless, the existing experimental evidence suggests that these CLPO and EPR materials have substantial aging endurance for typical reactor conditions. 28 refs., 26 figs., 3 tabs.

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A coupled mechanical/hydrologic model for WIPP shaft seals

Ehgartner, Brian L.

Effective sealing of the Waste Isolation Pilot Plant (WIPP) shafts will be required to isolate defense-generated transuranic wastes from the accessible environment. Shafts penetrate water-bearing hard rock formations before entering a massive creeping-salt formation (Salado) where the WIPP is located. Short and long-term seals are planned for the shafts. Short-term seals, a composite of concrete and bentonite, will primarily be located in the hard rock formations separating the water-bearing zones from the Salado Formation. These seals will limit water flow to the underlying long-term seals in the Salado. The long-term seals will consist of lengthly segments of initially unsaturated crushed salt. Creep closure of the shaft will consolidate unsaturated crushed salt, thereby reducing its permeability. However, water passing through the upper short-term seals and brine inherent to the salt host rock itself will eventually saturate the crushed salt and consolidation could be inhibited. Before saturating, portions of the crushed salt in the shafts are expected to consolidate to a permeability equivalent to the salt host rock, thereby effectively isolating the waste from the overlying water-bearing formations. A phenomenological model is developed for the coupled mechanical/hydrologic behavior of sealed WIPP shafts. The model couples creep closure of the shaft, crushed salt consolidation, and the associated reduction in permeability with Darcy's law for saturated fluid flow to predict the overall permeability of the shaft seal system with time. 17 refs., 6 figs., 1 tab.

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Crude oil sampling in SPR caverns: The development of an improved program via field and laboratory investigations

Heffelfinger, Grant S.

The Strategic Petroleum Reserve (SPR), a 600 million barrel crude oil reserve stored primarily in caverns leached in Gulf Coast salt domes, is maintained by the US Department of Energy (DOE). As part of a continuing program to monitor and characterize changes in the oil stored in the reserve, SPR caverns are periodically sampled at varying depths. Several different kinds of samples are withdrawn including pressurized samples, which enable a determination of the oil's vapor pressure and gas/oil ratio. These two parameters are particularly important to drawdown strategies because if the oil contains significant amounts of gas (therefore having a high vapor pressure and gas/oil ratio), additional equipment and decreased removal rates may be required during drawdown. Past pressurized sampling data was wrought with inconsistencies due to improper pressurized sampling and sample analysis techniques. This report documents the findings of an investigation taken to determine the source of the problems in the existing pressurized sampling and sample analysis methods and to establish reliable and cost effective methods of performing these tasks. In particular, flow-through pressurized sampling technology was found to be the most appropriate method of obtaining reliable samples. The gravity transfer method was found to be the most reliable method of moving the sample from the flow-through tool to a transportation container. In regards to sample analysis, it is recommended that gas chromatography replace the antiquated Podbielniak method, that the gas/oil ratio be measured via standard techniques rather than calculated using equations of state, and that a standard method be used to measure the sample's vapor pressure in a constant temperature PVT cell. 24 refs., 33 figs.

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Evaluation of the role of threshold pressure in controlling flow of waste-generated gas into bedded salt at the Waste Isolation Pilot Plant

Davies, Peter B.

Anoxic corrosion and microbial degradation of contact-handled transuranic waste may produce sufficient quantities of gas over a long time period to generate high pressure in the disposal rooms at the Waste Isolation Pilot Plant (WIPP) repository. Dissipation of pressure by outward gas flow will be inhibited by the low permeability of the surrounding rock and by capillary forces that resist gas penetration into this water-saturated rock. Threshold pressure is the gas pressure required to overcome capillary resistance to initial gas penetration and to the development of interconnected gas pathways that would outward gas flow. The primary objectives of this study are to estimate the magnitude of threshold pressure in the bedded salt that surrounds the WIPP repository and to evaluate the role this parameter plays in controlling the outward flow of waste-generated gas. 54 refs., 9 figs., 4 tabs.

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Structural testing of the Los Alamos National Laboratory Heat Source/Radioisotopic Thermoelectric Generator shipping container

Bronowski, D.R.; Madsen, M.M.

The Heat Source/Radioisotopic Thermoelectric Generator shipping container is a Type B packaging design currently under development by Los Alamos National Laboratory. Type B packaging for transporting radioactive material is required to maintain containment and shielding after being exposed to the normal and hypothetical accident environments defined in Title 10 Code of Federal Regulations Part 71. A combination of testing and analysis is used to verify the adequacy of this package design. This report documents the test program portion of the design verification, using several prototype packages. Four types of testing were performed: 30-foot hypothetical accident condition drop tests in three orientations, 40-inch hypothetical accident condition puncture tests in five orientations, a 21 psi external overpressure test, and a normal conditions of transport test consisting of a water spray and a 4 foot drop test. 18 refs., 104 figs., 13 tabs.

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Some high voltage dc breakdown properties of thick film circuits on alumina

Dybwad, G.L.

This report describes high voltage dc breakdown tests on various PtAu and Au thick film hybrid microcircuits on alumina (Al{sub 2}O{sub 3}). Samples were prepared with current thick film design and manufacturing rules. The purpose was to determine the voltage margins between current design rules and typical applied voltages on real circuits. We also analyzed what happened during a breakdown event. We used a versatile computer-controlled test set to obtain breakdown data. This showed that design conductors 10 mil wide with equal design spaces on alumina and coated with a fired protective glaze (DuPont 9137) had the highest breakdown values (2700 Vdc). Bare design circuits and Au conductor crossover features had a lower breakdown value (1400 to 1600 Vdc). Both these values are well above logic circuit applied voltages ({le}50v). This may account for the excellent field performance obtained to date. Ambient humidity changes to 43% R.H. and voltage rise rates between 3 and 2300 V/sec had little influence on breakdown values ({le}200 Vdc). Voltage breakdown values were little influenced by our two geometries: point-to-line samples which simulated corners and long parallel line samples. Breakdown behaved like a spark in air rather than an arc. Breakdown in glaze went through it to air rather than along the glaze/alumina interface. The spark was found to be similar to lightning in that it consisted of a string of current pulses lasting a total of 1 to 2 seconds. Spark locations were from surface asperities or defects near but not at the point of minimum optically measured separation. Hence, we found that circuits made using current design rules for hybrid microcircuit manufacture are adequate or conservative as regards safe margins against logic voltage dc breakdown to the extent studied here. 13 refs., 19 figs.

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SANDAC V computer electromagnetic interface characteristics: Problems and solutions. [Sandia Airborne Computer (SANDAC)]

Russell, G.A.

Electromagnetic Interference (EMI) problems have resulted in the redesign of the SANDAC V computer case and shielding of its connecting cables. In this report are detailed discussions on the use of computer models and of the tests performed to solve the EMI problems. Included is documentation on the specific changes made to the SANDAC V computer case and the shielding done on the connecting cables. Also documented are the current EMI capabilities relative to MIL Std. 461.

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Performance indicator report, first quarter, CY 1991: Sandia National Laboratories

Conway, E.

This report represents the first quarterly submittal of data by Sandia National Laboratories (SNL) for the Department Of Energy (DOE) Headquarters Performance Indicator Program. Secretary of Energy Notice (SEN-29-91) directed that a Department-wide uniform systems of Performance Indicators (PIs) for trending and analyzing operational data to help assess and support progress in improving performance and in strengthening line management control of operations relating to environmental, safety, and health activities'' be developed. Trending and analysis of data depicting the performance of facilities is an essential element in creating a culture of continuous improvement,'' where performance gains are maintained and deteriorating environmental, safety, and health conditions are identified early. In addition, good practices that can benefit other DOE operations areas should be identified. The program defines 21 Pi's grouped into four broad areas: (1) personnel safety; (2) operational incidents; (3) environmental releases (normal operations); and (4) management (including waste generation). SNL is required to submit data on 21 PIs for four facilities/reporting elements that were selected by DOE at Albuquerque and Livermore. 31 figs.

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An analysis of parameters affecting slapdown of transportation packages

Bergmann, V.L.; Ammerman, D.J.

In the certification of packages for transport of radioactive material, the issue of slapdown must be addressed. Slapdown is a secondary impact of the body caused by rotational accelerations induced during eccentric primary impact. In this report, several parameters are evaluated that affect slapdown severity of packages for the transport of nuclear material. The nose and tail accelerations in a slapdown event are compared to those experienced by the same cask in a side-drop configuration, in which there is no rotation, for a range of initial impact angles, impact limiter models, and friction coefficients for two existing cask geometries. In some cases, the rotation induced during a shallow-angle impact is sufficient to cause accelerations at the tail during secondary impact to be greater than those at the nose during initial impact. Furthermore, both nose and tail accelerations are often greater than the side-on accelerations. The results described here have been calculated using the code SLAPDOWN, which approximates the impact response of deformable bodies. Finally, SLAPDOWN has been used to estimate the coefficient of friction acting at the nose and tail for one particular cask during one specific slapdown drop test by comparison of results with experimental data. 2 refs., 16 figs., 3 tabs.

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General implementation of thin-slot algorithms into the finite-difference time-domain code, TSAR, based on a slot data file

Riley, Douglas J.

Two methods for modeling arbitrary narrow apertures in finite- difference time-domain (FDTD) codes are presented in this paper. The first technique is based on the hybrid thin-slot algorithm (HTSA) which models the aperture physics using an integral equation approach. This method can model slots that are narrow both in width and depth with regard to the FDTD spatial cell, but is restricted to planar apertures. The second method is based on a contour technique that directly modifies the FDTD equations local to the aperture. The contour method is geometrically more flexible than the HTSA, but the depth of the aperture is restricted to the actual FDTD mesh. A technique to incorporate both narrow-aperture algorithms into the FDTD code, TSAR, based on a slot data file'' is presented in this paper. Results for a variety of complex aperture contours are provided, and limitations of the algorithms are discussed.

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Feasibility study of a 200 ampere battery

Baldwin, A.R.

The results of a Sandia National Laboratories program to design and develop a high-current thermal battery for the Hypersonic Weapons Technology Program are presented. The feasibility of a 200 A, 150 s, 12 Vdc primary battery was demonstrated under ambient conditions. New header feedthrough design concepts were used, and new internal current collectors and internal power leads were considered. The Li(Si)/LiBr-LiCl-LiF/FeS{sub 2} electrochemical system has shown exceptional performance at the high-current operation conditions. A high-rate Zinc/Silver Oxide secondary cell was also evaluated, and the results are presented in this report. These cells exhibited excellent high-rate discharge performance. 5 refs., 19 figs., 8 tabs.

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Technical summary of the Performance Assessment Calculational Exercises for 1990 (PACE-90); Volume 1, ``Nominal configuration`` hydrogeologic parameters and calculational results: Yucca Mountain Site Characterization Project

Barnard, R.

A Performance Assessment Calculational Exercise for 1990 (PACE-90) was coordinated by the Yucca Mountain Site Characterization Project Office for a total-system performance-assessment problem. The primary objectives of the exercise were to develop performance-assessment computational capabilities of the Yucca Mountain Project participates and to aid in identifying critical elements and processes associated with the calculation. The problem defined for PACE-90 was simulation of a ``nominal case`` groundwater flow and transport of a selected group of radionuclides through a portion of Yucca Mountain. Both 1-D and 2-D calculations were run for a modeling period of 100,000 years. The nuclides used, {sup 99}Tc, {sup 135}Cs, {sup 129}I, and {sup 237}Np, were representative of ``classes`` of long-lived nuclides expected to be present in the waste inventory. Movement of the radionuclides was simulated through a detailed hydrostratigraphy developed from Yucca Mountain data specifically for this exercise. The results showed that, for the specified conditions with the conceptual models used in the problem, no radioactive contamination reached the water table, 230 m below the repository. However, due to the unavailability of sufficient site-specific data, the results of this exercise cannot be considered a comprehensive total-system- performance assessment of the Yucca Mountain site as a high-level- waste repository. 46 refs., 94 figs., 19 tabs.

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Hydrogen Reactions with Dangling Bonds in Si and Si-SiO2 Structures

Myers, S.M.; Brower, K.L.; Follstaedt, D.M.; Richards, P.M.; Stein, H.J.; Wampler, W.R.

Hydrogen is highly mobile in Si and vitreous SiO2, and it reacts strongly with dangling bonds residing on Si and O atoms. These interactions have important consequences for metal-oxide- semiconductor structures, with noteworthy effects including the passivation of electrically active defects, mediation of radiation sensitivity, chemical passivation of etched Si surfaces, and still poorly understood effects on epitaxial growth from H-containing media. Despite the significance of these H reactions, fundamental understanding of them has remained seriously deficient; the H bonding energies have been known semiquantitatively at best, and the detailed reaction paths and rate-determining energetics of intermediate states have remained largely speculative. We are addressing these issues through a coordinated program of experiment and theory with the goal of a unified, quantitatively predictive understanding.

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Results 97801–98000 of 99,299
Results 97801–98000 of 99,299