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Critical detonation thickness in vapor-deposited pentaerythritol tetranitrate (PETN) films

AIP Conference Proceedings

Tappan, Alexander S.; Knepper, Robert A.; Wixom, Ryan R.; Marquez, Michael P.; Ball, James P.; Miller, Jill C.

The use of physical vapor deposition is an attractive technique to produce microenergetic samples to study sub-millimeter explosive behavior. Films of the high explosive PETN (pentaerythritol tetranitrate) were deposited through vacuum thermal sublimation. Deposition conditions were varied to understand the effect of substrate cooling capacity and substrate temperature during deposition. PETN films were characterized with surface profilometry and scanning electron microscopy. Detonation velocity versus PETN film thickness was analyzed using a variation of the standard form for analysis of the diameter effect. Results were compared with previous work conducted on PETN films deposited with lower substrate cooling capacity. Seemingly subtle variations in PETN deposition conditions led to differences in detonation behaviors such as critical thickness for detonation, detonation velocity at "infinite" thickness, and the shape of the critical thickness curves. © 2012 American Institute of Physics.

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Controlling the microstructure of vapor-deposited pentaerythritol tetranitrate (PETN) films

Proceedings - 14th International Detonation Symposium, IDS 2010

Knepper, Robert; Tappan, Alexander S.; Wixom, Ryan R.

We have demonstrated the ability to control the microstructure of PETN films deposited using physical vapor deposition by altering the interface between the film and substrate. Evolution of surface morphology, average density, and surface roughness with film thickness were characterized using surface profilometry and scanning electron microscopy. While films on all of the substrates investigated showed a trend toward a lower average density with increasing film thickness, there were significant variations in density, pore size, and surface morphology in films deposited on different substrates.

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Results 76–100 of 142
Results 76–100 of 142