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Photofragmentation approaches for the detection of polyatomic molecules

Lasers and Electro-Optics/Quantum Electronics and Laser Science Conference: 2010 Laser Science to Photonic Applications, CLEO/QELS 2010

Reichardt, Thomas A.; Hoops, Alexandra A.; Headrick, Jeffrey M.; Farrow, Roger L.; Settersten, Thomas B.; Bisson, Scott E.; Kulp, Thomas J.

We review three photofragmentation detection approaches, describing the detection of (1) vapor-phase mercuric chloride by photofragment emission, (2) vapor-phase nitro-containing compounds by photofragmentation-ionization, and (3) surface-bound organophosphonate compounds by photofragmentation-laser-induced fluorescence. © 2010 Optical Society of America.

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Time-resolved picosecond pure-rotational coherent anti-stokes Raman spectroscopy for thermometry and species concentration in flames

Lasers and Electro-Optics/Quantum Electronics and Laser Science Conference: 2010 Laser Science to Photonic Applications, CLEO/QELS 2010

Kliewer, Christopher J.; Farrow, Roger L.; Settersten, Thomas B.; Kiefer, Johannes; Patterson, Brian D.; Gao, Yi; Settersten, Thomas B.

Time-resolved picosecond pure-rotational coherent anti-Stokes Raman spectroscopy is demonstrated for thermometry and species concentration determination in flames. Time-delaying the probe pulse enables successful suppression of unwanted signals. A theoretical model is under development. ©2010 Optical Society of America.

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Measuring individual overpotentials in an operating solid-oxide electrochemical cell

Physical Chemistry Chemical Physics

El Gabaly Marquez, Farid E.; Grass, Michael; McDaniel, Anthony H.; Farrow, Roger L.; Linne, Mark A.; Hussain, Zahid; Bluhm, Hendrik; Liu, Zhi; McCarty, Kevin F.

We use photo-electrons as a non-contact probe to measure local electrical potentials in a solid-oxide electrochemical cell. We characterize the cell in operando at near-ambient pressure using spatially-resolved X-ray photoemission spectroscopy. The overpotentials at the interfaces between the Ni and Pt electrodes and the yttria-stabilized zirconia (YSZ) electrolyte are directly measured. The method is validated using electrochemical impedance spectroscopy. Using the overpotentials, which characterize the cell’s inefficiencies, we compare without ambiguity the electro-catalytic efficiencies of Ni and Pt, finding that on Ni H2O splitting proceeds more rapidly than H2 oxidation, while on Pt, H2 oxidation proceeds more rapidly than H2O splitting. © the Owner Societies.

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In-situ investigation of SOFC patterned electrodes using ambient-pressure X-ray photoelectron spectroscopy

ECS Transactions

McDaniel, Anthony H.; El Gabaly, F.; Akhadov, E.; Farrow, Roger L.; McCarty, Kevin F.; Linne, M.A.; Decaluwe, S.C.; Zhang, C.; Eichhorn, B.; Jackson, G.S.; Liu, Z.; Grass, M.; Hussain, Z.; Bluhm, H.

Single chamber electrochemical cells were fabricated by patterning working and counter electrodes of Ni and Pt on single-crystal Y2O 3-stabilized ZrO2. Cells were characterized in mixed atmospheres of H2 and H2O at ratios of 1:1 and 1:20 at nominally 923 K and 67 Pa total pressure. Potential sweep and impedance measurements were conducted simultaneously with ambient-pressure x-ray photoelectron spectroscopy (APXPS), which is a unique synchrotron-based probe designed for in-situ chemical characterization of surfaces using photoemission at gas pressures large enough to achieve realistic densities of faradic current. Electrochemically induced oxidation of Ni was observed under anodic polarization and could be reversed by applying a cathodic bias. The thin-film microstructure could also be manipulated electrochemically in that pores exposing underlying electrolyte would open through the Ni film after polarization. Application of APXPS to resolve fundamental details of high-temperature electrochemical process in-situ is discussed. ©The Electrochemical Society.

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Power scaling of fiber-based amplifiers seeded with microchip lasers

Proceedings of SPIE - The International Society for Optical Engineering

Schrader, Paul E.; Fève, Jean P.; Farrow, Roger L.; Kliner, Dahv A.V.; Schmitt, Randal L.; Do, Binh T.

We summarize the performance of mode-filtered, Yb-doped fiber amplifiers seeded by microchip lasers with nanosecond-duration pulses. These systems offer the advantages of compactness, efficiency, high peak power, diffraction-limited beam quality, and widely variable pulse energy and repetition rate. We review the fundamental limits on pulsed fiber amplifiers imposed by nonlinear processes, with a focus on the specific regime of nanosecond pulses. Different design options for the fiber and the seed laser are discussed, including the effects of pulse duration, wavelength, and linewidth. We show an example of a microchip-seeded, single-stage, single-pass fiber amplifier that produced pulses with 1.1 MW peak power, 0.76 mJ pulse energy, smooth temporal and spectral profiles, diffractionlimited beam quality, and linear polarization.

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Design of refractive-index and rare-earth-dopant distributions for large-mode-area fibers used in coiled high-power amplifiers

Proceedings of SPIE - The International Society for Optical Engineering

Farrow, Roger L.; Hadley, G.R.; Kliner, Dahv A.V.; Koplow, Jeffrey P.

We have numerically compared the performance of various designs for the core refractive-index (RI) and rare-earth-dopant distributions of large-mode-area fibers for use in bend-loss-filtered, high-power amplifiers. We first established quantitative targets for the key parameters that determine fiber-amplifier performance, including effective LP01 modal area (Aeff, both straight and coiled), bend sensitivity (for handling and packaging), high-order mode discrimination, mode-field displacement upon coiling, and index contrast (manufacturability). We compared design families based on various power-law and hybrid profiles for the RI and evaluated confined rare-earth doping for hybrid profiles. Step-index fibers with straight-fiber Aeff values > 1000 μm2 exhibit large decreases in Aeff and transverse mode-field displacements upon coiling, in agreement with recent calculations of Hadley et al. [Proc. of SPIE, Vol. 6102, 61021S (2006)] and Fini [Opt. Exp. 14, 69 (2006)]. Triangular-profile fibers substantially mitigate these effects, but suffer from excessive bend sensitivity at Aeff values of interest. Square-law (parabolic) profile fibers are free of modal distortion but are hampered by high bend sensitivity (although to a lesser degree than triangular profiles) and exhibit the largest mode displacements. We find that hybrid (combined power-law) profiles provide some decoupling of these tradeoffs and allow all design goals to be achieved simultaneously. We present optimized fiber designs based on this analysis.

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High-peak-power (>1.2 MW) pulsed fiber amplifier

Proceedings of SPIE - The International Society for Optical Engineering

Farrow, Roger L.; Kliner, Dahv A.V.; Schrader, Paul E.; Hoops, Alexandra A.; Moore, Scan W.; Hadley, G.R.; Schmitt, Randal L.

We report results from Yb-doped fiber amplifiers seeded with two microchip lasers having 0.38-ns and 2.3-ns pulse durations. The shorter duration seed resulted in output pulses with a peak power of > 1.2 MW and pulse energy of 0.67 mJ. Peak power was limited by nonlinear processes that caused breakup and broadening of the pulse envelope as the pump power increased. The 2.3-ns duration seed laser resulted in output pulses with a peak power of >300 kW and pulse energy of > 1.1 mJ. Pulse energies were limited by the onset of stimulated Brillouin scattering and ultimately by internal optical damage (fluences in excess of 400 J/cm 2 were generated). In both experiments, nearly diffraction-limited beam profiles were obtained, with M 2 values of < 1.2. Preliminary results of a pulse-amplification model are in excellent agreement with the experimental results of the amplifiers operating in the low-to-moderate gain-depletion regime.

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Bent-waveguide modeling of large-mode-area, double-clad fibers for high-power lasers

Optics InfoBase Conference Papers

Ronald Hadley, G.; Farrow, Roger L.; Smith, A.V.

We have developed analytical and numerical models to address propagation of light through bent fiber amplifiers, including the mode distortion that results from fiber bending, and changes in beam profile resulting from self-focusing. © 2005 Optical Society of America.

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19 Results
19 Results