Publications

Anwar, Ishtiaque A.; Hatambeigi, Mahya H.; Chojnicki, Kirsten C.; Reda Taha, Mahmoud R.; Stormont, John C.

Abstract not provided.

Hatambeigi, Mahya H.; Anwar, Ishtiaque A.; Chojnicki, Kirsten C.; Reda Taha, Mahmoud R.; Stormont, John C.

Abstract not provided.

Anwar, Ishtiaque A.; Hatambeigi, Mahya H.; Chojnicki, Kirsten C.; Reda Taha, Mahmoud R.; Stormont, John C.

Abstract not provided.

Hatambeigi, Mahya H.; Anwar, Ishtiaque A.; Chojnicki, Kirsten C.; Reda Taha, Mahmoud R.; Stormont, John C.

Abstract not provided.

Journal of Natural Gas Science and Engineering

Hatambeigi, Mahya; Chojnicki, Kirsten C.; Taha, Mahmoud R.; Stormont, John C.

Understanding the nature of fluid flow through fractured wellbore cement is fundamental for evaluating the leakage potential and risk assessments of leaky wellbores. In this study, the conditions that require considering visco-inertial flow for describing the gas flow through wellbore cement fractures were investigated. Nitrogen gas flow tests were conducted on fractured cement samples under varying pressure conditions and flow rates, covering both viscous and visco-inertial flow regimes. The data substantially deviated from Darcy's law at higher flowrates and were well-fit to Forchheimer's equation for visco-inertial flow. The inertial coefficient and critical Reynolds number were expressed as a function of the hydraulic aperture. The empirical function obtained from the experiments was used as an input to numerical simulations which showed the significant role of visco-inertial flow in wellhead pressure build-up and leakage rates, and demonstrated the importance of visco-inertial flow when modeling gas flow through wellbore cement fractures.

Hatambeigi, Mahya H.; Anwar, Ishtiaque A.; Reda Taha, Mahmoud R.; Stormont, John C.; Chojnicki, Kirsten C.

Abstract not provided.

Hart, David B.; Chojnicki, Kirsten C.; Sobolik, Steven R.; Park, Byoung P.

The Department of Energy maintains an up-to-date documentation of the number of available full drawdowns of each of the caverns owned by the Strategic Petroleum Reserve (SPR). This information is important for assessing the SPR's ability to deliver oil to domestic oil companies expeditiously if national or world events dictate a rapid sale and deployment of the oil reserves. Sandia was directed to develop and implement a process to continuously assess and report the evolution of drawdown capacity, the subject of this report. A cavern has an available drawdown if after that drawdown, the long-term stability of the cavern, the cavern field, or the oil quality are not compromised. Thus, determining the number of available drawdowns requires the consideration of several factors regarding cavern and wellbore integrity and stability, including stress states caused by cavern geometry and operations, salt damage caused by dilatant and tensile stresses, the effect of enhanced creep on wellbore integrity, and the sympathetic stress effect of operations on neighboring caverns. A consensus has now been built regarding the assessment of drawdown capabilities and risks for the SPR caverns. The process involves an initial assessment of the pillar-to-diameter (P/D) ratio for each cavern with respect to neighboring caverns. A large pillar thickness between adjacent caverns should be strong enough to withstand the stresses induced by closure of the caverns due to salt creep. The first evaluation of P/D includes a calculation of the evolution of P/D after a number of full cavern drawdowns. The most common storage industry standard is to keep this value greater than 1.0, which should ensure a pillar thick enough to prevent loss of fluids to the surrounding rock mass. However, many of the SPR caverns currently have a P/D less than 1.0 or will likely have a low P/D after one or two full drawdowns. For these caverns, it is important to examine the structural integrity with more detail using geomechanical models. Finite-element geomechanical models have been used to determine the stress states in the pillars following successive drawdowns. By computing the tensile and dilatant stresses in the salt, areas of potential structural instability can be identified that may represent "red flags" for additional drawdowns. These analyses have found that many caverns will maintain structural integrity even when grown via drawdowns to dimensions resulting in a P/D of less than 1.0. The analyses have also confirmed that certain caverns should only be completely drawn down one time. As the SPR caverns are utilized and partial drawdowns are performed to remove oil from the caverns (e.g., for occasional oil sales authorized by the Congress or the President), the changes to the cavern caused by these procedures must be tracked and accounted for so that an ongoing assessment of the cavern's drawdown capacity may be continued. A proposed methodology for assessing and tracking the available drawdowns for each cavern was presented in Sobolik et al. (2018). This report includes an update to the baseline drawdowns for each cavern, and provides an initial assessment of the evolution of drawdown expenditure for several caverns

Environmental Science and Technology

Yoon, Hongkyu Y.; Chojnicki, Kirsten C.; Martinez, Mario J.

In this work, we have characterized the calcium carbonate (CaCO3) precipitates over time caused by reaction-driven precipitation and dissolution in a micromodel. Reactive solutions were continuously injected through two separate inlets, resulting in transverse-mixing induced precipitation during the precipitation phase. Subsequently, a dissolution phase was conducted by injecting clean water (pH = 4). The evolution of precipitates was imaged in two and three dimensions (2-, 3-D) at selected times using optical and confocal microscopy. With estimated reactive surface area, effective precipitation and dissolution rates can be quantitatively compared to results in the previous works. Our comparison indicates that we can evaluate the spatial and temporal variations of effective reactive areas more mechanistically in the microfluidic system only with the knowledge of local hydrodynamics, polymorphs, and comprehensive image analysis. Our analysis clearly highlights the feedback mechanisms between reactions and hydrodynamics. Pore-scale modeling results during the dissolution phase were used to account for experimental observations of dissolved CaCO3 plumes with dissolution of the unstable phase of CaCO3. Mineral precipitation and dissolution induce complex dynamic pore structures, thereby impacting pore-scale fluid dynamics. Pore-scale analysis of the evolution of precipitates can reveal the significance of chemical and pore structural controls on reaction and fluid migration.

Journal of Petroleum Science and Engineering

Anwar, Ishtiaque; Chojnicki, Kirsten C.; Bettin, Giorgia B.; Taha, Mahmoud R.; Stormont, John C.

Leakage along wellbores is of concern for a variety of applications, including sub-surface fluid storage facilities, geothermal wells, and CO2 storage wells. We have investigated whether corroded casing is permeable to gas and can serve as a leakage pathway along wellbores. Three specimens were prepared from laboratory steel plates corroded using different mechanisms to reflect different possible field conditions and produce a variety of corrosion rates. Single-phase gas flow measurements were made under a range of gas pressures to investigate flow in both the viscous and visco-inertial flow regimes. Tests were conducted at different confining stresses (range from 3.45 to 13.79 MPa) following both loading and unloading paths. The gas flow test results suggest corroded casing can serve as a significant leakage path along the axis of a wellbore. Transmissivity was found to be sensitive to the variation in confining stress suggesting that the corrosion product is deformable. Gas slip factors and the coefficients of inertial resistance of the corrosion product were comparable to those available in the literature for other porous media. Post-test examination of the corrosion product revealed it to be a heterogeneous, mesoporous material with mostly non-uniform slit type porosity. There was no discernable difference in the composition of corrosion product from specimens corroded by different mechanisms.

Chojnicki, Kirsten C.

Abstract not provided.

Sobolik, Steven R.; Hart, David B.; Park, Byoung P.; Chojnicki, Kirsten C.

The Department of Energy maintains an up-to-date documentation of the number of available full drawdowns of each of the caverns owned by the Strategic Petroleum Reserve (SPR). This information is important for assessing the SPR's ability to deliver oil to domestic oil companies expeditiously if national or world events dictate a rapid sale and deployment of the oil reserves. What factors go into assessing available drawdowns? Determining the number of drawdowns requires the consideration of several factors regarding cavern and wellbore integrity and stability, including stress states caused by cavern geometry and operations, salt damage caused by dilatant and tensile stresses, the effect of enhanced creep on wellbore integrity, and the sympathetic stress effect of operations on neighboring caverns. A consensus has now been built regarding the assessment of drawdown capabilities and risks for the SPR caverns. The process involves an initial assessment of the pillar-to-diameter (P/D) ratio for each cavern with respect to neighboring caverns. Ideally, it is desired to keep this value greater than 1.0, which is in line with most industry design standards and should ensure cavern integrity and prevent loss of fluids to the surrounding rock mass. However, many of the SPR caverns currently have a P/D less than 1.0, or will likely have a low P/D after one or two full drawdowns. For these caverns, it is important to examine the structural integrity with more detail using geomechanical models. Finite-element geomechanical models have been used to determine the stress states in the pillars following successive drawdowns. By computing the tensile and dilatant stresses in the salt, areas of potential structural instability can be identified that may represent "red flags" for additional drawdowns. These analyses have found that many caverns will maintain structural integrity even when grown via drawdowns to dimensions resulting in a P/D of less than 1.0. The analyses have also confirmed that certain caverns should only be completely drawn down one time. As the SPR caverns are utilized and partial drawdowns are performed to remove oil from the caverns (e.g., for occasional oil sales authorized by the Congress or the President), the changes to the cavern volumes casused by these procedures must be tracked and accounted for so that an ongoing assessment of the cavern's drawdown capacity may be continued. A proposed methodology for assessing and tracking the available drawdowns for each cavern is presented in this report.

Chojnicki, Kirsten C.

In 2017 small-scale drawdowns at the Strategic Petroleum Reserve (SPR) supported oil sales for the Bipartisan Budget Act of 2015 and the 21st Century Cures Act of 2015 as well as exchanges supporting relief efforts for hurricane Harvey. These drawdowns may affect cavern stability and available drawdowns, thus is important to assess the leaching effects on the cavern shape. Cavern shape estimates from the SANSMIC solution mining code suggest the shapes of 28 caverns were altered in 2017 to varying degrees depending on the total volume of water injected, the initial cavern shape and the distance between the hanging string depth and the oil-brine interface depth. A flaring of the cavern floor occurred in 13 caverns, a geomechanically unfavorable outcome that may require operational changes to preserve cavern integrity. Of the three caverns with post-sale sonars, SANSMIC predictions compared favorably to two but underpredicted the third.

Chojnicki, Kirsten C.

Abstract not provided.

Anwar, Ishtiaque A.; Hatambeigi, Mahya H.; Taha, Mahmoud R.; Bettin, Giorgia B.; Chojnicki, Kirsten C.; Stormont, John C.

Abstract not provided.

Chojnicki, Kirsten C.; Hatambeigi, Mahya H.; Anwar, Ishtiaque A.; Taha, Mahmoud R.; Bettin, Giorgia B.; Chojnicki, Kirsten C.; Stormont, John C.

Abstract not provided.

Chojnicki, Kirsten C.; Cooper, Marcia A.; Guo, Shuyue G.

Surrogate laboratory experiments were conducted to understand how cavities surrounding an explosive event in a bounded material influence the transfer of energy to the surface of the material. Exploding bridgewires were detonated in a cavity that had been created in an optically accessible polymer material. The shock propagation was investigated through five paths, three through spherical cavities of varying size filled with air, one without a cavity and one in air. Shock propagation was imaged using the schlieren technique. The path effects were determined by measuring energy at the polymer surface using a pressure sensor. All cavities were successful at reducing the peak pressure nearly 100% from the case without a cavity, a reduction close to air. The degree of reduction was not uniform over all frequencies. Overall, our findings suggest that cavities influence both the amount and frequency content of the energy transfer from source to surface.

Chojnicki, Kirsten C.

Pore-scale aperture effects on flow in pore networks was studied in the laboratory to provide a parameterization for use in transport models. Four cases were considered: regular and irregular pillar/pore alignment with and without an aperture. The velocity field of each case was measured and simulated, providing quantitatively comparable results. Two aperture effect parameterizations were considered: permeability and transmission. Permeability values varied by an order of magnitude between the cases with and without apertures. However, transmission did not correlate with permeability. Despite having much greater permeability the regular aperture case permitted less transmission than the regular case. Moreover, both irregular cases had greater transmission than the regular cases, a difference not supported by the permeabilities. Overall, these findings suggest that pore-scale aperture effects on flow though a pore-network may not be adequately captured by properties such as permeability for applications that are interested in determining particle transport volume and timing.

Chojnicki, Kirsten C.; Cooper, Marcia A.; Guo, Shuyue G.

Abstract not provided.

Heath, Jason; Nemer, Martin N.; Chojnicki, Kirsten C.

Mixing of injected raw (undersaturated) water with brine in Strategic Petroleum Reserve (SPR) salt caverns affects the shape of cavern walls due to leaching. Cavern shape impacts cavern geomechanical stability and available volume for oil storage. Raw water injection occurs during initial solution mining of caverns, remedial leaching of caverns, and oil drawdown. Of interest are factors that control the degree of raw water-brine mixing and thereby the concentration of the aqueous fluid mixture that contacts the salt cavern walls. It is hypothesized that poorly-mixed fresh water could potentially cause undesirable and non-uniform leaching , for example, if buoyant poorly-mixed fresh water collects and preferentially leaches under the oil-brine interface . This report presents current understanding of controls on incomplete-to-complete mixing of raw water and brine, focusing on implications for SPR cavern leaching. In the context of mixing, we review the following: SPR leaching operations; models of leaching; field measurements of leaching and cavern shapes; and previous laboratory experiments of mixing and /or leaching performed at Sandia National Laboratories. We present recent laboratory experiments in 2014-2016 that focused explicitly on understanding controls of poor-to-well mixed conditions. We find that well-mixed conditions are expected for typical operating conditions of the SPR.

Martinez, Mario J.; Chojnicki, Kirsten C.; Kucala, Alec K.; Wang, Yifeng; Yoon, Hongkyu Y.; Wang, Lichun W.; Cardenas, Meinhard C.

Abstract not provided.

Chojnicki, Kirsten C.; Yoon, Hongkyu Y.; Martinez, Mario J.

Abstract not provided.

Chojnicki, Kirsten C.; Yoon, Hongkyu Y.; Martinez, Mario J.

Abstract not provided.

Kucala, Alec K.; Wang, Yifeng; Martinez, Mario J.; Cardenas, Bayani C.; Guiltinan, Eric J.; Chojnicki, Kirsten C.; Yoon, Hongkyu Y.

Abstract not provided.

Chojnicki, Kirsten C.; Yoon, Hongkyu Y.; Martinez, Mario J.

Abstract not provided.

Martinez, Mario J.; Yoon, Hongkyu Y.; Dewers, Thomas D.; Kucala, Alec K.; Chojnicki, Kirsten C.

Abstract not provided.