Nanoscale Phase Segregation of a Molecular System using Metal-Organic Framework for Energy Transfer
Abstract not provided.
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Abstract not provided.
First-Principles Investigation of Metal-Organic Frameworks for Photovoltaics
Abstract not provided.
Effects of polarizability on the adsorption of noble gases at low pressures in monohalogenated isoreticular metal-organic frameworks
Journal of Physical Chemistry C
A systematic investigation of the effects of linker polarizability on the adsorption properties of weakly interacting gases (N 2, Ar, Kr, and Xe) is reported. Experimental and simulated adsorption properties were measured for a complete isoreticular series of monohalogenated metal-organic frameworks (MOFs). Variations on IRMOF-2, in which one linker hydrogen is replaced with -F, -Cl, -Br, or -I, comprise the series. Both experimental and simulated results indicate that increasing linker polarizability correlates with increased gas uptake. Evidence of increased adsorbate interaction with increased linker polarizability is also observed in the Kr/N 2, Xe/N 2, and Xe/Kr selectivity data and in isosteric heats of adsorption. Unexpectedly, comparison between simulated and experimental isotherms reveals that the agreement between the two improves with the size of the adsorbate, with essentially identical results for Xe. This is apparently due to the creation of regions inaccessible to any of the noble gases as a result of halogen functionalization. Simulated adsorption isotherms are also reported for radon, which is difficult to measure experimentally due to its radioactivity. © 2012 American Chemical Society.
Connecting structure and function in MOF-based luminescence: Rational design of novel materials for chemical sensing and radiation detection
Abstract not provided.
Probing the effects of nano-confinement on charge transfer in metal-organic frameworks
Abstract not provided.
Particle Discrimination Using Nanoporous Metal-Organic Frameworks
Abstract not provided.
Highly ordered crystalline nanoporous frameworks for nano-heterojunction photovoltaics
Abstract not provided.
Effects of Pore Polarizability on the Interactions between Weakly Interacting Gases and Metal-organic Frameworks
Abstract not provided.
Electronic Properties of Photovoltaic Metal Organic Frameworks from First-principles Calculations
Abstract not provided.
Metal-Organic Frameworks: A Rapidly Growing Class of Versatile Nanoporous Materials
Advanced Materials
Abstract not provided.
Designing metal-organic frameworks for radiation detection
Abstract not provided.
Concentrating Noble Gases from Air using Nanoporous Framework Materials
Abstract not provided.
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