Thick film Au metallizations are commonly used as conductors in hybrid microelectronics that operate at high frequencies. Discrete components are attached to these conductors with 5OPb/5OIn solder. Intermetallic compounds form and grow in the solid state with time; AuIn[sub 2] is the primary compound formed in the Au-5OPb/50In system. A hybrid failed after being artificially aged to consume all of the Au and then subjected to normal thermal cycle and vibration testing. Postmortem analysis revealed that three capacitors had debonded. The failed parts were studied to determine the failure mechanism(s) and define a parametric study to characterize the mechanisms that bond the Au thick film to the ceramic substrate.
This is a peer review report of the Environmental and Molecule Sciences Laboratory. Although the Pretreatment, Treatment, and Waste Forms comments are focused specifically on pretreatment treatment, and waste forms, the group recognizes that the life cycle designation is a somewhat arbitrary breakdown of a series of activities that form a continuum in the environmental restoration and waste management program. Consequently, some of the comments made here are relevant in a broader context or even for EM as a whole. particular, characterization activities pervade all life cycles in environmental restoration/waste management. As we use the term in this section, characterization'' refers to the process monitoring and control that are required during pretreatment and treatment. Most of the technology presentations during the review identified links to support this area and delineated to varying degrees the specific ties to the Hanford Site cleanup requirements. Overall, the EMSL especially its planned facilities, are most impressive, and DOE and PNL are urged to proceed with all due haste toward its completion. Specific issues or concerns identified during the review are included in the following section.
Scientific visualization is playing an increasingly important role in the analysis and interpretation of massively parallel CFD simulations due to the enormous volume of data that can be generated on these machines. In this paper we will describe the development of a visualization technique based on a parallel analogue to the Marching Cubes algorithm. The algorithm has been developed for Multiple-Instruction, Multiple-Data (MIMD) massively parallel computers and is designed to take advantage of the heterogeneous programming capabilities of the MIMD architecture. We examine several different configurations and conclude that for producing animations the best one, in terms of both frame generation time and disk usage, is to run the two applications heterogeneously and send the resulting geometry description directly to a workstation for rendering, thereby totally eliminating the use of files from the animation process.
Sandia National Laboratories is prototyping a service for providing a distributed visualization capability between its Albuquerque, New Mexico and Livermore, California sites. The service will allow TCP/EP LAN users to process computationally intensive codes on the Cray Y-MP 8/864 and use the Application Visualization System, (AVS) running on a visualization server to display the results to desktops in Livermore (or Albuquerque). The long-haul environment presents several technical challenges such as high delays (up to 42 milliseconds), potential error rates, and security concerns which can affect the quality of the services. The network design requires low latency switch gear and high speed LAN connections (FDDI) to make the visualization/computational services useful to the customer. This paper will describe tie network design used and will report performance characteristics of the applications utilizing this service.
AC impedance and x-ray diffraction measurements versus temperature and pressure ternary intercalation compounds are reported. Results support our previously established empirical correlation between superconducting onset temperature and 300K fcc lattice constant. Compounds which do not follow this correlation either phase separate or are otherwise unstable at low T and/or high P.
We have demonstrated removal of H from a H-passivated Si(100) surface by low energy ([approximately]50 eV) He ion bombardment. The extent of the removal of H from the surface can be controlled by varying the duration of He bombardment and plasma parameters. This, in turn, means that the growth rate by this method can also be controlled. Si[sub 2]H[sub 6] was shown to adsorb in a self-limiting manner on the Si(100) surface.
The earth`s ionosphere consists of an ionized plasma which will interact with any electromagnetic wave propagating through it. The interaction is particularly strong at vhf and uhf frequencies but decreases for higher microwave frequencies. These interaction effects and their relationship to the operation of a wide-bandwidth, synthetic-aperture, space-based radar are examined. Emphasis is placed on the dispersion effects and the polarimetric effects. Results show that high-resolution (wide-bandwidth) and high-quality coherent polarimetrics will be very difficult to achieve below 1 GHz.
SAFSIM (System Analysis Flow SIMulator) is a FORTRAN computer program that provides engineering simulations of user-specified flow networks at the system level. It includes fluid mechanics, heat transfer, and reactor dynamics capabilities. SAFSIM provides sufficient versatility to allow the simulation of almost any flow system, from a backyard sprinkler system to a clustered nuclear reactor propulsion system. In addition to versatility, speed and robustness are primary goals of SAFSIM development. The current capabilities of SAFSIM are summarized and some sample applications are presented. It is applied here to a nuclear thermal propulsion system and nuclear rocket engine test facility.
Photovoltaic (PV) systems offer a cost-effective solution to provide electrical power for a wide variety of applications, with battery performance playing a major role in their success. This paper presents some of the results of an industry meeting regarding battery specifications and ratings that photovoltaic system designers require, but do not typically have available to them. Communications between the PV industry and the battery industry regarding appropriate specifications have been uncoordinated and poor in the past. This paper also discusses the effort under way involving the PV industry and battery manufacturers, and provides a working draft of specifications to develop and outline the information sorely needed on batteries. The development of this information is referred to as ``Application Notes for Batteries in Photovoltaic Systems.`` The content of these ``notes`` has been compiled from various sources, including the input from the results of a survey on battery use in the photovoltaic industry. Only lead-acid batteries are discussed
In one design of molten-salt central receivers, the molten salt flows in a serpentine path, down one panel of tubes then up the next and down again continuing in this fashion through the receiver. There have been concerns about this design because in the down flow sections, the heat flux incident on the tubes can cause flow instability since the flow is in direct opposition to the buoyant forces. In extreme cases the buoyant forces can cause flow stagnation or reversal. An analysis of flow stability within individual tubes and down flow sections of receiver panels is presented. When the partial derivative of the pressure drop with respect to mass flow rate is negative ({partial_derivative}{Delta}P/{partial_derivative}{sup {lg_bullet}} < 0), the flow is unstable and could cause serious damage to the receiver. Stability maps are developed that show safe operating regimes where inertial forces dominate over buoyant forces. The data is then normalized using the Grashof and Reynolds numbers.
United States Department of Energy has established its first Advanced Research Objective in the Solids Transport Program. The scientific, engineering, and management goals are discussed in some detail. Scientific progress to date is summarized. Comments are made on the technical direction of further Advanced Research Objectives.
We have developed a Li/SOCl{sub 2} ``D`` cell for applications requiring 10 to 15 years life at very low drain rates, typically less than 150 {mu}A. Maximizing cell safety and reliability, while delivering very good energy density, have been the goals of our study. We have achieved these goals by designing the cell to be application specific. The low-rate cell has been optimized to deliver up to 16 Ah at drain rates of less than 70 mA. By virtue of its low surface area, 145 cm{sub 2}, the cell has demonstrated excellent safety behavior. Safety testing has been performed on individual cells as well as on two-cell and four-cell batteries. Single cells did not vent when short-circuited. We were able to produce benign venting in a two cell string, but only when the string was partially discharged before shorting. The vent mechanism is a 300 psi rupture pressure burst disc manufactured by BS&B Safety Systems. We define benign venting as full opening of the 3/8 in. dia vent hole without deformation of the case. Material is expelled from the cell without flame, and the cell stack remains largely intact. We have not produced venting of the Sandia-designed low rate cell under any other abuse test conditions. The vent functions as an ultimate safety mechanism in the case of severe abuse, but resistance to venting under normal use and mild abuse conditions is key to the achievement of high reliability.
A new class of ion-exchange materials that can selectively separate low parts per million level concentrations of Cs{sup +} from 3--6 molar concentrations of Na{sup +} over a wide pH range has recently been developed as a result of a collaborative effort between Sandia National Laboratories and Texas A&M University. The materials, called crystalline silicotitanates, show potential for application in the treatment of aqueous nuclear waste solutions.
In order to develop a procedure for measuring cation diffusion coefficients below 1000{degrees}C, we have examined the suitability of several diffusion couple configurations involving single crystals of garnet. Initial experiments using an enriched {sup 25}MgCl{sup 2} proved ineffective in providing a uniform and coherent surface for analysis by ion microprobe. A technique was developed using thin film deposition. Thin films ({approximately} 1000 {Angstrom}) of MgO{sub x} (x < 1) can be applied to polished mineral surfaces by evaporating MgO powder under high vacuum with a thermal-resistance strip heater. Thermal resistance evaporation is efficient. Samples of single crystal grossular and pyrope garnets with thin films of MgO, as created by these techniques, were annealed for various times at 800, 900, and 1000{degrees}C, at several log fO{sub 2} values, and 1 atm. Optical, SEM, and ion microprobe analyses reveal no disruption of the interface. Profiles of elemental counts vs depth exhibit expected patterns going through the thin film into the garnet substrate. Our experimental matrix of garnet diffusion runs includes over 60 cut and polished crystals of pyrope composition that are being run at various oxygen fugacity conditions from 600 to 1000{degrees}C.
The Los Alamos National Laboratory (LANL) Mechanical Engineering and Electronics Division, in partnership with Sandia National Laboratories and Programmed Composites, is advancing the development of thin-walled, high modulus short-fiber compression-molded composite materials fabrication. In this paper, we investigate component uniformity, structural integrity, thermal conductivity, and radiation resistance; discuss the scanning-electron microscopic inspection of the graphite fiber distribution and orientation, and describe the process used in selecting the reinforcement fiber length and modulus and for choosing the hydrophobic, cyanate-ester resin.
During the last two decades there has been considerable interest in developing alternatives to conventional chemical propulsion for space missions. Laser propulsion has been identified as a serious contender for the task of inexpensively delivering small payloads to low-earth orbit. Recent advances in the development of lasers powered directly by nuclear reaction products offer the potential for new propulsion methods, namely, reactor-laser propulsion. Such systems would allow ``nuclear propulsion`` without placing nuclear systems in space.
Alternate organometallic Sb sources are being investigated to improve the characteristics of InSb grown by MOCVD. InSb grown using trimethylindium (TMIn) and trimethylantimony (TMSb) or triethylantimony (TESb) yielded similar quality materials under similar growth conditions. InSb grown using triethylindium (TEIn) and TESB under similar growth conditions yielded very poor quality n-type material. Three new organometallic Sb sources, triisopropyl-antimony (TIPSb), tris(dimethylamino)antimony (TDMASb), and tertiarybutyldimethylantimony (TBDMSb) are being investigated. Growth of InSb using TIPSb, TDMASb, or TBDMSb and TMIn was investigated over 350 to 475{degrees}C. InSb grown from TDMASb had similar properties to InSb grown from TMIn and TMSb when using a similar temperature and V/III ratio range. Growth rates of InSb using TMIn and either TIPSb or TBDMSb at temperatures {le} 425{degrees}C were proportional to both TMIn flow rate and temperature. Surface morphology of InSb grown using either TIPSb or TBDMSb was rough for growth temperatures {le} 425{degrees}C; this may be due to complex decomposition and methyl groups on surface. The InSb with the highest mobility was grown at 400{degrees}C and a V/III ratio of 3 using TIPSb. It was n-type with a carrier concentration of 2.5 {times} 10{sup 15} cm{sup {minus}3} and a mobility of 78,160 cm{sup 2}/Vs at 77 K. Both n- and p-type InSb were grown using TBDMSb with mobilities up to 67,530 and 7773 cm{sup 2}/Vs, respectively at 77 K. Mobility for InSb using either TIPSb or TBDMSb was optimized by going to lower temperatures, pressures, V/III ratios; however, surface morphology improved with higher temperature, pressure, V/III ratio. High mobility InSb with smooth surfaces at T {le} 425{degrees}C was not obtained with TIPSb or TBDMSb and TMIn.
We present the use of an STM to make quantitative observations of time-dependent mass flow associated with the decay of two-dimensional clusters on the Au(lll) surface. When formed and observed in air, layered islands with well-defined edges located on larger terraces are generally found to decay in such a way that their areas decrease linearly in time over periods ranging from minutes to several hours depending on the island size. This is in contrast to the behavior of similar features formed and observed under ultra high vacuum conditions, which do not appear to decay over experimental periods of several days. The linear decay is consistent with models that have been used previously to describe growth of 2-dimensional clusters on surfaces. We discuss possible decay mechanisms`, and the role that adsorbates may play in influencing the decay.
In support of the UST, WeDID, VOC/Non-Arid, and VOC/Arid, and VOC/Arid Integrated Demonstrations, organic contaminants and nitrates in Hanford Underground Storage Tank (UST) wastes, polymeric organics in weapon components, and chlorocarbon soil contaminants have been destroyed by exposure to high-temperature steam during bench tests with a quartz reactor and full-scale tests that used the Synthetica Detoxifier, a commercial one-ton-per-day steam reforming waste destruction system. Reactivation of Granular Activated Carbon (GAC) in the Detoxifier and Thermal Gravimetric Analyses (TGA) of the decomposition of sodium nitrate have also been performed.
We have successfully grown ZnMnTe alloys by molecular beam epitaxy using GaAs as a substrate. Bulk MnTe has the wurtzite crystal structure but the structural phase of the material was confirmed to be zinc-blende by standard {theta}-2{theta} x-ray diffraction techniques. The composition was also determined using x-ray diffraction techniques. Manganese concentration was also estimated from magnetization measurements taken as a function of temperature. Magnetoluminescence studies were performed at 1.4K on the acceptor-bound exciton in the semimagnetic semiconductor ZnMnTe alloys. As expected, the photoluminescence peak energy decreased with increasing magnetic field.
At some landfills, hazardous wastes were placed into disposal pits with other waste oils. Volatile organic wastes, such as cleaning solvents, when combined with oil are much more difficult to remove from the soils because the oil makes the volatile organic chemical evaporate much slower. The typical vacuum extraction remediation method could become a lengthy campaign. Since all chemicals evaporate faster when they are heated, if the contaminated soil could be heated, the chemicals would be easier to remove from the soil. By using heating techniques developed by the Oil and Gas Industry to enhance the removal of oil and gas resources from the soil, the problem of removing contamination from the soils could be solved. The Thermal Enhanced Vapor Extraction System (TEVES) demonstration will combine vacuum vapor extraction technology with powerline frequency soil heating and radiofrequency soil heating to accelerate the soil decontamination process. The premise that soil heating technology can actually reduce the costs of soil decontamination is complicated by the high capital costs of the soil heating equipment and the cost of electrode installation. By performing this field demonstration, Sandia will be able to collect the information needed to see if this new technology will improve the decontamination of soils.
Sandia National Laboratories is a large multiprogram Research and Development laboratory which is operated by a contractor for the US Department of Energy. In the Laboratories, lasers are both the subject of research and the tools that are used in other research, development, and testing activities. Since 1979, laser safety training has been the primary focus of the Laboratories` laser safety program. Approximately 1 100 personnel have been trained in formal courses during that time period. The formal course, presented on site by a contractor, consists of two full days of instruction. The course contents include the following topics: Laser technology and safety overview; Federal and ANSI laser standards summaries; Biological effects of laser radiation; Classification of lasers; Laser hazard analysis; Review of ANSI Z136.1 control measures; Laser eye protection. Recent emphasis on regulatory requirements, conduct of operations, and quality management has revealed a need to change the laser safety training curriculum. A new course for users of low power lasers (Class 2 and 3a) is being developed. A refresher course, a management awareness (self-study) course, and major changes in the current course are planned.
A solar photocatalytic process has been under development at both Sandia National Laboratories and the National Renewable Energy Laboratory (formerly the Solar Energy Research Institute). This process uses solar ultraviolet light to activate a titanium dioxide catalyst which oxidizes organic contaminants in water. In the summer of 1991, a solar photocatalytic detoxification of water system was installed and tested at a California Superfund Site located at Lawrence Livermore National Laboratory. The site was designated a Superfund Site because of widespread groundwater contamination which resulted from the release of chlorinated solvents, principally trichloroethylene, when the site was a Naval Air Station in the early 1940s. The objectives of these experiments were to measure the effects of process variables and the process efficiency in an actual remediation setting, to collect experimental data and operating experience in photocatalytic oxidation of organic contaminants, to develop accurate models of the system operation and to develop control strategies.
The Materials Interface Interaction Tests (MIIT) program involves the comparative performance-evaluation testing of multiple US and foreign nuclear waste glasses (nonradioactive), potential canister and overpack metals, brine, and geologic materials in the rock salt repository environment at the Waste Isolation Pilot Plant (WIPP) facility. We emplaced about 2000 materials specimens onto fiftn, separate test assemblies and exposed them to a heated, salt-brine environment at the WIPP for multi-year periods. We successfully terminated the in situ conduct of the MIIT in July 1991, after five years of testing, and retrieved all samples for posttest laboratory analyses. These 5-year glass and metal samples, along with samples previously retrieved after 0.5, 1, and 2 years, are being analyzed in multiple international laboratories, in a cooperative testing effort. Individual test participants will present available laboratory results, and interpretations, on MIIT specimens in this workshop. Our focus in this paper is to summarize technical details and repository-relevant observations on the in situ conduct, sampling, and termination operations of the MIIT experimental program. Such information should be useful for the interpretation of the laboratory-based analyses. This information also will be relevant and instructive for other organizations contemplating, planning, or conducting additional materials-related, in situ tests.
