Publications

This report describes a capacity planning project for Engineering Information Management (EIM) systems at Sandia National Laboratories. The purpose was to develop a method for predicting the ability of current hardware computer systems to meet future demands and to address the magnitude of required upgrades. Specific activities included the generation and analysis of alternatives, the selection of analytic modeling as the appropriate vehicle, construction and validation of the model, and the development of recommendations.

Ion diode research on Sandia National Laboratories' Particle Beam Fusion Accelerator (PBFA) II has progressed significantly during the past two years as we have operated in the shot-a-day model with well-diagnosed proton and lithium ion diode loads. During this period, we have succeeded in demonstrating efficient proton beam generation and in focusing the beam to a full width at half maximum (FWHM) spot size of 5.2 mm. Power and energy densities equivalent to 5.4 (+0.9, /minus/0.8) TW/cm/sup 2/ and 73 kJ/cm/sup 2/, respectively, on a 6 mm diameter sphere from the full diode were obtained. Tests of ion diode operation with a simple Plasma Opening Switch (POS), opening at a current of 1-2 MA, indicate efficient energy coupling and a rapid turn on of iron when the POS opens. A model of diode operation has been developed which successfully describes the operating impedance of applied-B ion diodes on PBFA II, PBFA I, Proto II, and Proto I. In addition, we have developed the capability to perform particle simulations which have helped to determine optimized insulating magnetic field profiles and anode shapes for efficient ion beam generation and focusing. Lithium ion source experiments on PBFA II have succeeded in delivering 26 kJ of lithium ions to the axis using a field-enhanced LiF ion source. Several active lithium ion sources, which should allow improved lithium began generation and focusing, are now being prepared for testing on PBFA II. 11 refs., 10 figs., 2 tabs.

Personnel at Sandia National Laboratories, the Naval Research Laboratory, Cornell University, and Los Alamos National Laboratory are developing cost effective beams of lithium ions to bridge the energy gap between lasers and underground nuclear explosions in the national Inertial Fusion Program. We plan to probe the threshold for igniting thermonuclear fuel in the laboratory on the Particle Beam Fusion Accelerator II (PBFA II). We have met our April 1, 1989, milestone of 5 trillion watts per square centimeter power density on PBFA II. We wish to adapt the existing Hermes III accelerator at Sandia into a pre-prototype module of the DOE Laboratory Microfusion Facility for military applications in support of the DOE decision in the mid 90s on the best particle beam or laser for the facility. A German-American study concludes that our lithium ion approach offers the lowest cost option for fusion energy. 7 figs.

Superconducting polycrystalline thin films in the Tl-Ca-Bu-Cu-O system have been prepared by electron beam evaporation followed by appropriate sintering and annealing. Transition temperatures to 110 K and critical current densities to 600,000 A/cm/sup 2/ have been attained in oxygen annealed films. However, with only 16 minutes of air sintering and no oxygen anneal, oriented films have been obtained with T/sub c/'s to 107 K and J/sub c/'s to 450,000 A/cm/sup 2/. Single film devices utilizing a parallel array of weak links and a coplanar control line have been fabricated from the films. Oscillators as well as AM and FM modulators operating between 3 and 6 GHz have been demonstrated using this device concept. 24 refs., 4 figs.

A Personnel and Material Tracking System (PMTS) demonstrated at Argonne National Laboratories-West (ANL-W) in 1987 has resulted in the further development of this system. The results of the demonstration indicated immediate potential for the Material Monitoring/Tracking (MM) portion of the system. The MM system provides the separate functions of (1) observing all container movements, (2) authorized access approval,and (3) initiation and receipt of material transfers. All three functions are coordinated through a single computer which is known as the Computer Augmented Material Access (CAMA) computer. The Wireless Alarm Transmission of Container handling (WATCH) system provides Function 1, and the Mobile Accountability Verification Inventory Station (MAVIS) system provides Functions 2 and 3. Faster communications and the expanded and refined software package developed to provide Functions 2 and 3 stands out as the major accomplishment of this project. Increased functionality with enhanced protection against the insider threat in a more friendly operator interface is provided by this software. 3 refs., 2 figs.

In our instrumentation development efforts we find it necessary to be able to evaluate the performance of waveform digitizing systems with sampling rates from a few kilohertz to more than a gigahertz. Our goal has been to develop an integrated system which can provide quantitative results on the performance of systems and subsystems. Here we describe a system which is controlled by a Microvax II with instrumentation control through the IEEE-488 buss. The evaluation procedure is delineated in reference to a Trial Waveform Digitizer Standard generated by the Waveform Measurements and Analysis committee appointed by the Instrumentation and Measurement Society of IEEE. The standard has been recently accepted by the IEEE and will become a published standard. In this work, special focus is given to the accurate measurement of effective-bit performance and differential nonlinearity of waveform digitizers. 3 refs., 8 figs.

This paper presents some simple concepts for fixtures that can be used in two and three-axis vibration testing. Two, two-axis fixtures were built and tested in the laboratory. Test results are shown, and serve to confirm the validity of the concept. Simple methods for extending the concepts for three-axis testing are discussed. 6 refs., 9 figs.

This paper presents a combined analytical and experimental method for establishing a set of equations to evaluate the equivalent forces acting on a structure. The method requires that a finite element model of the structure be established. It further requires that the accelerator responses to the external forces be measured at a number of points on the structure. The equivalent forces established in the analysis are a representation of the actual forces. The equivalent forces concentrate the effects of the external forces at the degrees of freedom where the acceleration responses are measured. 6 refs., 4 figs., 1 tab.

Second harmonic generation was measured for a thin corona-poled film of a dicyanovinyl azo dye incorporated in the side-chain methacrylate polymer. Measurements were performed at a wavelength of 1.58 ..mu..m as a function of incident angle for both p- and s-polarized incident light. From these measurements the form and magnitude of the second harmonic coefficient tensor were determined. The molecular distribution implied by the data is consistent with a thermodynamic potential containing only the dipolar orienting energy acting during poling. We have also demonstrated anomalous-dispersion phase-matched second harmonic generation for the first time using electric field induced second harmonic generation (EFISH) in a liquid solution of Foron Brilliant Blue S-R (FBB). Results are described. 10 refs., 4 figs., 2 tabs.

We report on the first ferroelectric measurements of chemically prepared KNbO/sub 3/ thin films. Polycrystalline KNbO/sub 3/ thin films were fabricated by dip coating substrates with methanolic solutions of potassium hydroxide and niobium ethoxide. Perovskite KNbO/sub 3/ was obtained for both bulk gels and films by using 800/degree/C firing treatments. For films, the intermediate temperature processing schedule was critical for the complete conversion of low temperature phases to perovskite KNbO/sub 3/. Raman spectroscopy and x-ray diffraction analysis confirmed that properly processed films possessed the orthorhombic distortion of the perovskite structure at room temperature. In response to a 1 kHz, sinusoidal field of 300 kV/cm amplitude, we measured the following ferroelectric properties: (1) a remanent polarization of 4.5 ..mu..C/cm/sup 2/, (2) a spontaneous polarization of 8.3 ..mu..C/cm/sup 2/, and (3) a coercive field of 55 kV/cm.

Sandia National Laboratories, in cooperation with industry and other national laboratories, has been benchmarking computer codes (''Structural Code Benchmarking for the Analysis of Impact Response of Nuclear Material Shipping Cask,'' R.E. Glass, Sandia National Laboratories, 1985; ''Sample Problem Manual for Benchmarking of Cask Analysis Codes,'' R.E. Glass, Sandia National Laboratories, 1988; ''Standard Thermal Problem Set for the Evaluation of Heat Transfer Codes Used in the Assessment of Transportation Packages, R.E. Glass, et al., Sandia National Laboratories, 1988) used to predict the structural, thermal, criticality, and shielding behavior of radioactive materials packages. The first step in the benchmarking of the codes was to develop standard problem sets and to compare the results from several codes and users. This step for structural analysis codes has been completed as described in ''Structural Code Benchmarking for the Analysis of Impact Response of Nuclear Material Shipping Casks,'' R.E. Glass, Sandia National Laboratories, 1985. The problem set is shown in Fig. 1. This problem set exercised the ability of the codes to predict the response to end (axisymmetric) and side (plane strain) impacts with both elastic and elastic/plastic materials. The results from these problems showed that there is good agreement in predicting elastic response. Significant differences occurred in predicting strains for the elastic/plastic models. An example of the variation in predicting plastic behavior is given, which shows the hoop strain as a function of time at the impacting end of Model B. These differences in predicting plastic strains demonstrated a need for benchmark data for a cask-like problem. 6 refs., 5 figs.

Obtaining robust phase estimates from phase differences is a problem common to several areas of importance to the optics and signal processing community. Specific areas of application include speckle imaging and interferometry, adaptive optics, compensated imaging, and coherent imaging such as synthetic-aperture radar. The purpose of this paper is to relate the equations describing the phase estimation problem to the general form of elliptic partial differential equations, and illustrate results of reconstructions on large M by N grids using existing, published, and readily available Fortran subroutines. 15 refs., 2 figs.

Vacuum arc remelting (VAR) is the principal secondary melting process used to produce ingots for almost all wrought Alloy 718 applications. We will attempt, with this paper, to summarize our previous work along with other unpublished work as it applies to VAR of Alloy 718. Successful application for a particular alloy/ingot diameter combination is believed to be dependent on achieving quasisteady thermal/solutal conditions at the solidification interfaces. Local thermal environment is strongly influenced by fluid flows which in turn are driven by global temperature gradients (convection) and magnetohydrodynamic (MHD) forces created by the arc's current distribution. Quasisteady conditions are enhanced when the metal vapor arc is stabilized in the diffuse mode where it provides optimal melting efficiency, macrouniform heating, and axisymmetrical fluid flows in the molten pool atop the ingot. Furnace conditions of low ambient gas pressures (<0.01 torr) and short electrode gaps (<10 mm) stabilize the diffuse mode. A transition from convective to magnetically dominant fluid flow occurs in the pool atop the ingot between 6.6 and 7.6 kA for production size ingots. Constricted arcs are stabilized at elevated ambient gas pressures and electrode gaps. Under these arc conditions fluid flows become unsymmetrical with respect to the ingot axis, ''shelf'' forms on portions of the ingot periphery, and melting efficiency is decreased. 19 refs., 13 figs.

Metalloporphyrins have appropriate properties for photosensitizing and catalysts solar energy storage reactions. Fundamental spectroscopic studies of metalloporphyrins and related enzymes that carry out C/sub 1/ chemistry can identify the factors controlling reactivity of the metal complexes. Research has concentrated on mimicking biological methanogenesis through investigation of the enzyme methylreductase, which carries out the final step in the reduction of Co/sub 2/ to methane. Transient and difference Raman spectroscopies were used to investigate the structural features of methylreductase, its nickel-hydrocorphin Cofactor F/sub 430/, and hydrocorphin and porphrin analogs of the active nickel complex. in particular, axial ligation at the nickel site was evaluated under a variety of conditions with the goal of elucidating the mechanism of methane synthesis. Studies of the tin-and antimony-porphyrin photoredox cycles were also carried out as possible solar-driven sources of reductant for biomimetic methane generation. 1 ref., 1 fig.

Packagings for transporting radioactive materials are required to survive exposure to environments. Package designers investigate design and analysis problems through structural and thermal testing of various components or models, using instrumentation to measure physical responses. The acquisition of high quality data from instrumentation is an essential part of the testing activity. To provide this quality of data, we are developing a mobile instrumentation data acquisition system dedicated for use in cask testing. This system is designed to acquire and analyze structural and thermal test data, and to provide leakage measurement capabilities. The mobile instrumentation system is housed in a 13.4m (44-ft) trailer transporter, which is self-contained with air conditioning, heating, and halon fire protection systems. External power from a commercial or motor generator source is line conditioned prior to distribution to the data acquisition equipment inside the trailer, and lightning protection is provided at the point where the measurement devices interface to the data acquisition equipment. This system is capable of performing data analyses and display of the acquired information within thirty minutes after an experiment.

Abstract not provided.

Beginning in April 1985, a working group on heat transfer met under the auspices of the Organization for Economic Cooperation and Development's Committee on Reactor Safety to define a standard problem set which could be used to benchmark codes used to predict cask thermal response. The problem definitions and solutions which resulted from these meetings as described in ''Standard Thermal Problem Set for the Evaluation of Heat Transfer Codes Used in the Assessment of Transportation Packages,'' R.E. Glass, et al., Sandia National Laboratories, 1988 are summarized in this paper. The problems that were defined address each of the major heat transfer mechanisms (conduction, convection, and radiation) that occur in a cask both during normal transport and as a result of the all- engulfing fire scenario. The problems were kept geometrically simple to minimize the resources required to obtain a solution while still addressing actual phenomena. This has resulted in a set of one- and two-dimensional problems. The solutions to this problem set include closed form analytical solutions, experimental data, and consensus of numerical solutions. For each problem the range of numerical solutions are presented. 1 ref., 4 figs., 2 tabs.

Wood is often used as the energy absorbing material in impact limiters, because it begins to crush at low strains, then maintains a near constant crush stress up to nearly 60 percent volume reduction, and there ''locks up.'' Hill has performed tests that show how wood is one of the best absorbers of energy per pound. However, wood's orthotropic behavior for large crush is difficult to model. In the past, analysts have used isotropic foam-like material models for modeling wood. A new finite element technique is presented in this paper that gives a better model of wood crush than the model currently in use. The orthotropic technique is based on locally isotropic, but globally orthotropic (LIGO) assumptions in which alternating layers of hard and soft crushable material are used. Each layer is isotropic; however, by alternating hard and soft thin layer, the resulting global behavior is orthotropic. In the remainder of this paper, the new technique for modeling orthotropic wood crush will be presented. The model is used to predict the crush behavior for different grain orientations of a 5 /times/ 5 inch sample of balsa wood. As an example problem, an impact limiter containing balsa wood as the crushable material is analyzed using both an isotropic model and the alternating layer model. 9 refs., 7 figs.

There has been considerable work over the past few years to study shock-induced solid state chemistry. In the present report, issues raised in the area are reviewed and critical concepts are discussed. The distinctive nature of solid state chemistry compared to liquid and gas phase chemistry is emphasized and material probes suitable for the study of solids are described. In order for solids to react in times less than one microsecond, unusual processes must be initiated in shock compression. Chief among the unique shock processes is the mixing of reactants by the large kinetic energy of shock-compression pulses. Mixing and fluid-like flow can lead to sufficiently intimate contact between reactants to permit complete chemical reaction in the solid state on the time scale of the experiment. Shock-induced solid state chemistry may be described as an unusually intense mechanochemical process. 24 refs., 2 figs.

Solar One is the world's largest central receiver power plant. During the last 4 years the plant availability was 80%, 83%, and 96%, respectively, during hours of sunshine. This reliability is considered to be excellent considering the plant is a first-of-a-kind facility and because it has been subjected to daily cyclic service. In this paper we present the frequencies and causes of the plant outages that occurred. The ten most important causes comprised 72% of the total outage time. Qualitative insights related to the cause and mitigation of these ten are provided. The information presented in this paper will be useful to studies aimed at improving the reliability of future solar central receiver power plants. It is also useful to members of the utility industry who are considering investing in this technology or are considering cyclic operation of conventional power plants. 4 refs., 3 figs.

Several issues have been identified as pertinent to sealing of radioactive waste repositories in bedded salt formations. These issues include: overall seal system functions and strategy for waste isolation; performance requirements for the seal system; need for redundancy; locations of long-term seals in excavations and boreholes; requirements for sealing interbeds and the disturbed rock zone (DRZ) seal stability for the required lifetime; and need for short-term seals in addition to long-term seals. These issues are defined in general terms, and some principles that may be useful in addressing them are presented. Although this presentation derives from experience with bedded salt, it has applicability to domal salt as well.

The following research is proposed: (1) Perform four to six new time-resolved lethality experiments on cadmium at projectile velocities 7 km/s, greater than that of our previous work at 5.2 km/s. The increased velocity will substantially increase the mass percentage of vaporization. Through simulation of these experiments, computer codes can be validated for hypervelocity impact when vaporization occurs. (2) Perform an additional four to six 1-D lethality experiments on zinc. This material undergoes substantial vaporization under the experimental conditions, and would expand our knowledge about the sensitivity of KEW lethality to shock-induced vaporization. (3) Perform two to four ballistic impact experiments with the ballistics gun at Sandia to provide a full validation of computational capabilities used in simulating the 1-D experiments. These experiments would probe phenomenology that is similar to the 1-D experiments, but with multi-dimensional debris propagation. This will extend the confidence in computer modeling to conditions analagous to KEW lethality applications.

A method which is capable of calculating the unsteady flow field around circular-arc bluff bodies of zero thickness is presented. This method utilizes linear vortex panels to model the body surface and a portion of the wake surfaces. Discrete vortices are used to model the remainder of the wake surfaces. Separation is assumed to occur at the sharp edges of the bodies. Numerical results for circular-arc bodies with included angles of less than 180/degree/ are compared with experimental data and found to be in good agreement. 31 refs., 15 figs.

A new recovery parachute system has been designed for the F111 crew escape module (CEM). The system includes a cluster of three 49-ft-dia ringslot-solid parachutes, a Kevlar deployment bag, and an explosively fired drogue gun to deploy the pilot parachute. Tests have been conducted that indicate the parachute system will meet the rate of descent requirement of 25 ft/sec at 5000 ft pressure altitude. To control the drag load developed by the parachutes, a new central reefing/disreefing system has been developed. Since the recovery parachute system is normally deployed crosswind from the CEM, line sail of the suspension lines during early tests was a problem but has been minimized by a dual pilot parachute system. 6 refs., 7 figs.

The possibility of capturing cosmic dust at hypervelocity has been demonstrated in the laboratory and in the unintended Solar Max spacecraft. This technology will enable a comet coma sample return mission and be important for the earth orbital cosmic dust collection mission, i.e., the Space Station Cosmic Dust Collection Facility. Since the only controllable factor in an intact capture of cosmic dust is the capturing medium, characterizing the effectiveness and properties of available capture media would be very important in the development of the technique for capturing hypervelocity cosmic dust intact. We have evaluated various capture underdense media for the relative effectiveness for intact capture. 2 refs., 2 figs.