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Exploiting interfacial water properties for desalination and purification applications

Cygan, Randall T.; Jiang, Ying B.; Alam, Todd M.; Brinker, C.J.; Bunker, B.C.; Leung, Kevin L.; Nenoff, T.M.; Nyman, M.; Ockwig, Nathan O.; Orendorff, Christopher O.; Rempe, Susan R.; Singh, Seema S.; Criscenti, Louise C.; Stevens, Mark J.; Thurmer, Konrad T.; Van Swol, Frank; Varma, Sameer V.; Crozier, Paul C.; Feibelman, Peter J.; Houston, Jack E.; Huber, Dale L.

A molecular-scale interpretation of interfacial processes is often downplayed in the analysis of traditional water treatment methods. However, such an approach is critical for the development of enhanced performance in traditional desalination and water treatments. Water confined between surfaces, within channels, or in pores is ubiquitous in technology and nature. Its physical and chemical properties in such environments are unpredictably different from bulk water. As a result, advances in water desalination and purification methods may be accomplished through an improved analysis of water behavior in these challenging environments using state-of-the-art microscopy, spectroscopy, experimental, and computational methods.

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Synthesis and self-assembly of fcc phase FePt nanorods

Journal of the American Chemical Society

Chen, Min; Pica, Timothy; Jiang, Ying B.; Li, Peng; Yano, Kazuaki; Liu, J.P.; Datye, Abhaya K.; Fan, Hongyou F.

We report a synthesis of FePt nanorods by confining decomposition of Fe(CO)5 and reduction of Pt(caca)2 in surfactant reverse cylindrical micelles. The controlled nucleation and growth kinetics in confined environment allows easy control over Fe/Pt composition, nanorod uniformity, and nanorod aspect ratio. The FePt nanorods tend to self-assemble into ordered arrays along three-dimensions. Directed assembly under external magnetic field leads to two-dimensional ordered arrays, parallel to the substrate magnetic field. We expect that with optimized external magnetic fields, we should be able to assemble these nanorods into orientated one or two-dimensional arrays, providing a uniform anisotropic magnetic platform for varied applications in enhanced data storage, magneto-electron transport, etc. Copyright © 2007 American Chemical Society.

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Proposed research on class I components to test a general approach to accelerated aging under combined stress environments

Cygan, Randall T.; Jiang, Ying B.; Alam, Todd M.; Brinker, C.J.; Bunker, B.C.; Leung, Kevin L.; Nenoff, T.M.; Nyman, M.; Ockwig, Nathan O.; Orendorff, Christopher O.; Rempe, Susan R.; Singh, Seema S.; Criscenti, Louise C.; Stevens, Mark J.; Thurmer, Konrad T.; Van Swol, Frank; Varma, Sameer V.; Crozier, Paul C.; Feibelman, Peter J.; Houston, Jack E.; Huber, Dale L.

This report summarizes research on the aging of Class I components in environments representative of nuclear power plants. It discusses Class IE equipment used in nuclear power plants, typical environments encountered by Class IE components, and aging techniques used to qualify this equipment. General discussions of radiation chemistry of polymers and accelerated aging techniques are also included. Based on the inadequacies of present aging techniques for Class IE equipment, a proposal for an experimental program on electrical cables is presented. One of the main purposes of the proposed work is to obtain relevant data in two areas of particular concern--the effect of radiation dose rate on polymer degradation, and the importance of synergism for combined thermal and radiation environments. A new model that allows combined environment accelerated aging to be carried out is introduced, and it is shown how the experimental data to be generated can be used to test this model.

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5 Results
5 Results