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Systematic study of radioluminescence and light propagation effects in scintillating nanoguide materials

Sweany, Melinda D.; Witzke, Ryan J.; Feng, Patrick L.; Brubaker, Erik M.

Nanoguide optical waveguides are thermally processed materials based on polymers that have different refractive indices. Scintillating versions of these materials have been under development since 2019 and feature PMMA as the low refractive index constituent and Organic Glass Scintillator-polymer blends as the high index component. Characterization efforts to date have focused on the functional characteristics of nanoguide pertaining to its envisioned use in high-resolution transmission radiogra

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Melt Blending: A Tool to Simplify Plastic Scintillator Synthesis

IEEE Transactions on Nuclear Science

Myllenbeck, Nicholas R.; Garcia, Gail F.H.; Benin, Annabelle L.; Feng, Patrick L.; Witzke, Ryan J.; Tran, Huu

Plastic scintillators are widely used as radiation detection media in homeland security and nuclear physics applications. Their attributes include low cost, scalability to large detector volumes, and additive compounding to enable additional material and detection features, such as pulse shape discrimination (PSD), gamma-ray spectroscopy, aging resistance, and coincidence timing. However, traditional chemically cured plastic scintillators (CCS) require long reaction times, and hazardous wet chemical procedures performed by specially trained personnel, and can leave residual monomer, resulting in deleterious optical and material properties. Here, we synthesize melt blended scintillators (MBSs) in 2.5 days using easily accessible solid-state compounding of commercially-available poly(styrene) with 30-60 wt% fluorene-based compound 'P2' to create monolithic detectors with < 100 ppm residual monomer, in several form factors. The best scintillation performance was recorded for 60 wt% P2 in Styron 665, including gamma-ray light yield 139% of EJ- 200 commercial scintillator and PSD figure of merit (FOM) value of 2.65 at 478 keVee, approaching P2 organic glass scintillator (OGS). The capability of MBS to generate fog-resistant scintillators and poly(methyl methacrylate) (PMMA)-based scintillators for use in challenging environments is also demonstrated.

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