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Abstract not provided.

Solar Two was a collaborative, cost-shared project between 11 U. S. industry and utility partners and the U. S. Department of Energy to validate molten-salt power tower technology. The Solar Two plant, located east of Barstow, CA, comprised 1926 heliostats, a receiver, a thermal storage system, a steam generation system, and steam-turbine power block. Molten nitrate salt was used as the heat transfer fluid and storage media. The steam generator powered a 10-MWe (megawatt electric), conventional Rankine cycle turbine. Solar Two operated from June 1996 to April 1999. The major objective of the test and evaluation phase of the project was to validate the technical characteristics of a molten salt power tower. This report describes the significant results from the test and evaluation activities, the operating experience of each major system, and overall plant performance. Tests were conducted to measure the power output (MW) of the each major system, the efficiencies of the heliostat, receiver, thermal storage, and electric power generation systems and the daily energy collected, daily thermal-to-electric conversion, and daily parasitic energy consumption. Also included are detailed test and evaluation reports.

This proposal provides the rationale for an advanced system called Diagnostics-while-drilling (DWD) and describes its benefits, preliminary configuration, and essential characteristics. The central concept is a closed data circuit in which downhole sensors collect information and send it to the surface via a high-speed data link, where it is combined with surface measurements and processed through drilling advisory software. The driller then uses this information to adjust the drilling process, sending control signals back downhole with real-time knowledge of their effects on performance. The report presents background of related previous work, and defines a Program Plan for US Department of Energy (DOE), university, and industry cooperation.

The goal of this document is to estimate the potential impact of proposed new Diagnostics-While-Drilling technology on the cost of electricity (COE) produced with geothermal energy. A cost model that predicts the COE was developed and exercised over the range of conditions found for geothermal plants in flashed-steam, binary, and enhanced-reservoir (e.g., Hot Dry Rock) applications. The calculations were repeated assuming that DWD technology is available to reduce well costs and improve well productivity. The results indicate that DWD technology would reduce the geothermal COE by 2--31%, depending on well depth, well productivity, and the type of geothermal reservoir. For instance, for a typical 50-MW, flashed-steam geothermal power plant employing 3-MW wells, 6,000-ft deep, the model predicts an electricity cost of 4.9 cents/kwh. With the DWD technology envisioned, the electricity cost could be reduced by nearly 20%, to less than 4 cents/kwh. Such a reduction in the cost of electricity would give geothermal power a competitive edge over other types of power at many locations across the US and around the world. It is thus believed that DWD technology could significantly expand the role of geothermal energy in providing efficient, environment-friendly electric generating capacity.

A high-speed data link that would provide dramatically faster communication from downhole instruments to the surface and back again has the potential to revolutionize deep drilling for geothermal resources through Diagnostics-While-Drilling (DWD). Many aspects of the drilling process would significantly improve if downhole and surface data were acquired and processed in real-time at the surface, and used to guide the drilling operation. Such a closed-loop, driller-in-the-loop DWD system, would complete the loop between information and control, and greatly improve the performance of drilling systems. The main focus of this program is to demonstrate the value of real-time data for improving drilling. While high-rate transfer of down-hole data to the surface has been accomplished before, insufficient emphasis has been placed on utilization of the data to tune the drilling process to demonstrate the true merit of the concept. Consequently, there has been a lack of incentive on the part of industry to develop a simple, low-cost, effective high-speed data link. Demonstration of the benefits of DWD based on a high-speed data link will convince the drilling industry and stimulate the flow of private resources into the development of an economical high-speed data link for geothermal drilling applications. Such a downhole communication system would then make possible the development of surface data acquisition and expert systems that would greatly enhance drilling operations. Further, it would foster the development of downhole equipment that could be controlled from the surface to improve hole trajectory and drilling performance. Real-time data that would benefit drilling performance include: bit accelerations for use in controlling bit bounce and improving rock penetration rates and bit life; downhole fluid pressures for use in the management of drilling hydraulics and improved diagnosis of lost circulation and gas kicks; hole trajectory for use in reducing directional drilling costs; and downhole weight-on-bit and drilling torque for diagnosing drill bit performance. In general, any measurement that could shed light on the downhole environment would give us a better understanding of the drilling process and reduce drilling costs.

This report describes progress on the development of engineered photocatalysts for the detoxification of water polluted with toxic organic compounds and heavy metals. We examined a range of different oxide supports (titania, alumina, magnesia and manganese dioxide) for tin uroporphyrin and investigated the efficacy of a few different porphyrins. A water-soluble octaacetic-acid-tetraphenylporphyrin and its derivatives have been synthesized and characterized in an attempt to design a porphyrin catalyst with a larger binding pocket. We have also investigated photocatalytic processes on both single crystal and powder forms of semiconducting SiC with an ultimate goal of developing a dual-semiconductor system combining TiO{sub 2} and SiC. Mathematical modeling was also performed to identify parameters that can improve the efficiency of SiC-based photocatalytic systems. Although the conceptual TiO{sub 2}/SiC photodiode shows some promises for photoreduction processes, SiC itself was found to be an inefficient photocatalyst when combined with TiO{sub 2}. Alternative semiconductors with bandgap and band potentials similar to SiC should be tested in the future for further development and a practical utilization of the dual photodiode concept.

Solar Two will be the world`s largest operating solar central receiver power plant. It is expected to begin operating in April 1996; it is currently undergoing start-up and checkout. The plant will use sunlight reflected from 1926 sun-tracking mirrors to heat molten nitrate salt flowing in a heat exchanger (receiver) that sits atop a 200 foot tower. The heated salt will be stored in a tank for use, when needed, to generate superheated steam for producing electricity with a conventional Rankine-cycle turbine/generator. The purpose of the project is to validate molten-salt solar central receiver technology and to reduce the perceived risks associated with the first full-scale commercial plants. Already, much has been learned during the project including the effects of trace contaminants in the salt and the large effect of wind on the receiver. There is also much that remains to be learned. This report describes the technical status of the Solar Two project including a summary of lessons learned to date.

This study has demonstrated the feasibility of TiO{sub 2} photocatalysis to treat EDTA and several metal-EDTA complexes that can be found in industrial wastewaters. For the EDTA complexes of metals capable of photodeposition, such as Cu and Pb, certain reaction conditions were shown to facilitate the simultaneous complex degradation and photodeposition of these metals onto the catalyst. With metals that do not easily photodeposit, such as Ni and Cd, it is shown that the complex degradation is still facilitated, and can enhance other metals removal processes after photocatalytic treatment. Because the treatment of these metal-EDTA complexes typically requires special measures, there may exist situations where TiO{sub 2} photocatalysis could actually be the preferred method of treatment. However, its use should be compared economically to other more established advanced oxidation technologies. This necessity is demonstrated in the economic comparison to ozone treatment for EDTA degradation alone, where ozone treatment appears to be the clear choice in this application.

A number of experiments were conducted to determine the economic viability of applying various ultraviolet (UV) oxidation processes to a waste water stream containing approximately 12 mg/L total organic carbon (TOC), predominately ethylene glycol. In all experiments, a test solution was illuminated with either near-UV or a far-UV light alone or in combination with a variety of photocatalysts and oxidants. Based upon the outcomes of this project, both UV/photocatalysis and UV/ozone processes are capable of treating the water sample to below detection capabilities of TOC. However, the processes are fairly energy intensive; the most efficient case tested required 11 kWh per order of magnitude reduction in TOC per 1000 L. If energy consumption rates of 5-10 kWh/1000 L are deemed reasonable, then further investigation is recommended.

This report describes the results of experiments performed to determine the viability of titanium dioxide photocatalysis towards the treatment of water contaminated with different metal-EDTA complexes. Both the PB-EDTA and Ni-EDTA complexes were chosen for study, as they represent respectively metals that are and are not capable of photodeposition onto the TiO{sub 2} catalyst during the photoreaction. Batch reactions were carried out in a jacketed glass pot reactor using 300 ml of 50m g/l metal chelated with an equimolar amount of EDTA and 0.1wt% of TiO{sub 2} in the solution. The UV source used was a 100 W low-pressure Hg spot lamp. The two systems were studied using Degussa P-25 titanium dioxide, and Aldrich titanium dioxide loaded with Pt and Au. Around 80% removal of the Ni-EDTA complex was attained after 120 min using both catalysts with no photodeposition of Ni onto the catalyst. However, pH precipitation treatment of the reacted solutions indicated that the Ni was still complexed, probably to complexing agents that were EDTA oxidation products. Apparent zero-order kinetics was observed in the P-25 catalyst reaction, whereas apparent first-order kinetics was observed in the metal-loaded TiO{sub 2} catalyst. In contrast the Pb-EDTA complex was completely removed in 10 min using both catalysts. Also, complete Pb deposition onto the catalyst was attained in 30 min for both catalysts. The Pb deposition seemed to first require the degradation of the complex. Total organic carbon was reduced in the Ni-EDTA system 15--21% using both catalysts, and about 33% in the Pb-EDTA system using both catalysts. No reduction of either metal or metal complex was observed when no catalyst was present and the other conditions held constant.

Tests were performed to evaluate the corrosivity of several nitrate salt mixtures on the containment materials likely to be used in a molten-salt solar central receiver power plant. Objective was to determine if common salt impurities (e.g., chloride) aggravate corrosion. The test was conducted for 7008 hours on A36 carbon steel at 320C and 304 and 316 stainless steels at 570C. Seven salt mixture containing a variety of impurity concentrations were used. Corrosion rates were determined by descaled weight loss for coupons removed periodically from the melts. The nitrate mixtures were analyzed for changes in impurity levels and accumulation of soluble corrosion products. Test results indicate generally that corrosion is slow and that impurities do not contribute dramatically to corrosion rates of carbon and stainless steels.

Researchers around the world have demonstrated the effectiveness of titanium dioxide-based photocatalysis for decontaminating water containing hazardous organics and heavy metals. A great advantage of this process is that the organic is completely destroyed, leaving behind only water, carbon dioxide and dilute mineral acids. Also, the process has potential for doing two decontamination jobs at once: oxidizing organics while reducing toxic metals. As part of a program sponsored by the DOE, Sandia National Laboratories is carrying out large-scale tests to study the solar destruction of organics at realistic processing rates in addition to laboratory work aimed at determining the applicability of solar detoxification to the removal of heavy metals. In this paper, we present up-to-date results from Sandia's effort. The large-scale tests illustrate the effectiveness of solar detoxification for a variety of organics and compare measured reaction rates against published values of the rate constants for attack by aqueous hydroxyl radicals. This comparison highlights the importance of hydroxyl radical chemistry in solar detoxification processes. It is concluded that solar detoxification is only feasible for easily destroyed compounds like TCE, and PCE. The chlorinated methanes and ethanes are much more difficult to destroy and require very large solar collectors. In the second part of the paper, laboratory data are presented for a variety of different metals, including Ag, Cd, Cu, Hg, Ni, and Pt. The concentration of dissolved oxygen is one of the variables in the study. It is shown that the presence of dissolved metals can have a profound effect on organic oxidation rate, and that oxygen is not necessarily required for oxidation to occur. It is concluded that solar detoxification would be useful for removing mercury and silver but not for copper, nickel nor cadmium. 38 refs., 7 figs., 2 tabs.