Synthesis and characterization of ionic liquids containing copper manganese or zinc coordination cations
Dalton Transactions
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Jump to search filtersSynthesis of an ionic liquid with an iron coordination cation
Dalton Transactions
An iron-based ionic liquid, Fe((OHCH2CH2) 2NH)6(CF3SO3)3, is synthesized in a single-step complexation reaction. Infrared and Raman data suggest NH(CH2CH2OH)2 primarily coordinates to Fe(iii) through alcohol groups. The compound has Tg and Td values of -64°C and 260°C, respectively. Cyclic voltammetry reveals quasi-reversible Fe(iii)/Fe(ii) reduction waves. © 2010 The Royal Society of Chemistry.
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