Publications Details

Improved quantum yield in geometrically constrained tetraphenylethylene-based metal-organic frameworks

Sava Gallis, Dorina F.; Deneff, Jacob I.; Reyes, Raphael A.; Rodriguez, Mark A.; Valdez, Nichole R.; Rohwer, Lauren E.; Stawiasz, Katherine J.; Woods, Toby J.; Lawal, Abdul; Moore, Jeffrey S.

Herein, we report the synthesis of a novel, tetraphenylethylene-based ligand for metal-organic frameworks (MOFs). Incorporation of this ligand into a Zn- or Eu-based MOF increased the quantum yield (QY) by almost 2.5× compared to the linker alone. Furthermore, the choice of guest solvent impacted the QY and solvatochromatic response. These shifts are consistent with solvent dielectric constant as well as molecular polarizability.