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Formation, motion and high temperature superconductivity of large bipolarons
Bipolaronic superconductivity requires two exceptional circumstances. First, at least some charge carriers must form bipolarons. Second, these bipolarons must be mobile (move coherently). However, beyond quasi-one-dimensional electronic systems, bipolarons have heretofore always been found to be ''small.'' Small (bi)polarons are very compact (bi)polarons that localize rather than move coherently. Thus, small bipolarons are not suitable carriers for bipolaronic superconductivity. However, in analogy with the case of large polarons, less compact bipolarons, ''large'' bipolarons, are expected to be mobile. These observations lead one to ask if and when large bipolarons can form in multi-dimensional electronic systems. Here the results of studies of the formation, motion and superconductivity of large bipolarons are summarized. 5 refs.