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Diffusive Properties of UNESE Core Samples via Continuously Monitored Mass Spectroscopy

Broome, Scott T.; Paul, Matthew J.

The transport properties of porous geological media are of fundamental importance when modeling the migration of chemical and radiological species in subterranean systems. Due to their relatively high mobility, short-lived noble gas species are of particular interest as detection of these species at the surface is a tell-tale indicator of recent nuclear activity. However, determining the diffusivity of these species is challenging due to their inert and transparent nature, requiring chemically insensitive techniques, such as mass spectroscopy, to quantify noble gas concentrations. The work described herein details recent advances in the methodology for determining diffusivity on porous media and results obtained on samples relevant to the UNESE project.