Publications Details
Condensed phase thermochemistry of reactor core debris
This paper discusses a nonideal solution model of the metallic phases of reactor core debris. The metal phase model is based on the Kohler equation for a 37 component system. The binary subsystems are assumed to have subregular interactions. The model is parameterized by comparison to available data and by estimating subregular interactions using the methods developed by Miedama et al. The model is shown to predict phase separation in the metallic phase of core debris. The model also predicts reduced chemical activities of zirconium and tellurium in the metal phase. A model of the oxide phase of core debris is described briefly. The model treats the oxide phase as an associated solution. The chemical activities of solution components are determined by the existence and interactions of species formed from the components.