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Dynamic Electromechanical Characterization of Axially Poled PZT 95/5

Furnish, Michael D.

We are conducting a comprehensive experimental study of the electromechanical behavior of poled PZT 95/5 (lead zirconate titattate). As part of this study, eight plane-wave tests have been conducted on axially poled PZT 95/5 at stress levels ranging from 0.9 to 4.6 GPa, using VISAR and electrical diagnos- tics. Observed wave velocities were slightly decreased from ultrasonic vahtes, by contrast' with unpoled samples. Compression waveforms show a step at 0.6 GPa more marked than for normally poled or unpoled samples; this may correspond to a poling effect on the ferroelectric/antiferroelectric transition. A similar step is observed on release. The released charge upon loading to 0.9 GPa is consistent with nearly complete depoling. Loading to higher stresses gave lower currents (factor of 10), suggesting shock-induced conduc- tivity or electrical breakdown.

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The Development of a Ceramic Mold for Hot-Forging of Micro-Magnets

Garino, Terry J.

A new mold material has been developed for use in making rare-earth permanent magnet components with precise dimensions in the 10 to 1000 µm range by hot-forging. These molds are made from molds poly(methyl)methacrylate (PMMA) made by deep x-ray lithography (DXRL). An alumina bonded with colloidal silica has been developed for use in these molds. This material can be heated to 950°C without changing dimensions where it develops the strength needed to withstand the hot-fmging conditions (750°C, 100 MPa). In addition, it disintegrates in HF so that parts can be easily removed after forging.

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Anisotropic Magnetism in Field-Structured Composites

Journal of Applied Physics

Martin, James E.

Magnetic field-structured-composites (FSCs) are made by structuring magnetic particle suspensions in uniaxial or biaxial (e.g. rotating) magnetic fields, while polymerizing the suspending resin. A uniaxial field produces chain-like particle structures, and a biaxial field produces sheet-like particle structures. In either case, these anisotropic structures affect the measured magnetic hysteresis loops, with the magnetic remanence and susceptibility increased significantly along the axis of the structuring field, and decreased slightly orthogonal to the structuring field, relative to the unstructured particle composite. The coercivity is essentially unaffected by structuring. We present data for FSCs of magnetically soft particles, and demonstrate that the altered magnetism can be accounted for by considering the large local fields that occur in FSCs. FSCS of magnetically hard particles show unexpectedly large anisotropies in the remanence, and this is due to the local field effects in combination with the large crystalline anisotropy of this material.

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Thermal Fusing Model of Conducting Particle Composites

Journal of Applied Physcis

Martin, James E.

Composites of carbon black particles in polyethylene are known to exhibit an unusually rapid increase in resistivity as the applied field is increased, making this material useful in automatically resettable fuses. In this application the composite is in series with the circuit it is protecting: at low applied voltages this circuit is the load, but at high applied voltages the composite becomes the load, limiting the current to the circuit. We present a simple model of this behavior in terms of a network of nonlinear conductors. Each conductor has a conductance that depends on its instantaneous Joule heating. It is shown that in the fusing regime, where the current through the composite decreases with increasing voltage, an plate-like dissipation instability develops normal to the applied field. Experimental evidence of this phenomena is described.

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Syngas Conversion to Fuels and Chemicals

Jackson, Nancy B.

Iron catalysts are particularly useful for Fischer-Tropsch (FT) synthesis when the H2 to CO ratio of the synthesis gas is low since iron exhibits water gas shift as well as FT activity. Iron catalysts are active for Fischer Tropsch synthesis only when in the carbide state. The active iron carbide catalyst has a 1-3 nm carbonaceous layer, which can only be found on the carbided iron catalyst (no carbonaceous material is found on iron oxide particles that maybe present). This paper will address the nature of the carbonaceous material that is required for product formation. The carbonaceous material is amorphous, does not require hydrogen to form, and is the starting material for FT products.

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Hydrogen as a New Alloying Element in Metals

Shapovalov, Vladimir

Hydrogen was regarded as a harmful impurity in many alloys and particularly in steels where it gives rise to a specific type of embrittlement and forms various discontinuities like flakes and blowholes. For this reason, the researcher efforts were mainly focused on eliminating hydrogen's negative impacts and explaining its uncommonly high diffusivity in condensed phases. Meanwhile, positive characteristics of hydrogen as an alloying element remained unknown for quite a long time. Initial reports in this field did not appear before the early 1970s. Data on new phase diagrams are given for metal-hydrogen systems where the metal may or may not form hydrides. Various kinds of hydrogen impact on structure formation in solidification, melting and solid-solid transformations are covered. Special attention is given to the most popular alloys based on iron, aluminum, copper, nickel, magnesium and titanium. Detailed is what is called gas-eutectic reaction resulting in a special type of gas-solid structure named gasarite. Properties and applications of gasars - gasaritic porous materials - are dealt with. Various versions of solid-state alloying with hydrogen are discussed that change physical properties and fabrication characteristics of metals. Details are given on a unique phenomenon of anomalous spontaneous deformation due to combination of hydrogen environment and polymorphic transformation. All currently known versions of alloying with hydrogen are categorized for both hydride-forming and non-hydrid forming metals.

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Particle Defect Reduction in the Endura Titanium Nitride PVD Sputter System

Peebles, Diane

Particles are inevitably generated in physical vapor deposition (PVD) systems due to the delamination of deposited films on various process chamber parts and shielding. Non-collimated (blanket) and collimated PVD Titanium Nitride (TiN) deposition processes are used for metal ARC (anti-reflective coating) and underlayers, and for the "contact liner" deposition steps (TiN adhesion layers before plug formation). Probe yield analysis and SRAM bit failure analysis, using conventional failure analysis, have shown that particles at these process steps can have a significant impact on wafer yields. In many typical semiconductor wafer fabs, particles generated by TiN film deposition rank consistently at or near the top of the defect pareto. This paper summarizes the results of defect reduction experiments conducted on an Applied Materials Endura Physical Vapor Deposition (PVD) system and various off-line experiments examining film and adhesion characteristics. It includes the results of film adhesion and shield temperature control experiments aimed at reducing defect levels. Key fidings, particle reduction results, and recommended defect reduction measures are presented. The reduction in particles not only can improve yields, but also result in substantial cost savings through the extension of chamber kit end-of-life (EOL).

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Transformation Mechanism and Kinetics for the Pressure-Induced Phase Transition in Shocked CdS

Knudson, Marcus D.

The pressure-induced phase transition in CdS was investigated using picosecond time-resolved electronic spectroscopy in plate impact shock wave experiments. Real-time changes in the electronic spectra were observed, with 100 ps time resolution, in single crystals of CdS shocked along the c and a axes to peak stresses between 35 and 90 kbar (above the phase transition stress of approximately 30 kbar measured in continuum studies). When shocked to stresses above approximately 50 kbar along the crystal c axis and 60 to 70 kbar along the crystal a axis, the crystals undergo a very rapid change in electronic structure, indicating that significant structural changes occur within the first 100 ps. These results, along with previous ns continuum measurements, make a strong case for a metastable state during the phase transition in shocked CdS. Ab-initio periodic Hartree-Fock calculations (with DFT correlation corrections) were employed to examine the compression of CdS and to determine a possible lattice structure for the proposed metastable structure. These results, along with details of the transformation kinetics and orientational dependence, will be discussed. Work supported by ONR.

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Use of Stimulated Emission to Measure R-Line Shifts in Shocked Ruby Crystals

Knudson, Marcus D.

In previous studies, ruby R-line shifts under shock compression and tension have been measured using the spontaneous luminescence from optically pumped samples. Signal intensities obtained through the use of this method are limited by the short time duration of the experiments (100 ns to several ps) in comparison to the long lifetime of the luminescence (approximately 3 ins). We have investigated the use of stimulated emission as a technique for measuring R-line shifts in shocked ruby crystals. Feasibility experiments were performed both at ambient conditions and under shock compression to 60 kbar using an experimental configuration similar to that used for time resolved ruby luminescence measurements in previous shock wave studies. Signal gain due to stimulated emission was observed, with gains ranging from 1.1 to 3.4, in agreement with calculations performed for the particular experimental configuration used. The present results make a good case for incorporating this technique to measure shock induced R-line shifts in ruby. Work supported by DSWA.

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First Principles Calculations of the Interaction of Blast Waves with Aqueous Foams

Harper, Frederick T.

A series of two-dimensional hydrodynamic calculations using the two-dimensional Second- order Hydrodynamic Automated Mesh Refinement Code (SHAMRC) developed by Applied Research Associates, Inc. (ARA), was made with the objective of understanding the behavior of aqueous foams in the presence of a C4-generated blast wave. A full three-phase water equation-of-state was incorporated in the first calculation. Comparison of the results of the first calculation with experimental data collected by Sandia National Laboratories (SNL) indicated that the interaction was much more complicated than could be represented by a mixture of detonation products, air, and water in local temperature and pressure equilibrium. Other models were incorporated in the code to examine the effects of thermal non-equilibrium between water and the gases and allowed for two-phase flow. The water droplets were allowed to slip relative to the gas velocity, providing non-equilibrium for the velocity distribution. These models permitted heated liquid droplets to be accelerated at high pressures and transported through and ahead of the decaying shock front. The droplets then exchanged momentum and energy with the foam ahead of the shock and preconditioned the medium through which the shock was propagating. This process had the effect of diffusing the shock front and its associated energy. These relatively high resolution calculations develop numerical representations of the Rayleigh-Taylor instabilities at the detonation products/foam interface. This unstable interface plays in important role in understanding the behavior of the interaction of the detonation products with the foam. Figure 4 clearly shows the developing instabilities at the interface and an inward facing shock at a radius of 25 cm. The results of the calculations using the various models can be edited to provide the total energy exchanged between materials, the fraction of water vaporized, and the extent of detonation products as a function of time.

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Issues Arising from Plasma-Wall Interactions in Inner-Class Tokamaks

Nuclear Fusion

Wampler, William R.

This section reviews physical processes involved in the implantation of energetic hydrogen into plasma facing materials and its subsequent diffusion, release, or immobilization by trapping or precipitation within the material. These topics have also been discussed in previous reviews. The term hydrogen or H is used here generically to refer to protium, deuterium or tritium.

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Status of Repetitive Pulsed Power at Sandia National Laboratories

Schneider, Larry X.

Multi-kilojoule repetitive pulsed power technology moved from a laboratory environment into its first commercial application in 1997 as a driver for ion beam surface treatment. Sandia's RHEPP II, a repetitive 2.5 kJ/pulse electron beam accelerator, has supported the development of radiation treatment processes for polymers and elastomers, food products, and high dose- rate effects testing for defense programs since early 1996. Dos Lineas, an all solid-state testbed, has demonstrated synchronization techniques for parallel magnetic modulator systems and is continuing the development of design standards for long lifetime magnetic switches and voltage adders at a shot rate capability that exceeds 5x106 pulses per day. This paper will describe progress in multi-kilojoule class repetitive pulsed power technology development, limitations of magnetic switching technology for accelerator and modulator applications, and future research and development directions.

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Magnetic Modulator Lifetime Tests Using the Sandia Reliability Test-Bed

Reed, Kim W.

Experimental results are presented that provide design guidelines for high repetition rate, long-life pulsed power magnetic modulators. Fault mechanisms that occurred during a series of 32 million shots at 100 pps, with continuous runs of up to 5.7 million shots (~16 hours) on the Dos Lineas magnetic modulator are described. An effort to explain the fault mechanisms and how to avoid them is made. Factors that limit the long life performance of a variety of components including switches, cables and oil are encountered. The high reliability of the magnetic switch technology is demonstrated.

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Predicted Pulsed-Power/Flash-Lamp Performance of the NIF Main Amplifier

Smith, David L.

The laser glass for the National Ignition Facility (NIF) Main Amplifier system is pumped by a system of 192 pulsed power/flash lamp assemblies. Each of these 192 assemblies consists of a 1.6 MJ (nominal) capacitor bank working with a Pre-Ionization/Lamp Check (PILC) pulser to drive an array of 40 flash lamps. This paper describes the predicted performance of these Power Conditioning System (PCS) modules in concert with flashlamp assemblies in NIF. Each flashlamp assembly consists of 20 parallel sets of lamps in series pairs. The sensitivity of system performance to various design parameters of the PILC pulser and the main capacitor bank is described. Results of circuit models are compared to sub-scale flashlamp tests and to measurements taken in tests of a PCS module driving a flashlamp assembly in the First Article NIF Test Module facility at Sandia National Laboratories. Also included are predictions from a physics-based, semi-empirical amplifier gain code.

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Investigation of the Transmission of Substituent Effects by (29)si NMR

Assink, Roger A.

Long range substituent effects on the 29Si NMR chemical shifts in a series of alkylene and arylene-bridged triethoxysilanes were observed over as many as 11 bonds. The hydrolysis reaction of an ethoxide caused the resonance of the silicon on the opposing end of the bridging unit to move downfield. The alkylene bridging units ranged from ethylene to octylene while the arylene bridging units included phenyl and biphenyl. Resonance assignments were confirmed by the absence of these shifts for the triethoxysilyl in l-triphenylsilyl-2-triethoxysilylethane. The magnitude of the downfield shift decreased as the length of the bridging unit between silicon atoms increased. Transmission of the substituent effect along a polyethylene chain was successfully modeled by a through-bond mechanism with an attenuation factor of 1.88 for each methylene unit.

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Investigation of Solidification in the Laser Engineered Net shaping (LENS) Process

Griffith, Michelle L.

The Laser Engineered Net Shaping (LENSm) process is a laser assisted, direct metal manufacturing process under development at Sandia National Laboratories. The process incorporates features from stereo lithography and laser surfacing, using CAD file cross-sections to control the forming process. Powder metal particles (less than 150 micrometers) are delivered in a gas stream into the focus of a NdYAG laser to form a molten pool. The part is then driven on an x/y stage to generate a three-dimensional part by layer wise, additive processing. In an effort to understand the thermal behavior of the LENS process, in-situ high-speed thermal imaging has been coupled with microstructural analysis and finite element modeling. Cooling of the melt is accomplished primarily by conduction of heat through the part and substrate, and depending on the substrate temperature and laser input energy, cooling rates can be varied from 10 sup2; to 10 sup3; K s-l. This flexibility allows control of the microstructure and properties in the part. The experiments reported herein were conducted on 316 stainless steel, using two different particle size distributions with two different average particle sizes. Thermal images of the molten pool were analyzed to determine temperature gradients and cooling rates in the vicinity of the molten pool, and this information was correlated to the microstructure and properties of the part. Some preliminary finite element modeling of the LENS process is also presented.

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Next Generation Thin Films for Photovoltaics: InGaAsN

Jones, Eric D.

A new semiconductor alloy system, InGaAsN, has been identified as a can- didate material for multi junction solar cells having efficiencies greater than 40%. The introduction of small amounts of nitrogen ( 2%) into the InGaAs alloy system greatly reduces the band gap energy, with reductions approaching 0.4 eV for 2% nitrogen content With the appropriate ratio of indium to nitrogen concentrations, InGaAsN can be lattice matched to GaAs.

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Spatially-Resolved Ion Trajectory Measurements During Cl(2) Reactive Ion Beam Etching and Ar Ion Beam Etching

Vawter, G.A.; Woodworth, Joseph R.; Zubrzycki, Walter J.

The angle of ion incidence at the etched wafer location during RIBE and IBE using Cl2, Ar and O2 ion beams has been characterized using an ion energy and angle analyzer. Effects of beam current and accelerator grid bias on beam divergence and the spatial uniformity of the spread of incident angles are measured. It is observed that increased total beam current can lead to reduced current density at the sample stage due to enhanced beam divergence at high currents. Results are related to preferred etch system design for uniform high-aspect-ratio etching across semiconductor wafers.

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Advanced LabVIEW Labs

Jones, Eric D.

In the world of computer-based data acquisition and control, the graphical interface program LabVIEW from National Instruments is so ubiquitous that in many ways it has almost become the laboratory standard. To date, there have been approximately fifteen books concerning LabVIEW, but Professor Essick's treatise takes on a completely different tack than all of the previous discussions. In the more standard treatments of the ways and wherefores of LabVIEW such as LabVIEW Graphical Programming: Practical Applications in Instrumentation and Control by Gary W. Johnson (McGraw Hill, NY 1997), the emphasis has been instructing the reader how to program LabVIEW to create a Virtual Instrument (VI) on the computer for interfacing to a particular instruments. LabVIEW is written in G a graphical programming language developed by National Instruments. In the past the emphasis has been on training the experimenter to learn G . Without going into details here, G incorporates the usual loops, arithmetic expressions, etc., found in many programming languages, but in an icon (graphical) environment. The net result being that LabVIEW contains all of the standard methods needed for interfacing to instruments, data acquisition, data analysis, graphics, and also methodology to incorporate programs written in other languages into LabVIEW. Historically, according to Professor Essick, he developed a series of experiments for an upper division laboratory course for computer-based instrumentation. His observation was that while many students had the necessary background in computer programming languages, there were students who had virtually no concept about writing a computer program let alone a computer- based interfacing program. Thus the beginnings of a concept for not only teaching computer- based instrumentation techniques, but aiso a method for the beginner to experience writing a com- puter program. Professor Essick saw LabVIEW as the perfect environment in which to teach computer-based research skills. With this goal in mind, he has succeeded admirably. Advanced LabVIEW Labs presents a series of chapters devoted to not only introducing the reader to LabVIEW, but also to the concepts necessary for writing a successful computer pro- gram. Each chapter is an assignment for the student and is suitable for a ten week course. The first topic introduces the while loop and waveform chart VI'S. After learning how to launch LabVIEW, the student then leans how to use LabVIEW functions such as sine and cosine. The beauty of thk and subsequent chapters, the student is introduced immediately to computer-based instruction by learning how to display the results in graph form on the screen. At each point along the way, the student is not only introduced to another LabVIEW operation, but also to such subjects as spread sheets for data storage, numerical integration, Fourier transformations', curve fitting algorithms, etc. The last few chapters conclude with the purpose of the learning module, and that is, com- puter-based instrumentation. Computer-based laboratory projects such as analog-to-digital con- version, digitizing oscilloscopes treated. Advanced Lab VIEW Labs finishes with a treatment on GPIB interfacing and finally, the student is asked to create an operating VI for temperature con- trol. This is an excellent text, not only as an treatise on LabVIEW but also as an introduction to computer programming logic. All programmers, who are struggling to not only learning how interface computers to instruments, but also trying understand top down programming and other programming language techniques, should add Advanced Lab-VIEW Labs to their computer library.

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A 2-D Self-Consistent DSMC Model for Chemically Reacting Low Pressure Plasma Reactors

Bartel, Timothy J.

This paper will focus on the methodology of using a 2D plasma Direct Simulation Monte Carlo technique to simulate the species transport in an inductively coupled, low pressure, chemically reacting plasma system. The pressure in these systems is typically less than 20 mtorr with plasma densities of approximately 10{sup 17} {number_sign}/m{sup 3} and an ionization level of only 0.1%. This low ionization level tightly couples the neutral, ion, and electron chemistries and interactions in a system where the flow is subsonic. We present our strategy and compare simulation results to experimental data for Cl{sub 2} in a Gaseous Electronics Conference (GEC) reference cell modified with an inductive coil.

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Z-Pinch Generated X-Rays Demonstrate Indirect-Drive ICF Potential

Physical Review Letters

Sanford, Thomas W.L.

Hohlraums (measuring 6-mm in diameter by 7-mm in height) have been heated by x-rays from a z-pinch. Over measured x-ray input powers P of 0.7 to 13 TW, the hohlraum radiation temperature T increases from {approximately}55 to {approximately}130 eV, and is in agreement with the Planckian relation P-T{sup 4}. The results suggest that indirect-drive ICF studies involving NIF relevant pulse shapes and <2-mm diameter capsules can he studied using this arrangement.

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Cs, Sr, and Ba Sorption on Clays and Fe-Oxides

Westrich, Henry R.

Technical guidance for performance assessment (PA) of low-level radioactive waste (LLRW) sites is currently dependent upon experimental retardation factors (K{sub D}'s) to predict radionuclide transport. Accurate predictions of waste transport or retardation will require mechanistic models of radionuclide sorption so as to be applicable to a wide range of soil/groundwater environments. To that end, we have investigated Cs{sup +}, Sr{sup +}, and Ba{sup 2+} sorption on several clay and Fe-oxide minerals. Relative metal binding strengths for montmorillonite clay decrease from Ba{sup 2+} to Sr{sup +}, which is similar to that sorption trend noticed for kaolinite. Molecular dynamics simulations for kaolinite suggest that Cs{sup +} is sorbed at aluminol (010) edge sites as an inner-sphere complex and weakly sorbed as an outer-sphere complex on (001) basal surfaces. Sorption is thought to occur on similar sites for smectite clays, however, the basal plane residual charge and its increased basal plane exposure should have a greater influence on metal sorption. On the other hand, phase transformation kinetics (e.g., ferrihydrite to goethite) is a very important control of metal sorption and resorption for Fe-oxides/hydroxides. These results provide a basis for understanding and predicting metal sorption on complex soil minerals.

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Large Distributed Data Acquisition System at the Z Facility

Potter, James E.

Experiments at the Z machine generate over four hundred channels of waveform data on each accelerator shot. Most experiments require timing accuracy to better than one nanosecond between multiple distributed recording locations throughout the facility. Experimental diagnostics and high speed data recording equipment are typically located within a few meters of the 200 to 300 terawatt X- ray source produced during Z-pinch experiments. This paper will discuss techniques used to resolve the timing of the several hundred data channels acquired on each shot event and system features which allow viewing of waveforms within a few minutes after a shot. Methods for acquiring high bandwidth signals in a severe noise environment will also be discussed.

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A High Resolution Sub-Micron Retarding Field Energy Analyzer for Low Temperature Plasma Analysis

Blain, Matthew G.

A retarding potential energy analyzer having 750 nm diameter, self-aligned grid apertures and micron scale grid separation has been fabricated using polycrystalline silicon and silicon dioxide. High resolution in situ measurements of ion velocity distributions have been demonstrated in inductively coupled argon plasmas. Measurement results agree well with those from a macroscopic analyzer. Important differences are observed in the energies of plasma ions when measured with respect to chamber wall versus those measured with respect to the plasma floating potential. Preliminary measurements under rf bias conditions have also been made and results follow the expected trends.

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Chemical Soil Physics Phenomena for Chemical Sensing of Buried UXO

Phelan, James M.

Technology development efforts are under way to apply chemical sensors to discriminate inert ordnance and clutter from live munitions that remain a threat to reutilization of military ranges. However, the chemical signature is affected by multiple environmental phenomena that can enhance or reduce its presence and transport behavior, and can affect the distribution of the chemical signature in the environment. For example, the chemical can be present in the vapor, aqueous, and solid phases. The distribution of the chemical among these phases, including the spatial distribution, is key in designing appropriate detectors, e.g., gas, aqueous or solid phase sampling instruments. A fundamental understanding of the environmental conditions that affect the chemical signature is needed to describe the favorable and unfavorable conditions of a chemical detector based survey to minimize the consequences of a false negative. UXO source emission measurements are being made to estimate the chemical flux from a limited set of ordnance items. Phase partitioning analysis has been completed to show what the expected concentrations of chemical analytes would be fi-om total concentrations measured in the soil. The soil moisture content in the dry region has been shown to be critical in the attenuation of soil gas concentrations by increased sorption to soil particles. Numerical simulation tools have been adapted to include surface boundary conditions such as solar radiation, surface boundary layer (which is a function of wind speed), precipitation and evaporation, and plant cover/root density to allow transport modeling and evaluate long term processes. Results of this work will provide performance targets for sensor developers and support operational decisions regarding field deployments.

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Computational Fluid Dynamics Modeling of a Lithium/Thionyl Chloride Battery with Electrolyte Flow

Nagasubramanian, Ganesan

A two-dimensional model is developed to simulate discharge of a lithium/thionyl chloride primary battery. The model accounts for not only transport of species and charge, but also the electrode porosity variations and the electrolyte flow induced by the volume reduction caused by electrochemical reactions. Numerical simulations are performed using a finite volume method of computational fluid dynamics. The predicted discharge curves for various temperatures are compared to the experimental data with excellent agreement. Moreover, the simulation results. in conjunction with computer visualization and animation techniques, confirm that cell utilization in the temperature and current range of interest is limited by pore plugging or clogging of the front side of the cathode as a result of LiCl precipitation. The detailed two-dimensional flow simulation also shows that the electrolyte is replenished from the cell header predominantly through the separator into the front of the cathode during most parts of the discharge, especially for higher cell temperatures.

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Task V of the IEA Photovoltaic Power Systems Program: Implementing Accomplishments and Activities

Bower, Ward

The International Energy Agency (IEA) is an energy forum for 24 industrialized countries and was established in 1974 as an autonomous body within the Organization for Economic Cooperation and Development (OECD). The IEA Photovoltaic Power Systems (PVPS) program implementing agreement was signed in 1993, and renewed for another five years in 1998. Twenty-two countries are collaborating under the auspices of the IEA in the PVPS to address common technical and informational barriers that often limit the rate at which photovoltaic technologies advance into the markets. Task V of the IEA PVPS is entitled "Grid Interconnection of Building-Integrated and Other Dispersed Photovoltaic Power Systems." The task sponsored a workshop in September 1997 on grid-interconnection of photovoltaic systems and is planning a second workshop to address impacts of more penetration of dispersed systems into the utility grid. This paper will summarize the accomplishments of Task V over the last five years and will detail the planned work for the next three years.

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Risk Insights Gained from Fire Incidents

Nowlen, Steven P.

There now exist close to 20 years of history in the application of Probabilistic Risk Assessment (PRA) for the analysis of fire risk at nuclear power plants. The current methods are based on various assumptions regarding fire phenomena, the impact of fire on equipment and operator response, and the overall progression of a fire event from initiation through final resolution. Over this same time period, a number of significant fire incidents have occurred at nuclear power plants around the world. Insights gained from US experience have been used in US studies as the statistical basis for establishing fire initiation frequencies both as a function of the plant area and the initiating fire source.To a lesser extent, the fire experience has also been used to assess the general severity and duration of fires. However, aside from these statistical analyses, the incidents have rarely been scrutinized in detail to verify the underlying assumptions of fire PRAs. This paper discusses an effort, under which a set of fire incidents are being reviewed in order to gain insights directly relevant to the methods, data, and assumptions that form the basis for current fire PRAs. The paper focuses on the objectives of the effort, the specific fire events being reviews methodology, and anticipated follow-on activities.

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Mass-Transport-Limited Electrodeposition of High-Surface-Area Coatings for Surface Acoustic Wave Sensor Technology

Ricco, Antonio J.; Staton, Alan W.; Yelton, W.G.

The sensitivity of surface acoustic wave (SAW) sensors has been enhanced by increasing the active surface area of these devices. Electrodepositions of Ni, Pd, and Pt in a mass-transport-limited mode with trace foreign metals yield highly dendritic crystal structures of uniform macroscopic thickness. The concentration of metal ions, supporting electrolyte, agitation, and additives greatly impact the crystal morphology of the deposit. This methodology can be used simply and economically to provide high-area films in selective regions.

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Soft Mathematical Aggregation in Safety Assessment and Decision Analysis

Cooper, James A.

This paper improves on some of the limitations of conventional safety assessment and decision analysis methods. It develops a top-down mathematical method for expressing imprecise individual metrics as possibilistic or fuzzy numbers and shows how they may be combined (aggregated) into an overall metric, also portraying the inherent uncertainty. Both positively contributing and negatively contributing factors are included. Metrics are weighted according to significance of the attribute and evaluated as to contribution toward the attribute. Aggregation is performed using exponential combination of the metrics, since the accumulating effect of such factors responds less and less to additional factors. This is termed soft mathematical aggregation. Dependence among the contributing factors is accounted for by incorporating subjective metrics on overlap of the factors and by correspondingly reducing the overall contribution of these combinations to the overall aggregation. Decisions corresponding to the meaningfulness of the results are facilitated in several ways. First, the results are compared to a soft threshold provided by a sigmoid function. Second, information is provided on input ''Importance'' and ''Sensitivity,'' in order to know where to place emphasis on controls that may be necessary. Third, trends in inputs and outputs are tracked in order to add important information to the decision process. The methodology has been implemented in software.

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Maglift Monorail

Kelley, John B.

In the 1990s, significant experience has been gained with high-speed passenger rail technologies. On the one hand, high speed versions of conventional-configuration trains, such as the French TGV, have proven themselves in service; on the other hand, magnetic levitation (maglev) trains such as the German Transrapid, which some expected to supplant conventional trains in some high speed applications, have not yet proven themselves and face a problematic future. This is because of maglev's high capital cost, the magnetic drag which it introduces, and the high development risks associated with this complex technology. This paper examines a new form of high-speed train expected to be capable of speeds of 300 mph, the Maglift Monorail. The Maglift Monorail was developed by simplifying and improving two well-understood technologies--wheelsets and LIMs--and then integrating them. The solution is a vehicle with flangeless wheels mounted in two axes, powered by a high-efficiency and light-weight LIM, positioned to give magnetic lift (maglift), i.e., electromagnetic force in the vertical direction which reduces the vehicle weight on the suspension, and thereby reduces static and rolling drag. Maglift can be considered a form of maglev as it uses the same electromagnetic forces to lift and propel the vehicle. This solution is presented in a Spanish-designed monorail system which has a unique suspension designed to minimize friction while giving great stability and turning capability. This monorail vehicle is propelled by the Seraphim motor (Segmented Rail Phased Induction Motor) which virtually eliminates magnetic drag and provides significant maglift. The Maglift Monorail achieves lower operating costs and a greater overall reduction in drag than conventional noncontact maglev does, and it does so without incurring maglev's high capital costs or its technology development risks.

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Agent Communications using Distributed Metaobjects

Goldsmith, Steven Y.

There are currently two proposed standards for agent communication languages, namely, KQML (Finin, Lobrou, and Mayfield 1994) and the FIPA ACL. Neither standard has yet achieved primacy, and neither has been evaluated extensively in an open environment such as the Internet. It seems prudent therefore to design a general-purpose agent communications facility for new agent architectures that is flexible yet provides an architecture that accepts many different specializations. In this paper we exhibit the salient features of an agent communications architecture based on distributed metaobjects. This architecture captures design commitments at a metaobject level, leaving the base-level design and implementation up to the agent developer. The scope of the metamodel is broad enough to accommodate many different communication protocols, interaction protocols, and knowledge sharing regimes through extensions to the metaobject framework. We conclude that with a powerful distributed object substrate that supports metaobject communications, a general framework can be developed that will effectively enable different approaches to agent communications in the same agent system. We have implemented a KQML-based communications protocol and have several special-purpose interaction protocols under development.

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Some Possible Methods for Detection of Clandestin Production of Nuclear Materials

Marlow, Keith W.

When one considers the possibility of clandestine production of nuclear materials, one must consider the nature of the state. A Nuclear Weapon State (NWS) already has production facilities, and even though these might be safeguarded, the NWS could more easily hide the activities than could a Non-Nuclear Weapon State (NNWS). In this paper, some of the properties of production facilities are discussed in relation to how this would relate to vulnerability to detection. The observable and methods of detection are discussed, as well as the possibility that significant help by another country could totally eliminate one or more of the steps needed for a complete production cycle.

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What is the Entanglement Length in a Polymer Melt

Grest, Gary S.

We present the results of molecular dynamics simulations of very long model polymer chains analyzed by various experimentally relevant techniques. The segment motion of the chains is found to be in very good agreement with the reptation model. We also calculated the plateau modulus G0N. The predictions of the entanglement length Ne from G0N and from the mean square displacement of the chain segments disagree by a factor of about 2.2(2), indicating an error in the prefactor in the standard formula for G0N. We show that recent neutron spin echo measurements were carried out for chain lengths which are too small to allow for a correct determination of Ne.

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The Potential Uses of Commercial Satellite Imagery in the Middle East

Vannoni, Michael

It became clear during the workshop that the applicability of commercial satellite imagery to the verification of future regional arms control agreements is limited at this time. Non-traditional security topics such as environmental protection, natural resource management, and the development of infrastructure offer the more promising applications for commercial satellite imagery in the short-term. Many problems and opportunities in these topics are regional, or at least multilateral, in nature. A further advantage is that, unlike arms control and nonproliferation applications, cooperative use of imagery in these topics can be done independently of the formal Middle East Peace Process. The value of commercial satellite imagery to regional arms control and nonproliferation, however, will increase during the next three years as new, more capable satellite systems are launched. Aerial imagery, such as that used in the Open Skies Treaty, can also make significant contributions to both traditional and non-traditional security applications but has the disadvantage of requiring access to national airspace and potentially higher cost. There was general consensus that commercial satellite imagery is under-utilized in the Middle East and resources for remote sensing, both human and institutional, are limited. This relative scarcity, however, provides a natural motivation for collaboration in non-traditional security topics. Collaborations between scientists, businesses, universities, and non-governmental organizations can work at the grass-roots level and yield contributions to confidence building as well as scientific and economic results. Joint analysis projects would benefit the region as well as establish precedents for cooperation.

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Efficient Injection of Electron Beams into Magnetic Guide Fields

Chorny, V.; Cooperstein, G.; Dubyna, V.; Frolov, O.; Harper-Slaboszewicz, V.; Hinshelwood, D.; Schneider, R.; Solovyov, V.; Tsepilov, H.; Vitkovitsky, I.; Ware, K.

Preliminary experimental and modeling study of injection and transport of high current electron beams in current-neutralized background gas has been performed. Initial analysis of the results indicates that high current triaxial ring diode operates very reproducibly in the pinch mode. High current density beam can be injected efficiently into the drift region, using azimuthal guide field with reduced intensity near the injection region. This was shown to improve the effectiveness of capturing the beam for the transport. The transport length was insufficient to measure losses, such as would arise from scattering with the background gas.

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Rapidly Adaptable Instrumentation Tester (RAIT)

Vargo, Timothy D.

Emerging technologies in the field of "Test & Measurement" have recently enabled the development of the Rapidly Adaptable Instrumentation Tester (RAIT). Based on software developed with LabVIEW®, the RAIT design enables quick reconfiguration to test and calibrate a wide variety of telemetry systems. The consequences of inadequate testing could be devastating if a telemetry system were to fail during an expensive flight mission. Supporting both open-bench testing as well as automated test sequences, the RAIT has significantly lowered total time required to test and calibrate a system. This has resulted in an overall lower per unit testing cost than has been achievable in the past.

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Chemical Sensing at the Parts Per Trillion Level with a Fiber Optic Sensor

Butler, Michael A.; Andrzejewski, William A.

Chemical detection of gaseous species at very low vapor pressures is possible for materials with very low, saturation vapor pressures. A saturation vapor pressure implies equilibrium with the solid or liquid phase of the material. Thus partitioning of the gaseous species into a phase such as a polymer, will result in a very large concentration of the species in the solid phase and greatly enhanced ability to detect this species. The concentration in the polymer of the species to be detected is limited by the volubility of the species in that phase. In this presentation we discuss such a situation were 2-nitro-diphenylamine (2NDPA) is detected in the gas phase at room temperature at the few parts per trillion level.

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Equivalent-Circuit Model for the TSM Reasonator with a Viscoeleastic Film Near Film Resonance

Bandey, H.L.; Martin, Steve W.; Cernosek, Richard W.

A new equivalent-circuit model for the thickness shear mode resonator with a surface viscoelastic layer will be described. This model is valid only in the vicinity of a film resonance but is a reasonable approximation away from resonance. A simple resonant parallel circuit containing a resistor, a capacitor, and an inductor represents the electrical impedance of the film. These elements describe the film's viscous power dissipation, elastic energy storage, and kinetic energy storage, respectively. Resonator response comparisons between this lumped- element model and the general transmission-line model show good agreement over a range of film phase conditions and not just near film resonance. Under certain conditions, it will be shown that two peaks in the admittance magnitude are observed for operation at film resonance.

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Mass-Transport-Limited Electrodeposition of High-Surface-Area Coatings for Surface Acoustic Wave Sensor Technology

Ricco, A.J.; Staton, A.W.; Yelton, W.G.

The sensitivity of surface acoustic wave (SAW) sensors has been enhanced by increasing the active surface area of these devices, Electrodepositions of Ni, Pd, and Pt in a mass-transport-limited mode with trace foreign metals yield highly dendritic crystal structures of uniform macroscopic thickness. The concentration of metal ions, supporting electrolyte, agitation, and additives greatly impact the crystal morphology of the deposit. This methodology can be used simply and economically to provide high-area films in selective regions.

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Reactions and Diffusion During Annealing-Induced H(+) Generation in SOI Buried Oxides

Fleetwood, Daniel M.

We report experimental results suggesting that mobile protons are generated at strained Si-O-Si bonds near the Si/SiO2 interface during annealing in forming gas. Our data further suggest that the presence of the top Si layer plays a crucial role in the mobile H+ generation process. Finally, we show that the diffusion of the reactive species (presumably H2 or H0) towards the H+ generation sites occurs laterally along the buried oxide layer, and can be impeded significantly due to the presence of trapping sites in the buried oxide.

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Inverters - Critical Photovoltaic Balance-of-System Components: Status, Issues Perspectives, and New-Millennium Opportunities

Bower, Ward

The balance-of-system (BOS) of a photovoltaic installation includes the array structure, trackers, ac and dc wiring, overcur-rent protection, disconnects, interconnects, inverters, charge controllers, energy storage and system controllers. The inverter (sometimes called power-conditioning subsystem (PCS), power conditioner or static power converter) is the key electrical power-handling component of a photovoltaic (PV) power system that has, ac loads. This paper will focus on the inverter and its related functions as the critical electrical BOS element in photovoltaic systems. An evolutionary summary for inverter hardware development, primarily in the US, will shed light on the paths that have been taken to arrive at today's state-of-the-technology. Recent developments, integrated packaging and opportunities for practical technology and hardware advancements will be presented. This paper will also touch on elementary battery issues as they relate to inverters and their control functions. Batteries are also critical, but often misunderstood, BOS components in stand- alone systems.

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Contamination of the Northern Oceans from Releases of Radioactivity from the Former Soviet Union

Gomez, Leo S.

During the Cold War the handling of Soviet military nuclear wastes was a classified topic--kept secret to hide the status and readiness of Soviet military forces. Following the end of the Cold War information about the handling of nuclear wastes by agencies of the Former Soviet Union (FSU) became available. The US Government response to the disclosure of disposal of radioactive wastes into the Arctic Ocean and into rivers that drain into the Arctic Ocean was the finding of the Arctic Nuclear Waste Assessment Program (ANWAP) in the Office of Naval Research (ONR). Projects were aided by ANWAP to study the behavior, transport, and fate of radionuclides in the Arctic Ocean. One of the research teams, the Risk Assessment Integration Group (RAIG) assessed the potential risks to humans and to the environment, particularly in the US Alaskan Arctic.

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Results 92051–92100 of 99,299
Results 92051–92100 of 99,299