Publications Details
The effects of pressure on the /beta/ molecular relaxation process in polyvinylidene fluoride
The hydrostatic pressure dependence of the /beta/ molecular relaxation process of polyvinylidene fluoride (PVDF) has been investigated to 20 kbar. This relaxation is known to have a strong influence on the electrical and mechanical properties of PVDF. The observed large slowing down of the relaxation process is discussed in terms of the Vogel/endash/Fulcher equation. There is an increase in both the energy barrier to dipolar motion and the reference temperature (T/sub 0/) for the kinetic relaxation process which represents the ''static'' dipolar freezing temperature for the process.