Publications Details

Rapid anodic dissolution based SCC of an Al-Li-Cu alloy by isolated pit solutions

Buchheit Jr., R.G.; Moran, J.P.; Wall, F.D.; Stoner, G.E.

Pre-exposure induced stress corrosion cracking (SCC) of an Al-Li-Cu, AA 2090, was studied using a variety of test techniques. Results from SCC testing in a simulated isolated pit solution are correlated with electrochemical corrosion rate data obtained for individual phases in the subgrain boundary region. These experimental data, combined with existing data on the crevice chemistry of isolated pits in Al-Li alloys and X-ray diffraction studies of solid corrosion products formed in crevice environments are used to propose a model for pre-exposure induced cracking based on anodic dissolution along subgrain boundaries. Key features of the model are selective dissolution of the subgrain boundary T{sub 1} phase (Al{sub 2}CuLi) at the crack tip and passivation of crack walls by the formation of an Li{sub 2}[Al{sub 2}(OH){sub 6}]{sub 2}{center_dot}CO{sub 3}{center_dot}nH{sub 2}O barrier film.