Publications Details

Propagation of dissolution/precipitation waves in porous media

Novak, C.F.

The transport of a chemically reactive fluid through a permeable medium is governed by many classes of chemical interactions. Dissolution/precipitation (D/P) reactions are among the interactions of primary importance because of their significant influence on the mobility of aqueous ions. In general, D/P reactions lead to the propagation of coherent waves. This paper provides an overview of the types of wave phenomena observed in one-dimensional (1D) and two-dimensional (2D) porous media for systems in which mineral D/P is the dominant type of chemical reaction. It is demonstrated that minerals dissolve in sharp waves in 1D advection-dominated transport, and that these waves separate zones of constant chemical compositions in the aqueous and mineral phases. Analytical solutions based on coherence methods are presented for solving 1D advection-dominated transport problems with constant and variable boundary conditions. Numerical solutions of diffusion-dominated transport in porous media show that sharp D/P fronts occur in this system as well. A final example presents a simple dual-porosity system with advection in an idealized fracture and solute diffusion into an adjacent porous matrix. The example illustrates the delay of contaminant release from the 2D domain due to a combination of physical retardation and chemical retardation.