Publications Details
New high-{Tc} benchmarks for organic superconductors based on ET (electron-donor) and C{sub 60} (electron-acceptor) molecules
The highest {Tc}`s achieved in organic electron-donor-based systems occur in two isostructural ET salts, viz., {kappa}-[(ET){sub 2}Cu][N(CN){sub 2}]X, X = Br ({Tc} = 11.6 K, ambient pressure), X = Cl ({Tc} = 12.8 K, 0.3 kbar) whereas for the electron-acceptor-based systems derived from C{sub 60} they occur in K{sub 3}C{sub 60} ({Tc} = 19 K), Rb{sub 3}C{sub 60} ({Tc} = 29 K), Rb{sub x}Cs{sub y}C{sub 60} ({Tc} 33 K) and Rb{sub x}Tl{sub y}C{sub 60} ({Tc} {approx} 45 K). Research performed at Argonne National Laboratory, and based on the ET and C{sub 60} systems, is reviewed.