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Molecular Sieve Films From Zeolite-Silica Microcomposites
Inorganic thin films with molecular sieving properties have been formed by embedding microcrystals of zeolite Y and chabazite in a glassy silica matrix. The silica matrix was derived from sols prepared from tetraethylorthosilicate hydrolyzed under either acidic or basic conditions in alcoholic solution. Dip-coating, deposition of suspensions, or coating of zeolite dispersions with the glassy silica matrix were used to create the zeolite-silica films. The access of different probe molecules into the zeolitic part of the thin film was examined with in situ FTIR techniques and temperature-programmed-desorption studies. With all combinations of deposition techniques and silica matrices, the resulting films showed the molecular sieving properties of the parent zeolite. © 1989, Elsevier Science & Technology. All rights reserved.