Publications Details

Infrared absorption in boron carbides: Dependence on isotope and carbon concentration

Stein, H.

Infrared reflectance and transmittance measurements between 500 and 1800 cm{sup {minus}1} were obtained on boron carbides with between 10 and 20 atomic percent carbon. Measurements on both boron and carbon isotopically enriched samples indicate that all prominent modes involve boron motion, and that all but a mode near 950 cm{sup {minus}1} involve carbon motion. Since the spectrum remains qualitatively unaltered as a function of carbon concentration, its prominent features must have a common structural origin. 5 refs., 4 figs., 2 tabs.