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Double layer capacitance of carbon foam electrodes

Delnick, F.M.; Ingersoll, D.; Firsich, D.

We have evaluated a wide variety of microcellular carbon foams prepared by the controlled pyrolysis and carbonization of several polymers including: polyacrylonitrile (PAN), polymethacrylonitrile (PMAN), resorcinol/formaldehyde (RF), divinylbenzene/methacrylonitrile (DVB), phenolics (furfuryl/alcohol), and cellulose polymers such as Rayon. The porosity may be established by several processes including: Gelation (1-5), phase separation (1-3,5-8), emulsion (1,9,10), aerogel/xerogel formation (1,11,12,13), replication (14) and activation. In this report we present the complex impedance analysis and double layer charging characteristics of electrodes prepared from one of these materials for double layer capacitor applications, namely activated cellulose derived microcellular carbon foam.