Publications Details
A test of the Arrhenius extrapolation assumption for a nitrile rubber
The Arrhenius relation predicts a linear relation between log of time to property change and inverse absolute temperature, with the Arrhenius activation energy E{sub a} given from the slope. For a nitrile rubber, Arrhenius behavior is observed for elongation vs air-oven aging temperature, with a E{sub a} of 22 kcal/mol. Confidence in extrapolation to low temperatures can be increased by measuring oxygen consumption. From 95 to 52 C, the E{sub a} for oxygen consumption is identical to that for elongation; however, below 52 C, the E{sub a} for oxygen consumption drops slightly to 18 kcal/mol, indicating that the extrapolation assumption probably overestimates the tensile property lifetime by a factor of about 2 at 23 C.