MOF-Templated Growth of Molecular Ag-clusters for Small Molecule Sensing
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Proposed for publication in Computational Geometry: Theory and Applications.
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Proposed for publication in IEEE Transactions on Instrumentation and Measurement.
A technique for characterizing the pulse profile of a radio-frequency (RF) amplifier over a very wide power range under fast-pulsing conditions is presented. A pulse-modulated transmitter is used to drive a device under test (DUT) with a phase-coded signal that allows for an increased measurement range beyond standard techniques. A measurement receiver that samples points on the output pulse power profile and performs the necessary signal processing and coherent pulse integration, improving the detectability of low-power signals, is described. The measurement technique is applied to two sample amplifiers under fast-pulsing conditions with a pulsewidth of 250 ns at 3-GHz carrier frequency. A full measurement range of greater than 160 dB is achieved, extending the current state of the art in pulse-profiling techniques.
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Explosive growth in photovoltaic markets has fueled new creative approaches that promise to cut costs and improve reliability of system components. However, market demands require rapid development of these new and innovative technologies in order to compete with more established products and capture market share. Often times diagnostics that assist in R&D do not exist or have not been applied due to the innovative nature of the proposed products. Some diagnostics such as IR imaging, electroluminescence, light IV, dark IV, x-rays, and ultrasound have been employed in the past and continue to serve in development of new products, however, innovative products with new materials, unique geometries, and previously unused manufacturing processes require additional or improved test capabilities. This fast-track product development cycle requires diagnostic capabilities to provide the information that confirms the integrity of manufacturing techniques and provides the feedback that can spawn confidence in process control, reliability and performance. This paper explores the use of digital radiography and computed tomography (CT) with other diagnostics to support photovoltaic R&D and manufacturing applications.
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A combined experimental and constitutive modeling program for weak porous sandstone deformation is described. A series of axisymmetric compression tests were performed over a range of mean stresses to study dilatational, compactional and transitional regimes. Experimental results were used both to derive constitutive parameters for testing localization theory and to parameterize a poroelastic-plastic model. Observed strain localization, imaged syn-deformationally using acoustic emissions, includes high- and low-angle shear and low angle compactional features or 'bands'. Isotropic elastic moduli measured via unloading loops show a progressive degradation pre-failure as decreasing functions of work-conjugate plastic strains and increasing functions of stress magnitude. The degradation pathway is unique for samples which underwent localization versus those that underwent spatially pervasive pore collapse. Total shear and volume strains are partitioned into elastic and plastic portions including the ''coupling'' strain associated with modulus degradation. Plastic strain calculated with and without the coupling term is compared with regard to localization predictions. Both coupled and uncoupled cases predict high angle shear bands for uniaxial and low mean stress conditions on the dilatational side of the yield surface. Uncoupled predictions show progressively lower angle shear bands approaching the transitional regime (stress conditions approaching the 'cap' surface). When elastic-plastic coupling is accounted for, compaction bands are predicted for the transitional regime, as are observed in the experiments. Finite element modeling efforts are described using a 3-invariant, mixed-hardening, continuous yield surface, elasto-plasticity model that includes several features important for porous sandstone constitutive behavior and observed experimentally, including non-associativity, nonlinear elasticity, elastic-plastic coupling, and kinematic hardening. Modeled deformational behavior attending stress paths relevant for several reservoir production scenarios are described.
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