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Collective systems are typically defined as a group of agents (physical and/or cyber) that work together to produce a collective behavior with a value greater than the sum of the individual parts. This amplification or synergy can be harnessed by solving an inverse problem via an information-flow/communications grid: given a desired macroscopic/collective behavior find the required microscopic/individual behavior of each agent and the required communications grid. The goal of this report is to describe the fundamental nature of the Hamiltonian function in the design of collective systems (solve the inverse problem) and the connections between and values of physical and information exergies intrinsic to collective systems. In particular, physical and information exergies are shown to be equivalent based on thermodynamics and Hamiltonian mechanics.

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TYPE SAND Report YEAR 2007

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Peptide and Protein Characterization by Mass Spectrometry: Applications to the Desulfovibrio vulgaris Hildenborough Proteome

Gaucher, Sara P.

Abstract not provided.

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TYPE Presentation YEAR 2007

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Autothermal reforming of natural gas to synthesis gas:reference: KBR paper #2031

Mann, David; Rice, Steven

This Project Final Report serves to document the project structure and technical results achieved during the 3-year project titled Advanced Autothermal Reformer for US Dept of Energy Office of Industrial Technology. The project was initiated in December 2001 and was completed March 2005. It was a joint effort between Sandia National Laboratories (Livermore, CA), Kellogg Brown & Root LLC (KBR) (Houston, TX) and Sued-Chemie (Louisville, KY). The purpose of the project was to develop an experimental capability that could be used to examine the propensity for soot production in an Autothermal Reformer (ATR) during the production of hydrogen-carbon monoxide synthesis gas intended for Gas-to-Liquids (GTL) applications including ammonia, methanol, and higher hydrocarbons. The project consisted of an initial phase that was focused on developing a laboratory-scale ATR capable of reproducing conditions very similar to a plant scale unit. Due to budget constraints this effort was stopped at the advanced design stages, yielding a careful and detailed design for such a system including ATR vessel design, design of ancillary feed and let down units as well as a PI&D for laboratory installation. The experimental effort was then focused on a series of measurements to evaluate rich, high-pressure burner behavior at pressures as high as 500 psi. The soot formation measurements were based on laser attenuation at a view port downstream of the burner. The results of these experiments and accompanying calculations show that soot formation is primarily dependent on oxidation stoichiometry. However, steam to carbon ratio was found to impact soot production as well as burner stability. The data also showed that raising the operating pressure while holding mass flow rates constant results in considerable soot formation at desirable feed ratios. Elementary reaction modeling designed to illuminate the role of CO{sub 2} in the burner feed showed that the conditions in the burner allow for the direct participation of CO{sub 2} in the oxidation chemistry.

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TYPE SAND Report YEAR 2007

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