Inorganic nanoclusters dispersed in organic matrices are of importance to a number of emerging technologies. However, obtaining useful properties from such organic-inorganic composites often requires high concentrations of well-dispersed nanoclusters. In order to achieve this goal the chemistry of the particle surface and the matrix must be closely matched. This is based on the premise of minimization of the interfacial free energy; an excess of free energy will cause phase separation and ultimately aggregation. Thus, the optimal system is one in which the nanoclusters are stabilized by the same molecules that make up the encapsulant. Yet, the organic matrix is typically chosen for its bulk properties, and therefore may not be amenable to chemical modification. Also, the organic-inorganic interface is often critical to establishing and maintaining the desired nanocluster (and hence composite) properties, placing further constraints on proposed chemical modification. For these reasons we have adopted the use of aminefunctionalized trimethoxysilanes (ormosils) as an optical grade encapsulant. In this work, we demonstrate that ormosils can produce beneficial optical effects that are derived from interfacial phenomena, which can be maintained throughout the encapsulation process.
A series of field tests sponsored by Sandia National Laboratories has simultaneously demonstrated the hard-rock drilling performance of different industry-supplied drag bits as well as Sandia's new Diagnostics-While-Drilling (DWD) system, which features a novel downhole tool that monitors dynamic conditions in close proximity to the bit. Drilling with both conventional and advanced ("best effort") drag bits was conducted at the GTI Catoosa Test Facility (near Tulsa, OK) in a well-characterized lithologic column that features an extended hard-rock interval of Mississippi limestone above a layer of highly abrasive Misener sandstone and an underlying section of hard Arbuckle dolomite. Output from the DWD system was closely observed during drilling and was used to make real-time decisions for adjusting the drilling parameters. This paper summarizes penetration rate and damage results for the various drag bits, shows representative DWD display data, and illustrates the application of these data for optimizing drilling performance and avoiding trouble.
Many MEMS devices are based on polysilicon because of the current availability of surface micromachining technology. However, polysilicon is not the best choice for devices where extensive sliding and/or thermal fields are applied due to its chemical, mechanical and tribological properties. In this work, we investigated the mechanical properties of three new materials for MEMS/NEMS devices: silicon carbide (SiC) from Case Western Reserve University (CWRU), ultrananocrystalline diamond (UNCD) from Argonne National Laboratory (ANL), and hydrogen-free tetrahedral amorphous carbon (ta-C) from Sandia National Laboratories (SNL). Young's modulus, characteristic strength, fracture toughness, and theoretical strength were measured for these three materials using only one testing methodology - the Membrane Deflection Experiment (MDE) developed at Northwestern University. The measured values of Young's modulus were 430GPa, 960GPa, and 800GPa for SiC, UNCD, and ta-C, repectively. Fracture toughness measurments resulted in values of 3.2, 4.5, and 6.2 MPa×m 1/2, respectively. The strengths were found to follow a Weibull distribution but their scaling was found to be controlled by different specimen size parameters. Therefore, a cross comparison of the strengths is not fully meaningful. We instead propose to compare their theoretical strengths as determined by employing Novozhilov fracture criterion. The estimated theoretical strength for SiC is 10.6GPa at a characteristic length of 58nm, for UNCD is 18.6GPa at a characteristic length of 37nm, and for ta-C is 25.4GPa at a characteristic length of 38nm. The techniques used to obtained these results as well as microscopic fractographic analyses are summarized in the article. We also highlight the importance of characterizing mechanical properties of MEMS materials by means of only one simple and accurate experimental technique.
Experimental modal analysis (EMA) was carried out on a micro-machined acceleration switch to characterize the motions of the device as fabricated and to compare this with analytical results for the nominal design. Finite element analysis (FEA) of the nominal design was used for this comparison. The acceleration switch was a single-crystal silicon disc supported by four fork-shaped springs. We shook the base of the die with step sine type excitation. A Laser Doppler Velocimeter (LDV) in conjunction with a microscope was used to measure the velocities of the die at several points. The desired first three modes of the structure were identified. The fundamental natural frequency that we measured in this experiment gives an estimate of the actuation g-level for the specified stroke. The fundamental resonance and actuation g-level results from the EMA and the FEA showed large variations. The discrepancy prompted thorough dimensional measurement of the acceleration switch, which revealed discrepancies between the nominal design and tested component.
Sandia National Laboratories has previously tested a capability to impose a 7.5 g-rms (30 g peak) radial vibration load up to 2 kHz on a 25 lb object with superimposed 50 g acceleration at its centrifuge facility. This was accomplished by attaching a 3,000 lb Unholtz-Dickie mechanical shaker at the end of the centrifuge arm to create a "Vibrafuge". However, the combination of non-radial vibration directions, and linear accelerations higher than 50g's are currently not possible because of the load capabilities of the shaker and the stresses on the internal shaker components due to the combined centrifuge acceleration. Therefore, a new technique using amplified piezo-electric actuators has been developed to surpass the limitations of the mechanical shaker system. They are lightweight, modular and would overcome several limitations presented by the current shaker. They are 'scalable', that is, adding more piezo-electric units in parallel or in series can support larger-weight test articles or displacement/frequency regimes. In addition, the units could be mounted on the centrifuge arm in various configurations to provide a variety of input directions. The design along with test results will be presented to demonstrate the capabilities and limitations of the new piezo-electric Vibrafuge.
Structural assemblies often include bolted connections that are a primary mechanism for energy dissipation and nonlinear response at elevated load levels. Typically these connections are idealized within a structural dynamics finite element model as linear elastic springs. The spring stiffness is generally tuned to reproduce modal test data taken on a prototype. In conventional practice, modal test data is also used to estimate nominal values of modal damping that could be used in applications with load amplitudes comparable to those employed in the modal tests. Although this simplification of joint mechanics provides a convenient modeling approach with the advantages of reduced complexity and solution requirements, it often leads to poor predicted responses for load regimes associated with nonlinear system behavior. In this document we present an alternative approach using the concept of a "whole-joint" or "whole-interface" model [1]. We discuss the nature of the constitutive model, the manner in which model parameters are deduced, and comparison of structural dynamic prediction with results for experimental hardware subjected to a series of transient excitations beginning at low levels and increasing to levels that produced macro-slip in the joint. Further comparison is performed with a traditional "tuned" linear model. The ability of the whole-interface model to predict the onset of macro-slip as well as the vast improvement of the response levels in relation to those given by the linear model is made evident. Additionally, comparison between prediction and high amplitude experiments suggests areas for further work.
This paper addresses the coupling of experimental and finite element models of substructures. In creating the experimental model, difficulties exist in applying moments and estimating resulting rotations at the connection point between the experimental and finite element models. In this work, a simple test fixture for applying moments and estimating rotations is used to more accurately estimate these quantities. The test fixture is analytically "subtracted" from the model using the admittance approach. Inherent in this process is the inversion of frequency response function matrices that can amplify the uncertainty in the measured data. Presented here is the work applied to a two-component beam model and analyses that attempt to identify and quantify some of these uncertainties. The admittance model of one beam component was generated experimentally using the moment-rotation fixture, and the other from a detailed finite element model. During analytical testing of the admittance modeling algorithm, it was discovered that the component admittance models generated by finite elements were ill conditioned due to the inherent physics.
In order to create an analytical model of a material or structure, two sets of experiments must be performed-calibration and validation. Calibration experiments provide the analyst with the parameters from which to build a model that encompasses the behavior of the material. Once the model is calibrated, the new analytical results must be compared with a different, independent set of experiments, referred to as the validation experiments. This modeling procedure was performed for a crushable honeycomb material, with the validation experiments presented here. This paper covers the design of the validation experiments, the analysis of the resulting data, and the metric used for model validation.
Processing-in-Memory (PIM) technology encompasses a range of research leveraging a tight coupling of memory and processing. The most unique features of the technology are extremely wide paths to memory, extremely low memory latency, and wide functional units. Many PIM researchers are also exploring extremely fine-grained multi-threading capabilities. This paper explores a mechanism for leveraging these features of PIM technology to enhance commodity architectures in a seemingly mundane way: accelerating MPI. Modern network interfaces leverage simple processors to offload portions of the MPI semantics, particularly the management of posted receive and unexpected message queues. Without adding cost or increasing clock frequency, using PIMs in the network interface can enhance performance. The results are a significant decrease in latency and increase in small message bandwidth, particularly when long queues are present.
The processes and functional constituents of biological photosynthetic systems can be mimicked to produce a variety of functional nanostructures and nanodevices. The photosynthetic nanostructures produced are analogs of the naturally occurring photosynthetic systems and are composed of biomimetic compounds (e.g., porphyrins). For example, photocatalytic nanotubes can be made by ionic self-assembly of two oppositely charged porphyrins tectons [1]. These nanotubes mimic the light-harvesting and photosynthetic functions of biological systems like the chlorosomal rods and reaction centers of green sulfur bacteria. In addition, metal-composite nanodevices can be made by using the photocatalytic activity of the nanotubes to reduce aqueous metal salts to metal atoms, which are subsequently deposited onto tube surfaces [2]. In another approach, spatial localization of photocatalytic porphyrins within templating surfactant assemblies leads to controlled growth of novel dendritic metal nanostructures [3].
Conference Proceedings of the Society for Experimental Mechanics Series
Hasselman, Timothy; Wathugala, G.W.; Urbina, Angel; Paez, Thomas L.
Mechanical systems behave randomly and it is desirable to capture this feature when making response predictions. Currently, there is an effort to develop predictive mathematical models and test their validity through the assessment of their predictive accuracy relative to experimental results. Traditionally, the approach to quantify modeling uncertainty is to examine the uncertainty associated with each of the critical model parameters and to propagate this through the model to obtain an estimate of uncertainty in model predictions. This approach is referred to as the "bottom-up" approach. However, parametric uncertainty does not account for all sources of the differences between model predictions and experimental observations, such as model form uncertainty and experimental uncertainty due to the variability of test conditions, measurements and data processing. Uncertainty quantification (UQ) based directly on the differences between model predictions and experimental data is referred to as the "top-down" approach. This paper discusses both the top-down and bottom-up approaches and uses the respective stochastic models to assess the validity of a joint model with respect to experimental data not used to calibrate the model, i.e. random vibration versus sine test data. Practical examples based on joint modeling and testing performed by Sandia are presented and conclusions are drawn as to the pros and cons of each approach.
Achieving good scalability for large simulations based on structured adaptive mesh refinement is non-trivial. Performance is limited by the partitioner's ability to efficiently use the underlying parallel computer's resources. Domainbased partitioners serve as a foundation for techniques designed to improve the scalability and they have traditionally been designed on the basis of an independence assumption regarding the computational flow among grid patches at different refinement levels. But this assumption does not hold in practice. Hence the effectiveness of these techniques is significantly impaired. This paper introduces a partitioning method designed on the true premises. The method is tested for four different applications exhibiting different behaviors. The results show that synchronization costs on average can he reduced by 75 percent. The conclusion is that the method is suitable as a foundation in general hierarchical methods designed to improve the scalability of structured adaptive mesh refinement applications.
43rd AIAA Aerospace Sciences Meeting and Exhibit - Meeting Papers
Barone, Matthew F.; Roy, Christopher J.
Simulations of a low-speed square cylinder wake and a supersonic axisymmetric base wake are performed using the Detached Eddy Simulation (DES) model. A reduced-dissipation form of the Symmetric TVD scheme is employed to mitigate the effects of dissipative error in regions of smooth flow. The reduced-dissipation scheme is demonstrated on a 2D square cylinder wake problem, showing a dramatic increase in accuracy for a given grid resolution. The results for simulations on three grids of increasing resolution for the 3D square cylinder wake are compared to experimental data and to other LES and DES studies. The comparisons of mean flow and global mean flow quantities to experimental data are favorable, while the results for second order statistics in the wake are mixed and do not always improve with increasing spatial resolution. Comparisons to LES studies are also generally favorable, suggesting DES provides an adequate subgrid scale model. Predictions of base drag and centerline wake velocity for the supersonic wake are also good, given sufficient grid refinement. These cases add to the validation library for DES and support its use as an engineering analysis tool for accurate prediction of global flow quantities and mean flow properties.