This paper describes a concept in which dry air is injected into an unsaturated formation to reduce the soil moisture content, referred to here as a dry (or sometimes tensiometric) barrier. The objective is to reduce the hydraulic conductivity of the unsaturated media to the point where liquid phase transport becomes negligible, thereby achieving containment. The concept could be applied in subsurface formations to provide containment from a leaking facility, or it could be incorporated into a cover design to provide redundancy for a capillary barrier. The air injection process could in principle be coupled with a vacuum extraction system to recover soil vapors, which would then provide a remediation process that would be appropriate if volatile organic compounds were present. Work to date has consisted of a combined theoretical, laboratory, and field research investigation. The objective of this research was to demonstrate the technical feasibility of the dry barrier concept by identifying the parameters which determine its effectiveness. Based on the results obtained for the experimental and theoretical studies, feasibility analyses were prepared for as a modification for a landfill cover design to prevent infiltration from atmospheric precipitation and for potential application of dry barriers to achieve subsurface containment and removal of volatile constituents. These analyses considered the technical as well as the economic aspects of the dry barrier concept.
Rigid Foam is a chemical delay foam used to completely encapsulate an object or to block access to an area. Prior studies have indicated that the final foam product is essentially non-toxic. The purpose of this study was to evaluate and summarize the current chemical and toxicological data available on the components of Rigid Foam and to update the information available on the toxicity of the final Rigid Foam product. Since the possibility exists for a partial deployment of Rigid Foam where only one of the components is released, this study also examined the toxicity of its chemical constituents. Rigid Foam is composed of an {open_quotes}A{close_quotes} and {open_quotes}B{close_quotes} Component. The {open_quotes}A{close_quotes} component is primarily a polymeric isocyanate and the {open_quotes}B{close_quotes} component is a mixture of polyols. In addition to the primary constituents, dichlorodifluoromethane and trichlorofluoromethane are present as blowing agents along with catalysts and silicone surfactants necessary for foaming. The pre-deployed {open_quotes}A{close_quotes} and {open_quotes}B{close_quotes} components are stored in separate vessels and are brought together in static mixing nozzles for dispersal. The results of this evaluation indicate that a completely deployed Rigid Foam under normal conditions is essentially non-toxic as determined previously. However, in the event of a partial deployment or deployment of an individual component directly at an unprotected individual, the degree of hazard is increased due to the toxic and corrosive nature of the individual constituents. The health hazard would depend on the properties of the material to which the person was exposed.
The source term for assessing events that involve the combustion of metallic plutonium (Pu) presents a continuing need in carrying out safety evaluations in support of DOE programs involving nuclear weapons. For production, storage, transport and decommissioning operations, an accident sequence that frequently must be evaluated involves metallic Pu being exposed in a fire environment. There are significant data on which to base an estimate for the source term which has been surveyed recently by Mishima et al (Mishima, 1993), but much of the surveyed work relates to well controlled laboratory experiments with relatively small amounts of Pu. One of the most relevant sources of information was the work by Stewart (Stewart, 1959) of the UK Atomic Weapon Research Establishment at Aldermaston. That work, referred to as the Vixen A Trials provides direct experimental data on the aerosolization and environmental releases from relatively large metallic Pu shapes immersed in a ``petrol`` fire. A new analysis of the air sampler data from the two Vixen A Trials experiments involving chunks of plutonium exposed to hydrocarbon fuel fires indicated a respirable release fraction (referenced to total plutonium involved) of 0.0001 to 0.0003 (1 E-4 to 3 E-4) depending on the parameters used in the atmospheric transport and dispersion model used. A value of 3 E-4 is recommended as an upper limit for use in safety assessment studies involving similar accident scenarios.
Sandia National Laboratories has been involved with rocket systems for many years. Some of these systems have carried high explosive onboard, while others have had FTS for destruction purposes whenever a potential hazard is detected. Recently, Sandia has also been involved with flight tests in which a target vehicle is intentionally destroyed by a projectile. Such endeavors always raise questions about the safety of personnel and the environment in the event of a premature detonation of the explosive or an activation of the FTS, as well as intentional vehicle destruction. Previous attempts to investigate fragmentation hazards for similar configurations have analyzed fragment size and shape in detail but have computed only a limited number of trajectories to determine the probabilities of impact and casualty expectations. A computer program SAFETIE has been written in support of various SNL flight experiments to compute better approximations of the hazards. SAFETIE uses the AMEER trajectory computer code and the Engineering Sciences Center LAN of Sun workstations to determine more realistically the probability of impact for an arbitrary number of exclusion areas. The various debris generation models are described.
The neutron fluences and spectra and the gamma ray doses inside and in the vicinity of a guidance system exposed to the Sandia Pulsed Reactor II (SPR II) in four configurations have been determined. This project required customization of the environment and the application of new techniques to determine the spectra within the system. The required radiation environment was achieved, and the experimental results clearly demonstrated that the radiation environment inside the system was very different from that seen outside. This example demonstrates very clearly that experimenters must consider the effect the test apparatus may have on the environment inside the system.
Sandia National Laboratories, New Mexico, conducts the Utility Battery Storage Systems Program, which is sponsored by the US Department of Energy`s Office of Energy Management. In this capacity, Sandia is responsible for the engineering analyses, contract development, and testing of rechargeable batteries and systems for utility-energy-storage applications. This report details the technical achievements realized during fiscal year 1993.
The advent of micro- or binary optics technology has made possible the fabrication of a variety of new optical devices. Optical fabrication is no longer limited by surfaces that can be made by grinding and polishing, or even diamond turning. In fact, optics with no symmetry, no smooth surfaces, and that perform multiple functions can be readily fabricated. While these optics have a large number of applications, they are extremely useful for systems that require arrays of small optics or aperture multiplexing, since these are fabricated using computer controlled photo-lithography and etching processes. We have applied binary optics technology to construct various wavefront sensing using four mask processes to create 16 level optics. They are binary in the sense that they use discrete phase levels, not in the sense of using only two levels (they might more properly be called digital optics). We have found that 16 levels is adequate for most systems, giving greater than 99% of efficiency.
This report presents the results of testing of selected propellants and primers to Electrostatic Discharge (ESD) characteristic of the human body. It describes the tests and the fixturing built to accommodate loose material (propellants) and the packed energetic material of the primer. The results indicate that all powders passed and some primers, especially the electric primers, failed to pass established requirements which delineate insensitive energetic components. This report details the testing of components and materials to four ESD environments (Standard ESD, Severe ESD, Modified Standard ESD, and Modified Severe ESD). The purpose of this study was to collect data based on the customer requirements as defined in the Sandia Environmental Safety & Health (ES&H) Manual, Chapter 9, and to define static sensitive and insensitive propellants and primers.
This report summarizes the purchasing and transportation activities of the Purchasing and Materials Management Organization for Fiscal Year 1993. Activities for both the New Mexico and California locations are included.
Assessment of the hoist failure rate for the Payload Transporter Type III (PT-III) hoist was completed as one of the ground transportation tasks for the Minuteman II (MMIII) Weapon System Safety Assessment. The failures of concern are failures that lead to dropping a reentry system (RS) during hoist operations in a silo or the assembly, storage, and inspection building for a MMIII wing. After providing a brief description of the PT-III hoist system, the author summarizes his search for historical data from industry and the military services for failures of electric hoist systems. Since such information was not found, the strategy for assessing a failure rate was to consider failure mechanisms which lead to load-drop accidents, estimate their rates, and sum the rates for the PT-III hoist failure rate. The author discusses failure mechanisms and describes his assessment of a chain failure rate that is based on data from destructive testing of a chain of the type used for the PT-III hoist and projected usage rates for hoist operations involving the RS. The main result provides upper bounds for chain failure rates that are based on these data. No test data were found to estimate failure rates due to mechanisms other than chain failure. The author did not attempt to quantify the effects of human factors on the PT-III hoist failure rate.
The measurement of layer-to-layer feature overlay will, in the foreseeable future, continue to be a critical metrological requirement for the semiconductor industry. Meeting the image placement metrology demands of accuracy, precision, and measurement speed favors the use of electrical test structures. In this paper, a two-dimensional, modified voltage-dividing potentiometer is applied to a short-loop VLSI process to measure image placement. The contributions of feature placement on the reticle and overlay on the wafer to the overall measurement are analyzed and separated. Additional sources of uncertainty are identified, and methods developed to monitor and reduce them are described.
This report briefly discusses the following research being conducted at Sandia Laboratories: Advanced Manufacturing -- Sandia technology helps keep US industry in the lead; Microelectronics-Sandia`s unique facilities transform research advances into manufacturable products; Energy -- Sandia`s energy programs focus on strengthening industrial growth and political decisionmaking; Environment -- Sandia is a leader in environmentally conscious manufacturing and hazardous waste reduction; Health Care -- New biomedical technologies help reduce cost and improve quality of health care; Information & Computation -- Sandia aims to help make the information age a reality; Transportation -- This new initiative at the Labs will help improve transportation, safety,l efficiency, and economy; Nonproliferation -- Dismantlement and arms control are major areas of emphasis at Sandia; and Awards and Patents -- Talented, dedicated employees are the backbone of Sandia`s success.
Test results sponsored by the USNRC have shown that reinforced shear wall (Seismic Category I) structures exhibit stiffnesses and natural frequencies which are smaller than those calculated in the design process. The USNRC has sponsored Sandia National Labs to perform an evaluation of the effects of the reduced frequencies on several existing seismic PRAs in order to determine the seismic risk implications inherent in these test results. This report presents the results for the re-evaluation of the seismic risk for three nuclear power plants: the Peach Bottom Atomic Power Station, the Zion Nuclear Power Plant, and Arkansas Nuclear One -- Unit 1 (ANO-1). Increases in core damage frequencies for seismic initiated events at Peach Bottom were 25 to 30 percent (depending on whether LLNL or EPRI hazard curves were used). At the ANO-1 site, the corresponding increases in plant risk were 10 percent (for each set of hazard curves). Finally, at Zion, there was essentially no change in the computed core damage frequency when the reduction in shear wall stiffness was included. In addition, an evaluation of deterministic ``design-like`` structural dynamic calculations with and without the shear stiffness reductions was made. Deterministic loads calculated for these two cases typically increased on the order of 10 to 20 percent for the affected structures.
The major thrust of the study leading to this report was a quick, but in-depth, understanding of the process for using multimedia computer equipment for information exchange within our engineering office and within the school environment. That is, how feasible is it to augment the typical office memo or school instruction sheet with pictures, video, and sounds? What specialized skills, hardware, and software are needed by those of us who want to use the technology? The brief study period allowed for an examination of available hardware and software, observation of current approaches to multimedia within our particular environment, and the development of applications, all within the context of several project areas: The Sandia Science Advisors program; a Sandia scientific project associated with the National Information Infrastructure Testbed; the curriculum of Monte Vista Elementary School of Albuquerque Public Schools; and the University of New Mexico Medical School Health Scene project.
Due to the recently enacted California regulations requiring zero emission vehicles be sold in the market place by 1998, electric vehicle research and development (R&D) is accelerating. Much of the R&D work is focusing on the Achilles` heel of electric vehicles -- advanced batteries. This report provides an assessment of the R&D work currently underway in advanced batteries and electric vehicles in the following countries: Denmark, France, Germany, Italy, Japan, Russia, and the United Kingdom. Although the US can be considered one of the leading countries in terms of advanced battery and electric vehicle R&D work, it lags other countries, particularly France, in producing and promoting electric vehicles. The US is focusing strictly on regulations to promote electric vehicle usage while other countries are using a wide variety of policy instruments (regulations, educational outreach programs, tax breaks and subsidies) to encourage the use of electric vehicles. The US should consider implementing additional policy instruments to ensure a domestic market exists for electric vehicles. The domestic is the largest and most important market for the US auto industry.
This Sandia publication seeks to facilitate technology exchange with industries, universities, and government agencies. It presents brief highlights of four projects. First is a project to simulate the use of airbags to soften the landing of a probe on Mars. Second is the use of a computer simulation system to facilitate the testing of designs for different experiments, both for experimental layout and results analysis. Third is the development of a system for in-house testing of batteries and capacitive energy storage systems, for deployment at the manufacturing sites, as opposed to final use areas. Finally is information on a noncontact measurement system which can be used to determine axes on objects of different shapes, with high precision.
Concern for the environment and cost reduction are the driving forces for a broad effort in government and the private sector to develop new, more cost-effective technologies for characterizing, monitoring and remediating environmental sites. Secondary goals of the characterization, monitoring and remediation (CMR) activity are: minimize secondary waste generation, minimize site impact, protect water tables, and develop methods/strategies to apply new technologies. The Sandia National Laboratories (SNL) project in directional boring for CMR of waste sites with enhanced machinery from the underground utility installation industry was initiated in 1990. Preliminary activities included surveying the directional drilling access needs of various DOE sites, identifying an existing class of machinery that could be enhanced for environmental work through development, and establishing a mutually beneficial working relationship with an industry partner. Since that time the project has tested a variety of prototype machinery and hardware built by the industrial partner, and SNL. The project continues to test and develop the machinery and technique refinements needed for future applications at DOE, DOD, and private sector sites. The original goal of cost-effectiveness is being met through innovation, adaptation, and application of fundamental concepts. Secondary goals are being met via a basic philosophy of ``cut/thrust and compact cuttings without adding large quantities of fluid`` to an environmental problem site. Technology transfer to the private sector is ongoing and ultimately should result in commercial availability of the machinery. Education of regulatory agencies resulting in restructuring appropriate regulatory standards for specification of the horizontal drilling techniques will be a final project goal.
The Beneficial Uses Shipping System cask is a Type B packaging developed by Sandia National Laboratories for the U.S. Department of Energy. The cask is designed to transport special form radioactive source capsules (cesium chloride and strontium fluoride) produced by the Department of Energy`s Hanford Waste Encapsulation and Storage Facility. This paper describes the cask system and the analyses performed to predict the response of the cask in impact, puncture, and fire accident conditions as specified in the regulations. The cask prototype has been fabricated and Certificates of Compliance have been obtained.
L-{alpha}-alanine, a nontoxic polycrystalline amino acid, has been investigated for use in high-precision, high-level absorbed-dose measurements in mixed neutron/photon environments such as research and test reactors. The technique is based on the use of electron paramagnetic resonance spectroscopy to determine the extent of free radical production in a sample exposed to ionizing radiation, and has been successfully used for photon absorbed-dose measurements at levels exceeding 10{sup 5} Gy with high measurement precision. Application of the technique to mixed environments requires knowledge of the energy-dependent response of the dosimeter for both photons and neutrons. Determination of the dosimeter response to photons is accomplished by irradiations in {sup 60}Co and bremsstrahlung sources and by calculations of energy-dependent photon kerma. Neutron response is determined by irradiations in conjunction with CaF{sub 2}:Mn thermoluminescence dosimeters and by calculations of energy-dependent neutron kerma. Several neutron environments are used, including those provided by the Annular Core Research Reactor and Sandia Pulsed Reactor.
The RADTRAN 4 computer code for transportation risk assessment is the central code in a system that contains both other codes and data libraries. Some of these codes and data libraries supply input data for RADTRAN; others perform supplemental calculations. RADTRAN 4 will be released by the IAEA in an international version known as INTERTRAN 2 in 1995. In the United States, RADTRAN 4 and its supporting system may be accessed via the INTERNET, a precursor to the Information Superhighway. Similar networks are being contemplated elsewhere in the world, and the RADTRAN System may serve as a prototype for systems on these networks. A system is desirable for the following reasons. Some classes of data and data-handling methods are country-specific and some are not -- ancillary codes and data libraries that provide the latter are not affected by national and regional borders while the former must be provided on a country-by-country basis. Making the invariant portions available to all users in an international system would simplify quality assurance (QA) and, therefore, the reliability and consistency of risk results. Among the classes of data used in RADTRAN 4 (and INTERTRAN 2) and the supplemental calculational capabilities that are essentially invariant for all countries and regions are: (1) radionuclide characteristics such as half-life, photon energy, and dose-conversion factors; (2) characteristics of radioactive-material packages found in international commerce; (3) features of highly standardized international transportation modes (primarily sea and air); and (4) uncertainty analysis. These features and their related QA benefits are discussed.
Using Saturn as a driver, we are pursueing both photoresonantly pumped andphotoionization/recombination lasers. Our lasing targets are gas cells with thin windowsthat are pumped by a z pinch 2 cm away radiating 10 TW. In both schemes the lasant and gasfill is neon. We will present evidence for inversion in the sodium/neon photoresonantscheme but we have yet to detect the lasing transition itself. To increase our chances ofmeasuring this line we have introduced potassium into a sodium z-pinch and have eliminatedoxygen from the gas cell windows. We have measured the spatial dependence of ionizationbalance across the gas cell, and this measurement is consistent with propagation of a shockfront across the gas cell target. We have measured the Li-like neon Sf-3d transition toincrease more rapidly with fill pressure than all other measured lines. Based on this resultwe have performed experiments emphasizing the photoionization/recombination laserscheme that use a flat field grazing incidence spectrometer to provide good spatial resolutionof the 4f-3d, 4d-3p, and Sf-3d lines of Li-like neon. We have attempted a gain lengthmeasurement by imaging parallel to a baffle that varies the length of the target illuminated.
As the United States embarks upon a major effort to cleanup its nuclear defense facilities, a large quantity of low-level waste (LLW) will be generated. This LLW must be managed and ultimately placed into final disposal. Much of this waste is expected to exceed certain limits defined in U.S. regulations (Title 10, U.S. Code of Federal Regulations, part 61) called Class C. The waste which exceeds Class C, called Greater-than-Class-C (GTCC), poses a major challenge to waste managers. Each GTCC waste form must be placed into costly geologic disposal unless separate approval is obtained from the United States regulator to place it into less costly {open_quotes}near-surface{close_quotes} land burial. Management of GTCC will also require, to some extent, storage and transport prior to its final disposal. A further LLW stream exists in the United States also stemming from the prior operations of United States defense facilities, viz., radioactively contaminated and irradiated scrap metal which has been accumulating over the past forty years. Similarly, as cleanup, decontamination, and decommissioning proceeds, this contaminated scrap metal inventory is expected to grow rapidly. This paper explores the notion of the authors that an opportunity for a synergistic solution to two difficult waste management problems may be available in the United States today, and perhaps may similarly be available in other nuclear countries as well. The possibility exists for fabricating packagings from contaminated scrap metal (which would otherwise be part of the waste inventory) and for using these packaging for storage, transport and disposal of GTCC in near-surface burial facilities without reopening or repacking. This approach is appealing and should lead to major safety and cost benefits. An examination of existing regulations with the intent to propose additions, changes, or clarifications that would effectively and beneficially regulate such combined activity is proposed.
This work addressed two major areas concerning joining of advanced borated stainless steels. These areas included the development of a understanding of the physical metallurgy of borated stainless steels and the development of welding processes and post-weld heat treatments for these alloys. Differential thermal analysis experiments were conducted on ten heats of borated stainless steel to determine the transformation temperatures and melting behavior of the alloys. On-heating solidus temperatures were measured for all of the alloys and were used to define the temperatures associated with the fusion line during welding. Isothermal heat treatments designed to evaluate the effects of elevated temperature exposures on the toughness of the borated grades were conducted. These tests were used to determine if significant changes in the microstructure or mechanical properties of weld heat-affected zones (HAZ) occur. Specifically, the tests addressed the solid-state region of the HAZ. The test matrix included a variety of alloy compositions and thermal exposures at temperatures near the on-heating solidus (as determined by the DTA experiments). Welding experiments designed to assess the mechanical properties and microstructure of gas-tungsten arc and electron beam welds were conducted.
MELCOR is a fully integrated, engineering-level computer code, being developed at Sandia National Laboratories for the USNRC. This code models the entire spectrum of severe accident phenomena in a unified framework for both BWRs and PWRs. As part of an ongoing assessment program, the MELCOR computer code has been used to analyze a station blackout transient in Surry, a three-loop Westinghouse PWR. Basecase results obtained with MELCOR 1.8.2 are presented, and compared to earlier results for the same transient calculated using MELCOR 1.8.1. The effects of new models added in MELCOR 1.8.2 (in particular, hydrodynamic interfacial momentum exchange, core debris radial relocation and core material eutectics, CORSOR-Booth fission product release, high-pressure melt ejection and direct containment heating) are investigated individually in sensitivity studies. The progress in reducing numeric effects in MELCOR 1.8.2, compared to MELCOR 1.8.1, is evaluated in both machine-dependency and time-step studies; some remaining sources of numeric dependencies (valve cycling, material relocation and hydrogen burn) are identified.