Publications

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Supercritical carbon dioxide (sCO2) Brayton power cycles have the potential to significantly improve the economic viability of concentrating solar power (CSP) plants by increasing the thermal to electric conversion efficiency from around 35% using high-temperature steam Rankine systems to above 45% depending on the cycle configuration. These systems are the most likely path toward achieving the Department of Energy's (DOE) Office of Energy Efficiency and Renewable Energy (EERE) SunShot targets for CSP tower thermal to electric conversion efficiency above 50% with dry cooling to air at 40 °C and a power block cost of less than 900 $/kWe. Many studies have been conducted to optimize the performance of various sCO2 Brayton cycle configurations in order to achieve high efficiency, and a few have accounted for drivers of cost such as equipment size in the optimization, but complete techno-economic optimization has not been feasible because there are no validated models relating component performance and cost. Reasonably accurate component cost models exist from several sources for conventional equipment including turbines, compressors, and heat exchangers for use in rough order of magnitude cost estimates when assembling a system of conventional equipment. However, cost data from fabricated equipment relevant to sCO2 Brayton cycles is very limited in terms of both supplier variety and performance level with most existing data in the range of 1 MWe power cycles or smaller systems, a single completed system around 7 MWe by Echogen Power Systems, and numerous ROM estimates based on preliminary designs of equipment for 10 MWe systems. This data is highly proprietary as the publication of individual data by any single supplier would damage their market position by potentially allowing other vendors to undercut their stated price rather than competing on reduced manufacturing costs. This paper describes one approach to develop component cost models in order to enable the techno-economic optimization activities needed to guide further research and development while protecting commercially proprietary information from individual vendors. Existing cost models were taken from literature for each major component used in different sCO2 Brayton cycle configurations and adjusted for their magnitude to fit the limited vendor cost data and estimates available. A mean fit curve was developed for each component and used to calculate updated cost comparisons between previously-reviewed sCO2 Brayton cycle configurations for CSP applications including simple recuperated, recompression, cascaded, and mixed-gas combined bifurcation with intercooling cycles. These fitting curves represent an average of the assembled vendor data without revealing any individual vendor cost, and maintain the scaling behavior with performance expected from similar equipment found in literature.

Printed circuit heat exchangers (PCHEs) have an important role in supercritical CO2 (sCO2) Brayton cycles because of their small footprint and the high level of recuperation required for this power cycle. Compact heat exchangers like PCHEs are a rapidly evolving technology, with many companies developing various designs. One technical unknown that is common to all compact heat exchangers is the flow distribution inside the headers that affects channel flow uniformity. For compact heat exchangers, the core frontal area is often large compared with the inlet pipe area, increasing the possibility of flow maldistribution. With the large area difference, there is potential for higher flow near the center and lower flow around the edges of the core. Flow maldistribution increases pressure drop and decreases effectiveness. In some header geometries, flow separation inside the header adds to the pressure drop without increasing heat transfer. This is the first known experiment to test for flow maldistribution by direct velocity measurements in the headers. A PCHE visualization prototype was constructed out of transparent acrylic for optical flow measurements with Particle Image Velocimetry (PIV). The channels were machined out of sheets to form many semi-circular cross sections typical of chemically-etched plates used in PCHE fabrication. These plates were stacked and bolted together to resemble the core geometry. Two header geometries were tested, round and square, both with a normally-oriented jet. PIV allows for velocities to be measured in an entire plane instantly without disturbing the flow. Small particles of approximately 10 micrometers in diameter were added to unheated water. The particles were illuminated by two laser flashes that were carefully timed, and two images were acquired with a specialized digital camera. The movement of particle groups was detected by a cross-correlation algorithm with a result of about 50k velocity measurements in a plane. The velocity distribution inside the header volume was mapped using this method over many planes by traversing the PCHE relative to the optical equipment. The level of flow maldistribution was measured by the spatially-changing velocity coming out of the channels. This effect was quantified by the coefficient of variation proposed by Baek et al. The relative levels of flow maldistribution in the different header geometries in this study were assessed. With highly-resolved velocity measurements, improvements to header geometry to reduce flow maldistribution can be developed.

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In a common electric power plant, heat is used to boil water into steam which drives a turbine. The steam from the turbine outlet is condensed with cooling water. This is the common Rankine cycle and, even after decades of development is relatively inefficient and water intensive. Alternatively, a closed Brayton cycle recirculates the working fluid, and the turbine exhaust is used in a recuperating heat exchanger to heat the turbine feed. A "supercritical cycle' is a closed Brayton cycle in which the working fluid, such as supercritical carbon dioxide (sCO2), is maintained above the critical point during the compression phase of the cycle. The key property of the fluid near its critical point is its higher gas density, closer to that of a liquid than of a gas, allowing for the pumping power in the compressor to be significantly reduced resulting in improved efficiency. Other advantages include smaller component size and the reduced use of water, not only due to the increased efficiency, but also due sensible heat rejection which facilitates dry air cooling compared to air-cooled steam condensers. A Sandia National Laboratories commercialization review concluded that the technology has applicability across various power generation applications including fossil fuels, concentrated solar power and nuclear power. In 2006, Sandia National Laboratories (SNL), recognizing the potential advantages of a higher efficiency power cycle, used internal funds to establish a testing capability and began partnering with the U.S. Department of Energy Office of Nuclear Energy to develop a laboratory-scale test assembly to show the viability of the underlying science and demonstrate system performance. Since that time, SNL has generated power, verified cycle performance, and developed cycle controls and maintenance procedures. The test assembly has successfully operated in different configurations (simple Brayton, waste heat cycle, and recompression) and tested additives to the s-CO2 working fluid. Our current focus is to partner with industry and develop cycle components and control strategies sufficient to support a successful commercial offering. This paper has been developed for the Energy Policy Institute's (EPI's) 6th Annual Energy Policy Research Conference scheduled for 8 & 9 September 2016 in Santa Fe, NM. We describe the cycle in more detail and describe specific benefits and applications. The paper will also include current technology development activities and future plans.

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The high-temperature particle - supercritical carbon dioxide (sCO2) Brayton power system is a promising option for concentrating solar power (CSP) plants to achieve SunShot metrics for high-temperature operation, efficiency, and cost. This system includes a falling particle receiver to collect solar thermal radiation, a dry-cooled sCO2 Brayton power block to produce electricity, and a particle to sCO2 heat exchanger to couple the previous two. While both falling particle receivers and sCO2 Brayton cycles have been demonstrated previously, a high temperature, high pressure particle/sCO2 heat exchanger has never before been demonstrated. Industry experience with similar heat exchangers is limited to lower pressures, lower temperatures, or alternative fluids such as steam. Sandia is partnering with three experienced heat exchanger manufacturers to develop and down-select several designs for the unit that achieves both high performance and low specific cost to retire risks associated with a solar thermal particle/sCO2 power system. This paper describes plans for the construction of a particle sCO2 heat exchanger testbed at Sandia operating above 700 °C and 20 MPa, with the ability to couple directly with a previously-developed falling particle receiver for on-sun testing at the National Solar Thermal Test Facility (NSTTF).

The high-temperature particle - supercritical carbon dioxide (sCO2) Brayton power system is a promising option for concentrating solar power (CSP) plants to achieve SunShot metrics for high-temperature operation, efficiency, and cost. This system includes a falling particle receiver to collect solar thermal radiation, a dry-cooled sCO2 Brayton power block to produce electricity, and a particle to sCO2 heat exchanger to couple the previous two. While both falling particle receivers and sCO2 Brayton cycles have been demonstrated previously, a high temperature, high pressure particle/sCO2 heat exchanger has never before been demonstrated. Industry experience with similar heat exchangers is limited to lower pressures, lower temperatures, or alternative fluids such as steam. Sandia is partnering with three experienced heat exchanger manufacturers to develop and down-select several designs for the unit that achieves both high performance and low specific cost to retire risks associated with a solar thermal particle/sCO2 power system. This paper describes plans for the construction of a particle sCO2 heat exchanger testbed at Sandia operating above 700 °C and 20 MPa, with the ability to couple directly with a previously-developed falling particle receiver for on-sun testing at the National Solar Thermal Test Facility (NSTTF).

This report outlines the work completed for a Laboratory Directed Research and Development project at Sandia National Laboratories from October 2012 through September 2015. An experimental supercritical carbon dioxide (sCO ₂ ) loop was designed, built, and o perated. The experimental work demonstrated that sCO ₂ can be uti lized as the working fluid in an air - cooled, natural circulation configuration to transfer heat from a source to the ultimate heat sink, which is the surrounding ambient environment in most ca ses. The loop was also operated in an induction - heated, water - cooled configuration that allows for measurements of physical parameters that are difficult to isolate in the air - cooled configuration. Analysis included the development of two computational flu id dynamics models. Future work is anticipated to answer questions that were not covered in this project.

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This paper evaluates cost and performance tradeoffs of alternative supercritical carbon dioxide (s-CO2) closed-loop Brayton cycle configurations with a concentrated solar heat source. Alternative s-CO2 power cycle configurations include simple, recompression, cascaded, and partial cooling cycles. Results show that the simple closed-loop Brayton cycle yielded the lowest power-block component costs while allowing variable temperature differentials across the s-CO2 heating source, depending on the level of recuperation. Lower temperature differentials led to higher sensible storage costs, but cycle configurations with lower temperature differentials (higher recuperation) yielded higher cycle efficiencies and lower solar collector and receiver costs. The cycles with higher efficiencies (simple recuperated, recompression, and partial cooling) yielded the lowest overall solar and power-block component costs for a prescribed power output.

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