Development Validation and Benchmarking of Quantitative Risk Assessment Tools for Hydrogen Refueling Stations
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DOE has identified consistent safety, codes, and standards as a critical need for the deployment of hydrogen technologies, with key barriers related to the availability and implementation of technical information in the development of regulations, codes, and standards. Advances in codes and standards have been enabled by risk-informed approaches to create and implement revisions to codes, such as National Fire Protection Association (NFPA) 2, NFPA 55, and International Organization for Standardization (ISO) Technical Specification (TS)-19880-1. This project provides the technical basis for these revisions, enabling the assessment of the safety of hydrogen fuel cell systems and infrastructure using QRA and physics-based models of hydrogen behavior. The risk and behavior tools that are developed in this project are motivated by, shared directly with, and used by the committees revising relevant codes and standards, thus forming the scientific basis to ensure that code requirements are consistent, logical, and defensible.
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The Overall Objectives of this study are: 1).Create compact gaseous and delivered liquid hydrogen reference station designs appropriate for urban locations, enabled by hazard/harm mitigations, near-term technology improvements, and layouts informed by risk (performance-based design). 2) Disseminate results and obtain feedback through reports and a workshop with stakeholders representing code/standard development organization, station developers, code officials, and equipment suppliers. 3) Identify and provide designs for compact station concepts which enable siting on 3-times the number of stations in the dense urban example of San Francisco.
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Safety standards development for maintenance facilities of liquid and compressed natural gas fueled vehicles is required to ensure proper facility design and operating procedures. Standard development organizations are utilizing risk-informed concepts to develop natural gas vehicle (NGV) codes and standards so that maintenance facilities meet acceptable risk levels. The present report summarizes Phase II work for existing NGV repair facility code requirements and highlights inconsistencies that need quantitative analysis into their effectiveness. A Hazardous and Operability study was performed to identify key scenarios of interest using risk ranking. Detailed simulations and modeling were performed to estimate the location and behavior of natural gas releases based on these scenarios. Specific code conflicts were identified, and ineffective code requirements were highlighted and resolutions proposed. These include ventilation rate basis on area or volume, as well as a ceiling offset which seems ineffective at protecting against flammable gas concentrations. ACKNOWLEDGEMENTS The authors gratefully acknowledge Bill Houf (SNL -- Retired) for his assistance with the set-up and post-processing of the numerical simulations. The authors also acknowledge Doug Horne (retired) for his helpful discussions. We would also like to acknowledge the support from the Clean Cities program of DOE's Vehicle Technology Office.
Hydrogen Risk Assessment Models (HyRAM) is a software toolkit that provides a basis for quantitative risk assessment and consequence modeling for hydrogen infrastructure and transportation systems. HyRAM integrates validated, analytical models of hydrogen behavior, statistics, and a standardized QRA approach to generate useful, repeatable data for the safety analysis of various hydrogen systems. HyRAM is a software developed by Sandia National Laboratories for the U.S. Department of Energy. This document demonstrates how to use HyRAM to recreate a hydrogen system and obtain relevant data regarding potential risk. Specific examples are utilized throughout this document, providing detailed tutorials of HyRAM features with respect to hydrogen system safety analysis and risk assessment.
Several jurisdictions with critical tunnel infrastructure have expressed the need to understand the risks and implications of traffic incidents in tunnels involving hydrogen fuel cell vehicles. A risk analysis was performed to estimate what scenarios were most likely to occur in the event of a crash. The results show that the most likely consequence is no additional hazard from the hydrogen, although some factors need additional data and study to validate. This includes minor crashes and scenarios with no release or ignition. When the hydrogen does ignite, it is most likely a jet flame from the pressure relief device release due to a hydrocarbon fire. This scenario was considered in detailed modeling of specific tunnel configurations, as well as discussion of consequence concerns from the Massachusetts Department of Transportation. Localized concrete spalling may result where the jet flame impinges the ceiling, but this is not expected to occur with ventilation. Structural epoxy remains well below the degradation temperature. The total stress on the steel structure was significantly lower than the yield stress of stainless steel at the maximum steel temperature even when the ventilation was not operational. As a result, the steel structure will not be compromised. It is important to note that the study took a conservative approach in several factors, so observed temperatures should be lower than predicted by the models.
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