Publications

Current work in the area of integrated materials monitoring/tracking and accounting at Argonne National Laboratory-West (ANL-W) has resulted from the development of materials accounting system by Los Alamos National Laboratory (LANL) and a demonstrated personnel and materials tracking system by Sandia National Laboratories (SNL). The integration of these two systems has culminated in the current system effort which is called the ARGonne Unified Safeguard (ARGUS) system. The ARGUS system is made up of three major components. These components perform the functions of observing all container movements, authorized materials access approval, initiation and receipt of materials transfers, and perform materials accounting for the facility. ARGUS system benefits can be summarized through system capabilities as follows: near real-time accountability, full traceability of materials access and transfer, enforcement of approved personnel access to materials, electronic confirmation of materials surveillance procedures during materials access and transfers, continuous surveillance of all material not directly involved in the manufacturing process, transfer and receipt, and automatic notification to security for identified anomalies. This paper will concentrate on the overall ARGUS system, its operational impacts and advantages. 2 refs., 2 figs.

An Optimal Projection reduced order controller is designed and implemented on an experimental controlled structure testbed. Twenty modes of the test structure lie within the controller bandwidth. Four strain sensor signals are fed back through an eighteenth order dynamic controller into four stress actuators (not collocated with the sensors) to reduce the vibration of the structure. Five independent performance measures are simultaneously minimized with an Optimal Projection controller derived from a 58th order state space model. The controller reduces the RMS vibration response by up to 65% without saturating the actuators and without destabilizing high frequency modes. The Optimal Projection controller always performs better than a sub-optimal controller based on ordinary Linear Quadratic Gaussian theory. The homotopy algorithm used to solve the Optimal Projection synthesis equations is described, and both analytical and experimental results are presented. 26 refs., 6 figs., 5 tabs.

The unsteady thin-layer Navier-Stokes equations for a perfect gas are solved with a linearized block Alternating Direction Implicit finite-difference solution procedure. Solution errors due to numerical dissipation added to the governing equations are evaluated. Errors in the numerical predictions on three different grids are determined where Richardson extrapolation is used to estimate the exact solution. Accurate computational results are tabulated for the hypersonic laminar flow over a spherical body which can be used as a benchmark test case. Predictions obtained from the code are in good agreement with inviscid numerical results arid experimental data.

The Solar One Pilot Plant successfully demonstrated the feasibility of solar central receiver power plants. During its operating years much data were collected regarding the efficiency and availability of the various plant systems. This paper summarizes these statistics and compares them to goals developed by the Department of Energy. Based on this comparison, design and operation improvements are recommended so that future central receiver plants can more closely attain these goals. 9 refs., 4 figs., 1 tab.

This paper explores the relative contributions of radiative and convective heat transfer to objects in large pool fires. The partitioning process depends on many factors. Results include measurements of the temperature of the objects in the fire, the flames surrounding the object, the total heat flux to the objects and the radiative component of the heat transfer at a few locations using transpiration radiometers. These measurements will be compared with calculations. Agreement between the measured radiative heat flux and the calculated radiative heat flux is good. The convective contribution was calculated from the total and radiative parts and was found to be from 10--20% of the total. 18 refs., 18 figs.

28C256 EEPROM total dose and dose-rate results are presented. Mode dependent total dose failure occurred at 9.5 krad(Si) when writing and 33 krad(Si) when reading. Average upset and latch-up thresholds were 3.8 /times/ 10/sup 8/ rad(Si)/s and 7.7 /times/ 10/sup 8/ rad(Si)/s, respectively. 3 refs., 5 tabs.

Development of the Advanced Small Site Program (ASSP) will satisfy the requirement for a small to medium sized security system uses commercially available, low cost, state-of-the-art technology to enhance its performance. The system addresses all aspects of technical security. These aspects include control and display; perimeter and interior sensors; data and video transmissions; video assessment; reduced installation, operation, and maintenance costs. Major system features include use of multi-level graphics with touchscreen inputs to control all sensor and video functions. An optional feature allows the use of fiber optics for data or video transmissions. Integration of functional components into modular sub-systems eases the task of expanding, maintaining, and operating the system. The system's automatic restart function permits a fully loaded system to configure itself in less than ten minutes. Site personnel will be able to create and modify a configuration data file of the site. The ASSP software uses this file data to run its programs. The configuration file contains the number of sensors, sectors, buildings, cameras, sensor thresholds, sensor priorities,and other site specific information. An off-line program obtains this information through a series of queries to the site personnel. This information is written to a data configuration file. This paper describes the functions and integration of this system. 11 figs.

Magmatic activity, and particularly silicic magmatic activity, is the fundamental process by which continental crust forms and evolves. Drilling in the Inyo Chain, a 600-year-old chain of volcanic vents in California, has shown the close relationship of silicic eruption to shallow dike emplacement, the control of eruptive style by shallow porous-flow degassing, the origin of obsidian by welding, the development of igneous zonation by viscosity segregation, and the character and size of conduits in relation to well- understood magmatic and phreatic eruptions. Planned drilling at the site of the largest eruption of the century, in the Mt. Katmai region of Alaska, will test models for explosive eruptions, elucidate the process of vapor-transport of metals, and provide the first measurements of rates of cooling and chemical alteration in a relatively simple, non-composite igneous system. -Author

This report describes a capacity planning project for Engineering Information Management (EIM) systems at Sandia National Laboratories. The purpose was to develop a method for predicting the ability of current hardware computer systems to meet future demands and to address the magnitude of required upgrades. Specific activities included the generation and analysis of alternatives, the selection of analytic modeling as the appropriate vehicle, construction and validation of the model, and the development of recommendations.

Thin silicon nitride (Si/sub 3/N/sub 4/) films are widely used as a dielectric in metal-nitride-oxide-silicon (MNOS) structures for radiation hard non-volatile memories. The retention of charge in these devices depends, among other things, on the chemistry of the films. It has been reported that charge transport in MNOS structures can be reduced by replacing the Si/sub 3/N/sub 4/ film by a silicon oxynitride (SiO/sub x/N/sub y/) film. In order to understand the relationship between chemistry and retention of charge, it is necessary to have a technique that can determine the chemistry of the films as a function of depth. This can be accomplished with Auger electron spectroscopy by using fingerprint spectra for each of the elements and compounds present in the sample. By using classical least-squares techniques, a unique combination of the standard spectra can be found that best fits the unknown spectrum. When this method is repeated for each spectrum in a depth profile, a chemical state depth profile is obtained. The use of this technique to profile oxynitride films where the SiO/sub 2/ content varies between 0 and 12 atomic percent is presented. 6 refs., 7 figs.

Time stepping algorithms are often used to solve parabolic and hyperbolic differential equations numerically. These algorithms are generally regarded as sequential in time; that is, the solution on a time level must be known before the computation of the solution at subsequent time levels can start. While this remains true in principle, we demonstrate that it is possible for processors to perform useful work on many time levels simultaneously. Specifically, it is possible for a processor assigned to a ''later'' time level to compute a very good initial guess for the solution based on approximations to the solutions on ''previous'' time levels, thus reducing the time required for solution. The reduction in the solution time can be measured as parallel speedup. We demonstrate two parallel time stepping algorithms that can be used for both linear and nonlinear problems. We compare the two algorithms and discuss their performance in terms of parameters associated with classical time stepping algorithms. 4 refs., 5 tabs.

A general representation approach is described which employs a hierarchy of holes and notches. A matching procedure is also described which allows non-ideal image hierarchies to be matched to class representations. The representation and matching methods are demonstrated on a set of handgun photographs. Examples of handguns which are different in detail are shown to exhibit the same class characteristics, while other similarly shaped objects are correctly distinguished from the handgun class. 6 refs., 8 figs.

We are currently investigating a solar-driven photocatalytic process that promises to destroy low concentrations of hazardous organic molecules in large volumes of contaminated groundwater or industrial waste streams. Preliminary results of laboratory-scale screening tests using a model compound, salicylic acid, and titanium dioxide catalyst have shown that no measurable reaction occurs without both uv light and catalyst; no measurable volatilization of the salicylic acid occurs at room temperature; salicylic acid destruction rates depend on catalyst supplier and concentration and on uv light intensity; and some intermediates are being formed and subsequently destroyed. Observed reaction rates are consistent with those observed in an initial pilot-scale solar test of a falling-film reactor, although further testing will be required to quantify the comparison. 10 refs., 5 figs.

A novel technique is presented for segmenting seismic waveforms. The method produces waveform segments which closely correspond to explosion and earthquake signal onsets as well as additional structure of interest. Noise spikes or glitches are also successfully isolated. The approach uses threshold parameters obtained from human segmentation judgment tests and requires only simple, time domain calculations. 6 refs., 3 figs.

Sandia National Laboratories (SNL) performs software security analyses of many systems having strong security requirements. This paper gives an overview of a software security analysis methodology that has evolved at SNL. This methodology is based on experience gained in the analysis of critical software-controlled systems. The paper describes analysis activities and how they relate to the traditional software life cycle. Topics discussed include: planning for the analysis; supporting the development and documentation of security requirements; identifying and analyzing the threat; acquiring and utilizing software design and implementation materials; identifying positive design features; scaling the analysis effort to the threat; analyzing the high-level design; analyzing the source-code and target implementations; reporting results; interacting with system and component development groups; and supporting the authentication of the software product before it is fielded. The paper also stresses the importance of independence of analysis and development groups.

In the early 1980s, the US Department of Energy/Defense Programs (DOE/DP) initiated a project to develop a safe and efficient transportation system for defense high-level waste (DHLW). Sandia National Laboratories (SNL) provides a technical oversight and test support and General Atomics provides the design and safety analysis of the shipping system. The specific activities include designing, testing, certifying and fabricating a legal-weight truck cask system for DHLW canisters that are expected to be first produced by the Defense Waste Processing Facility (DWPF) at the Savannah River Plant (SRP) in South Carolina and later produced by facilities in Washington and Idaho. A truck cask was selected in order to provide a flexible capability for transporting vitrified waste to support a variety of expected experimental program needs. The first planned shipping campaign was to transport a limited number of DHLW canisters from South Carolina to the Waste Isolation Pilot Plant (WIPP) in New Mexico. However, changes in experimental program plans the passage of the Nuclear Waste Policy Act in late 1982, and the subsequent decision to have DHLW permanently placed in the eventual civilian repository resulted in revisions to the mission of the cask development program funded by DOE/DP. 15 refs.

We have sputter-deposited aluminum oxide coatings using a dual ion beam system with a mixture of argon plus 10% oxygen as the working gas. Ambient substrate temperatures and substrate temperatures of 360{degree}C were maintained. The coatings were deposited at deposition rates between 7 and 10 nm/min, with and without concurrent ion bombardment from the second ion gun. Substantial variations in the microstructure and the amount of entrained gas in the coatings were observed. The coatings contain a mixture of varying amounts of {gamma}-Al{sub 2}O{sub 3} and amorphous aluminum oxide. Relatively large, 0.5 {mu}m islands of {gamma}-Al{sub 2}O{sub 3} crystallites surrounded by an amorphous matrix were observed in coatings deposited onto heated substrates with ion bombardment from the second ion gun during deposition. Coatings bombarded with a second ion beam during deposition contain more argon as determined by energy dispersive x-ray analysis. The Raman spectra exhibited by the coatings suggest a variation in chemical reactivity and/or porosity which depends on the deposition conditions. 18 refs., 6 figs.

The operation of TORE SUPRA at full power (25MW, 30s) has led to the design of a full set of actively pumped carbon limiters to remove at least 8MW and to partially control the particle balance. An interim version is now installed, composed of 5 vertical and one horizontal outboard (OPL) pump limiters, semi-inertially water cooled. The latter is a result of a collaboration between the US DOE and the Association EUR-CEA, it is fully instrumented and therefore can serve as a reference for the final design. Ohmic discharges (1.85T, 740kA, 8.5s) in helium have been used to test the thermal load on and the particle exhaust efficiency of the OPL. In these experiments the plasma is formed on the inner wall (R = 232 cm, a = 76 cm) and subsequently displaced (6 cm) outward, early on the current plateau, to lean on the OPL (R = 238 cm, a = 75 cm). In addition to the limiters above, a non-pumped outboard (ONLP) limiter of identical shape to the OPL served to produce similar discharges for better comparison and determination of particle control. A comparison is made hereafter of the thermal load and particle pumping effects on the OPL when the plasma is in contact either with the OPL/ONPL alone or with the OPL and the vertical limiters together. 3 refs., 1 fig., 2 tabs.

Particle collection, removal, and exhaust by the toroidal belt pump limiter ALT-III have been measured in deuterium discharges with co-, counter-, and balanced injection of 48 keV neutral hydrogen particles. Particle collection increases from 50-80 A to 150-320 A during 1.2 MW of co- or counter-injection or 2.4 MW of balanced injection. The removal rate for pumping at two of the eight blades (3 of 15 scoops) reaches 2.7 Torr-l/s with a removal efficiency of nearly 45%. Extrapolating these results to a full belt with 15 scoops and eight pumps yields 140 amps of removal. This compares favorably with the maximum injectable current of 50 A and suggests that ALT-II with full pumping can provide sufficient exhaust during NI heating. 4 figs.

The surface properties of symmetric microphase separated diblock copolymers of polystyrene (PS) and polymethylmethacrylate (PMMA) were investigated using X-ray photoelectron spectroscopy (XPS), the specular reflectivity of neutrons and secondary ion mass spectrometry (SIMS). PS, the lower surface energy component, exhibited a preferential affinity for the free surface. For copolymers that are far from the bulk microphase separation transition (MST), the surface consists of a layer of pure PS. When the system is close to the MST the surface is a mixture of PS and PMMA. The PS surface excess can be described by a N-{sup 1/2} dependence, where N is the number if segments that comprise the copolymer chain. It is shown that the surface undergoes an ordering transition at a temperature T{sub s} that is above that of the bulk MST. The ordering of the bulk lamellar morphology is induced by an ordering at the surface. This is analogous to the ferromagnetic order observed in systems such as Gd at temperatures above the bulk Curie temperature. The results here are discussed in light of previous work on copolymer surfaces and in light of mean field theory. 31 refs., 8 figs.

Oxygen ion beam bombardment has been studied as a means for incorporating oxygen into thin films of Y-Ba-Cu-oxide either by enhancing the transport of oxygen to substrates during ion-beam sputtering, or by direct incorporation of oxygen by ion-assisted deposition. Optical emission spectroscopy was used to study the ion-beam bombardment of bulk superconducting targets as the oxygen content of the ion beam was varied between 0% (pure argon) and 100% oxygen. This showed that oxygen did not directly combine with metallic elements in the target to increase the oxygen content of the stream of particles moving toward the substrate. The oxygen content of the sputter beam did, however, change the relative emission intensity from the various target components. Addition of a second ion beam directing an oxygen beam toward the substrate as the film is grown, caused large variations in the stoichiometry of the deposited films. At low ion currents, no increase in the oxygen content of the films was detected, while at relatively high currents, the oxygen incorporation increased. However, the sputtering of the metallic components of the film increased, leading to very low growth rates. 8 refs., 5 figs.

Intense beams of light ions are being developed at Sandia National Laboratories as a promising driver option for Inertial Confinement Fusion (ICF) implosions. The Particle Beam Fusion Accelerator II (PBFA II) will provide the physics basis for light-ion-beam driven ICF targets. Recent progress made in ion beam generation focusing on PBFA II has led to a record 5.4 TW/cm{sup 2} peak focal intensity with {gt}80 kJ proton energy delivered to a 6-mm diameter sphere. The driver-development program on PBFA II is reviewed. A design concept for a light ion beam driver for the Laboratory Microfusion Facility is also presented. 34 refs., 9 figs., 1 tab.

In an earlier paper, we reported that it is possible to train a first-order multi-layer feedforward network with backpropagation to classify raw 8-bit images of vehicles. We concluded that a linear feedforward network is capable of within-class generalization when trained with perspective views taken every 10{degree}, but it is incapable of one-class generalization. This paper describes the results of a set of experiments to train a feedforward network with second-order inputs to perform one-class classification on image data. We compare the results of the first-order network and the second-order network and show that the second order network is better able to generalize as a one-class classifier. 7 refs., 6 figs.

Short communication.

Ion beam studies on radiation enhanced sublimation (RES) have shown that above 800{degree} C energetic ions incident on graphite produce erosion in the form of carbon atoms with thermal energies and that the erosion rate rises roughly exponentially with temperature. Until recently, the question remained whether RES would scale linearly with flux over three to four orders of magnitude to the plasma edge fluxes in CIT and ITER, where the predicted erosion rates would severely limit the designs for plasma-facing components. Also, RES and carbon self-sputtering may also be involved in the carbon blooms'' observed in TFTR and JET. The data reported here from PISCES, a plasma source at UCLA, are the first RES data at fluxes approaching the plasma edge conditions in a large tokamak and they show little reduction from a direct linear dependence upon flux. Erosion rates measured by weight loss are reported for POCO graphite exposed to helium plasmas for a temperature range from 900--2000{degree} C, ion energies of 30--300 eV, ion fluxes of 1--6 {times} 10{sup 18} cm{sup {minus}2} s{sup {minus}1}, densities of 2--10 {times} 10{sup 12} cm{sup {minus}3} and electron temperatures of 4-10 eV. For these conditions, the amount of redeposition and carbon self-sputtering was minimal. Over 1700{degree} C, there is evidence of electron emission from the sample. 26 refs., 4 figs., 1 tabs.