Publications

Transport by groundwater within the Culebra Dolomite, an aquifer above the Waste Isolation Pilot Plant (WIPP), is the most probable mechanism for long-term release of radionuclides to the accessible environment. Radionuclides could be retarded by sorption if the groundwater is exposed to sufficient amounts of fracture-lining clays. In this natural-analog study, distributions of U and trace metals have been examined to constrain the strength of clay/solute interactions within the Culebra. Uranium solid/liquid distribution ratios, calculated from U concentrations of groundwaters and consanguineous fracture-filling clays, range from {approximately}80 to 800 m{ell}/g and imply retardation factors of 60 to 500 using a fracture-flow model. Retardation factors inferred from uranium-series disequilibria and {sup 14}C ages in Culebra groundwaters alone are much lower ({approximately}10), implying that clays may contain a significant unreactive component of U. Such a possibility is corroborated by Rb/Sr ages; these imply long-term stability of the clays,with resetting occurring more than 250 Ma ago. Factor analysis and mass-balance calculations suggest, however, that Mg-rich clays are dissolving in Pleistocene-age groundwaters and/or are converting to Na-rich smectites, and that B and Li are taken up from the water by the clays. Apparently, the solution chemistry reflects gradual equilibration of clays with groundwater, but thus far the bulk of the clays remain structurally intact. Measurements of the distribution of U in the Culebra will be more meaningful if the inert and exchangeable components of the U content of the clays can be quantified. 26 refs., 3 figs., 2 tabs.

The authors present sufficient conditions for the design of strictly positive real (SPR), fixed-order dynamic compensators. The primary motivation for designing SPR compensators is for application to positive real (PR) plants. When an SPR compensator is connected to a PR plant in a negative feedback configuration, the closed loop is guaranteed stable for arbitrary plant variations as long as the plant remains PR. Equations that are a modified form of the optimal projection equations, with the separation principle not holding in either the full- or reduced-order case, are given. A solution to the design equations in shown to exist when the plant is PR (or just stable). Finally, the closed-loop system consisting of a PR plant and an SPR compensator is shown to be S-structured Lyapunov stable.

Computer simulation of low-energy ion-solid processes has greatly broadened in scope in recent years. In particular, realistic descriptions of the ion-solid and solid-solid interactions can now be utilized. The molecular dynamics technique, in which the equations of motion of the interacting atoms are numerically integrated, can now be used to characterize ion-solid interactions in a range of model material systems. Despite practical limitations of this procedure, a number of substantial results have appeared. The available results are examined to investigate the qualitative influence that chemical interactions have on low-energy ion-solid processes. 26 refs., 4 figs.

Good quality, low temperature silicon nitride and oxynitride films were deposited downstream from an electron cyclotron resonance (ECR) plasma source using SiH{sub 4} and N{sub 2} gas mixtures. The Si/N ratio and H content in the deposited films were determined using Rutherford backscattering spectrometry (RBS)and elastic recoil detection (ERD). The H concentration was minimum for films with compositions closest to that of stoichiometric Si{sub 3}N{sub 4}. The optimum conditions for producing a stoichiometric Si{sub 3}N{sub 4}were: a SiH{sub 4}/N{sub 2} flow ratio between 0.1 and 0.2, and an electrically isolated sample far from the ECR source. Infrared absorption spectra showed that as the film composition changed from N rich to Si rich the dominant bonds associated with H changed from N-H to Si-H. The addition of O{sub 2} to the background gas formed an oxynitride with a low H content similar to the stoichiometric Si{sub 3}N{sub 4} 10 refs., 4 figs., 2 tabs.

We have used a Tl-Ca-Ba-Cu-O superconducting flux flow transistor (SFFT) as an active impedance converter between Josephson and FET circuitry. The input of the flux flow device is a control line of low impedance that can be driven by a tunnel junction. The output is the signal across the SFFT which is made of a parallel array of weak links. The output impedance is typically greater than 5 {Omega} with a maximum voltage swing of over 100 mV into a 50 {Omega} system. The switching of an all-Nb junction induced a 90 mV voltage swing at the FET input and over 200 mV at the FET output. The line driver can operate anywhere between 4.2K and 85K with minor changes in speed ({plus minus}5 ps) and output level ({plus minus}10 mV). The switching time measured was about 100 ps and was fixture limited. 13 refs., 5 figs.

Archimedes is a prototype mechanical assembly system which generates and executes robot assembly programs from a CAD model input. The system addresses the unrealized potential for flexibility in robotic mechanical assembly applications by automating the programming task. Input is a solid model of the finished assembly. Parts relationships and geometric constraints are deduced from the solid model. A rule-based planner generates a generic'' assembly plan that satisfies the geometric constraints, as well as other constraints embodied in the rules. A retargetable plan compiler converts the generic plan into code specific to an application environment. Execution of the compiled plan in a workcell containing an Adept Two robot, a vision system, and other parts handling equipment will be shown on videotape.

This concept brings a condensed source of tritium into close proximity with an inorganic phosphor. That source may thus become the equivalent of many atmospheres of tritium gas pressure. If both phosphor and tritium source material are optically clear, then a lamp's brightness may be made to scale with optical path length. Proof of principle of this concept has been demonstrated and will be described. A theoretical treatment is presented for the results here and for results from aerogel experiments.

Pressurized water reactor pressure vessels operate under US Nuclear Regulatory Commission (NRC) rules and regulatory guides that are intended to maintain a low probability of vessel failure. The NRC has also addressed neutron embrittlement of pressurized water reactor pressure vessels by imposing regulations on plant operation. Plants failing to meet the operating criteria specified by these rules and regulations are required, among other things, to analytically demonstrate fitness for service in order to continue safe operation. The initial flaw size or distribution of initial vessel flaws is a key input to the required vessel integrity analyses. A fracture mechanics sensitivity study was performed to quantify the effect of the assumed flaw distribution on the predicted vessel performance under a specified pressurized thermal shock transient and to determine the critical crack size. Results of the analysis indicate that vessel performance in terms of the estimated probability of failure is very sensitive to the assumed flaw distribution. 20 refs., 3 figs., 2 tabs.

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Inorganic zeolites show promise as an alternative to traditional tritium gas tube light sources. Greater proximity of tritium atoms and luminescing centers, as well as greater tritium loading density, have been obtained within the zeolite aluminosilicate matrix. Zeolites are in addition optically clear and radiation stable. The zeolite radioluminescence program is described. Procedures for obtaining light sources are presented and results are discussed. 12 refs., 1 fig.

Solderability of Class II environmentally exposed Ni-Sn plated Cu substrates was evaluated with 60Sn-40Pb solder. Tin thickness were 10, 50, and 150 {mu}in. The 10 {mu}in. plating gave the smallest solder meniscus rise. A general decrease in contact angle, or increase in wettability, was observed with increasing Sn plating. The environmental exposures retarded the wetting rate and increased the time to maximum wetting, particularly with only 10 {mu}in. of Sn. Although the solderability of the 50 and 150 {mu}in. surfaces were not significantly affected by the test conditions, an intermediate plating thickness of 100 {mu}in. is preferred for processing flexibility. 13 refs., 6 figs., 1 tab.

SICADS is a generic command, control and display software package which provides the capability to generate security systems which employ different hardware and system configurations, but which are controlled by the same software. SICADS was designed to avoid the task of developing new software for each site. By reusing software, expenses are reduced and software quality is increased. Tested software can be reused without modifications. Configurations of security systems vary from site to site. In many systems, a seemingly minor change in configuration has required significant software modifications. SICADS has been designed to isolate site specific information into data files so that it can be easily tailored to fit a site's requirements without changing the software. Using SICADS, it is possible to generate systems which distribute processing and control over several computers and consoles. 1 fig.

The ion-hose instability can catastrophically disrupt a classical electron beam propagating in the ion-focussed regime (IFR). Ion hose is driven by a resonant interaction between the smooth electron-betatron and ion-betatron orbits. In a classical beam phase correlations decay secularly in time c(t)/c(t{sub 0}) {approximately} (t{sub 0}/t){sup n} (0 < n {le} 2). In a stochastic electron beam the electron orbits are chaotic. Such a beam can be immune to resonant instabilities because phase correlations decay exponentially fast c(t)/c(0) {approximately} e{sup {minus}ht} thus destroying the coherence of the electron response on the growth time 1/{gamma}{sub g} if h {approximately} {gamma}{sub g}. Using the same principles we can also envision a stochastic damping cell in which electron phase correlations damp exponentially c(z)/c(0) {approximately} e{sup {minus}hz} thus centering and conditioning a beam more effectively than a classical phase-mixing cell in which c(z)/c(z{sub 0}) {approximately} (z{sub 0}/z){sup n}. A triple-Bennett'' IFR system and the analogous triple-wire'' damping cell are analyzed. The K-entrophy is introduced as a figure-of-merit for such stochastic electron beam systems. 16 refs., 7 figs.

Strained layer structures have received a great deal of attention due both to their possible application in electronic devices and their intrinsic interest. The study of strained layer quantum wells grown using lattice mismatched materials has been widely developed for III-V semiconductors. Strained layer quantum wells grown using II-VI materials have not been studied nearly so much as those from III-V, but they are a rapidly growing field of semiconductor research. The wide gap II-VI materials are of interest because they are generally direct gap materials. This makes them attractive for optoelectronic devices. The majority of the work on strained layer structures in the wide gap tellurium based materials has focused in two areas. The first is the inclusion of Mn to produce dilute magnetic semiconductors (DMS) strained layers and superlattices. The other area is CdTe/ZnTe quantum wells and superlattices. Some related work has been done with CdZnTe/ZnTe structures. For the CdZnTe/CdTe very little work has been done and the majority of that used very small amounts of Zn. In this paper we will present the growth and optical characterization of Cd{sub 1-x}Zn{sub x}Te/CdTe strained single quantum wells (SSQW) where the Zn concentration ranges from about 10 to 50%. 10 refs., 3 figs.

Apollo's OmniBack backup system provides a convenient and effective way of storing network backup information on 8mm tape. In addition it has a journaling facility to write extensive log files, recording the backup process in almost any degree of detail desired. The directory structure and file names used are logical and well-defined. Summary files announce the degree of success of the backup as specified in the work file. The system will run unattended under the UNIX cron command, allowing the backup to be performed during the night when user demands on the network are small and most user files are free.

Agencies that are prime contractors to the Department of Energy (DOE) have developed and are currently instituting a quality initiative which applies a QML-like methodology to a complete discrete semiconductor process. Our goal is to demonstrate that improving the quality of this process is a more efficient method than screening to improve the quality of the semiconductor. The QML methodology, MIL-I-38535, is used to achieve this goal for integrated circuits. Our methods, for discrete semiconductor, applies many of the principles found in this specification to provide structured continuous improvement. Improvement in product performance reduces incoming inspection requirements, resulting in reduced cost and product lead time. This paper describes our methodology for this initiative, which consists of a certification, qualification, and monitoring (CQM) program for the complete semiconductor process. This process includes all technical and administrative activities that effect the quality of a device, beginning with circuit design and ending with the installation of the manufactured device into the electronic component assembly. For the initial application, our CQM program is being implemented on a small signal transistor. Four companies are involved in the partnership: Sandia National Laboratories, a design agency and prime contractor to the DOE; Allied-Signal Aerospace Company, Kansas City Division, a production agency and prime contractor to the DOE (for electronic component assembly); Alliance Electronics, a prime contractor and supplier (for procurement and testing); and Motorola Inc., Semiconductor Products Sector, a manufacturer. 2 refs.

A Nuisance Alarm Data System (NADS) was developed to gather long-term background alarm data on exterior intrusion detectors as part of their evaluation. Since nuisance alarms play an important part in the selection of intrusion detectors for use at Department of Energy (DOE) facilities, an economical and reliable way to monitor and record these alarms was needed. NADS consists of an IBM Personal Computer and printer along with other commercial units to communicate with the detectors, to gather weather data and to record video for assessment. Each alarm, its assessment and the weather conditions occurring at alarm time are placed into a database that is used in the evaluation of the detector. The operating software is written in Turbo Pascal for easy maintenance and modification. A portable system, based on the NADS design, has been built and shipped to other DOE locations to do on-site alarm monitoring. This has been valuable for the comparison of different detectors in the on-site environment and for testing new detectors when the appropriate conditions do not exist or cannot be simulated at the Exterior Intrusion Detection Testbed.

The Department of Energy (DOE) is investigating the use of ductile cast iron (DCI) as a candidate material for radioactive material transportation cask construction. The investigation will include materials testing and full-scale cask testing. The major effort will focus on materials qualification and cask evaluation of the 9 meter and puncture drop test events. The test plan shall include a series of drop tests, and several core bars will be removed from the casting wall for material properties testing. Of particular interest is the evaluation of the material microstructure and fracture toughness parameters. Test instrumentation, used to define cask deceleration loads and strain during the drop tests, will be strategically placed in areas of the greatest structural interest. Part of the testing will include placement of an induced flaw. At the conclusion of the cask drop tests, the induced flaw(s) will be sectioned from the cask body for metallurgical examination. All test results will be documented in the safety analysis report for packaging for submission to the US Nuclear Regulatory Commission (NRC). The goal of this program is a certificate of compliance for DCI from the NRC to transport high-level radioactive materials. The acceptance of DCI within the USA cask design community will offer an alternative to present-day materials for cask construction, and its entry has the potential of providing significant cost-savings.

Accommodation of lattice mismatch is investigated for the case of large ({epsilon} > 0.02) mismatch. The conventional Matthews- Blakeslee mechanism for creation of misfit dislocations is found to be inadequate for the case of large lattice relaxation owing to interactions amongst the misfit dislocations at the interface. In particular, the regime where the separation D between misfit dislocations is much less than the strained layer thickness h is considered here. The energetics of insertion of dense misfit dislocation networks is examined. According to St Venant's Principle, the existence of a new length scale, D, serves as a cutoff for the stress fields of the dislocation network. This observation has several consequences, including the prevention of relaxation by repulsive interaction amongst threading dislocation segments and the melting'' of moderately relaxed heterointerfaces at conventional semiconductor growth temperatures. A number of experimental observations may be explained via these models.

Infrared reflectance and transmittance measurements between 500 and 1800 cm{sup {minus}1} were obtained on boron carbides with between 10 and 20 atomic percent carbon. Measurements on both boron and carbon isotopically enriched samples indicate that all prominent modes involve boron motion, and that all but a mode near 950 cm{sup {minus}1} involve carbon motion. Since the spectrum remains qualitatively unaltered as a function of carbon concentration, its prominent features must have a common structural origin. 5 refs., 4 figs., 2 tabs.

The thermal neutron absorption cross sections of geologic materials are of first-order importance to the interpretation of pulsed neutron porosity logs and of second-order importance to the interpretation of steady-state porosity logs using dual detectors. Even in the latter case, uncertainties in log response can be excessive whenever formations are encountered that possess absorption properties appreciably greater than the limestones used in most tool calibrations. These effects are of importance to logging operations directed at geothermal applications where formation vary from igneous to sedimentary and which may contain solution-deposited minerals with very large cross-section values. Most measurements of cross-section values for geologic materials have been made for hydrocarbon production applications. Hence, the specimen materials are sedimentary and clean in the sense that they are not altered by geothermal fluids. This investigation was undertaken to measure cross-section values from a sequence of igneous materials obtained from a single hole drilled in an active hydrothermal system. 3 refs., 1 fig.

An automatic optical track identification/counting system has been developed for counting the total number of fission tracks on a fused quartz solid state track recorder. The system is capable of analyzing up to twenty recorders a day with an operator input of less than two hours. The uncertainty introduced by the counting system is about one percent. 6 refs., 2 figs.

A new runaway electron suppression paddle was designed with the PTA code package to reduce the runaway electron population in the Advanced Toroidal Facility (ATF), Oak Ridge National Laboratory. The PTA code package is a unique application of PATRAN, the Integrated TIGER Series, and ABAQUS for modeling high energy electron impact on magnetic fusion components and materials. By its nature, ATF is susceptible to runaway electron formation and confinement resulting in the production of a high level of hard x-rays near the machine. Four previous stainless steel paddles proved effective in reducing the runaway electron population; however, electrons above 15 MeV have still been observed. Melting and bending were observed in each of the previous paddles, reducing their effectiveness. Scoping experiments are under way to further characterize the runaway electrons in ATF. Data from these experiments will provide insight into runaway electron damage mechanisms. Proposals for the insertion of a new paddle in ATF are being considered. These analyses add to the knowledge of runaway electron damage and will aid in the design of future components to withstand runaway electron discharges in all magnetic fusion devices, including tokamaks. 8 refs., 3 figs., 1 tab.

System tuning often occurs in response to observed changes in key performance indicators. But, how do we determine if a change is significant Our indicators are random variables. They display a natural'' variation. This presentation reviews techniques that may provide a great deal of assistance in determining the significance of a change -- and more importantly -- when and what to tune. The techniques were developed by Dr. William Shewhart at Bell Labs and refined by internationally known quality specialist W. Edwards Deming. Although founded on statistical theory, the techniques are easy to use, require no formal statistical training, and may help you

The US Department of Energy National Photovoltaics Program considers the photovoltaic (PV) concentrator technology as a viable entity, likely to penetrate the utility market in the foreseeable future. To achieve this, it has launched the National Photovoltaic Concentrator Initiative under the management of Sandia National Laboratories. The objective of this program is to encourage PV concentrator system design and manufacture, with a view to bringing the energy cost to $0.12/kWh in the next four years and to $0.06/kWh by the year 2000. To achieve these goals, the systems have to perform reliably for 20 to 30 years. This necessitates a stringent quality assurance/quality control (QA/QC) program in all phases of PV concentrator design, production, and installation. In order to assist the PV industry in this effort a project was initiated to provide a generic QA/QC guide, capable of being adapted by any PV concentrator industry to prepare its individual QA/QC plan. The draft plan of the guide was prepared and circulated to various government laboratories and industries involved in PV concentrator work. Their input is now being incorporated into a final document, which will serve as an industry standard. 1 ref., 1 fig.