Publications

Electroheological suspensions typically contain particles of approximately one {mu}m in diameter. Thus light-scattering offers a natural method of probing the microstructure of these suspensions. We report the development of an index matched single-scattering fluid, as well a slight-scattering studies of this fluid in both a quiescent and sheared regime. In the first case, the results are in agreement with a phenomenological theory of coarsening based on thermal fluctuations. In the second case, they agree with an ``independent droplet`` model of the suspensions structure under shear.

The success of technology transfer agreements depends not just on the technical work, but on how well the arrangements to protect and dispose of the intellectual properties that make up the technologies are handled. Pertinent issues that impact the protection and disposition of intellectual properties during the technology transfer process at Sandia National Laboratories, a multiprogram laboratory operated for the Department of Energy by the Martin Marietta Corporation, are discussed. Subjects addressed include the contracting mechanisms (including the Cooperative Research and Development Agreement [CRADA] and the Work-for-Others agreement), proprietary information, The Freedom of Information Act, patents and copyrights, the statement of work, Protected CRADA Information, licensing considerations, title to intellectual properties, march-in rights, and nondisclosure agreements.

An evaluation of the key elements affecting Direct Containment Heating (DCH) was performed for the Surry plant. This involved determining the dominant high pressure core damage sequences, the probability of proceeding to vessel breach at high pressure, the DCH loads, and the containment strength. Each of these factors was evaluated separately, and then the results were combined to give the overall threat from DCH. The maximum containment failure probability by DCH for Surry is 10{sup {minus}3} when considering four base DCH scenarios and using the two-cell equilibrium (TCE) model. However, higher contamination failure probabilities are estimated in sensitivity cases. When the depressurization and containment loads aspects are combined, the containment failure probability (conditional on station blackout sequence) is less than 19{sup {minus}2}. CONTAIN calculations were performed to provide insights regarding DCH phenomenological uncertainties and potential conservatisms in the TCE model. The CONTAIN calculations indicated that the TCE calculations were conservative for Surry and that the dominant factors were neglect of heat transfer to surroundings and complete combustion of hydrogen on DCH time scales.

A major obstacle to understanding of unsaturated fracture flow is the paucity of physical data on both fracture aperture structure and the effects of phase structure on permeability. An experimental procedure is developed for collecting detailed data on aperture and phase structure from a transparent analog fracture. Stable phase structures of varying complexity are creating within the horizontal analog fracture. Wetting phase permeability is measured under steady-state conditions. A process based model for wetting phase relative permeability is explored. Average distribution of the wetting phase is shown to provide insufficient information for modeling relative permeability; descriptive models must account for spatial structure of the phases.

Migration of hazardous contaminants within geologic settings depends on natural processes. Climatic fluctuations can affect the magnitudes and rates of many of these processes. In any long-term environmental evaluation of natural processes, responses to climatic change must be considered. Four generalized categories of natural responses to Quaternary climatic change are recognized for the Nevada Test Site (NTS) region of southwestern Nevada and adjacent California: (1) biologic, (2) geomorphic, (3) hydrologic (including surface and subsurface) and (4) pedologic/diagenetic. Specific examples that correspond to the four categories illustrate the broad range of complex natural processes the are affected by climatic change. These responses dictate the potential effects of climatic change on contaminant transport, effects that are being examined by existing and planned environmental-restoration and waste-management programs within the region. Regulatory requirements for many of these programs include long-term (>10,000-year) waste isolation because of radiologic components. The purpose here is not to be exhaustive in documenting all known natural responses to climatic change in the NTS region, but rather to give a flavor of the scope of interdisciplinary and interrelated fields of Quaternary science that must be considered in evaluating the possible effects of climatic change on long-term environmental programs.

The X Window System was originally developed in 1984 at Massachusetts Institute of Technology. It provides client-server computing functionality and also facilitates the establishment of a distributed computing environment. Since its inception the X Window System has undergone many enhancements. Despite these enhancements there will always be a functionality desired in the standard released version of X that is not supported or commercially or academically available. The developers of the X Window System have designed it in such a way that it is possible to add functionality that is not included in the standard release. This is called an extension. Extensions are one method used to develop a customized version of the X Window System to support a specialized application. This report presents the mechanics of adding an extension and examines a particular extension that was developed at Sandia National Laboratories to support data compression in X Windows which was one aspect of the Desktop Video and Collaborative Engineering Laboratory Directed Research and Development (LDRD).

This research investigates the relationship between execution discipline and performance. The hypothesis has two parts: 1. Different execution disciplines exhibit different performance for different computations, and 2. These differences can be effectively predicted by heuristics. A machine model is developed that can vary its execution discipline. That is, the model can execute a given program using either the control-driven, data-driven or demand-driven execution discipline. This model is referred to as a ``variable-execution-discipline`` machine. The instruction set for the model is the Program Dependence Web (PDW). The first part of the hypothesis will be tested by simulating the execution of the machine model on a suite of computations, based on the Livermore Fortran Kernel (LFK) Test (a.k.a. the Livermore Loops), using all three execution disciplines. Heuristics are developed to predict relative performance. These heuristics predict (a) the execution time under each discipline for one iteration of each loop and (b) the number of iterations taken by that loop; then the heuristics use those predictions to develop a prediction for the execution of the entire loop. Similar calculations are performed for branch statements. The second part of the hypothesis will be tested by comparing the results of the simulated execution with the predictions produced by the heuristics. If the hypothesis is supported, then the door is open for the development of machines that can vary execution discipline to increase performance.

This paper describes a collision avoidance system using Whole Arm Proximity (WHAP) sensors on an articulated robot arm. The capacitance-based sensors generate electric fields which completely encompass the robot arm and detect obstacles as they approach from any direction. The robot is moved through the workspace using a velocity command generated either by an operator through a force-sensing input device or a preprogrammed sequence of motions. The directional obstacle information gathered by the WHAP sensors is then used in a matrix column maximization algorithm that automatically selects the sensor closest to an obstacle during each robot controller cycle. The distance from this sensor to the obstacle is used to reduce the component of the command input velocity along the normal axis of the sensor, allowing graceful perturbation of the velocity command to prevent a collision. By scaling only the component of the velocity vector in the direction of the nearest obstacle, the control system restricts motion in the direction of an obstacle while permitting unconstrained motion in other directions. The actual robot joint positions and the WHAP sensor readings are communicated to an operator interface consisting of a graphical model of the Puma robot and its environment. Circles are placed on the graphical robot surface at positions corresponding to the locations of the WHAP sensor. As the individual sensors detect obstacles, the associated circles change color, providing the operator with visual feedback as to the location and relative size of the obstacle. At the same time, the graphical robot position is updated to reflect the actual state of the robot. This information, coupled with the selective constraints imposed by the WHAP control system, permit the operator to plan alternative paths around unmodeled, but sensed, obstacles.

This video cassette and its corresponding script describe efforts at Sandia Laboratories to develop surveillance equipment to include geophone sensors, point sensors, line sensors, and video surveillance cameras.

Four photovoltaic-powered lighting systems were installed in a National Forest Service campground in June of 1991. These systems have identical arrays, loads and charge controllers. The only difference was in the rated capacity of the battery bank for each system. The battery banks all use the same basic battery as a building block with four systems utilizing either one battery, two batteries, three batteries or four batteries. The purpose of the experiment is to examine the effect of the various battery sizes on the ability of the system to charge the battery, energy available to the load, and battery lifetime. Results show an important trend in system performance concerning the impact of charge controllers on the relation between array size and battery size which results in an inability to achieve the days of battery storage originally designed for.

During 1989-90, a refluxing liquid-metal pool-boiler solar receiver designed for dish/Stirling application at 75 kWt throughput was successfully demonstrated at Sandia National Laboratories. Significant features of this receiver included (1) boiling sodium as the heat transfer medium and (2) electric-discharge-machined (EDM) cavities as artificial nucleation sites to stabilize boiling. Following this first demonstration, a second-generation pool-boiler receiver that brings the concept closer to commercialization has been designed, constructed, and successfully tested. For long life, the new receiver is built from Haynes Alloy 230. For increased safety factors against film boiling and flooding, the absorber area and vapor-flow passages have been enlarged. To eliminate the need for trace heating, sodium has been replaced by the sodium-potassium alloy NaK-78. To reduce manufacturing costs, the receiver has a powdered-metal coating instead of EDM cavities for stabilization of boiling. To control incipient-boiling superheats, especially during hot restarts, it contains a small amount of xenon. In this paper, we present the receiver design and report the results of on-sun tests using a nominal 75 kWt test-bed concentrator to characterize boiling stability, hot-restart behavior, and thermal efficiency at temperatures up to 750°C. We also report briefly on late results from an advanced-concepts pool-boiler receiver.

The article presents the use of Monte Carlo simulations or incoherent scattering model to calculate profiles from precipitates embedded at different depths in thin specimens and then compared the simulations with experimental data measured from embedded particles. Incoherent scattering models is believed to be the best simulation for spatial resolution for x ray microanalysis in the AEM.

The development of UHF spark-switched L-C oscillators is described. L-C oscillators with center frequencies of 450 to 800 MHz were constructed. Q of the oscillators increased when a resonant antenna or antenna-reflector combination was added. Prototypes with simple fat-dipole antennas and small parabolic reflectors radiated normalized electric field strengths of 60 kV/m. The L-C oscillator, fat dipole, and small parabolic cylinder reflector were mounted in a way that will maximize the radiated power.

Codes and standards have served remarkably well in reducing both the frequency and consequences of pressure vessel and piping system failures. Past successful uses of safety standards show that safety can indeed be designed into potentially hazardous systems. Operational maintenance and inspection programs can also ensure and perpetuate design and manufactured reliability. However, as more advanced and challenging applications with high pressure systems and potentially hazardous operations are encountered we need to sharpen our technology, estimate reliability, quantify consequences, and manage risks with cost-effective process. Practical systems are constructed of several components, and design standards are not always available for every component. A variable level of safety is, therefore, admitted within a system and some assessment of the overall safety is desired. Additionally, when potential personnel safety consequences are large but isolated, secondary protective steps should be considered such as barricading, protective enclosures, or remote operation. This paper discusses rationale and activates that are based on probabilistic risk assessment (PRA) methods. While general application of PRA is not advocated at this time, certain derivative parts are suggested for use in closed-loop, risk management activities. Risk management process developments such as development of probabilistic data for threats to system safety and system response, component design requirements, system safety rules, distributed safety goals and technical derivations of numerical criteria are encouraged. Suggested activities are proposed as topics for future High Pressure Technology Development Activities.

Synthesis of hybrid organic-inorganic materials with ionic functionality within the polymer backbone has been achieved. A new family of hypervalent spiro anionic polysiliconates and polygermylates has been prepared. These materials were shown to be thermally stable to moderate temperatures and are completely air and moisture stable. Analysis by solution and solid state NMR verified the presence of the hypervalent functionality. We are currently examining the effect that alteration of the condensing reagent and/or the counterion may have on bulk properties of the ionomeric material.

Three concepts to measure incident flux (1) relative, real-time power measurement, (2) flux mapping and incident power measurement, and (3) real-time flux mapping) and two concepts to measure receiver surface temperatures low and high resolution temperature measurements) on an external central receiver are discussed along with the potential and shortcomings of these concepts to make the desired measurements and the uncertainties associated with the measurements caused by atmospheric and surface property variations. These concepts can aid in the operation and evaluation of the receiver and plant. Tests have shown that the incident flux distribution on a surface can be mapped out using a fixed, narrow white target and a CCD camera system by recording the images of the beam as it is passed over the target and by building a composite image. Tests with the infrared cameras have shown they are extremely valuable tools in determining temperature profiles during startup of the receiver and throughout operation. This paper describes each concept in detail along with the status of testing to determine the feasibility of these concepts.

The calculated valence charge density of the recently synthesized NaPd{sub 3}H{sub 2} compound is compared with that of palladium hydride, PdH, from which it can be derived.

Use of lead-indium solders in microelectronics packaging has increased over the last decade. Increased usage is due to improved properties, such as greater thermo-mechanical fatigue resistance, lower intermetallic formation rates with base metallizations, such as copper, and lower reflow temperatures. However, search of literature reveals no comprehensive studies on phase equilibrium relations between copper metal and lead-indium solder. Our effort involves a combination of experimental data acquisition and computer modeling to obtain the Cu-In-Pb ternary phase diagram. Isotherms and isopleths of interest at low temperatures are achieved by means of differential scanning calorimetry and electron probe microanalysis. Thermodynamic models of these sections served as a guide for efficient experimentation.

Nitrided gate oxides have been fabricated by furnace oxidation in N{sub 2}O with and without prior oxidation in O{sub 2}. SIMS nitrogen profiles show a sharp peak at the Si-insulator interface for both processes. Improved breakdown characteristics and reduced oxide damage after irradiation and charge injection are obtained.

The role of net positive oxide trapped charge and surface recombination velocity on excess base current in BJTs is identified. The effects of the two types of damage can be detected by plotting the excess base current versus base-emitter voltage. Differences and similarities between ionizing-radiation-induced and hot electron-induced degradation are discussed.

Short communication

The inertial confinement fusion (ICF) program at Sandia National Laboratories (SNL) is directed toward validating light ions as an efficient driver for ICF defense and energy applications. The light ion laboratory microfusion facility (LMF) is envisioned as a facility in which high gain ICF targets could be developed and utilized in defense-related experiments. The relevance of LMF technology to eventual inertial fusion energy (IFE) applications is assessed via a comparison of LMF technologies with those projected in the Light Ion Beam Reactor Assessment (LIBRA) conceptual reactor design study.

This paper summarizes the results of a study performed by the US and Germany to assess the technical and economic potential of central receiver power plants and to identify the necessary research and development (R&D) activities required to reach demonstration and commercialization. Second generation power plant designs, employing molten-salt and volumetric-air receivers, were assessed at the size of 30 and 100 MWe. The study developed a common guideline and used data from previous system tests and studies. The levelized-energy costs for the second generation plants were estimated and found to be competitive with costs from fossil-fueled power plants. Potential for further cost reductions exists if technical improvements can be introduced successfully in the long term. Additionally, the study presents results of plant reliability and uncertainty analyses. Mid- and long-term technical potentials are described, as well as recommendations for the R&D activities needed to reach the goal of large-scale commercialization. The results of this study have already helped direct research in the US and Europe. For example, the favorable potential for these technologies has led to the Solar Two molten-salt project in the US and the TSA volumetric receiver test in Spain. In addition, early analysis conducted within this study indicated that an advanced thermal storage medium was necessary to achieve favorable economics for the air plant. This led to the design of the thermal storage system currently being tested in Spain. In summary, each of the investigated receiver technologies has mid- and long-term potential for improving plant performance and reducing capital and energy costs (resulting in less than 10 cts/kWh given excellent insolation conditions) in an environmentally safe way and largely independent of fossil-fuel prices.

We have developed a novel molecular beam mass spectrometry technique that can quantitatively analyze the gas-phase composition in a CVD reactor. The technique simultaneously monitors a wide variety of radical and stable species, and their concentrations can be determined with sensitivities approaching 1 ppM. Measurements performed in a diamond deposition system have given us keen insights into the important phenomena that affect the growth environment. This paper first discusses the primary gas sampling design issues. In the second part, the details of the experimental results and their implications will be described.

Hydrotalcite coatings on aluminum alloys are being developed for corrosion protection of aluminum in aggressive saline environments. Coating bath composition, surface pretreatment, and alloying elements in aluminum all influence the performance of these coatings during salt spray testing. The coating bath, comprised of lithium carbonate, requires aging by dissolution of aluminum into the bath in order to grow corrosion resistant coatings. Coatings formed in non- aged baths do not perform well in salt spray testing. The alloying elements in aluminum alloys, especially copper, influence the coating growth and formation leading to thin coatings. The effect of the alloy elements is to limit the supply of aluminum to the coating/electrolyte interface and hinder growth of hydrotalcite upon aluminum alloys.