Publications

Grout, Ray G.; Chen, Jacqueline H.; Mascarenhas, Ajith A.; Yoo, Chunsang N.; Yu, Hongfeng Y.; Pebay, Philippe P.

Abstract not provided.

Proposed for publication in the Combustion and Flame Journal.

Frank, Jonathan H.; Yoo, Chunsang N.; Chen, Jacqueline H.

The catalytic effect of nitric oxide (NO) on the dynamics of extinction and re-ignition of a vortex-perturbed non-premixed hydrogen-air flame is studied in a counterflow burner. A diffusion flame is established with counterflowing streams of nitrogen-diluted hydrogen at ambient temperature and air heated to a range of temperatures that brackets the auto-ignition temperature. Localized extinction is induced by impulsively driving a fuel-side toroidal vortex into the steady flame, and the recovery of the extinguished region is monitored by planar laser-induced fluorescence (PLIF) of the hydroxyl radical (OH). The dynamics of flame recovery depend on the air temperature and fuel concentration, and four different recovery modes are identified. These modes involve combinations of edge-flame propagation and the expansion of an auto-ignition kernel that forms within the extinguished region. The addition of a small amount of NO significantly alters the re-ignition process by shifting the balance between chain-termination and chain-propagation reactions to enhance auto-ignition. The ignition enhancement by this catalytic effect causes a shift in the conditions that govern the recovery modes. In addition, the effects of NO concentration and vortex strength on the flame recovery are examined. Direct numerical simulations of the flame-vortex interaction with and without NO doping show how the small amount of OH produced by NO-catalyzed reactions has a significant impact on the development of an auto-ignition kernel. This joint experimental and numerical study provides detailed insight into the interaction between transient flows and ignition processes.

Proposed for publication in Combustion and Flame.

Yoo, Chunsang N.; Chen, Jacqueline H.; Frank, Jonathan H.

Combined experimental and numerical studies of the transient response of ignition to strained flows require a well-characterized ignition trigger. Laser deposition of a small radical pool provides a reliable method for initiating ignition of mixtures that are near the ignition limit. Two-dimensional direct numerical simulations are used to quantify the sensitivity of ignition kernel formation and subsequent edge-flame propagation to the oxidizer temperature and the initial width and amplitude of O-atom deposition used to trigger ignition in an axisymmetric counterflow of heated air versus ambient hydrogen/nitrogen. The ignition delay and super-equilibrium OH concentration in the nascent ignition kernel are highly sensitive to variations in these initial conditions. The ignition delay decreases as the amplitude of the initial O-atom deposition increases. The spatial distribution and the magnitude of the OH overshoot are governed by multi-dimensional effects. The degree of OH overshoot near the burner centerline increases as the diameter of the initial O-atom deposition region decreases. This result is attributed to preferential diffusion of hydrogen in the highly curved leading portion of the edge flame that is established following thermal runaway. The edge-flame speed and OH overshoot at the leading edge of the edge flame are relatively insensitive to variations in the initial conditions of the ignition. The steady edge-flame speed is approximately twice the corresponding laminar flame speed. The rate at which the edge flame approaches its steady state is insensitive to the initial conditions and depends solely on the diffusion time scale at the edge flame. The edge flame is curved toward the heated oxidizer stream as a result of differences in the chemical kinetics between the leading edge and the trailing diffusion flame. The structure of the highly diluted diffusion flame considered in this study corresponds to Linan's 'premixed flame regime' in which only the oxidizer leaks through the reaction zone such that the flame is located at fuel lean rather than stoichiometric mixture fraction conditions.

Journal of Fluid Mechanics

Chen, Jacqueline H.; Yoo, Chunsang N.

Abstract not provided.

Hoops, Alexandra A.; Chen, Jacqueline H.; Yoo, Chunsang N.

Abstract not provided.

Yoo, Chunsang N.; Chen, Jacqueline H.

Abstract not provided.