Publications

We have obtained dual-longitudinal-mode operation of a Q-switched Nd:YAG laser by simultaneous injection-seeding at two frequencies to produce pulses with modulation frequency discretely tunable from 185 MHz to greater than 17 GHz.

The Thermionic System Evaluation Test (TSET) is a ground test of an unfueled Russian TOPAZ-II in-core thermionic space reactor powered by electric heaters. The facility that will be used for testing of the TOPAZ-II systems is located at the New Mexico Engineering Research Institute (NMERI) complex in Albuquerque, NM. The reassembly of the Russian test equipment is the responsibility of International Scientific Products (ISP), a San Jose, CA, company and Inertek, a Russian corporation, with support provided by engineers and technicians from Phillips Laboratory (PL), Sandia National Laboratories (SNL), Los Alamos National Laboratory (LANL), and the University of New Mexico (UNM). This test is the first test to be performed under the New Mexico Strategic Alliance agreement. This alliance consist of the PL, SNL, LANL, and UNM. The testing is being funded by the Strategic Defense Initiative Organization (SDIO) with the PL responsible for project execution.

A revised nomenclature for defects in MOS devices is described which clearly distinguishes the language used to describe the physical location of defects from that used to describe their electrical response. ''Oxide traps'' are simply defects in the SiO{sub 2} layer, and ''interface traps'' are defects at the Si/SiO{sub 2} interface; nothing is presumed about how either communicates with the underlying Si. ''Fixed states'' are defined electrically as trap levels that do not communicate with the Si on the time scale, but ''switching states'' can exchange charge with the Si. Fixed states presumably are oxide traps, but switching states can either be interface traps or near-interfacial oxide traps that can communicate with the Si, i.e. ''border traps.'' Thus the term ''traps'' is reserved for defect location, and the term ''states'' for electrical response. This defect picture is used to provide new insight into the response of MOS capacitors with 45-nm radiation-hardened oxides to electrical stress and annealing; capacitance-voltage and thermally-stimulated-current measurements are used. 2 figs, 14 refs. (DLC)

Radioactive material transport casks use either lead or depleted uranium (DU) as gamma-ray shielding material. Stainless steel is conventionally used for structural containment. If a DU alloy had sufficient properties to guarantee resistance to failure during both nominal use and accident conditions to serve the dual-role of shielding and containment, the use of other structure materials (i.e., stainless steel) could be reduced. (It is recognized that lead can play no structural role.) Significant reductions in cask weight and dimensions could then be achieved perhaps allowing an increase in payload. The mechanical response of depleted uranium has previously not been included in calculations intended to show that DU-shielded transport casks will maintain their containment function during all conditions. This paper describesa two-part study of depleted uranium alloys: First, the mechanical behavior of DU alloys was determined in order to extend the limited set of mechanical properties reported in the literature. The mechanical properties measured include the tensile behavior the impact energy. Fracture toughness testing was also performed to determine the sensitivity of DU alloys to brittle fracture. Fracture toughness is the inherent material property which quantifies the fracmm resistance of a material. Tensile strength and ductility are significant in terms of other failure modes, however, as win be discussed. These mechanical properties were then input into finite element calculations of cask response to loading conditions to quantify the potential for claiming structural credit for DU. (The term structural credit'' describes whether a material has adequate properties to allow it to assume a positive role in withstanding structural loadings.)

The solution of ER/WM problems will rely on the use of expert judgments. These judgments should be able to withstand the same rigorous scrutiny as the decisions made to solve these problems. Therefore, those judgments that are likely to have a significant impact on the solution of ER/WM problems should be elicited and used in a formal manner. In this paper, we discuss the key areas of environmental management where expert judgments are expected to be crucial, as well as the process to formalize them. This process is a generic one and should only be construed as a roadmap; specific aspects of the process need to be tailored to address the problem at hand. By employing this process, the quality of the judgments is enhanced, and therefore, the likelihood that the solution of ER/WM problems will be a sound and defensible one is considerably increased.

Several different techniques are used to electrically characterize defects at or near the Si/SiO{sub 2} interface. Three common methods are the charge-pumping, midgap, and dual-transistor techniques. Each of these techniques offer advantages and disadvantages compared to the others. For instance, charge-pumping measurements are not significantly affected by charge lateral non-uniformities and can provide high-sensitivity measurements of the average density of interface traps. However, charge-pumping measurements cannot provide accurate measurements of the number of charged oxide traps. In contrast both the dual-tranistor and midgap techniques can provide good estimates for threshold-voltage shifts due to oxide traps and interface traps, but these estimates can break down when significant charge lateral non-uniformities are present in the oxide. Considering the widespread use of these, techniques, it is of practical and theoretical importance to quantitatively compare them. At the SISC, we will present a detailed comparison of the charge-pumping, midgap, and dual-tranistor techniques. Values for the density of interface traps measured using the three techniques will be compared for n- and P-channel transistors fabricated using several different process technologies, and under different process technologies, and under different irradiation and anneal conditions. Discrepancies between the different techniques are observed. Causes for the discrepancies will be explored at the SISC.

Environmental management involves making decisions that will lead to the solution of environmental restoration and waste management (ER/WM) problems. Not only are ER/WM problems technologically challenging, but they must be dealt with under politically and emotionally charged conditions. Furthermore, these decisions must be made based on less than certain information. Therefore, environmental managers must consider the sources of uncertainty that will impact the results of the decision-making process, treat them in an explicit manner, and assess their impact on the decision. Consequently, the process must be a defensible, objective, and transparent one; otherwise the foundation for solving ER/WM problems will not be sufficiently solid to survive the criticisms that such solutions are likely to be subjected to. The use of risk assessment and decision analysis tools helps the environmental manager achieve this goal. It is also important that these decisions consider the array of risk-related issues associated with ER/WM problems, which include the risk to the health and safety of the public as well as other risks such as economic risk. The solution of ER/WM problems must obtain and maintain a proper balance between all these issues. It is also crucial that the multiple stakeholders having an interest in the solution of ER/WM problems be involved in the decision-making process.

We discuss the use of light scattered from a latent image to control photoresist exposure dose and focus conditions which results in improved control of the critical dimension (CD) of the developed photoresist. A laser at a non-exposing wavelength is used to illuminate a latent image grating. The light diffracted from the grating is directly related to the exposure dose and focus and thus to the resultant CD in the developed resist. Modeling has been done using rigorous coupled wave analysis to predict the diffraction from a latent image as a function of the substrate optical properties and the photoactive compound (PAC) concentration distribution inside the photoresist. It is possible to use the model to solve the inverse problem: given the diffraction, to predict the parameters of the latent image and hence the developed pattern. This latent image monitor can be implemented in a stepper to monitor exposure in situ, or prior to development to predict the developed CD of a wafer for early detection of bad devices. Experimentation has been conducted using various photoresists and substrates with excellent agreement between theoretical and experimental results. The technique has been used to characterize a test pattern with a focused spot as small as 36{mu}m in diameter. Using diffracted light from a simulated closed-loop control of exposure dose, CD control was improved by as much as 4 times for substrates with variations in underlying film thickness, compared to using fixed exposure time. The latent image monitor has also been applied to wafers with rough metal substrates and focus optimization.

A brief overview of selected programs at Sandia is presented. This issue contains high-lights on the following: Reducing risk in nuclear reactors; energy and environment news in brief; eliminating bottlenecks in plastics recycling; new technologies remedy old waste problems; new technologies remedy old waste problems; safe disposal of military components; and heat pipes for stirling engine testing.

Sandia National Laboratories has, for several years, been engaged in the performance of both fire safety and electrical equipment qualification research under independent programs sponsored by the US Nuclear Regulatory Commission. Recent comparisons between electrical cable thermal damageability data gathered independently in these two efforts indicate that a direct correlation exists between certain of the recent cable thermal vulnerability information gathered under equipment qualification conditions and thermal damageability in a fire environment. This direct correlation allows for a significant expansion of the data base on estimated cable thermal vulnerability limits in a fire environment because of the wide range of cable types and products that have been evaluated as a part of the equipment qualification research. This paper provides a discussion of the basis for the derived correlation, and presents estimated cable thermal damage limits for a wide range of generic cable types and specific cable products. The supposition that a direct correlation exists is supported through direct comparisons of the test results for certain specific cable products. The proposed supplemental cable fire vulnerability data gained from examination of the equipment qualification results is presented. These results should be of particular interest to those engaged in the evaluation of fire risk for industrial facilities, including nuclear power plants.

C++ is rapidly gaining in popularity as a scientific programming language. The data encapsulation inherent in the class concept and the availability of operator overloading for compact representation of operations make it an ideal language for translating concepts in mathematical physics into computer code. Furthermore, its strong type checking and memory management features facilitate correct coding of algorithms. Unfortunately, C++ code which is written in the true spirit of the language is often very inefficient under current compiler implementations. Many of the inefficiency issues, such as unnecessary copy operations or proliferation of temporaries, have been well-characterized. Some may be alleviated by clever C++ coding, but others cannot be alleviated except by writing C-like code that sacrifices one or more of the best features of the language. This document describes a major source of efficiency problems in expressions using overloaded operators on array classes, and proposes certain minor modifications to the C++ language standard which will facilitate optimization of these expressions.

Sandia and Mound are developing a workcell that will automate the assembly of explosive components. Sandia is responsible for the automated powder dispenser subsystem. Automated dispensing of explosive powders in the past resulted in separation or segregation of powder constituents. The Automated Dry Powder Dispenser designed by Sandia achieves weight tolerances of {plus minus}0.1 mg while keeping powderoxidizer separation to a minimum. A software control algorithm compensates fore changes in powder flow due to lot variations, temperature, humidity, and the amount of powder left in the system.

Interfacial microchemical characterization is required in all aspects of surface processing as applied to transportation and utility technologies. Corrosion protection, fuel cells and batteries, wear surfaces, polymers and polymer-oxide interfaces, thin film multilayers, photoelectrochemical systems, and organized molecular assemblies are just a few examples of interfacial systems of interest to these industries. A number of materials and processing problems, both related to fundamental understanding and to monitoring manufacturing operations, have been identified where our microchemical characterization abilities need improving. Over twenty areas for research are identified where progress will contribute to improved understanding of materials and processes, improved problem-solving abilities, improved manufacturing consistency, and lower costs. Some of the highest priority areas for research include (1) developing techniques and methods with improved chemical specificity at interfaces, (2) developing fast, real-time surface and interface probes and (3) improving the cost and reliability of manufacturing monitors. Increased collaboration among University, Industry, and Government laboratories will be a prerequisite to making the required progress in a timely fashion.

This paper describes the application of linear control design techniques to the problem of nuclear reactor control. The control algorithm consists of generating a nominal trajectory within the control authority of the reactor rod drives, and then following this trajectory with a gain scheduled linear quadratic regulator (LQR). A controller based on this algorithm has generated power pulses up to 100 MW on Sandia's Annular Core Research Reactor (ACRR). Prompt critical control at $1.02 net reactivity and controlled start up rates over 350 DPM have also been demonstrated using tills controller.

There is a discrepancy between literature estimates of trapped-hole energies in irradiated SiO{sub 2} obtained via thermal and optical methods (0.6-1.4 eV and 3 eV, respectively). A method has been developed for obtaining an improved estimate of the energy distribution of trapped holes in irradiated SiO{sub 2}, which brings thermal and optical estimates into much closer agreement. Experimental and theoretical TSC (thermally stimulated current) spectra are shown for a soft MOS capacitor with a 350-nm oxide cycled through 4 irradiations (10 keV x rays) and TSC measurements. Four trap-energy distributions were also independently derived from TSC at different ramp rates for a 45-nm radiation-hardened oxide. The trap distributions inferred from TSC for the 45-nm hard oxide agree with each other and with that inferred for the soft 350-nm oxide. 2 figs, 8 refs. (DLC)

International Atomic Energy Agency (IAEA) inspectors must maintain continuity of knowledge on all safeguard samples, and in particular on those samples drawn from plutonium product and spent fuel input tanks at a nuclear reprocessing plant's blister sampling station. Integrity of safeguard samples must be guaranteed from the sampling point to the moment of sample analysis at the IAEA's Safeguards Analytical Laboratory (SAL Seibersdorf) or at an accepted local laboratory. These safeguard samples are drawn at a blister sampling station with inspector participation, and then transferred via a pneumatic post system to the facility's analytical laboratory. The transfer of the sample by the pneumatic post system, the arrival of the sample in the operator's analytical laboratory, and the storage of the sample awaiting analysis is very time consuming for the inspector, particularly if continuous human surveillance is required for all these activities. This process might be observed by ordinary surveillance methods, such as a video monitoring system, but again this would be cumbersome and time consuming for both the inspector and operator. This paper will describe a secure container designed to assure sample vial integrity from the point the sample is drawn to the treatment of the sample at the facility's analytical laboratory.

The use of fine-particle size (<40 nm) unsupported catalysts in the solubilization step of direct coal liquefaction may result in improved economics for direct coal liquefaction due to the possible enhanced yields of desired products, the potential for decreasing reaction severity, and the possibility of using less supported catalyst during liquefaction processing. To guide the research and development efforts for these new unsupported catalysts, it is necessary to evaluate the catalyst performance under standard test conditions so that the impacts of catalyst formulations from different laboratories can be compared. The objectives of this work are to develop standard coal liquefaction test procedures and to perform the testing of the novel fine-particle size liquefaction catalysts being developed in the DOE/PETC AR Coal Liquefaction program. As part of this effort, we have developed a factorial experimental design to enable evaluation of the catalysts over ranges of temperature, time, and catalyst loading. The standard test procedure uses DECS-17 Blind Canyon Coal and 9,10-dihydrophenanthrene (DHP) as the hydrogen donor. Product analyses include tetrahydrofuran (THF) conversion, heptane conversion, DHP recovery, and gas analyses. THF and heptane insoluble materials are analyzed for carbon, hydrogen, nitrogen and sulfur contents. Testing is performed in batch microautoclave reactors. The experimental design and test procedures are being evaluated using {minus}100 mesh pyrite as a catalyst.

Understanding the mechanisms of growth during vapor-phase deposition is critical for the precise control of surface morphology required by advanced electronic device structures. Yet only relatively recently have the tools for observing this growth on an atomic-level scale become available (via scanning tunneling microscopy (STM), reflection high energy electron diffraction (RHEED) and low-energy electron microscopy (LEEM)). We present results from our own RHEED and STM measurements in which we use computer simulations to aid in determining the fundamental surface processes which contribute to.the observed structures. In this study of low-energy ion bombardment and growth on Si(001), it is demonstrated how simulations enable us to determine the dominant atomistic process.

This report highlights the following topics: Photon Correlation Spectroscopy--a new application in jet fuel analysis, Testing news in brief; Solar test facility supports space station research; Shock isolation technique developed for piezoresistive accelerometer; High-speed photography captures Distant Image measurements; and, Radiation effects test revised for CMOS electronics.

Reflective Particle Tags were developed for uniquely identifying individual strategic weapons that would be counted in order to verify arms control treaties. These tags were designed to be secure from copying and transfer even after being lift under the control of a very determined adversary for a number of years. This paper discusses how this technology can be applied in other applications requiring confidence that a piece of equipment, such as a seal or a component of a secure, has not been replaced with a similar item. The hardware and software needed to implement this technology is discussed, and guidelines for the sign of systems that rely on these or similar randomly formed features for security applications are presented. Substitution of identical components is one of the easiest ways to defeat security seals, secure containers, verification instrumentation, and similar equipment. This technology, when properly applied, provides a method to counter this defeat scenario. This paper presents a method for uniquely identifying critical security related equipment. Guidelines for implementing identification systems based on reflective particles or similar random features without compromising their intrinsic security are discussed.

In 1991, Sandia National Laboratories acquired a Network Storage Service (NSS) as a result of a fully competitive procurement. The Network Storage Service, which provides access to over a terabyte of data storage in a two-tiered hierarchy, had minimal software security features. Before the NSS could be placed into production, it had to be accredited by the Department of Energy, Sandia's accrediting authority. Sandia was faced with implementing security features to allow the NSS to be operated in its secure computing network, which is a single security clearance, multiple data security level environment. This paper describes the software security design alternatives that were considered and what was ultimately implemented.

The time dependence of radiation-induced interface-trap charge buildup for MOS transistors of varying gate-oxide thickness was investigated in order to clarify how the location of hydrogen in the SiO{sub 2} contributes to N{sub it} buildup. Radiation-induced interface-trap buildup in wet and dry gate oxides is compared for irradiations and anneals at constant positive bias and for negative-bias irradiations followed by positive-bias anneals. Implications of these results for different models of interface-trap buildup are discussed. 2 figs, 9 refs. (DLC)

A non-contact, high-resolution laser ranging device has been incorporated into an instrument for accurately mapping the surface of WECS airfoils in the field. Preliminary scans of composite materials and bug debris show that the system has adequate resolution to accurately map bug debris and other surface contamination. This system, just recently delivered and now being debugged and optimized, will be used to characterize blade surface contamination on wind turbines. The technology used in this system appears to hold promise for application to many other measurements tasks, including a system for quickly and very accurately determining the profile of turbine blade molds and blades.

Short communication.

Sandia National Laboratories has completed the design and is now fabricating packages for shipment of tritium gas in conformance with 10 CFR 71. The package, referred to as the AL-SX, is quite unique in that its contents are a radioactive gas, and a large margin of safety has been demonstrated through overtesting. The AL-SX is small, 42 cm in diameter and 55 cm tall, and weighs between 55 kg empty and up to a maximum of 60 kg with contents and is designed for a 20-year service life. This paper describes the design of the AL-SX and certification testing performed on AL-SX packages and discusses containment of tritium and AL-SX manufacturing considerations.