Publications

Optical spectroscopic techniques were evaluated as nondestructive monitors of the aging of parachutes in nuclear weapons. We analyzed thermally aged samples of nylon and Kevlar webbing by photoluminescence spectroscopy and reflection spectroscopy. Infrared analysis was also performed to help understand the degradation mechanisms of the polymer materials in the webbing. The photoluminescence and reflection spectra were analyzed by chemometric data treatment techniques to see if aged-induced changes in the spectra correlated to changes in measured tensile strength. A correlation was found between the shapes of the photoluminescent bands and the measured tensile strengths. Photoluminescent spectra can be used to predict the tensile strengths of nylon and Kevlar webbing with sufficient accuracy to categorize the webbing sample as above rated tensile strength, marginal or below rated tensile strength. The instrumentation required to perform the optical spectroscopic measurement can be made rugged, compact and portable. Thus, optical spectroscopic techniques offer a means for nondestructive field monitoring of parachutes in the enduring stockpile/

Amorphous carbon is an elemental form of carbon with low hydrogen content, which may be deposited in thin films by the impact of high energy carbon atoms or ions. It is structurally distinct from the more well-known elemental forms of carbon, diamond and graphite. It is distinct in physical and chemical properties from the material known as diamond-like carbon, a form which is also amorphous but which has a higher hydrogen content, typically near 40 atomic percent. Amorphous carbon also has distinctive Raman spectra, whose patterns depend, through resonance enhancement effects, not only on deposition conditions but also on the wavelength selected for Raman excitation. This paper provides an overview of the Raman spectroscopy of amorphous carbon and describes how Raman spectral patterns correlate to film deposition conditions, physical properties and molecular level structure.

Samples of chemically-vapor-deposited micrometer and sub-micrometer-thick films of polysilicon were analyzed by transmission electron microscopy (TEM) in cross-section and by Raman spectroscopy with illumination at their surface. TEM and Raman spectroscopy both find varying amounts of polycrystalline and amorphous silicon in the wafers. Raman spectra obtained using blue, green and red excitation wavelengths to vary the Raman sampling depth are compared with TEM cross-sections of these films. Films showing crystalline columnar structures in their TEM micrographs have Raman spectra with a band near 497 cm{sup {minus}1} in addition to the dominant polycrystalline silicon band (521 cm{sup {minus}1}). The TEM micrographs of these films have numerous faulted regions and fringes indicative of nanometer-scale silicon structures, which are believed to correspond to the 497cm{sup {minus}1} Raman band.

There is considerable interest in the use of chemically vapor deposited (CVD) polycrystalline diamond films in advanced materials technology. However, most of the potential applications of CVD diamond films require well-controlled properties which depend on the film structure, and in turn, on the conditions under which the films are synthesized. The structure of the vapor-deposited diamond films is frequently characterized by Raman spectroscopy. Despite extensive research, much work still needs to be completed to understand the various features of the Raman spectra and to understand how the processing variables affect the spectral features. This paper examines the Raman spectra of diamond films prepared by a hot-filament-assisted CVD process as a function of substrate processing and deposition parameters.

We have obtained Raman spectra of icosahedral boron-rich solids. The spectra of α-rhombohedral boron, boron arsenide, and boron phosphide are consistent with highly-ordered materials. Polarization studies have resulted in symmetry assignments for most of the Raman bands of α-rhombohedral boron. In contrast, the Raman spectra of the boron carbides reveal local substitutional disorder. They also change progressively as a function of carbon content. A structural model for the boron carbides has been developed to explain the Raman and infrared absorption spectra, x-ray data, and electrical and thermal transport properties. Raman spectra of boron carbide samples enriched in ¹⁰B, ¹¹B, and ¹³C reveal details of the atomic motions. The vibrational frequencies and exceptionally narrow linewidths of certain Raman modes are discussed in terms of a ‘‘strong’’ bond model. In this model certain vibrational modes involving relatively stiff bonds between chain atoms, chain and icosahedral atoms, and atoms on different icosahedra are decoupled from the boride lattice by weak, intraicosahedral bonds.